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1. 发明授权

US4683279A Low melting urethane linked toluenediisocyanates 失效
标题翻译：低熔点氨基甲酸酯连接甲苯二异氰酸酯
公开(公告)号：US4683279A
公开(公告)日：1987-07-28
申请号：US882994
申请日：1986-07-08
申请人： Barton Milligan , William E. Starner , Roland E. Grandin , Jeremiah P. Casey
发明人： Barton Milligan , William E. Starner , Roland E. Grandin , Jeremiah P. Casey
IPC分类号： C08G18/76 , C07C67/00 , C07C239/00 , C07C271/28 , C08G18/80 , C08G18/81
CPC分类号： C08G18/8019 , C08G18/815 , C08G2120/00
摘要： This invention relates to urethane linked mixtures of 2,4- and 2,6-toluenediisocyanates (ULTDI dimers) having low melting points and to a method of forming these systems. The urethane linked toluenediisocyanates containing from 45-90% of the 2,4- and 10-55% of the 2,6- isomer by weight are formed by reacting two moles of an appropriate isomer mix of toluenediisocyanate, with one mole of a specific alkylene glycol, e.g., 1,2-butanediol, diethylene glycol or dipropylene glycol under conditions such that essentially only one of the isocyanate groups on a toluenediisocyanate molecule reacts with a hydroxyl group of the glycol. Conditions are controlled such that the urethane linked toluenediisocyanates are formed. The resulting product, which has two unreacted isocyanate groups, is suited for producing a variety of elastomers including polyurethane polyurethane/urea or polyurea elastomers.
摘要翻译：本发明涉及具有低熔点的2,4-和2,6-甲苯二异氰酸酯（ULTDI二聚体）与形成这些体系的方法的氨基甲酸酯连接的混合物。含有45-90％的2,4-和10-55％的2,6-异构体的氨基甲酸酯连接的甲苯二异氰酸酯是通过使两摩尔的甲苯二异氰酸酯的合适异构体混合物与1摩尔特定的亚烷基二醇，例如1,2-丁二醇，二甘醇或二丙二醇，在甲苯二异氰酸酯分子上基本上只有一个异氰酸酯基与二醇的羟基反应的条件下进行。控制条件使得形成氨基甲酸酯连接的甲苯二异氰酸酯。得到的具有两个未反应的异氰酸酯基的产物适用于生产各种弹性体，包括聚氨酯聚氨酯/脲或聚脲弹性体。

2. 发明授权

US4724256A Urethane linked hydroxy aromatic isocyanates 失效
标题翻译：氨基甲酸酯连接羟基芳族异氰酸酯
公开(公告)号：US4724256A
公开(公告)日：1988-02-09
申请号：US2840
申请日：1987-01-13
申请人： William E. Starner , Barton Milligan , Roland E. Grandin
发明人： William E. Starner , Barton Milligan , Roland E. Grandin
IPC分类号： C07C67/00 , C07C239/00 , C07C271/28 , C08G18/32 , C08G18/48 , C08G18/76 , C08G18/30
CPC分类号： C08G18/4825 , C08G18/3206 , C08G18/7614
摘要： This invention relates to urethane linked hydroxy aromatic isocyanates and to a process for producing such urethane linked hydroxy aromatic isocyanates. The compositions are formed by reacting one equivalent aromatic diisocyanate with one equivalent of an alkylene polyol under conditions such that only one of the isocyanate groups react with the hydroxyl group of the polyol. Conditions are controlled such that the urethane linked hydroxy aromatic isocyanates are formed. The resulting product is suited for producing a variety of elastomers including a one component polyurethane elastomer.

3. 发明授权

US4786703A Process for the preparation of polyisocyanate prepolymers and polyurethanes having high temperature performance and low hysteresis 失效
标题翻译：具有高温性能和低滞后性的多异氰酸酯预聚物和聚氨酯的制备方法
公开(公告)号：US4786703A
公开(公告)日：1988-11-22
申请号：US38810
申请日：1987-04-15
申请人： William E. Starner , Jeremiah P. Casey , Barton Milligan , Susan M. Clift
发明人： William E. Starner , Jeremiah P. Casey , Barton Milligan , Susan M. Clift
IPC分类号： C08G18/10 , C08G18/65 , C08G18/76 , C08G18/30
CPC分类号： C08G18/7621 , C08G18/10
摘要： This invention relates to a polyisocyanate prepolymer for polyurethane/urea elastomer synthesis and to the resulting elastomer. The prepolymer is formed by reacting toluenediisocyanate with a long chain polyol under conditions such that essentially a 2:1 adduct is formed. Excess toluenediisocyanate is removed prior to forming the elastomer.

