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1. 发明授权

US4843107A Process for the preparation of polyamines and their use for the preparation of polyurethanes 失效
标题翻译：制备多胺的方法及其用于制备聚氨酯的用途
公开(公告)号：US4843107A
公开(公告)日：1989-06-27
申请号：US173204
申请日：1988-03-24
申请人： Andreas Ruckes , Werner Rasshofer , Klaus Konig , Richard Kopp
发明人： Andreas Ruckes , Werner Rasshofer , Klaus Konig , Richard Kopp
IPC分类号： C08G18/64 , C08G18/10 , C08G18/50 , C08G73/02
CPC分类号： C08G18/5048 , C08G18/10
摘要： Polyamines containing primary amino groups are made by a one-shot process for the hydrolysis of prepolymers containing isocyanate end groups and having an isocyanate content of from 0.5 to 40 weight % with 0.75 to 40 mol of water per equivalent of isocyanate groups in the presence of very small quantities of sodium hydroxide in certain organic, polar solvents. The compounds containing isocyanate groups used for this process are isocyanate prepolymers (preferably containing urethane groups). Hydrolysis according to this process leads directly to the polyamines with elimination of carbon dioxide. These polyamines may be isolated by the usual methods and the removal of the small quantities of catalyst may advantageously be omitted. These polyamines are useful for the preparation of polyurethane(urea)s.
摘要翻译：含有伯氨基的多胺通过一步法制备，用于水解包含异氰酸酯端基并且异氰酸酯含量为0.5至40重量％的预聚物，每当异氰酸酯基为0.75至40摩尔水时，某些有机极性溶剂中极少量的氢氧化钠。用于该方法的含有异氰酸酯基团的化合物是异氰酸酯预聚物（优选含有氨基甲酸酯基团）。根据该方法的水解直接导致多胺消除二氧化碳。这些多胺可以通过常规方法分离，并且可以有利地省略少量催化剂的去除。这些多胺可用于制备聚氨酯（尿素）。

2. 发明授权

US4835224A Process for the preparation of polyamines and their use for the production of polyurethanes 失效
标题翻译：制备多胺的方法及其用于生产聚氨酯的方法
公开(公告)号：US4835224A
公开(公告)日：1989-05-30
申请号：US173349
申请日：1988-03-24
申请人： Andreas Ruckes , Werner Rasshofer , Klaus Konig , Richard Kopp
发明人： Andreas Ruckes , Werner Rasshofer , Klaus Konig , Richard Kopp
IPC分类号： C08G18/10 , C08G18/16 , C08G18/22 , C08G18/30 , C08G18/32 , C08G18/46 , C08G18/50 , C08G18/64
CPC分类号： C08G18/5048 , C08G18/10 , C08G18/4615 , C08G18/4623
摘要： Polyamines are produced by hydrolyzing an isocyanate compound in the presence of at least one of a selected group of catalysts and a water miscible polar organic solvent in substantially homogeneous phase at 40.degree.-170.degree. C. The catalyst employed is selected from potassium hydroxide, rubidium hydroxide, cesium hydroxide, potassium alcoholates, rubidium alcoholates, cesium alcoholates, potassium carboxylates, rubidium carboxylates and cesium carboxylates. These polyamines are useful in the production of polyurethane(urea)s.
摘要翻译：多胺通过在选择的催化剂组和水混溶性极性有机溶剂中的至少一种存在下，在40-170℃基本上均匀相中水解异氰酸酯化合物来制备。所用催化剂选自氢氧化钾，铷氢氧化物，氢氧化铯，醇钾，铷醇化物，醇铯，羧酸钾，羧酸铷和羧酸铯。这些多胺可用于生产聚氨酯（尿素）。

