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1. 发明授权

US4734444A Curable mixtures containing N-sulfonylaminosulfonium salts as cationically active catalysts 失效
标题翻译：含有N-磺酰基氨基锍盐作为阳离子活性催化剂的固化混合物
公开(公告)号：US4734444A
公开(公告)日：1988-03-29
申请号：US13965
申请日：1987-02-12
申请人： Andreas Henne , Wolfram Ochs , Helmut Tesch , Gunnar Schornick , Reinhold J. Leyrer
发明人： Andreas Henne , Wolfram Ochs , Helmut Tesch , Gunnar Schornick , Reinhold J. Leyrer
IPC分类号： C08G59/68 , C08K5/43 , G03F7/029 , C08G59/72
CPC分类号： G03F7/029 , C08G59/687 , C08K5/43 , Y10S430/115
摘要： Mixtures which are curable by heating or irradiation with actinic light contain one or more cationically curable compounds, such as an epoxy, an olefinically unsaturated monomer, amino resin or phenolic resin, and as a cationically active curing catalyst one or more N-sulfonylamino-sulfonium salts of the formula ##STR1## such as N-p-toluenesulfonyl-N-methylaminodiphenylsulfonium hexafluorophosphate with or without quinones or peroxides are suitable, inter alia, for producing moldings, coatings, relief images and resist patterns.
摘要翻译：通过加热或用光化光照射可固化的混合物含有一种或多种阳离子固化化合物，例如环氧树脂，烯属不饱和单体，氨基树脂或酚醛树脂，以及作为阳离子活性固化催化剂，一种或多种N-磺酰基氨基 - 锍具有或不具有醌或过氧化物的式“IMAGE”的盐如N-甲苯磺酰基-N-甲基氨基二苯基锍六氟磷酸盐尤其适用于制备模制品，涂料，浮雕图像和抗蚀剂图案。

2. 发明授权

US4447520A Acylphosphine oxides and their use 失效
标题翻译：酰基氧化膦及其用途
公开(公告)号：US4447520A
公开(公告)日：1984-05-08
申请号：US409555
申请日：1982-08-19
申请人： Andreas Henne , Anton Hesse , Manfred Jacobi , Gunnar Schornick , Rudolf Vyvial , Klaus Holoch
发明人： Andreas Henne , Anton Hesse , Manfred Jacobi , Gunnar Schornick , Rudolf Vyvial , Klaus Holoch
IPC分类号： C08F2/00 , C07F9/53 , C08F2/50 , C08F4/00 , C08K5/5397 , G03F7/029 , G03C1/68
CPC分类号： G03F7/029 , C07F9/5337 , C08F2/50 , C08K5/5397 , Y10S430/124
摘要： Acylphosphine oxides of the general formula ##STR1## where R.sup.1 is methyl or ethyl, R.sup.2 is a branched or straight-chain alkyl radical or chlorine, alkoxy or hydrogen, R.sup.3 and R.sup.4 are identical or different, and are each alkyl, alkoxy, alkylthio or chlorine and R.sup.5 is hydrogen, chlorine, alkoxy, alkylthio or alkyl, may be used as photoinitiators in photopolymerizable materials.
摘要翻译：其中R1是甲基或乙基，R2是支链或直链烷基或氯，烷氧基或氢的酰基氧化膦，其中R 1是甲基或乙基，R 3和R 4是相同或不同的，并且各自是烷基，烷氧基，烷硫基或氯和R 5是氢，氯，烷氧基，烷硫基或烷基，可用作可光聚合材料中的光引发剂。

