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1. 发明授权

US4786703A Process for the preparation of polyisocyanate prepolymers and polyurethanes having high temperature performance and low hysteresis 失效
标题翻译：具有高温性能和低滞后性的多异氰酸酯预聚物和聚氨酯的制备方法
公开(公告)号：US4786703A
公开(公告)日：1988-11-22
申请号：US38810
申请日：1987-04-15
申请人： William E. Starner , Jeremiah P. Casey , Barton Milligan , Susan M. Clift
发明人： William E. Starner , Jeremiah P. Casey , Barton Milligan , Susan M. Clift
IPC分类号： C08G18/10 , C08G18/65 , C08G18/76 , C08G18/30
CPC分类号： C08G18/7621 , C08G18/10
摘要： This invention relates to a polyisocyanate prepolymer for polyurethane/urea elastomer synthesis and to the resulting elastomer. The prepolymer is formed by reacting toluenediisocyanate with a long chain polyol under conditions such that essentially a 2:1 adduct is formed. Excess toluenediisocyanate is removed prior to forming the elastomer.

2. 发明授权

US4810769A Process of preparing polyurethanes cured with 2,6-idaminobenzoic acid derivatives and blends of the 2, 4 and 2,6 isomers 失效
标题翻译：制备用2,6-二氨基苯甲酸衍生物固化的聚氨酯和2,4和2,6异构体的共混物的方法
公开(公告)号：US4810769A
公开(公告)日：1989-03-07
申请号：US58439
申请日：1987-06-05
申请人： Jeremiah P. Casey , Susan M. Clift , Barton Milligan
发明人： Jeremiah P. Casey , Susan M. Clift , Barton Milligan
IPC分类号： C08G18/66 , C08G18/10 , C08G18/65 , C08G18/14 , C08G18/32
CPC分类号： C08G18/10
摘要： The present invention relates to polyurethanes and a method for making polyurethanes by reacting an organic diisocyanate, a glycol having a molecular weight of 500-5000 and a derivative of 2,6-diaminobenzoic acid or a blend comprising derivatives of 2,4-diaminobenzoic acid and 2,6-diaminobenzoic acid. The addition of the 2,6-diaminobenzoic acid derivative to the composition improves polyurethane processability and performance by decreasing chain extender reactivity and increasing hard segment regularity.

3. 发明授权

US4908394A Diaminobenzoate catalytic chain extenders 失效
标题翻译：二氨基苯甲酸酯催化增链剂
公开(公告)号：US4908394A
公开(公告)日：1990-03-13
申请号：US267217
申请日：1988-11-04
申请人： Jeremiah P. Casey , Susan M. Clift
发明人： Jeremiah P. Casey , Susan M. Clift
IPC分类号： C08G18/18 , C08G18/32
CPC分类号： C08G18/325 , C08G18/1825
摘要： The present invention relates to a process for the production of polyurethanes wherein a tertiary amine functionality is incorporated into the side chain of a diaminobenzoate to form catalytic polyurethane chain extender. These chain extenders are polyurethane catalysts which provide adequate cure without residual odor and safety hazards associated with the more traditional tertiary amine catalysts. When reacted with the isocyanate reactive group the non-tertiary amine portion of the chain extender is bound to the polymeric network thereby preventing diffusion of the catalyst species from the polyurethane and negating odor and toxicity as problems. The diaminobenzoate provides enhanced polyurethane physical properties.
摘要翻译：本发明涉及生产聚氨酯的方法，其中叔胺官能团被引入到二氨基苯甲酸酯的侧链中以形成催化聚氨酯增链剂。这些增链剂是提供足够固化而不具有与更传统的叔胺催化剂相关的残留气味和安全危害的聚氨酯催化剂。当与异氰酸酯反应性基团反应时，扩链剂的非叔胺部分结合到聚合物网络，从而防止催化剂物质从聚氨酯扩散，并且作为问题消除气味和毒性。二氨基苯甲酸酯提供增强的聚氨酯物理性能。