4. 发明授权

US4722989A Process for producing polyurethane/urea elastomers 失效
标题翻译：生产聚氨酯/尿素弹性体的方法
公开(公告)号：US4722989A
公开(公告)日：1988-02-02
申请号：US025911
申请日：1987-03-16
申请人： William E. Starner , Barton Milligan , Jeremiah P. Casey
发明人： William E. Starner , Barton Milligan , Jeremiah P. Casey
IPC分类号： C08G18/10 , C08G18/32 , C08G18/48 , C08G18/80 , C08G18/81 , C08G81/00
CPC分类号： C08G18/8019 , C08G18/815 , C08G2120/00
摘要： This invention relates to a solvent-free process for producing polyurethane/urea elastomers wherein an aromatic diisocyanate is reacted with a compound having active Zerewitinoff hydrogen atoms and an aromatic diamine chain extender. The improvement for producing urethanes having a wide range of properties comprises including a urethane-linked diisocyanate in the polyurethane urea elastomer. The urethane-linked diisocyanate is one that is formed by reacting toluenediisocyanate or substituent thereof with a short chain diol under conditions such that the urethane linked diisocyanate comprises two equivalents isocyanate per equivalent diol.

5. 发明授权

US4501922A Aromatic amines from alkali metal amide aminating agent and aromatic 失效
标题翻译：芳香胺由碱金属酰胺胺化剂和芳香族
公开(公告)号：US4501922A
公开(公告)日：1985-02-26
申请号：US509259
申请日：1983-06-29
申请人： Roland E. Grandin , Barton Milligan
发明人： Roland E. Grandin , Barton Milligan
IPC分类号： C07C209/02 , C07D213/73 , C07C85/00
CPC分类号： C07D213/73 , C07C209/02
摘要： This invention pertains to a process for preparing mononuclear aromatic amines by reacting an alkali metal amide with a mononuclear aromatic compound, e.g., benzene and toluene. The reaction is carried out in the presence of a metallic hydrogenation catalyst, suitably copper, nickel, rhodium or cobalt, the metal being present in an amount sufficient for catalyzing the reaction. The amine then is formed by adding a protonating agent to the resulting reaction product formed by the reaction of the alkali metal amide with the aromatic compound. The addition of the protonating agent liberates the amine.
摘要翻译：本发明涉及通过使碱金属氨化物与单核芳族化合物如苯和甲苯反应制备单核芳族胺的方法。该反应在金属氢化催化剂，适当的铜，镍，铑或钴的存在下进行，金属的存在量足以催化反应。然后通过将碱性金属胺与芳族化合物的反应形成的所得反应产物中加入质子化剂形成胺。加入质子化剂释放胺。

6. 发明授权

US4329501A Synthesis of alkyl amino benzenes from alkyl diamino benzenes 失效
标题翻译：从烷基二氨基苯合成烷基氨基苯
公开(公告)号：US4329501A
公开(公告)日：1982-05-11
申请号：US195565
申请日：1980-10-09
申请人： Barton Milligan , Roland E. Grandin
发明人： Barton Milligan , Roland E. Grandin
IPC分类号： C07C85/00 , C07C85/20
CPC分类号： C07C209/68
摘要： The conversion of alkyl diaminobenzenes to the alkyl amino benzenes is carried out by contacting the alkyl diamino benzene with hydrogen in the presence of a nonsupported cobalt catalyst. Optionally, the reaction is carried out in the presence of water so that the water insoluble product formed can be separated from the water soluble reactants and by-products.
摘要翻译：烷基二氨基苯转化为烷基氨基苯是通过在非负载的钴催化剂存在下使烷基二氨基苯与氢接触进行的。任选地，反应在水的存在下进行，使得形成的水不溶性产物可以与水溶性反应物和副产物分离。

7. 发明授权

US4810769A Process of preparing polyurethanes cured with 2,6-idaminobenzoic acid derivatives and blends of the 2, 4 and 2,6 isomers 失效
标题翻译：制备用2,6-二氨基苯甲酸衍生物固化的聚氨酯和2,4和2,6异构体的共混物的方法
公开(公告)号：US4810769A
公开(公告)日：1989-03-07
申请号：US58439
申请日：1987-06-05
申请人： Jeremiah P. Casey , Susan M. Clift , Barton Milligan
发明人： Jeremiah P. Casey , Susan M. Clift , Barton Milligan
IPC分类号： C08G18/66 , C08G18/10 , C08G18/65 , C08G18/14 , C08G18/32
CPC分类号： C08G18/10
摘要： The present invention relates to polyurethanes and a method for making polyurethanes by reacting an organic diisocyanate, a glycol having a molecular weight of 500-5000 and a derivative of 2,6-diaminobenzoic acid or a blend comprising derivatives of 2,4-diaminobenzoic acid and 2,6-diaminobenzoic acid. The addition of the 2,6-diaminobenzoic acid derivative to the composition improves polyurethane processability and performance by decreasing chain extender reactivity and increasing hard segment regularity.

