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1. 发明授权

US5916986A Coating composition for coatings resistant to environmental etch 失效
标题翻译：涂料组合物，耐环境腐蚀涂层
公开(公告)号：US5916986A
公开(公告)日：1999-06-29
申请号：US754049
申请日：1996-11-20
申请人： Anna M. Budde , James A. Laugal , Walter H. Ohrbom , Marvin L. Green , Mark R. Montagne
发明人： Anna M. Budde , James A. Laugal , Walter H. Ohrbom , Marvin L. Green , Mark R. Montagne
IPC分类号： B05D7/24 , C08J3/24 , C09D133/00 , C09D133/04 , C09D133/14 , C08F224/00 , C08F220/18 , C08F232/08
CPC分类号： C09D133/14 , C09D133/04 , Y10T428/31692 , Y10T428/31696
摘要： A sterically-hindered monomer is used to make a polymer which in turn is useful in coating compositions. The resulting residue of the sterically-hindered monomer is present in the polymer, as well as in a cured coating (preferably an automotive coating) produced using a coating composition having the polymer therein. The presence of the residue of the sterically-hindered monomer imparts in the cured coating a resistance to environmental etching.
摘要翻译：使用空间位阻单体制备聚合物，其又可用于涂料组合物。所得空间位阻单体的残余物存在于聚合物中，以及使用其中具有聚合物的涂料组合物制备的固化涂层（优选汽车涂料）中。空间位阻单体的残留物的存在赋予固化涂层耐环境蚀刻性。

2. 发明授权

US5635302A Substrate having coating resistant to environmental etch, coating composition therefor, process for making the coating composition, and process of coating a substrate with the composition 失效
标题翻译：具有耐环境蚀刻的涂层的基材，其涂料组合物，用于制备涂料组合物的方法，以及用该组合物涂布基材的方法
公开(公告)号：US5635302A
公开(公告)日：1997-06-03
申请号：US458053
申请日：1995-06-01
申请人： Anna M. Budde , James A. Laugal , Walter H. Ohrbom , Marvin L. Green , Mark R. Montagne
发明人： Anna M. Budde , James A. Laugal , Walter H. Ohrbom , Marvin L. Green , Mark R. Montagne
IPC分类号： B05D7/24 , C08J3/24 , C09D133/00 , C09D133/04 , C09D133/14 , B32B15/08 , C08F220/06 , C08F222/06 , C08F224/00 , C08F226/02 , C08F232/08 , C08F225/10
CPC分类号： C09D133/14 , C09D133/04 , Y10T428/31692 , Y10T428/31696
摘要： A sterically-hindered monomer is used to make a polymer which in turn is useful in coating compositions. The resulting residue of the sterically-hindered monomer is present in the polymer, as well as in a cured coating (preferably an automotive coating) produced using a coating composition having the polymer therein. The presence of the residue of the sterically-hindered monomer imparts in the cured coating a resistance to environmental etching.
摘要翻译：使用空间位阻单体制备聚合物，其又可用于涂料组合物。所得空间位阻单体的残余物存在于聚合物中，以及使用其中具有聚合物的涂料组合物制备的固化涂层（优选汽车涂料）中。空间位阻单体的残留物的存在赋予固化涂层耐环境蚀刻性。

3. 发明授权

US06992149B2 Use of carbamate-modified aminoplast resins to improve the appearance and performance of powder coatings 失效
标题翻译：使用氨基甲酸酯改性的氨基塑料树脂来改善粉末涂料的外观和性能
公开(公告)号：US06992149B2
公开(公告)日：2006-01-31
申请号：US10777301
申请日：2004-02-12
申请人： Walter H. Ohrbom , Thomas S. Richards , Timothy S. December , James A. Laugal
发明人： Walter H. Ohrbom , Thomas S. Richards , Timothy S. December , James A. Laugal
IPC分类号： C08L61/20 , C08G12/30
CPC分类号： C09D161/20 , C08G12/00 , C08G12/32 , C08G12/427 , C09D5/037
摘要： A powder coating composition comprising at least about 0.1% by weight of a reaction product of an aminoplast and a compound having one carbamate group has improved smoothness.
摘要翻译：包含至少约0.1重量％的氨基塑料和具有一个氨基甲酸酯基团的化合物的反应产物的粉末涂料组合物具有改善的平滑度。