4. 发明授权

US4937306A Aromatic diamine catalytic chain extenders 失效
标题翻译：芳香二胺催化增链剂
公开(公告)号：US4937306A
公开(公告)日：1990-06-26
申请号：US266463
申请日：1988-11-02
申请人： Jeremiah P. Casey , Susan M. Clift , Kenneth M. Kem
发明人： Jeremiah P. Casey , Susan M. Clift , Kenneth M. Kem
IPC分类号： C08G18/18 , C08G18/32 , C08G18/38
CPC分类号： C08G18/3825 , C08G18/1825 , C08G18/1841 , C08G18/3246 , C08G18/325
摘要： The present invention relates to a process for the production of polyurethanes wherein a tertiary amine functionality is incorporated into the side chain of an aromatic diamine, preferably a diaminobenzamide, to form a catalytic polyurethane chain extender. These chain extenders are polyurethane catalysts that provide adequate cure without residual odor and safety hazards associated with the more traditional tertiary amine catalysts. When reacted with the isocyanate reactive group the non-tertiary amine portion of the chain extender is bound to the polymeric network. Diffusion of the catalyst species from the polyurethane has been prevented, thus negating odor and toxicity as problems. The aromatic diamine provides enhanced polyurethane physical properties.
摘要翻译：本发明涉及一种生产聚氨酯的方法，其中叔胺官能团被并入芳族二胺的侧链，优选二氨基苯甲酰胺，以形成催化聚氨酯增链剂。这些增链剂是聚氨酯催化剂，其提供足够的固化而没有残留的气味和与更传统的叔胺催化剂相关的安全危害。当与异氰酸酯反应性基团反应时，扩链剂的非叔胺部分与聚合物网络结合。已经防止了催化剂种类从聚氨酯的扩散，因此不利于气味和毒性作为问题。芳族二胺提供增强的聚氨酯物理性能。

5. 发明授权

US5034426A Aromatic diamine catalytic chain extenders 失效
标题翻译：芳香二胺催化增链剂
公开(公告)号：US5034426A
公开(公告)日：1991-07-23
申请号：US468410
申请日：1990-01-22
申请人： Jeremiah P. Casey , Susan M. Clift , Kenneth M. Kem
发明人： Jeremiah P. Casey , Susan M. Clift , Kenneth M. Kem
IPC分类号： C08G18/18 , C08G18/32 , C08G18/38
CPC分类号： C08G18/1825 , C08G18/1841 , C08G18/3246 , C08G18/325 , C08G18/3825
摘要： The present invention relates to a process for the production of polyurethanes wherein a tertiary amine functionality is incorporated into the side chain of an aromatic diamine, preferably a diaminobenzamide, to form a catalytic polyurethane chain extender. These chain extenders are polyurethane catalysts that provide adequate cure without residual odor and safety hazards associated with the more traditional tertiary amine catalysts. When reacted with the isocyanate reactive group the non-tertiary amine portion of the chain extender is bound to the polymeric network. Diffusion of the catalyst species from the polyurethane has been prevented, thus negating odor and toxicity as problems. These aromatic diamines provide enhanced polyurethane physical properties.
摘要翻译：本发明涉及一种生产聚氨酯的方法，其中叔胺官能团被并入芳族二胺的侧链，优选二氨基苯甲酰胺，以形成催化聚氨酯增链剂。这些增链剂是聚氨酯催化剂，其提供足够的固化而没有残留的气味和与更传统的叔胺催化剂相关的安全危害。当与异氰酸酯反应性基团反应时，扩链剂的非叔胺部分与聚合物网络结合。已经防止了催化剂种类从聚氨酯的扩散，因此不利于气味和毒性作为问题。这些芳族二胺提供增强的聚氨酯物理性能。

6. 发明授权

US5856372A Microcellular elastomers with improved processability and properties 失效
标题翻译：具有改善加工性和性能的微孔弹性体
公开(公告)号：US5856372A
公开(公告)日：1999-01-05
申请号：US652062
申请日：1996-05-23
申请人： David J. Ho , William A. Gill , Susan M. Clift , Nigel Barksby
发明人： David J. Ho , William A. Gill , Susan M. Clift , Nigel Barksby
IPC分类号： C08G18/10 , C08G18/40 , C08G18/48 , C08G101/00
CPC分类号： C08G18/4866 , C08G18/10 , C08G18/4072 , C08G18/409 , C08G18/4825 , C08G2101/0008 , C08G2101/0066 , C08G2101/0083 , C08G2410/00 , Y10S521/914
摘要： Microcellular polyurethane elastomer shoe sole components have exceptional physical properties may be prepared from isocyanate-terminated prepolymers derived from polyoxypropylene diols having a molecular weight of from about 2000 Da to 8000 Da, an unsaturation less than about 0.02 meq/g, and a random oxyethylene content of from about 5 to about 15 weight percent. The shoe sole components exhibit high tensile strength, elongation, resilience, and in addition have excellent tear strength, particularly 90.degree. angle tear.
摘要翻译：具有特殊物理特性的微孔聚氨酯弹性体鞋底部件可以由衍生自分子量为约2000Da至8000Da，不饱和度小于约0.02meq / g的聚氧丙烯二醇的异氰酸酯封端的预聚物和随机氧化乙烯含量为约5至约15重量％。鞋底部件表现出高的拉伸强度，伸长率，回弹性，并且还具有优异的撕裂强度，特别是90°的角度撕裂。