8. 发明授权

US4816543A Polyurethane system using monotertiary-alkyltoluenediamine as a cross linker 失效
标题翻译：使用单三烷基甲苯二胺作为交联剂的聚氨酯体系
公开(公告)号：US4816543A
公开(公告)日：1989-03-28
申请号：US768886
申请日：1985-08-23
申请人： William F. Burgoyne, Jr. , Jeremiah P. Casey , Dale D. Dixon , Barton Milligan
发明人： William F. Burgoyne, Jr. , Jeremiah P. Casey , Dale D. Dixon , Barton Milligan
IPC分类号： C08G18/20 , C08G18/10 , C08G18/32 , C08G18/66
CPC分类号： C08G18/6618 , C08G18/10 , C08G18/324 , C08G2120/00
摘要： This invention relates to improved polyurethane systems prepared by reacting an organic polyisocyanate with a hydroxyl containing compound, the improvement comprising utilizing mono tertiary-alkyltoluenediamine where the tertiary-alkyl group is ortho to an amine group as a chain extender or component thereof. The ortho-tertiary-butyltoluenediamine isomer is particular effective for use in reaction injection molding of polyurethanes and can be formulated with polyol as a chain extender mix.
摘要翻译：本发明涉及通过使有机多异氰酸酯与含羟基的化合物反应制备的改进的聚氨酯体系，其改进包括使用叔烷基甲苯二胺，其中叔烷基与胺基邻近作为扩链剂或其组分。邻 - 叔丁基甲苯二胺异构体特别适用于聚氨酯的反应注射成型，并可与多元醇一起配制为扩链剂混合物。

9. 发明授权

US4745223A Mono-tertiary-alkylated toluenediamine and derivatives 失效
标题翻译：单叔烷基化甲苯二胺及其衍生物
公开(公告)号：US4745223A
公开(公告)日：1988-05-17
申请号：US768885
申请日：1985-08-23
申请人： William F. Burgoyne, Jr. , Jeremiah P. Casey , Dale D. Dixon , Barton Milligan
发明人： William F. Burgoyne, Jr. , Jeremiah P. Casey , Dale D. Dixon , Barton Milligan
IPC分类号： C07C211/51 , C08G18/32 , C07C87/58
CPC分类号： C08G18/324 , C08G2120/00
摘要： This invention relates to a class of tertiary-alkyltoluenediamines having alkyl groups ortho to an amine group. More particularly the aromatic diamines are represented by the formulas: ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 are C.sub.1-3 alkyl groups or R.sub.2 and R.sub.3 are combined to form a C.sub.5-6 membered ring.The above described alkylated aromatic diamines have been found to be well suited for use as a chain extender in forming polyurethane/urea elastomer systems and the mono tert-butyltoluenediamine isomers have been found to be nonmutagenic in the Ames test.
摘要翻译：本发明涉及一类具有与胺基邻位烷基的叔烷基甲苯二胺。更具体地，芳族二胺由下式表示：其中R 1，R 2和R 3是C 1-3烷基或R 2和R 3结合形成C 5-6元环。已经发现上述烷基化芳族二胺非常适合用作形成聚氨酯/脲弹性体体系的扩链剂，并且在Ames试验中已经发现单叔丁基甲苯二胺异构体是非引发剂。

10. 发明授权

US4341898A Synthesis of isocyanates from nitroalkanes 失效
标题翻译：从硝基烷烃合成异氰酸酯
公开(公告)号：US4341898A
公开(公告)日：1982-07-27
申请号：US264253
申请日：1981-05-18
申请人： Barton Milligan , Robert K. Pinschmidt, Jr.
发明人： Barton Milligan , Robert K. Pinschmidt, Jr.
IPC分类号： C07C263/14 , C07C265/12 , C07C118/00 , C07C125/063 , C07C125/07
CPC分类号： C07C263/00
摘要： A process for the preparation of aromatic isocyanates from nitroalkanes. A nitromethyl aromatic compound of the general formula: ##STR1## wherein R and R.sub.1 represent hydrogen, halogen, a C.sub.1 -C.sub.5 alkyl radical, a C.sub.1 -C.sub.4 alkoxy radical, nitro, isocyanato, an alkoxycarbonylamino, or nitromethyl radical, with R and R.sub.1 being the same or different, is heated in the presence of an effective amount of a Lewis acid or Bronsted acid substance to effect a dehydrogenation-isomerization reaction to yield an aromatic isocyanate of the general formula: ##STR2## The product of the reaction may be recovered as the aromatic isocyanate or the alcohol adduct, a carbamate.
摘要翻译：从硝基烷烃制备芳族异氰酸酯的方法。其中R和R 1代表氢，卤素，C 1 -C 5烷基，C 1 -C 4烷氧基，硝基，异氰酸酯基，烷氧基羰基氨基或硝基甲基，其中R和R 1 相同或不同，在有效量的路易斯酸或布朗斯台德酸物质存在下加热以进行脱氢异构化反应，得到下列通式的芳族异氰酸酯：反应的产物可以是作为芳族异氰酸酯或醇加成物，氨基甲酸酯回收。

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