4. 发明授权

US07060357B2 Powder coatings containing symmetrical additives 失效
标题翻译：包含对称添加剂的粉末涂料
公开(公告)号：US07060357B2
公开(公告)日：2006-06-13
申请号：US10265036
申请日：2002-10-04
申请人： Walter H. Ohrbom , David J. Law , Robert D. Weise , James A. Laugal
发明人： Walter H. Ohrbom , David J. Law , Robert D. Weise , James A. Laugal
IPC分类号： B32B27/40 , B32B27/42 , C08L75/04
CPC分类号： C09D5/037 , C08G2150/20 , C09D161/20 , Y10S525/934 , Y10T428/31551 , C08L2666/02
摘要： A coating composition contains solid particulates of a mixture of an aminoplast crosslinking agent, a solid polymer having functionality reactive with the aminoplast crosslinking agent, and a crystalline, carbamate-functional additive. The crystalline, carbamate-functional additive has a melting point of at least about 30° C. and is up to about 15% by weight of the powder coating composition.
摘要翻译：涂料组合物含有氨基塑料交联剂，具有与氨基塑料交联剂反应的官能团的固体聚合物和结晶的氨基甲酸酯官能添加剂的混合物的固体颗粒。结晶的氨基甲酸酯官能添加剂具有至少约30℃的熔点并且高达粉末涂料组合物的约15重量％。

5. 发明授权

US06822040B2 Basecoat composition with improved repair properties 失效
标题翻译：底漆组合物具有改进的修复性能
公开(公告)号：US06822040B2
公开(公告)日：2004-11-23
申请号：US09962700
申请日：2001-09-25
申请人： Leslie G. Baugh , David K. K. Lau , Thomas C. Balch , Sergio E. Balatan , Walter H. Ohrbom , James A. Laugal , David J. Law
发明人： Leslie G. Baugh , David K. K. Lau , Thomas C. Balch , Sergio E. Balatan , Walter H. Ohrbom , James A. Laugal , David J. Law
IPC分类号： C08L5100
CPC分类号： B05D7/536 , B05D7/577 , C09D133/08 , Y10T428/2982 , Y10T428/31529 , C08L2666/54 , C08L2666/14
摘要： A basecoat composition includes an acrylic polymer prepared from a combination of monomers including at least about 30% by weight ethyl acrylate, methyl acrylate, methyl methacrylate, or a combination of these. The basecoat composition also includes methylated melamine-formaldehyde resin and up to about 10% by weight of a butylated melamine-formaldehyde resin, based on the weight of the basecoat composition vehicle and butylated melamine resin. An at least partially cured layer of the basecoat composition offers improved adhesion with a coating composition layer applied over it and cured, whether the coating composition layer applied over it is another layer of the basecoat composition itself or a layer of a clearcoat composition.
摘要翻译：底漆组合物包括由包含至少约30重量％的丙烯酸乙酯，丙烯酸甲酯，甲基丙烯酸甲酯或它们的组合的单体组合组合制备的丙烯酸聚合物。底漆组合物还包括甲基化三聚氰胺甲醛树脂和最多约10重量％的丁基化三聚氰胺 - 甲醛树脂，基于底漆组合物载体和丁基化三聚氰胺树脂的重量。底涂层组合物的至少部分固化的层提供与涂覆在其上并且固化的涂料组合物层的改善的粘合性，涂覆在其上的涂料组合物层是否是底涂层组合物本身的另一层或透明涂层组合物层。