7. 发明授权

US5696221A Polyurethane/urea heat-cured and moisture-cured elastomers with improved physical properties 失效
标题翻译：具有改善物理性能的聚氨酯/尿素热固化和湿固化弹性体
公开(公告)号：US5696221A
公开(公告)日：1997-12-09
申请号：US680734
申请日：1996-07-15
申请人： Nigel Barksby , Bruce D. Lawrey , Susan M. Clift
发明人： Nigel Barksby , Bruce D. Lawrey , Susan M. Clift
IPC分类号： C08G18/10 , C08G18/48 , C08G18/66 , C07C257/00
CPC分类号： C08G18/6674 , C08G18/10 , C08G18/4866
摘要： Elastomers with improved physical properties, particularly hardness and rebound, may be prepared by the diamine chain extension or moisture cure of low isocyanate group content, toluene diisocyanate-based prepolymers prepared from a polyol component comprising a high molecular weight, low unsaturation polyoxypropylene diol and a low molecular weight diol. The elastomers are useful for applications such as rollers and other applications where hardness and rebound are important.
摘要翻译：具有改善的物理性能，特别是硬度和回弹性的弹性体可以通过二异氰酸酯链延伸或湿固化低异氰酸酯基含量，由由高分子量，低不饱和聚氧丙烯二醇和低分子量二醇。弹性体可用于诸如辊和其它应用的应用，其中硬度和回弹是重要的。

8. 发明授权

US06420445B1 Polyurethane and polyurethane/urea heat-cured and moisture-cured elastomers with improved physical properties 失效
标题翻译：具有改善物理性能的聚氨酯和聚氨酯/尿素热固化和湿固化弹性体
公开(公告)号：US06420445B1
公开(公告)日：2002-07-16
申请号：US09487087
申请日：2000-01-19
申请人： Nigel Barksby , Bruce D. Lawrey , Susan M. Clift
发明人： Nigel Barksby , Bruce D. Lawrey , Susan M. Clift
IPC分类号： C08J904
CPC分类号： C08G18/6674 , C08G18/12 , C08G18/4866 , C08G18/307
摘要： Elastomers with improved physical properties, particularly hardness, resilience, tear strength, and compression set, may be prepared by the chain extension or moisture cure of isocyanate-terminated prepolymers prepared from a polyol component comprising a high molecular weight, low unsaturation polyoxypropylene diol and a low molecular weight diol. The elastomers are useful for applications such as rollers and other applications for which these physical properties are important.
摘要翻译：具有改进的物理性能，特别是硬度，弹性，撕裂强度和压缩永久变形的弹性体可以通过由包含高分子量，低不饱和聚氧丙烯二醇和多元醇的多元醇组分制备的异氰酸酯封端的预聚物的链延长或水分固化来制备低分子量二醇。弹性体可用于诸如辊和其它这些物理性质重要的应用。

9. 发明授权

US5453478A Ortho-alkylated tolidines 失效
标题翻译：正烷基化的甲苯胺
公开(公告)号：US5453478A
公开(公告)日：1995-09-26
申请号：US28494
申请日：1993-05-04
申请人： Kevin R. Lassila , Michael E. Ford , Kenneth M. Kem , Susan M. Clift
发明人： Kevin R. Lassila , Michael E. Ford , Kenneth M. Kem , Susan M. Clift
IPC分类号： C08G18/10 , C08G59/10 , C08G59/50 , C08G69/26 , C08G73/10
CPC分类号： C08G73/10 , C08G18/10 , C08G59/10 , C08G59/5033 , C08G69/26
摘要： This invention relates to o-tolidines which have a tert-butyl substituent ortho to an amine group. These compositions are represented by the formula: ##STR1## where R.sub.1 =i-propyl, or t-butyl, and where R.sub.2 =hydrogen, i-propyl, or t-butyl.The compositions are useful in the preparation of polyepoxide resins as well as polyurethanes, polyamides and polyimides.
摘要翻译：本发明涉及在胺基上具有叔丁基取代基的邻甲苯胺。这些组合物由下式表示：R 2 =氢，异丙基或叔丁基。该组合物可用于制备聚环氧化物树脂以及聚氨酯，聚酰胺和聚酰亚胺。

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