3. 发明授权

US4843108A Process for the production of polyamines 失效
标题翻译：多胺生产工艺
公开(公告)号：US4843108A
公开(公告)日：1989-06-27
申请号：US173350
申请日：1988-03-24
申请人： Andreas Ruckes , Werner Rasshofer , Klaus Konig , Richard Kopp
发明人： Andreas Ruckes , Werner Rasshofer , Klaus Konig , Richard Kopp
IPC分类号： C08G18/08 , C08G18/00 , C08G18/10 , C08G18/30 , C08G18/32 , C08G18/40 , C08G18/50 , C08G18/64
CPC分类号： C08G18/5048 , C08G18/10
摘要： Polyamines are produced by hydrolyzing isocyanate compounds having an NCO content of from 0.5 to 40 wt. % with from 0.75 to 40 moles of water per equivalent of NCO groups in the presence of from 0.021 to 0.099 wt. % sodium hydroxide and at least 10 wt. % water-miscible polar organic solvent containing nitrile, ketone, sulfoxide or ether groups having a boiling point of from 56.degree. to 250.degree. C. The reaction mixture is maintained in a homogeneous phase. The reaction is carried out at 40.degree. to 170.degree. C. These polyamines are useful in the production of polyurethane(urea)s.
摘要翻译：多胺通过水解NCO含量为0.5〜40重量％的异氰酸酯化合物来制造。在0.021至0.099重量％的存在下，每当量NCO基团具有0.75至40摩尔水。％氢氧化钠和至少10wt。含有沸点为56〜250℃的腈，酮，亚砜或醚基的％水混溶性极性有机溶剂。将反应混合物保持在均匀相中。反应在40℃至170℃下进行。这些多胺可用于生产聚氨酯（尿素）。

4. 发明授权

US5705594A Polyamine crosslinking agent formulation and its preparation 失效
标题翻译：多胺交联剂配方及其制备
公开(公告)号：US5705594A
公开(公告)日：1998-01-06
申请号：US767564
申请日：1996-12-16
申请人： Klaus Konig , Otto Neuner , Werner Rasshofer
发明人： Klaus Konig , Otto Neuner , Werner Rasshofer
IPC分类号： C07D251/34 , C08G59/50 , C08J3/24 , C08K5/3492 , C08L63/00 , C08L73/02 , C08L79/02 , C08G18/08 , C08G18/10
CPC分类号： C08G59/5086 , C07D251/34
摘要： Liquid polyamine crosslinking agent formulations based on trimerized toluylene 2,4- and/or 2,6-diisocyanate, with formation of an isocyanurate structure and hydrolysis of the isocyanate groups to amine groups, are described. The novel crosslinking agent formulations have a content of 40 to 80% of the total weight of the solids content of the crosslinking agent formulation of 1,3,5-tris-(3-amino-4-methyl-phenyl,2-methyl-3-aminophenyl) isocyanurate (I) which is not further condensed, and a content of not more than 1.0% of the total weight of the crosslinking agent formulations of toluylene-2,4- and/or -2,6-diamine (III). For the preparation, toluylene diisocyanate is trimerized, to form the isocyanurate structure, until 10 to 25% of the NCO groups have been reacted. The toluylene diisocyanate which has not undergone condensation is then distilled off, the bottom product formed by this operation is taken up directly in a solvent A and the 30 to 70% strength by weight solution formed by this procedure is metered into a hydrolysis in water/N,N-dialkyl-carboxylic acid amide in the presence of a catalytic amount of a basic catalyst. After the hydrolysis, the crosslinking agent formulations are brought to a solids content of 35 to 60% of the total weight of the formulation by distilling off a portion of the solvents and adding a solvent B.
摘要翻译：描述了基于三聚甲苯2,4-和/或2,6-二异氰酸酯的液态多胺交联剂制剂，其形成异氰脲酸酯结构和将异氰酸酯基团水解为胺基。新型交联剂配方的含量为交联剂配方的1,3,5-三（3-氨基-4-甲基 - 苯基，2-甲基 - 苯基） - 苯胺的固体含量的总重量的40-80％ 3-氨基苯基）异氰脲酸酯（I），其不再进一步缩合，并且不大于甲苯-2,4-和/或-2,6-二胺（III）的交联剂配方的总重量的1.0重量％）。为了制备，将甲苯二异氰酸酯进行三聚，形成异氰脲酸酯结构，直到10〜25％的NCO基团都已反应。然后蒸馏除去未进行冷凝的甲苯二异氰酸酯，将通过该操作形成的底部产物直接溶于溶剂A中，并将通过该方法形成的30-70重量％的重量浓度的溶液计量加入水/ N，N-二烷基 - 羧酸酰胺在催化量的碱性催化剂存在下反应。水解后，通过蒸馏掉一部分溶剂并加入溶剂B使交联剂配方的固体含量达到制剂总重量的35至60％。

