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    • 4. 发明申请
    • METHOD FOR PRODUCING MULTILAYER COATING FILM
    • US20110108426A1
    • 2011-05-12
    • US12989157
    • 2009-04-21
    • Kouki HayashiDaichi KatoJunya Ogawa
    • Kouki HayashiDaichi KatoJunya Ogawa
    • B32B27/40B32B27/36B32B27/42B05D3/02
    • C09D5/037B05D7/00C08F257/02
    • The present invention relates to a method for producing a multilayer coating film, which comprises steps of applying a waterborne intermediate coating composition on an electrodeposited coating film to form an intermediate coating film; applying a waterborne base coating composition on the intermediate coating film to form a base coating film; applying a clear coating composition on the base coating film to form a clear coating film; and simultaneously baking and curing the intermediate coating film, the base coating film applied thereon, and the clear coating film further applied thereon in order to form a multilayer coating film, wherein the waterborne intermediate coating composition comprises an emulsion of a hydroxyl group-containing acrylic resin comprising 27 to 65% by weight of a styrene monomer, wherein the emulsion has a water-tolerance within a range of from 0.2 to 5 and a hexane-tolerance within a range of from 5 to 25; a hydroxyl group-containing polyester resin; a melamine resin; a carbodiimide; and an associative thickener, wherein the associative thickener comprises an urethane compound (A) represented by the formula (1), and an urethane compound (B) represented by the formula (2): R—(OA)m-O—C(═O)—NH—Y—NH—C(═O)—O-(AO)n—R (1) R—(OA)a-[O—C(═O)—NH—Y—NH—C(═O)—(OA)b]c-O—C(═O)—NH—Y—NH—C(═O)—O-(AO)d—R (2) wherein R independently represents a hydrocarbon group having 8 to 24 carbon atoms, Y independently represents a residue resulted from a removal of two isocyanate groups from a diisocyanate, OA independently represents an oxyalkylene group having 2 to 4 carbon atoms, AO independently represents an alkyleneoxy group having 2 to 4 carbon atoms, O represents an oxygen atom, C represents a carbon atom, N represents a nitrogen atom, m independently represents an integer of 20 to 500, n independently represents an integer of 20 to 500, a independently represents an integer of 1 to 100, d independently represents an integer of 1 to 100, b represents an integer of 40 to 500, c represents an integer of 1 to 5, b by c (or b×c) represents an integer of 150 to 2500, and R may be the same or different, and Y may be the same or different, wherein each of the urethane compounds (A) and (B) has at least 80% by weight of oxyethylene groups and ethyleneoxy groups relative to the total weight of the oxyalkylene groups and the alkyleneoxy groups, wherein weight ratio of the hydroxyl group-containing acrylic resin emulsion to the associative thickener is within a range of from 100/0.1 to 100/50 as a basis of the solid content, in order to provide the multilayer coating film with an excellent exterior appearance by a three coating and one baking (3C1B) procedure, wherein viscosity of the intermediate coating composition is controlled, and furthermore, ratio of hydrophilicity to hydrophobicity of the resin in the intermediate coating composition is controlled, in order to significantly suppress sagging of the waterborne intermediate coating composition during the coating procedure.
    • 10. 发明申请
    • Curable powder film-forming composition exhibiting improved flow and leveling
    • 表现出改善的流动性和流平性的可固化的粉末成膜组合物
    • US20030166758A1
    • 2003-09-04
    • US10360263
    • 2003-02-06
    • Karen A. BarkacDeirdre D. RaganKaren S. Rechenberg
    • C08K003/18C08K003/34
    • C08K3/22C08K3/36C09D5/037
    • A curable powder film-forming composition is provided, comprising (i) 5 to 95 percent by weight based on the total weight of the film-forming composition of a crosslinking agent; (ii) 5 to 95 percent by weight based on the total weight of the film-forming composition of a polymer containing a plurality of functional groups reactive with the crosslinking agent; and (iii) particles having a mean particle size less than 100 nm. The particles are substantially free of functional groups on the particle surface, and are present in an amount at least sufficient to improve the flow and leveling of the composition when applied to a substrate and cured, as measured by longwave scanning, compared to a similar cured coating without the particles. A multi-component composite coating composition is also provided, comprising a pigmented basecoat and a clear coat. The basecoat and/or clearcoat may be derived from the curable film-forming composition described above. Also provided are coated substrates in which the curable coating compositions or the multi-component composite coating compositions described above are applied to a substrate and cured to form a cured coating.
    • 提供了一种可固化的粉末成膜组合物,其包含(i)基于成膜组合物的总重量为5至95重量%的交联剂; (ii)基于成膜组合物的总重量为5〜95重量%的含有与交联剂反应的多个官能团的聚合物; 和(iii)平均粒度小于100nm的颗粒。 颗粒在颗粒表面上基本上不含官能团,并且存在的量至少足以改善组合物在施加到基底上时的流动和流平,并且通过长波扫描测量,与类似的固化 没有颗粒的涂层。 还提供了多组分复合涂料组合物,其包含着色的底漆和透明涂层。 底涂层和/或透明涂层可以衍生自上述可固化成膜组合物。 还提供了将上述可固化涂料组合物或多组分复合涂料组合物施用于基材并固化以形成固化涂层的涂布基材。