3. 发明授权

US4522693A Photopolymerizable composition with acylphosphine sulfide photoinitiator and method 失效
标题翻译：具有酰基膦硫化物光引发剂的光聚合组合物及方法
公开(公告)号：US4522693A
公开(公告)日：1985-06-11
申请号：US500429
申请日：1983-06-02
申请人： Andreas Henne , Anton Hesse , Guenter Heil , Gunnar Schornick
发明人： Andreas Henne , Anton Hesse , Guenter Heil , Gunnar Schornick
IPC分类号： C07F9/53 , C07F9/58 , C08F2/00 , C08F2/48 , C08F2/50 , C08K5/5398 , G03F7/029
CPC分类号： G03F7/029 , C07F9/5337 , C08K5/5398 , Y10S430/111 , Y10S430/122
摘要： Acylphosphine sulfides of the formula ##STR1## where R.sup.1 is alkyl, cycloalkyl or an unsubstituted or substituted phenyl, naphthyl or heterocyclic radical; R.sup.2 has the meaning of R.sup.1 and can be identical to or different from R.sup.1, or is alkoxy, unsubstituted or substituted phenoxy or phenoxyalkyl, or R.sup.1 or R.sup.2 are linked together to form a ring, which may contain further alkyl substituents and fused-on benzene rings; R.sup.3 is alkyl, a cycloaliphatic radical, substituted phenyl, an unsubstituted or substituted naphthyl or heterocyclic radical or the group ##STR2## where X is unsubstituted or substituted phenylene or an aliphatic or cycloaliphatic divalent radical; and where one or more of R.sup.1, R.sup.2 and R.sup.3 may be olefinically unsaturated.These acylphosphine sulfides can be prepared from acylphosphines and sulfur and can be used as photoinitiators in photopolymerizable compositions.
摘要翻译：其中R 1为烷基，环烷基或未取代或取代的苯基，萘基或杂环基团的酰基膦硫化物。 R 2具有R 1的含义并且可以与R 1相同或不同，或者是烷氧基，未取代或取代的苯氧基或苯氧基烷基，或者R 1或R 2连接在一起形成环，其可以含有其它烷基取代基和稠合在苯上戒指; R3是烷基，脂环族基团，取代的苯基，未取代或取代的萘基或杂环基团或基团，其中X是未取代或取代的亚苯基或脂族或脂环族二价基团; 并且其中R 1，R 2和R 3中的一个或多个可以是烯属不饱和的。这些酰基膦硫化物可以由酰基膦和硫制备，并且可以用作可光聚合组合物中的光引发剂。

4. 发明授权

US4559398A Curable epoxy resins 失效
标题翻译：可固化环氧树脂
公开(公告)号：US4559398A
公开(公告)日：1985-12-17
申请号：US636236
申请日：1984-07-31
申请人： Helmut Tesch , Andreas Henne , Manfred Heym , Herbert Stutz
发明人： Helmut Tesch , Andreas Henne , Manfred Heym , Herbert Stutz
IPC分类号： C07D233/60 , C07D521/00 , C08G59/68 , C08K5/3445
CPC分类号： C07D231/12 , C07D233/56 , C07D249/08 , C08G59/686 , C08K5/3445
摘要： A curable composition consisting ofA. 100 parts by weight of an epoxy resin,B. from 4 to 100 parts by weight of a conventional curing agent for epoxy resins, andC. from 0.1 to 5 parts by weight of an N-acylimidazole which possesses an aromatic acyl component which is substituted at the two positions ortho to the carbonyl groupcan be used to produce moldings, coatings, finishes, adhesives and composite fiber materials.
摘要翻译：由A.100重量份的环氧树脂组成的固化性组合物，B为4〜100重量份的环氧树脂的常规固化剂，以及0.1〜5重量份的N-酰基咪唑，其中，具有在羰基的邻位的两个位置被取代的芳族酰基组分可用于生产模制品，涂料，表面处理剂，粘合剂和复合纤维材料。

5. 发明申请

US20050222294A1 Acyl- and bisacylphosphine derivatives 有权
标题翻译：酰基和双酰基膦衍生物
公开(公告)号：US20050222294A1
公开(公告)日：2005-10-06
申请号：US10502658
申请日：2003-02-04
申请人： Ralf Noe , Andreas Henne , Matthias Maase
发明人： Ralf Noe , Andreas Henne , Matthias Maase
IPC分类号： C07F9/30 , C07F9/32 , C07F9/34 , C07F9/36 , C07F9/40 , C07F9/42 , C08F2/50 , C08F4/00 , G03F7/029 , C08G2/00
CPC分类号： C07F9/3294 , C07F9/3252 , C07F9/34 , C07F9/36 , C07F9/4065 , C07F9/409 , C07F9/4093 , C07F9/4096 , C07F9/425 , G03F7/029
摘要： The invention relates to the acyl- and bisacylphosphine derivatives according to formula (I), wherein Y represents O, S, NR3, N—OR3 or N—NR3R4, Z represents O, S, NR3, N—OR3, N—NR3R4 or a free pair of electrons, and FG represents a leaving group and the remaining groups are defined as in the description. The invention further relates to a method for the production of the inventive derivatives and to their use.
摘要翻译：本发明涉及式（I）的酰基和双酰基膦衍生物，其中Y代表O，S，NR 3，N-OR 3或N-NR 3， S 3 S 4 S 4，Z表示O，S，NR 3，N-OR 3，N-NR O 或者一对空电子，FG表示离去基团，其余的基团如说明书所定义。本发明还涉及本发明衍生物的制备方法及其用途。

