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1. 发明授权

US5283364A Hydrolysis process for polyamines 失效
标题翻译：多胺的水解过程
公开(公告)号：US5283364A
公开(公告)日：1994-02-01
申请号：US4808
申请日：1993-01-15
申请人： Werner Rasshofer , Klaus Konig , Hans-Joachim Meiners , Gerhard Grogler
发明人： Werner Rasshofer , Klaus Konig , Hans-Joachim Meiners , Gerhard Grogler
IPC分类号： C08G18/10 , C08G18/46 , C08G18/50 , C07C85/00
CPC分类号： C08G18/5048 , C08G18/10 , C08G18/4623
摘要： Polyamines containing primary amino groups are made by hydrolyzing an isocyanate with water in the presence of a solvent which is a carboxylic acid amide. The solvent must be used in a quantity of at least 10% by weight solvent based on 100% by weight of isocyanate. The weight ratio of solvent to water must be from 3 to 200. A homogeneous phase is maintained during the hydrolysis which is carried out at temperatures of from 20.degree. to 210.degree. C. A not incorporable basic and/or metal catalyst particularly alkali metal hydroxides may be employed. The polyamines produced by this process are particularly useful for the production of polyurethanes.
摘要翻译：含羧基酰胺的溶剂存在下，通过用水水解异氰酸酯制备含有伯氨基的多胺。溶剂必须使用至少10重量％的溶剂，基于100重量％的异氰酸酯。溶剂与水的重量比必须为3至200.在水解期间保持均相，其在20至210℃的温度下进行。不合并的碱性和/或金属催化剂，特别是碱金属氢氧化物可以被雇用。通过该方法生产的多胺特别可用于生产聚氨酯。

2. 再颁专利

USRE32677E Polyamines, a process for the production of polyamines and their use in the production of polyurethanes 失效
标题翻译：聚胺，一种生产聚胺的方法及其在聚氨酯生产中的应用
公开(公告)号：USRE32677E
公开(公告)日：1988-05-24
申请号：US848607
申请日：1986-04-07
申请人： Werner Rasshofer , Gerhard Grogler , Klaus Konig , Dieter Dieterich
发明人： Werner Rasshofer , Gerhard Grogler , Klaus Konig , Dieter Dieterich
IPC分类号： C08G18/00 , C07C67/00 , C07C209/00 , C07C209/62 , C07C211/13 , C08G18/10 , C08G18/32 , C08G18/50 , C08G18/64 , C08G18/83
CPC分类号： C08G18/83 , C08G18/10 , C08G18/5048 , C08G18/6415
摘要： The invention relates to a simplified, economic process for the production of polyamines by the alkaline hydrolysis of compounds containing terminal aromatic and/or aliphatic isocyanate groups (including modified isocyanates or NCO-prepolymers and semi-prepolymers with NCO-contents of from 0.5 to 40% by weight), with strong aqueous bases, direct isolation of the polyamines from the carbamate stage being possible by thermal carbamate decomposition and/or solvent extraction.The invention also relates to the use of the aromatic and/or aliphatic polyamines containing primary NH.sub.2 -groups obtainable by the process according to the invention for the production of polyurethanes, such as optionally cellular polyurethane plastics and polyurethane foams.

3. 发明授权

US4540720A Polyamines, a process for the production of polyamines and their use in the production of polyurethanes 失效
标题翻译：聚胺，一种生产聚胺的方法及其在聚氨酯生产中的应用
公开(公告)号：US4540720A
公开(公告)日：1985-09-10
申请号：US401472
申请日：1982-07-26
申请人： Werner Rasshofer , Gerhard Grogler , Klaus Konig , Dieter Dieterich
发明人： Werner Rasshofer , Gerhard Grogler , Klaus Konig , Dieter Dieterich
IPC分类号： C08G18/00 , C07C67/00 , C07C209/00 , C07C209/62 , C07C211/13 , C08G18/10 , C08G18/32 , C08G18/50 , C08G18/64 , C08G18/83 , C07C127/15 , C07C127/24
CPC分类号： C08G18/83 , C08G18/10 , C08G18/5048 , C08G18/6415
摘要： The invention relates to a simplified, economic process for the production of polyamines by the alkaline hydrolysis of compounds containing terminal aromatic and/or aliphatic isocyanate groups (including modified isocyanates or NCO-prepolymers and semi-prepolymers with NCO-contents of from 0.5 to 40% by weight), with strong aqueous bases, direct isolation of the polyamines from the carbamate stage being possible by thermal carbamate decomposition and/or solvent extraction.The invention also relates to the use of the aromatic and/or aliphatic polyamines containing primary NH.sub.2 -groups obtainable by the process according to the invention for the production of polyurethanes, such as optionally cellular polyurethane plastics and polyurethane foams.
摘要翻译：本发明涉及通过碱性水解含有末端芳族和/或脂族异氰酸酯基团的化合物（包括NCO-含量为0.5至40的改性异氰酸酯或NCO-预聚物和半预聚物来生产多胺的简化经济方法通过强碱水溶液，通过热氨基甲酸酯分解和/或溶剂萃取可以直接从氨基甲酸酯阶段分离多胺。本发明还涉及通过根据本发明的方法可获得的含有伯NH 2基团的芳族和/或脂族多胺用于生产聚氨酯，例如任选的细胞聚氨酯塑料和聚氨酯泡沫的用途。