5. 发明授权

US5283364A Hydrolysis process for polyamines 失效
标题翻译：多胺的水解过程
公开(公告)号：US5283364A
公开(公告)日：1994-02-01
申请号：US4808
申请日：1993-01-15
申请人： Werner Rasshofer , Klaus Konig , Hans-Joachim Meiners , Gerhard Grogler
发明人： Werner Rasshofer , Klaus Konig , Hans-Joachim Meiners , Gerhard Grogler
IPC分类号： C08G18/10 , C08G18/46 , C08G18/50 , C07C85/00
CPC分类号： C08G18/5048 , C08G18/10 , C08G18/4623
摘要： Polyamines containing primary amino groups are made by hydrolyzing an isocyanate with water in the presence of a solvent which is a carboxylic acid amide. The solvent must be used in a quantity of at least 10% by weight solvent based on 100% by weight of isocyanate. The weight ratio of solvent to water must be from 3 to 200. A homogeneous phase is maintained during the hydrolysis which is carried out at temperatures of from 20.degree. to 210.degree. C. A not incorporable basic and/or metal catalyst particularly alkali metal hydroxides may be employed. The polyamines produced by this process are particularly useful for the production of polyurethanes.
摘要翻译：含羧基酰胺的溶剂存在下，通过用水水解异氰酸酯制备含有伯氨基的多胺。溶剂必须使用至少10重量％的溶剂，基于100重量％的异氰酸酯。溶剂与水的重量比必须为3至200.在水解期间保持均相，其在20至210℃的温度下进行。不合并的碱性和/或金属催化剂，特别是碱金属氢氧化物可以被雇用。通过该方法生产的多胺特别可用于生产聚氨酯。

6. 发明授权

US4525590A Simplified process for the production of polyamines by the alkaline hydrolysis of compounds containing NCO-groups 失效
标题翻译：通过碱性水解含有NCO基团的化合物制备多胺的简化方法
公开(公告)号：US4525590A
公开(公告)日：1985-06-25
申请号：US398493
申请日：1982-07-15
申请人： Werner Rasshofer , Klaus Konig , Holger Meyborg , Walter Meckel , Armin Zenner
发明人： Werner Rasshofer , Klaus Konig , Holger Meyborg , Walter Meckel , Armin Zenner
IPC分类号： C07D251/34 , C07B61/00 , C07C67/00 , C07C213/02 , C07C239/00 , C07C265/02 , C07C265/12 , C07C269/02 , C07C271/20 , C07C271/46 , C07C273/18 , C07C275/00 , C07C275/30 , C07C275/40 , C07C275/62 , C08G18/00 , C08G18/10 , C08G18/50 , C08G18/64 , C08G18/83 , C07C125/06 , C07C127/15 , C07C127/24
CPC分类号： C08G18/83 , C08G18/10 , C08G18/5048 , C08G18/6415
摘要： The invention relates to an improved process for the production of polyamines containing urethane and/or urea and/or biuret and/or isocyanurate groups and, preferably, also alkylene ether, carbonate and/or acetal groups by the alkaline hydrolysis of corresponding compounds containing terminal aliphatic and/or aromatic isocyanate groups.To this end, the compounds containing terminal NCO-groups, preferably NCO-preadducts, are converted by means of selected bases into the carbamates and neutralized by introduction into equivalent quantities of acid or by the simultaneous introduction of the components in equivalent quantities into a reaction vessel, after which the polyamines are directly isolated by methods known per se.The invention also relates to the use of the polyamines obtained by the process for the production of polyurethanes.
摘要翻译：本发明涉及一种用于生产含氨基甲酸酯和/或脲和/或缩二脲和/或异氰脲酸酯基团的多胺的改进方法，并且优选还通过碱性水解含有末端的相应化合物的亚烷基醚，碳酸酯和/或缩醛基团脂族和/或芳族异氰酸酯基团。为此，含有末端NCO基团，优选NCO-前加合物的化合物通过选定的碱被转化成氨基甲酸酯并通过引入等量的酸中和或通过同时引入相当量的组分进入反应然后通过本身已知的方法直接分离多胺。本发明还涉及通过该方法生产聚氨酯得到的多胺的用途。