6. 发明授权

US6153784A Removal of halides from halide-containing nitrile mixtures 失效
标题翻译：从含卤素腈混合物中除去卤化物
公开(公告)号：US6153784A
公开(公告)日：2000-11-28
申请号：US24457
申请日：1998-02-17
申请人： Heinz-Josef Kneuper , Hans-Jurgen Weyer , Horst Neuhauser , Johann-Peter Melder , Andreas Henne , Karl-Heinz Ross , Rainer Becker
发明人： Heinz-Josef Kneuper , Hans-Jurgen Weyer , Horst Neuhauser , Johann-Peter Melder , Andreas Henne , Karl-Heinz Ross , Rainer Becker
IPC分类号： B01J27/18 , B01J31/02 , C07B61/00 , C07C209/48 , C07C211/09 , C07C253/14 , C07C253/34 , C07C255/04
CPC分类号： C07C253/14 , C07C209/48 , C07C253/34
摘要： Halides are removed from halide-containing nitrile mixtures by(a) thermally treating the halide-containing nitrile mixture,(b) subsequently adding a base to the thermally treated nitrile mixture and(c) subsequently separating off the base from the nitrile mixture.Amines are prepared by(A) reacting alkyl halides with metal cyanides in an at least two-phase reaction medium in the presence of halide-containing phase-transfer catalysts to give alkanenitriles,(B) separating off the resulting halide-containing alkanenitrile mixture phase and(C) further treating the halide-containing alkanenitrile mixture phase, as described in the stages(a)-(c) removing halides from halide-containing nitrile mixtures and(d) hydrogenating nitrites obtained in stage (c) to give amines, in the presence of suspended or fixed-bed catalysts.
摘要翻译：通过（a）热处理含卤素腈混合物，（b）随后向经热处理的腈混合物中加入碱，和（c）随后将腈与腈混合物分离，从卤化物腈混合物中除去卤化物。胺通过（A）在卤化物相转移催化剂存在下在至少两相反应介质中将烷基卤与金属氰化物反应得到烷腈，（B）将所得的含卤素的烷腈混合物相分离（C）进一步处理含卤化物的腈腈混合物相，如步骤（a） - （c）所述从卤化物腈混合物中除去卤化物，和（d）氢化阶段（c）中得到的亚硝酸盐，得到胺，在悬浮或固定床催化剂存在下。

7. 发明授权

US5679868A Preparation of glutaric dialdehyde 失效
标题翻译：戊二醛的制备
公开(公告)号：US5679868A
公开(公告)日：1997-10-21
申请号：US571092
申请日：1995-12-12
申请人： Heinz-Josef Kneuper , Rainer Becker , Eugen Gehrer , Juergen Schossig , Andreas Henne
发明人： Heinz-Josef Kneuper , Rainer Becker , Eugen Gehrer , Juergen Schossig , Andreas Henne
IPC分类号： B01J21/12 , B01J29/06 , C07B61/00 , C07C45/60 , C07C47/12
CPC分类号： C07C45/60
摘要： A process for the preparation of glutaric dialdehyde by the reaction of alkoxy dihydropyrans of the general formula I ##STR1## in which R stands for C.sub.1 to C.sub.20 alkoxy, with water at temperatures ranging from 0.degree. to 150.degree. C. and pressures of from 0.01 to 50 bar in the presence of a which microporous, crystalline aluminum silicate catalyst, e.g. a beta-type zeolite or pentasil catalyst having a pore diameter greater than 5.4 .ANG..
摘要翻译：通过其中R代表C 1至C 20烷氧基的通式I（I）的烷氧基二氢吡喃与0℃至150℃温度的水反应制备戊二醛的方法，在其中的微孔结晶硅酸铝催化剂存在下，为0.01至50巴 β型沸石或pentasil催化剂，其孔径大于5.4 ANGSTROM。

8. 发明授权

US06794530B1 Process for making &ggr;-alkoxyamines 失效
标题翻译：制备γ-烷氧基胺的方法
公开(公告)号：US06794530B1
公开(公告)日：2004-09-21
申请号：US09235242
申请日：1999-01-22
申请人： Wolfgang Friedrich , Heinz-Josef Kneuper , Karsten Eller , Andreas Henne , Rolf Lebkücher
发明人： Wolfgang Friedrich , Heinz-Josef Kneuper , Karsten Eller , Andreas Henne , Rolf Lebkücher
IPC分类号： C07C20948
CPC分类号： C07C213/02 , C07C253/30 , C07C217/08 , C07C217/48 , C07C255/13 , C07C255/37
摘要： A process for preparing &bgr;-alkoxynitriles by reacting &agr;,&bgr;-unsaturated nitriles with monohydric, dihydric or trihydric alcohols in the presence of basic catalysts at from −20 to +200° C. comprises using a diazabicycloalkene catalyst of the formula I where from 1 to 4 hydrogen atoms may be independently replaced by the radicals R1 to R4, in which case R1, R2, R3, R4 are each C1-20-alkyl, C6-20-aryl or C7-20-arylalkyl, and n and m are each an integer from 1 to 6.
摘要翻译：在-20至+ 200℃的碱性催化剂存在下，通过使α，β-不饱和腈与一元，二元或三元醇反应制备β-烷氧基腈的方法包括使用式I的二氮杂双环烯烃催化剂，其中1至 4个氢原子可以独立地被基团R 1至R 4取代，其中R 1，R 2，R 3，R 4各自为C 1-20 - 烷基，C 6 -20-芳基或C7-20-芳基烷基，且n和m各自为1至6的整数。

