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    • 2. 发明授权
    • Entanglement-inhibited macromolecules
    • 免疫抑制大分子
    • US5206303A
    • 1993-04-27
    • US634846
    • 1990-12-27
    • Mun-Fu TseAnthony J. DiasPrasadarao MekaKenneth O. McElrath
    • Mun-Fu TseAnthony J. DiasPrasadarao MekaKenneth O. McElrath
    • C08F290/00C08F291/00C08F299/00C08G81/00
    • C08F299/00C08F291/00C08G81/00
    • A grafted and/or functionalized macromolecule comprises entanglement-inhibited architecture wherein the polymer exhibits reduced melt viscosity. In one embodiment, the macromolecule comprises a polymer of an isoolefin having about 4 to about 7 carbon atom and a para-alkylstyrene, wherein a grafted macromonomer such as a terminally functionalized polystyryl chain of very narrow molecular weight distribution is attached to the para-alkyl group of the para-alkylstyrene such that entanglement of adjacent chains in the melt are inhibited. In addition to distributed macromonomer grafts, other functionality may be attached to the para-alkyl group of the para-alkylstyrene to introduce other desirable properties such as radiation curability. In another embodiment the macromolecule comprises a polymer of one or more simple olefinic monomers wherein a macromolecule is attached to pendent functionality and/or copolymerized into the polymer backbone. A particularly preferred macromonomer comprises a terminal norbornene functional group.
    • 接枝和/或官能化的大分子包括缠结抑制结构,其中聚合物表现出降低的熔体粘度。 在一个实施方案中,大分子包含具有约4至约7个碳原子的异烯烃聚合物和对 - 烷基苯乙烯,其中接枝的大分子单体如具有非常窄的分子量分布的末端官能化的聚苯乙烯基链连接到对位烷基 一组对位烷基苯乙烯,使得熔体中相邻链的缠结被抑制。 除了分散的大分子单体移植物之外,其它官能团可以连接到对烷基苯乙烯的对位烷基上以引入其它期望的性质,例如辐射固化性。 在另一个实施方案中,大分子包含一种或多种简单烯烃单体的聚合物,其中大分子连接至侧链官能团和/或共聚到聚合物主链中。 特别优选的大分子单体包括末端降冰片烯官能团。
    • 3. 发明授权
    • Entanglement-inhibited macromolecules
    • 缠结抑制大分子
    • US5294678A
    • 1994-03-15
    • US009692
    • 1993-01-27
    • Mun-Fu TseAnthony J. DiasPrasadarao MekaKenneth O. McElrath
    • Mun-Fu TseAnthony J. DiasPrasadarao MekaKenneth O. McElrath
    • C08F290/00C08F291/00C08F299/00C08G81/00C08F255/08C08F257/02
    • C08F299/00C08F291/00C08G81/00
    • A grafted and/or functionalized macromolecule comprises entanglement-inhibited architecture wherein the polymer exhibits reduced melt viscosity. In one embodiment, the macromolecule comprises a polymer of an isoolefin having about 4 to about 7 carbon atom and a para-alkylstyrene, wherein a grafted macromonomer such as a terminally functionalized polystyryl chain of very narrow molecular weight distribution is attached to the para-alkyl group of the para-alkylstyrene such that entanglement of adjacent chains in the melt are inhibited. In addition to distributed macromonomer grafts, other functionality may be attached to the para-alkyl group of the para-alkylstyrene to introduce other desirable properties such as radiation curability. In another embodiment the macromolecule comprises a polymer of one or more simple olefinic monomers wherein a macromolecule is attached to pendent functionality and/or copolymerized into the polymer backbone. A particularly preferred macromonomer comprises a terminal norbornene functional group.