7. 再颁专利

USRE32677E Polyamines, a process for the production of polyamines and their use in the production of polyurethanes 失效
标题翻译：聚胺，一种生产聚胺的方法及其在聚氨酯生产中的应用
公开(公告)号：USRE32677E
公开(公告)日：1988-05-24
申请号：US848607
申请日：1986-04-07
申请人： Werner Rasshofer , Gerhard Grogler , Klaus Konig , Dieter Dieterich
发明人： Werner Rasshofer , Gerhard Grogler , Klaus Konig , Dieter Dieterich
IPC分类号： C08G18/00 , C07C67/00 , C07C209/00 , C07C209/62 , C07C211/13 , C08G18/10 , C08G18/32 , C08G18/50 , C08G18/64 , C08G18/83
CPC分类号： C08G18/83 , C08G18/10 , C08G18/5048 , C08G18/6415
摘要： The invention relates to a simplified, economic process for the production of polyamines by the alkaline hydrolysis of compounds containing terminal aromatic and/or aliphatic isocyanate groups (including modified isocyanates or NCO-prepolymers and semi-prepolymers with NCO-contents of from 0.5 to 40% by weight), with strong aqueous bases, direct isolation of the polyamines from the carbamate stage being possible by thermal carbamate decomposition and/or solvent extraction.The invention also relates to the use of the aromatic and/or aliphatic polyamines containing primary NH.sub.2 -groups obtainable by the process according to the invention for the production of polyurethanes, such as optionally cellular polyurethane plastics and polyurethane foams.

8. 发明授权

US4540720A Polyamines, a process for the production of polyamines and their use in the production of polyurethanes 失效
标题翻译：聚胺，一种生产聚胺的方法及其在聚氨酯生产中的应用
公开(公告)号：US4540720A
公开(公告)日：1985-09-10
申请号：US401472
申请日：1982-07-26
申请人： Werner Rasshofer , Gerhard Grogler , Klaus Konig , Dieter Dieterich
发明人： Werner Rasshofer , Gerhard Grogler , Klaus Konig , Dieter Dieterich
IPC分类号： C08G18/00 , C07C67/00 , C07C209/00 , C07C209/62 , C07C211/13 , C08G18/10 , C08G18/32 , C08G18/50 , C08G18/64 , C08G18/83 , C07C127/15 , C07C127/24
CPC分类号： C08G18/83 , C08G18/10 , C08G18/5048 , C08G18/6415
摘要： The invention relates to a simplified, economic process for the production of polyamines by the alkaline hydrolysis of compounds containing terminal aromatic and/or aliphatic isocyanate groups (including modified isocyanates or NCO-prepolymers and semi-prepolymers with NCO-contents of from 0.5 to 40% by weight), with strong aqueous bases, direct isolation of the polyamines from the carbamate stage being possible by thermal carbamate decomposition and/or solvent extraction.The invention also relates to the use of the aromatic and/or aliphatic polyamines containing primary NH.sub.2 -groups obtainable by the process according to the invention for the production of polyurethanes, such as optionally cellular polyurethane plastics and polyurethane foams.
摘要翻译：本发明涉及通过碱性水解含有末端芳族和/或脂族异氰酸酯基团的化合物（包括NCO-含量为0.5至40的改性异氰酸酯或NCO-预聚物和半预聚物来生产多胺的简化经济方法通过强碱水溶液，通过热氨基甲酸酯分解和/或溶剂萃取可以直接从氨基甲酸酯阶段分离多胺。本发明还涉及通过根据本发明的方法可获得的含有伯NH 2基团的芳族和/或脂族多胺用于生产聚氨酯，例如任选的细胞聚氨酯塑料和聚氨酯泡沫的用途。