4. 发明授权

US4294934A Process for the production of elastic, optionally cellular, polyurethane ureas 失效
标题翻译：用于生产弹性，任选细胞的聚氨酯脲的方法
公开(公告)号：US4294934A
公开(公告)日：1981-10-13
申请号：US164752
申请日：1980-06-30
申请人： Gerhard Grogler , Jurgen Schwindt , Otto Ganster , Hans-Joachim Meiners , Hans-Dieter Ruprecht
发明人： Gerhard Grogler , Jurgen Schwindt , Otto Ganster , Hans-Joachim Meiners , Hans-Dieter Ruprecht
IPC分类号： C08G18/00 , C08G18/10 , C08G18/72 , C08G18/76 , C08G18/18 , C08G18/22
CPC分类号： C08G18/7671 , C08G18/10 , C08G2101/0008 , C08G2350/00 , C08G2380/00 , C08G2410/00 , Y10S528/906
摘要： The instant invention is directed to a process for the production of polyurethane urea elastomers having a gross density of more than 200 kg/m.sup.3 comprising: casting a reaction mixture of(A) an isocyanate prepolymer produced from(a) 1 mole of a compound containing at least 2 Zerewitinoff-active hydrogen atoms and having a molecular weight of from 400 to 10,000 and(b) 2 to 10 moles of diisocyanatodiphenylmethane,(B) an aromatic diamine, and(C) 0 to 50 mole percent, based on component (B), of a polyol containing primary hydroxyl groups and having a molecular weight of from 62 to 6000, the equivalent ratio between component (A) and components (B) + (C) amounting to between 0.9:1 and 1.3:1,into a mold, hardening the reaction mixture in the mold and subsequently removing it from the mold, the improvement wherein said isocyanate prepolymer (A) has been produced using an isomer mixture comprising:from 15 to 80 mole percent of 2,4'-diisocyanatodiphenylmethane,from 20 to 85 mole percent of 4,4'-diisocyanatodiphenylmethane, andfrom 0 to 20 mole percent of 2,2'-diisocyanatodiphenylmethane.
摘要翻译：本发明涉及生产总密度大于200kg / m 3的聚氨酯脲弹性体的方法，包括：浇铸（A）异氰酸酯预聚物的反应混合物，该异氰酸酯预聚物由（a）1摩尔含有至少2个Zerewitinoff活性氢原子，分子量为400至10,000，和（b）2至10摩尔二异氰酸二苯基甲烷，（B）芳族二胺和（C）0至50摩尔％，基于组分（ B），含有伯羟基并且分子量为62至6000的多元醇，组分（A）和组分（B）+（C）之间的当量比为0.9:1至1.3:1，转化为模具，使模具中的反应混合物硬化，随后将其从模具中除去，改进之处在于所述异氰酸酯预聚物（A）已经使用异构体混合物制备，所述异构体混合物包含：15至80摩尔％的2,4'-二异氰酸根合二苯基甲烷， 20至85摩尔％o f 4,4'-二异氰酸二苯基甲烷和0至20摩尔％的2,2'-二异氰酸二苯基甲烷。