6. 发明授权

US06740706B2 Method for obtaining coating compositions having reduced VOC 有权
标题翻译：获得具有降低的VOC的涂料组合物的方法
公开(公告)号：US06740706B2
公开(公告)日：2004-05-25
申请号：US10012075
申请日：2001-12-07
申请人： Walter H. Ohrbom , Robert D. Weise , James A. Laugal
发明人： Walter H. Ohrbom , Robert D. Weise , James A. Laugal
IPC分类号： C08L3304
CPC分类号： C08F2/44 , C08F2/06
摘要： The invention relates to an economical method of making a polymer having reduced VOCs and coating compositions containing such polymers. In one embodiment, the method of invention requires providing a reactant mixture (a), providing a solvent mixture (b) comprising a reactive component (c) which is substantially free of any heteroatoms and is not a crystalline solid at room temperature and comprises (i) from 12 to 72 carbon atoms, and (ii) at least two functional groups, and subjecting the reactant mixture (a) in the solvent mixture (b) to polymerization conditions sufficient to polymerize reactant mixture (a) to provide a mixture (d) of a polymer (a′) in solvent mixture (b), wherein reactive component (c) under the polymerization conditions is substantially nonreactive: (1) with the components of reactive mixture (a), (2) in the polymerization of reactant mixture (a) and (3) with the polymer (a′). Coating compositions of the invention comprising polymers made by the disclosed method provide low VOCs without any reduction in application or performance properties.
摘要翻译：本发明涉及制备具有降低的VOC的聚合物和含有这种聚合物的涂料组合物的经济方法。在一个实施方案中，本发明的方法需要提供反应物混合物（a），提供包含基本上不含任何杂原子并且在室温下不是结晶固体的反应性组分（c）的溶剂混合物（b），并且包含 i）12至72个碳原子，和（ii）至少两个官能团，并使溶剂混合物（b）中的反应物混合物（a）经受足以聚合反应混合物（a）的聚合条件以提供混合物 d）在溶剂混合物（b）中的聚合物（a'），其中在聚合条件下的反应性组分（c）基本上是非反应性的：（1）在反应混合物（a），（2）反应物混合物（a）和（3）与聚合物（a'）。包含通过所公开的方法制备的聚合物的本发明的涂料组合物提供低VOC，而不会降低应用或性能。

7. 发明授权

US06962730B2 Coating composition containing crosslinkable monomeric difunctional compounds having at least thirty carbon atoms 有权
标题翻译：包含具有至少30个碳原子的可交联单体双官能化合物的涂料组合物
公开(公告)号：US06962730B2
公开(公告)日：2005-11-08
申请号：US10351079
申请日：2003-01-23
申请人： Walter H. Ohrbom , John A. Gilbert , Patricia A. Herrel , Marvin L. Green , Joanne Casale , Thomas G. Savino
发明人： Walter H. Ohrbom , John A. Gilbert , Patricia A. Herrel , Marvin L. Green , Joanne Casale , Thomas G. Savino
IPC分类号： C09D5/02 , C09D133/14 , C09D201/00 , C09D201/02 , B05D3/00
CPC分类号： C09D5/02 , C09D133/14 , C09D201/00 , C09D201/02 , C09D201/025
摘要： The invention provides coating compositions comprising a reactive component (a) which is substantially free of any heteratoms and is a not a crystalline solid at room temperature and which comprises from (i) 12 to 72 carbon atoms, and (ii) at least two functional groups, and (b) a crosslinking agent comprising a plurality of functional groups (iii) reactive with the functional groups (ii) of compound (a), wherein functional groups (ii) and (iii) are selected such that reaction there between produces a thermally irreversible chemical linkage. The coating compositions of the invention provide improved solids, chip resistance, flexibility and/or scratch & mar resistance while maintaining desirable and/or improved performance characteristics with regard to environmental etch, relative humidity, QCT, chip resistance, thermoshock resistance, cold crack resistance, adhesion and the like.
摘要翻译：本发明提供涂料组合物，其包含基本上不含任何杂原子的反应性组分（a），并且在室温下不是结晶固体，并且其包含（i）12至72个碳原子，和（ii）至少两个官能基团，和（b）包含与化合物（a）的官能团（ⅱ）反应的多个官能团（ⅲ）的交联剂，其中选择官能团（ⅱ）和（ⅲ），使得其中的反应产生热不可逆化学键。本发明的涂料组合物在环境蚀刻，相对湿度，QCT，芯片电阻，耐热裂纹性，耐寒裂纹性方面保持理想和/或改进的性能特征，提供了改进的固体，耐芯片性，柔性和/ ，粘合等。

8. 发明授权

US06531560B1 Carbamate-functional resins having improved adhesion, method of making the same, and method of improving intercoat adhesion 有权
公开(公告)号：US06531560B1
公开(公告)日：2003-03-11
申请号：US09677063
申请日：2000-09-29
申请人： Donald H. Campbell , Walter H. Ohrbom , Joseph Borst , Michael A. Gessner , Donald L. St. Aubin , Marvin L. Green , Bruce E. Oermann
发明人： Donald H. Campbell , Walter H. Ohrbom , Joseph Borst , Michael A. Gessner , Donald L. St. Aubin , Marvin L. Green , Bruce E. Oermann
IPC分类号： C08F12602
CPC分类号： C08G18/8116 , C08F8/00 , C08F2800/20 , C08F2810/50 , C08G18/3823 , C09D201/025 , Y10T428/31551 , Y10T428/31573 , Y10T428/31645 , C08F2220/325 , C08F220/34 , C08F220/20 , C08F212/08
摘要： The invention provides carbamate-functional resins and coating compositions incorporating said resins that have improved adhesion with respect to subsequently applied films or coatings. More particularly, the invention relates to carbamate-functional addition polymers having at least 250 grams of polymer per carbamate group which are made with less than 35 percent by weight of nonfunctional monomers, preferably with less than 20 percent by weight and most preferably from 0 to less than 10 percent by weight, based on the total weight of the polymer. The invention further provides a method of making a carbamate-functional polymer and carbamate-functional polymers made by the claimed method. Finally, the invention provides a method for improving the adhesion of a first coating composition to a subsequently applied material as well as a method of making a composite comprising a coated substrate, an adhesive composition, and a glass having at least one surface.