9. 发明授权

US4680367A Process for the production of urea group-containing polyisocyanates 失效
标题翻译：制备含脲基的多异氰酸酯的方法
公开(公告)号：US4680367A
公开(公告)日：1987-07-14
申请号：US783590
申请日：1985-10-03
申请人： Richard Kopp , Gerhard Grogler , Heinrich Hess , Klaus Konig
发明人： Richard Kopp , Gerhard Grogler , Heinrich Hess , Klaus Konig
IPC分类号： C08G18/00 , B01J13/00 , C07C273/18 , C08G18/02 , C08G18/08 , C08G18/30 , C08G18/70 , C08G18/72 , C08G18/78 , C08G18/80 , C08G18/83
CPC分类号： C08G18/703 , C07C273/1809 , C08G18/7825 , C08G18/8045
摘要： The present invention is directed to a process for the production of urea group-containing, finely divided solid polyisocyanates by emulsifying or suspending a urea group-free organic polyisoycanate in an excess of water so that said organic polyisocyanate amounts to about 1 to 65% by weight of the reaction mixture, said water containing about 0.01 to 5% by weight, based on the aqueous phase, of a protective colloid and reacting the organic polyisocyanate with water to yeild a urea group-containing polyisocyanate.
摘要翻译：本发明涉及通过在过量的水中乳化或悬浮不含脲基团的有机聚异氰酸酯来制备含尿素基团的细分固体多异氰酸酯的方法，使得所述有机多异氰酸酯的量为约1至65％反应混合物的重量，所述水含有基于水相的约0.01至5重量％的保护胶体，并使有机多异氰酸酯与水反应以产生含脲基的多异氰酸酯。

10. 发明授权

US4734532A Process for the preparation of 4,4'-dinitrodibenzyls 失效
标题翻译：制备4,4'-二硝基二苄基的方法
公开(公告)号：US4734532A
公开(公告)日：1988-03-29
申请号：US871018
申请日：1986-06-04
申请人： Richard Kopp , Gerhard Grogler , Klaus Konig , Manfred Schmidt
发明人： Richard Kopp , Gerhard Grogler , Klaus Konig , Manfred Schmidt
IPC分类号： C07C67/00 , C07C201/00 , C07C201/12 , C07C205/06 , C07C205/12 , C07C79/10
CPC分类号： C07C201/12
摘要： 4,4'-dinitrodibenzyls are prepared by reaction of 4-nitrotoluenes, in the presence of an organic solvent and/or diluent, with an alkali metal-alcoholate and/or an alkaline earth metal alcoholate, and subsequent treatment of the reaction mixture with an aqueous solution of hypohalous acids and/or their salts or with chlorine, bromine or an aqueous solution of hydrogen peroxide and/or its salts, or with organic or inorganic peracids and/or their salts.
摘要翻译： 4,4'-二硝基二苄基通过4-硝基甲苯在有机溶剂和/或稀释剂存在下与碱金属醇盐和/或碱土金属醇化物反应制备，随后用反应混合物处理次卤酸和/或其盐的水溶液或氯，溴或过氧化氢和/或其盐的水溶液，或与有机或无机过酸和/或其盐的水溶液。

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