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    • 2. 发明授权
    • Supported, non (metal-promoted) carbon-containing molybdenum sulfide
catalysts for selective nitrogen removal
    • 支持非金属促进的含碳钼硫化物催化剂,用于选择性除氮
    • US4457836A
    • 1984-07-03
    • US494539
    • 1983-05-13
    • Robert L. SeiverCharles RebickDuane A. Goetsch
    • Robert L. SeiverCharles RebickDuane A. Goetsch
    • B01J27/051C10G45/04
    • B01J27/051C10G45/04
    • A process for selectively removing nitrogen from petroleum distillate feedstocks, notably lube oil distillates or lube base stocks without significant desulfurization of said petroleum distillate feedstocks, especially lube oil distillates or lube base stocks, while hydrotreating the oil to improve odor, color, improve stability, and the like. In accordance therewith, a supported, non (metal-promoted) carbon-containing molybdenum sulfide HDN/HDS selective hydrotreating catalyst is formed from a precursor composite made by compositing a preselected quantity of a porous, refractory inorganic oxide with a complex salt characterized by the formula B.sub.x [MoO.sub.y S.sub.4-y ] where B is (a) an alkyl substituted diammonium ion, or (2) an alkyl substituted ammonium ion or quaternary ammonium ion; x is 1 where B is an alkyl substituted diammonium ion, or 2 where B is an alkyl substituted ammonium or quaternary ammonium ion; and y is 0, or a fraction or whole number ranging up to 3. The supported, non (metal-promoted) carbon-containing molybdenum sulfide HDN/HDS selective lube oil hydrotreating catalyst is then formed from the precursor composite by heating said composite, and heat decomposing the salt of said catalyst precursor composite in the presence of hydrogen, hydrocarbon and sulfur.
    • 选择性地从石油馏出物原料中除去氮的方法,特别是润滑油馏出物或润滑油基础油,而不显着地脱硫所述石油馏分原料,特别是润滑油馏出物或润滑油基础油,同时加氢处理油以改善气味,颜色,提高稳定性, 等等。 据此,通过将预选量的多孔耐火无机氧化物与复合盐形成的前体复合材料形成载体,非(金属促进的)含碳钼硫化物HDN / HDS选择性加氢处理催化剂, 式Bx [MoOyS4-y]其中B是(a)烷基取代的二铵离子,或(2)烷基取代的铵离子或季铵离子; x是1,其中B是烷基取代的二铵离子,或2,其中B是烷基取代的铵或季铵离子; y为0,或最多为3的分数或全数。然后通过加热所述复合材料,由前体复合材料形成负载的非金属促进的含碳钼硫化物HDN / HDS选择性润滑油加氢处理催化剂, 并在氢,烃和硫的存在下热分解所述催化剂前体复合物的盐。