9. 发明授权

US5994479A Curable coating compositions containing blends of carbamate-functional compounds 失效
标题翻译：含有氨基甲酸酯官能化合物的混合物的可固化涂料组合物
公开(公告)号：US5994479A
公开(公告)日：1999-11-30
申请号：US997317
申请日：1997-12-23
申请人： Marvin L. Green , John D. McGee , Brian D. Bammel , Danielle A. Regulski , Walter H. Ohrbom
发明人： Marvin L. Green , John D. McGee , Brian D. Bammel , Danielle A. Regulski , Walter H. Ohrbom
IPC分类号： C08G18/40 , C08G18/80 , C09D5/02 , C09D5/03 , C09D161/20 , C09D175/00 , C09D201/02 , C08G8/28 , C08G59/14 , C08L63/00 , C08L67/04
CPC分类号： C09D161/20 , C08G18/8077 , C09D201/025 , Y10T428/31551
摘要： The present invention provides a curable coating composition comprising(a) a first component comprising at least two functional groups, at least one of which is a carbamate or urea group that is the reaction product of:(1) a hydroxyl group that is the result of a ring-opening reaction between an epoxy group and an organic acid group, and(2) cyanic acid or a carbamate or urea group;(b) a curing agent having a plurality of functional groups that are reactive with component (a), and(c) a second component having functional groups that are reactive with component (a) or component (b) or both components (a) and (b).
摘要翻译：本发明提供一种可固化涂料组合物，其包含（a）包含至少两个官能团的第一组分，其中至少一个为氨基甲酸酯或脲基，其为：（1）作为结果的羟基的反应产物的环氧基和有机酸基之间的开环反应，和（2）氰酸或氨基甲酸酯或脲基; （b）具有多个与组分（a）反应的官能团的固化剂，和（c）具有与组分（a）或组分（b）或两种组分（a）反应的官能团的第二组分）和（b）。

10. 发明授权

US08686090B2 Use of urea crystals for non-polymeric coatings 有权
标题翻译：尿素晶体用于非聚合物涂层
公开(公告)号：US08686090B2
公开(公告)日：2014-04-01
申请号：US10732850
申请日：2003-12-10
申请人： Marvin L. Green , Swaminathan Ramesh , Walter H. Ohrbom
发明人： Marvin L. Green , Swaminathan Ramesh , Walter H. Ohrbom
IPC分类号： B01F17/00 , B05D3/02 , C08F283/00 , C08F283/02 , C08F283/04 , C08G6/02 , C08G8/28 , C08G12/42 , C08G18/00 , C08G18/08 , C08G18/28 , C08G18/42 , C08G18/67 , C08G18/83 , C08G63/08 , C08G63/44 , C08G63/91 , C08G65/32 , C08G67/02 , C08G69/00 , C08G69/44 , C08K5/00 , C08L51/00 , C08L61/00 , C08L61/02 , C08L63/00 , C08L67/00 , C08L67/02 , C08L69/00 , C08L71/00 , C08L75/00 , C08L77/00 , C08L79/00
CPC分类号： C09D175/02 , C08G18/2865 , C08G18/4615 , C09D201/025
摘要： The thermosetting, non-polymeric coating composition includes at least one monomeric material having a plurality of carbamate and/or urea groups, at least one crosslinker reactive with the at least one monomeric material, and a sag control agent that is a crystalline reaction product of an amine and an isocyanate.
摘要翻译：热固性非聚合物涂料组合物包括至少一种具有多个氨基甲酸酯和/或脲基团的单体材料，至少一种与至少一种单体材料反应的交联剂，以及一种下垂控制剂，其为下列物质的结晶反应产物：胺和异氰酸酯。

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