    • 接枝和/或官能化的大分子包括缠结抑制结构,其中聚合物表现出降低的熔体粘度。 在一个实施方案中,大分子包含具有约4至约7个碳原子的异烯烃聚合物和对 - 烷基苯乙烯,其中接枝的大分子单体如具有非常窄的分子量分布的末端官能化的聚苯乙烯基链连接到对位烷基 一组对位烷基苯乙烯,使得熔体中相邻链的缠结被抑制。 除了分散的大分子单体移植物之外,其它官能团可以连接到对烷基苯乙烯的对位烷基上以引入其它期望的性质,例如辐射固化性。 在另一个实施方案中,大分子包含一种或多种简单烯烃单体的聚合物,其中大分子连接至侧链官能团和/或共聚到聚合物主链中。 特别优选的大分子单体包括末端降冰片烯官能团。
    • 10. 发明授权
    • Composite materials comprising polar polymers and single-wall carbon nanotubes
    • 复合材料包括极性聚合物和单壁碳纳米管
    • US06936653B2
    • 2005-08-30
    • US10389256
    • 2003-03-14
    • Kenneth O. McElrathKenneth A. SmithThomas M. TianoMargaret E. Roylance
    • Kenneth O. McElrathKenneth A. SmithThomas M. TianoMargaret E. Roylance
    • B82B1/00C08K7/06C08K7/24C08L101/00H01B1/24C08K3/04
    • C08K7/24B82Y10/00B82Y30/00H01B1/24Y10S977/753
    • The invention relates to a composite comprising a weight fraction of single-wall carbon nanotubes and at least one polar polymer wherein the composite has an electrical and/or thermal conductivity enhanced over that of the polymer alone. The invention also comprises a method for making this polymer composition. The present application provides composite compositions that, over a wide range of single-wall carbon nanotube loading, have electrical conductivities exceeding those known in the art by more than one order of magnitude. The electrical conductivity enhancement depends on the weight fraction (F) of the single-wall carbon nanotubes in the composite. The electrical conductivity of the composite of this invention is at least 5 Siemens per centimeter (S/cm) at (F) of 0.5 (i.e. where single-wall carbon nanotube loading weight represents half of the total composite weight), at least 1 S/cm at a F of 0.1, at least 1×10−4 S/cm at (F) of 0.004, at least 6×10−9 S/cm at (F) of 0.001 and at least 3×10−16 S/cm (F) plus the intrinsic conductivity of the polymer matrix material at of 0.0001. The thermal conductivity enhancement is in excess of 1 Watt/m-° K. The polar polymer can be polycarbonate, poly(acrylic acid), poly(acrylic acid), poly(methacrylic acid), polyoxide, polysulfide, polysulfone, polyamides, polyester, polyurethane, polyimide, poly(vinyl acetate), poly(vinyl alcohol), poly(vinyl chloride), poly(vinyl pyridine), poly(vinyl pyrrolidone), copolymers thereof and combinations thereof. The composite can further comprise a nonpolar polymer, such as, a polyolefin polymer, polyethylene, polypropylene, polybutene, polyisobutene, polyisoprene, polystyrene, copolymers thereof and combinations thereof.
    • 本发明涉及一种复合材料,其包含单壁碳纳米管的重量分数和至少一种极性聚合物,其中复合材料的电和/或热导率比单独聚合物的电导率和/或导热系数增强。 本发明还包括制备该聚合物组合物的方法。 本申请提供复合组合物,其在宽范围的单壁碳纳米管负载下具有超过本领域已知的超过一个数量级的电导率。 电导率增强取决于复合材料中单壁碳纳米管的重量分数(F)。 本发明的复合材料的电导率在(F)为0.5时每厘米至少5西门子(S / cm)(即单壁碳纳米管负载重量占总复合重量的一半),至少1 S / F,在(F)为0.004时至少为1×10 -4 S / cm,在(F)时为至少6×10 -9 S / cm 0.001和至少3×10 -6 / cm(F)加上聚合物基质材料的固有电导率为0.0001。 热导率提高超过1瓦/米-2°K。极性聚合物可以是聚碳酸酯,聚(丙烯酸),聚(丙烯酸),聚(甲基丙烯酸),聚氧化物,多硫化物,聚砜,聚酰胺,聚酯 ,聚氨酯,聚酰亚胺,聚(乙酸乙烯酯),聚(乙烯醇),聚(氯乙烯),聚(乙烯基吡啶),聚(乙烯基吡咯烷酮),其共聚物及其组合。 复合材料还可以包含非极性聚合物,例如聚烯烃聚合物,聚乙烯,聚丙烯,聚丁烯,聚异丁烯,聚异戊二烯,聚苯乙烯,其共聚物和它们的组合。