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    • 5. 发明授权
    • Methods of lithographically patterning a substrate
    • 平版印刷基板的方法
    • US08309297B2
    • 2012-11-13
    • US11868328
    • 2007-10-05
    • Yoshiki HishiroScott SillsHiroyuki MoriTroy GugelPaul D. ShirleyLijing GouAdam Olson
    • Yoshiki HishiroScott SillsHiroyuki MoriTroy GugelPaul D. ShirleyLijing GouAdam Olson
    • G03F7/22
    • G03F7/2022G03F7/203
    • A method of lithographically patterning a substrate that has photoresist having removal areas and non-removal areas includes first exposing at least the non-removal areas to radiation effective to increase outer surface roughness of the photoresist in the non-removal areas at least post-develop but ineffective to change photoresist solubility in a developer for the photoresist to be cleared from the non-removal areas upon develop with the developer. Second exposing of radiation to the removal areas is conducted to be effective to change photoresist solubility in the developer for the photoresist to be cleared from the removal areas upon develop with the developer. The photoresist is developed with the developer effective to clear photoresist from the removal areas and to leave photoresist in the non-removal areas that has outer surface roughness in the non-removal areas which is greater than that before the first exposing. Other implementations and embodiments are contemplated.
    • 光刻图案化具有去除区域和非去除区域的光致抗蚀剂的基板的方法包括首先将至少不去除区域暴露于有效地增加非去除区域中的光致抗蚀剂的外表面粗糙度至少后显影 但是在用显影剂显影时,光致抗蚀剂的显影剂中的光致抗蚀剂溶解度无法改变,以从非去除区域中清除。 进行辐射到去除区域的第二次曝光是有效的,以改变光致抗蚀剂在显影剂中的溶解度,以使光致抗蚀剂在用显影剂显影时从除去区域中清除。 用显影剂显影光致抗蚀剂有效地从去除区域清除光致抗蚀剂,并且在非去除区域中留下光致抗蚀剂,其在非去除区域中的外表面粗糙度大于第一次曝光之前的表面粗糙度。 预期其他实现和实施例。
    • 6. 发明授权
    • Resist pattern and reflow technology
    • 抗蚀图案和回流技术
    • US07846623B2
    • 2010-12-07
    • US12081098
    • 2008-04-10
    • Yoshiki Hishiro
    • Yoshiki Hishiro
    • B32B5/14
    • H01L21/0271G03F7/40H01L21/312Y10T428/24802
    • A reflow stabilizing solution for treating photoresist patterns and a reflow technology are disclosed. The reflow stabilizing solution comprises a polymer and is applied after the photoresist material has been developed and patterned. By treating the photoresist with the reflow stabilizing solution after resist patterning and further subjecting the reflow stabilizing solution to a heat treatment, the non-volatile polymer remains in between adjacent resist patterns and acts as a stopper to the reflowed photoresist. In this manner, the non-volatile polymer provides structural and mechanical support for the reflowed resist, preventing resist collapse at high temperatures and allowing the formation of reflowed resist structures having line width dimensions in the submicron range.
    • 公开了一种用于处理光刻胶图案的回流稳定溶液和回流技术。 回流稳定溶液包含聚合物,并且在光致抗蚀剂材料已经显影和图案化之后被施加。 通过在抗蚀剂图案化之后用回流稳定溶液处理光致抗蚀剂,并进一步对回流稳定溶液进行热处理,非挥发性聚合物保留在相邻抗蚀剂图案之间,并作为回流光致抗蚀剂的阻挡剂。 以这种方式,非挥发性聚合物为回流的抗蚀剂提供结构和机械支撑,防止高温下的抗塌陷,并允许形成具有亚微米范围的线宽度尺寸的回流抗蚀剂结构。
    • 7. 发明授权
    • Methods of eliminating pattern collapse on photoresist patterns
    • 消除光刻胶图案上的图案崩溃的方法
    • US07687406B2
    • 2010-03-30
    • US11487403
    • 2006-07-17
    • Jon DaleyYoshiki Hishiro
    • Jon DaleyYoshiki Hishiro
    • H01L21/302H01L21/461
    • H01L21/0335G03F7/40
    • A stabilizing solution for treating photoresist patterns and methods of preventing profile abnormalities, toppling and resist footing are disclosed. The stabilizing solution comprises a non-volatile component, such as non-volatile particles or polymers, which is applied after the photoresist material has been developed. By treating the photoresist with the solution containing a non-volatile component after developing but before drying, the non-volatile component fills the space between adjacent resist patterns and remains on the substrate during drying. The non-volatile component provides structural and mechanical support for the resist to prevent deformation or collapse by liquid surface tension forces.
    • 公开了一种用于处理光致抗蚀剂图案的稳定溶液以及防止轮廓异常,倾倒和抵抗基脚的方法。 稳定溶液包含非挥发性组分,例如在光致抗蚀剂材料已经显影之后施加的非挥发性颗粒或聚合物。 通过在显影之后但干燥之前用含有非挥发性成分的溶液处理光致抗蚀剂,非挥发性组分填充相邻抗蚀剂图案之间的空间,并在干燥期间保留在基材上。 非挥发性组分为抗蚀剂提供结构和机械支撑,以防止液体表面张力产生变形或塌陷。