5. 发明授权

US4902825A N,N'-bis(trans-4-isocyanatocyclohexyl)urea, a process for its preparation and its use 失效
标题翻译： N，N'-双（反式-4-异氰酸根合环己基）脲，其制备方法及其用途
公开(公告)号：US4902825A
公开(公告)日：1990-02-20
申请号：US255915
申请日：1988-10-11
申请人： Andreas Ruckes , Werner Rasshofer , Richard Kopp , Gerhard Grogler
发明人： Andreas Ruckes , Werner Rasshofer , Richard Kopp , Gerhard Grogler
IPC分类号： C07C67/00 , C07C239/00 , C07C275/26 , C08G18/46 , C08G18/50 , C08G18/78 , C08G18/80
CPC分类号： C08G18/8045 , C07C275/26 , C08G18/4615 , C08G18/4623 , C08G18/5048 , C08G18/7825
摘要： The present invention relates to N,N'-bis-(4-isocyanatocyclohexyl)urea obtained from the reaction with water of cyclohexane-1,4-diisocyanate having a high trans isomer content. This invention further relates to the process for preparing the N,N'-bis(4-isocyanatocyclohexyl)urea and to its use in the synthesis of polyurethanes.
摘要翻译：本发明涉及由与反式异构体含量高的环己烷-1,4-二异氰酸酯与水的反应得到的N，N'-双（4-异氰酸根合环己基）脲。本发明还涉及制备N，N'-双（4-异氰酸根合环己基）脲的方法及其在合成聚氨酯中的用途。

6. 发明授权

US4390640A Process for the production of optionally-foamed polyurethanes 失效
标题翻译：用于生产任选发泡聚氨酯的方法
公开(公告)号：US4390640A
公开(公告)日：1983-06-28
申请号：US342303
申请日：1982-01-25
申请人： Werner Rasshofer , Geza Avar , Hans-Albrecht Freitag , Gerhard Grogler , Richard Kopp
发明人： Werner Rasshofer , Geza Avar , Hans-Albrecht Freitag , Gerhard Grogler , Richard Kopp
IPC分类号： C08G18/00 , C08G18/22 , C08G18/24 , C08J9/02 , C08G18/14
CPC分类号： C08G18/246
摘要： This invention relates to a process for the production of polyurethanes, particularly polyurethane foam moldings having a compact skin and a cellular core, using special tin activators.
摘要翻译：本发明涉及使用特殊的锡活化剂来生产聚氨酯的方法，特别是具有紧密表皮和细胞芯的聚氨酯泡沫塑料模制品。

7. 发明授权

US4665177A Tetrahydropyrimidines, a process for their production and their use as catalysts in the production of polyurethane plastics 失效
标题翻译：四氢嘧啶，它们的生产工艺及其在聚氨酯塑料生产中用作催化剂
公开(公告)号：US4665177A
公开(公告)日：1987-05-12
申请号：US762347
申请日：1985-08-05
申请人： Werner Rasshofer , Gerhard Grogler , Richard Kopp
发明人： Werner Rasshofer , Gerhard Grogler , Richard Kopp
IPC分类号： C07D239/06 , C08G18/20
CPC分类号： C07D239/06 , C08G18/20
摘要： This invention relates to new tetrahydropyrimidines, to a process for their production and to their use as catalysts in the production of polyurethane plastics, including polyurethane foams.
摘要翻译：本发明涉及新的四氢嘧啶，它们的生产方法和用作生产聚氨酯塑料（包括聚氨酯泡沫）中的催化剂。

8. 发明授权

US4368278A Process for the production of polyurethanes using cyclic N-hydroxyalkyl-substituted compounds containing amidine groups as catalysts 失效
标题翻译：使用含有脒基作为催化剂的环状N-羟基烷基取代的化合物生产聚氨酯的方法
公开(公告)号：US4368278A
公开(公告)日：1983-01-11
申请号：US251011
申请日：1981-04-03
申请人： Werner Rasshofer , Gerhard Grogler , Kurt Findeisen
发明人： Werner Rasshofer , Gerhard Grogler , Kurt Findeisen
IPC分类号： C08G18/00 , C08G18/18 , C08G18/20 , C08G18/14
CPC分类号： C08G18/2009
摘要： A polyurethane is made by reacting a polyisocyanate with a compound having at least two isocyanate-reactive hydrogen atoms and having a molecular weight of from 400 to 10,000 in the presence of a catalyst. The catalyst employed is a cyclic N-hydroxyalkyl-substituted compound containing an amidine group. Polyurethanes made in accordance with this process are useful as shoe soles, upholstery material, sound insulating materials, coating compositions, packaging materials and mattresses.
摘要翻译：通过使多异氰酸酯与具有至少两个异氰酸酯反应性氢原子且在催化剂存在下的分子量为400至10,000的化合物反应制备聚氨酯。所使用的催化剂是含有脒基的环状N-羟烷基取代的化合物。根据该方法制备的聚氨酯可用作鞋底，装饰材料，隔音材料，涂料组合物，包装材料和床垫。