9. 发明授权

US5910612A Preparation of anhydrous 2-amino-1-methoxypropane 失效
标题翻译：无水2-氨基-1-甲氧基丙烷的制备
公开(公告)号：US5910612A
公开(公告)日：1999-06-08
申请号：US82543
申请日：1998-05-21
申请人： Joachim Simon , Andreas Henne , Heinz Lingk
发明人： Joachim Simon , Andreas Henne , Heinz Lingk
IPC分类号： C07C213/02 , C07C213/10 , C07C217/08 , C07C209/02
CPC分类号： C07C213/02 , C07C213/10
摘要： The process for preparing anhydrous 2-amino-1-methoxypropane proceeds by(a) admixing a 2-amino-1-methoxypropane-containing water-containing reaction mixture, obtainable from the reaction of 1-methoxy-2-propanol with ammonia on a catalyst, with sodium hydroxide solution, forming an aqueous phase containing sodium hydroxide solution and a 2-amino-1-methoxypropane-containing phase,(b) separating off the 2-amino-1-methoxypropane-containing phase from the aqueous phase and(c) distilling the 2-amino-1-methoxypropane-containing phase, an azeotrope of water and 2-amino-1-methoxypropane, which is recycled to step (a) or (b), first being produced and anhydrous 2-amino-1-methoxypropane then being produced.
摘要翻译：制备无水2-氨基-1-甲氧基丙烷的方法是：（a）将可从1-甲氧基-2-丙醇反应得到的含2-氨基-1-甲氧基丙烷的含水反应混合物与氨混合，催化剂，用氢氧化钠溶液，形成含有氢氧化钠溶液和含2-氨基-1-甲氧基丙烷的相的水相，（b）从水相中分离出含2-氨基-1-甲氧基丙烷的相和（ c）蒸馏出含有2-氨基-1-甲氧基丙烷的相，再循环至步骤（a）或（b）的水和2-氨基-1-甲氧基丙烷的共沸物，首先制得无水2-氨基-1-甲氧基丙烷，然后生产1-甲氧基丙烷。

10. 发明授权

US4719297A Acylphosphine compounds and their use as photoinitiators 失效
标题翻译：酰基膦化合物及其作为光引发剂的用途
公开(公告)号：US4719297A
公开(公告)日：1988-01-12
申请号：US673218
申请日：1984-11-20
申请人： Andreas Henne , Anton Hesse , Manfred Jacobi , Guenter Wallbillich , Bernd Bronstert
发明人： Andreas Henne , Anton Hesse , Manfred Jacobi , Guenter Wallbillich , Bernd Bronstert
IPC分类号： C08K5/00 , C07F9/30 , C07F9/36 , C07F9/38 , C07F9/40 , C07F9/58 , C08F2/00 , C08F2/48 , C08F2/50 , C08K5/49 , C08K5/51 , C08K5/5313 , C08K5/5398 , C08L33/00 , C08L33/02 , C08L67/00 , G03F7/029 , C07F9/32 , C07F9/65
CPC分类号： C08K5/5398 , C07F9/307 , C07F9/36 , C07F9/4065 , C08F2/50 , C08K5/5313 , G03F7/029
摘要： Acylphosphine compounds of the formula I ##STR1## where X is oxygen, sulfur or an electron pair, R.sup.1 is R.sub.4 or OR.sup.4, R.sup.2 is --OM, where M is a monovalent cation, R.sup.3 is aryl which is substituted at least at the two positions ortho to the carbonyl group, and R.sup.4 is hydrogen, alkyl or aryl, are very effective photoinitiators for photopolymerizable materials, such as coating compositions, finishes, printing inks, unsaturated polyesters, recording media and preferably aqueous polymer dispersions or solutions.
摘要翻译：式I的酰基膦化合物其中X是氧，硫或电子对，R1是R4或OR4，R2是-OM，其中M是一价阳离子，R3是至少在两个位置被取代的芳基羰基的邻位，R4是氢，烷基或芳基，是光聚合材料如涂料组合物，表面处理剂，印刷油墨，不饱和聚酯，记录介质，优选含水聚合物分散体或溶液的非常有效的光引发剂。

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