9. 发明授权

US5077339A Heat-curing reactive powders based on polyurethanes 失效
标题翻译：基于聚氨酯的热固化活性粉末
公开(公告)号：US5077339A
公开(公告)日：1991-12-31
申请号：US621200
申请日：1990-11-30
申请人： Gerhard Grogler , Heinrich Hess , Richard Kopp , Werner Rasshofer
发明人： Gerhard Grogler , Heinrich Hess , Richard Kopp , Werner Rasshofer
IPC分类号： C08G18/00 , C08G18/08 , C08G18/42 , C08G18/46 , C08G18/50 , C08G18/65 , C08G18/70 , C08G18/76 , C08G18/78 , C08G18/79 , C08G18/80 , C09D5/46
CPC分类号： C08G18/7818 , C08G18/0871 , C08G18/4238 , C08G18/4615 , C08G18/5048 , C08G18/6505 , C08G18/6529 , C08G18/703 , C08G18/7678 , C08G18/798 , C08G18/8038 , C08G2140/00 , C08G2150/20 , C08G2170/20 , Y10S525/902 , Y10S525/936
摘要： The present invention relates to the preparation of powdered heat-curable reaction mixtures in which melt suspension of (a) solid polyisocyanates having melting points above about 60.degree. C., (b) molten high molecular weight isocyanate-reactive compounds having molecular weights of from 400 to 10,000 that have melting or softening points of 50.degree. C. to 150.degree. C., and (c) optionally, solid or liquid low molecular weight chain-extending or crosslinking compounds having molecular weights of from 62 to 399, are added to an inert solvent containing an emulsifier, thereby forming powdered heat-curable reaction mixtures in which components (a), (b), and (c) remain in uncrossedlinked form. The invention further relates to the use of the heat-curing reaction mixtures for the preparation of high-quality polyurethane polyurea plastics.
摘要翻译：本发明涉及粉末状热固化反应混合物的制备，其中（a）熔点高于约60℃的固体聚异氰酸酯的熔体悬浮液，（b）熔融的高分子量异氰酸酯反应性化合物，其分子量为 400至10,000，其熔点或软化点为50℃至150℃，和（c）任选地，分子量为62至399的固体或液体低分子量链延长或交联化合物加入到含有乳化剂的惰性溶剂，从而形成其中组分（a），（b）和（c）保持非交联形式的粉末状热固化反应混合物。本发明还涉及热固化反应混合物用于制备高品质聚氨酯聚脲塑料的用途。

10. 发明授权

US4663415A Process for the preparation of stabilized polyamines, stabilized polyamines with retarded reactivity and their use for polyurethane production 失效
标题翻译：用于制备稳定的多胺，具有延迟反应性的稳定的多胺及其用于聚氨酯生产的方法
公开(公告)号：US4663415A
公开(公告)日：1987-05-05
申请号：US759818
申请日：1985-07-29
申请人： Gerhard Grogler , Richard Kopp , Heinrich Hess , Werner Rasshofer
发明人： Gerhard Grogler , Richard Kopp , Heinrich Hess , Werner Rasshofer
IPC分类号： C08G18/00 , C08G18/08 , C08G18/10 , C08G18/32 , C08G18/65 , C08G18/66 , C09D175/04 , C08G18/79
CPC分类号： C08G18/6618 , C08G18/10 , C08G18/3253
摘要： This invention relates to a process for the production of solid polyamines stabilized by a polyadduct covering and showing retarded reactivity comprising reacting(1) one or more solid organic polyamines in particulate form, said polyamines containing at least two primary and/or secondary amino groups and having melting points above 50.degree. C., and(2) from 0.1 to 25 equivalent % of isocyanate per amine equivalent of a water insoluble, difunctional and/or higher functional polyisocyanate,said reaction being conducted at a temperature below the melting point of said solid polyamine, and being conducted in the presence of(3) a liquid medium selected from the group consisting of(a) organic compounds containing two or more hydroxy groups and having molecular weights of from 62 to 10,000,(b) plasticizers,(c) water, and(d) mixtures thereofto form a suspension of polyadduct-covered stabilized polyamines in the liquid medium.
摘要翻译：本发明涉及用于生产由多加成分稳定的固体多胺的方法，其覆盖并显示延迟反应性，包括使（1）一种或多种颗粒形式的固体有机多胺，所述多胺含有至少两个伯和/或仲氨基和具有高于50℃的熔点，和（2）0.1至25当量异氰酸酯/胺当量的水不溶性，双官能和/或更高官能的多异氰酸酯，所述反应在低于所述固体多胺，并且在（3）选自（a）含有两个或多个羟基并且分子量为62至10,000的有机化合物的组分的存在下进行，（b）增塑剂，（c ）水，和（d）它们的混合物以在液体介质中形成多加合物覆盖的稳定化多胺的悬浮液。

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