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1. 发明授权

US4710523A Photocurable compositions with acylphosphine oxide photoinitiator 失效
标题翻译：具有酰基氧化膦光引发剂的光固化组合物
公开(公告)号：US4710523A
公开(公告)日：1987-12-01
申请号：US571794
申请日：1984-01-18
申请人： Peter Lechtken , Ingolf Buethe , Manfred Jacobi , Werner Trimborn
发明人： Peter Lechtken , Ingolf Buethe , Manfred Jacobi , Werner Trimborn
IPC分类号： C07F9/32 , C07F9/40 , C07F9/46 , C07F9/48 , C07F9/53 , C08F2/50 , C08F4/00 , C08F4/32 , G03F7/029 , C08L63/10
CPC分类号： C07F9/4065 , C07F9/3252 , C07F9/46 , C07F9/48 , C07F9/4841 , C07F9/5337 , G03F7/029
摘要： Acylphosphine oxide compounds of the general formula ##STR1## where R.sup.1 is alkyl, cyclohexyl, cyclopentyl, aryl which is unsubstituted or substituted by halogen, alkyl or alkoxy, or an S-containing or N-containing five-membered or six-membered heterocyclic radical,R.sup.2 has one of the meanings of R.sup.1 (but R.sup.1 and R.sup.2 may be identical or different) or is alkoxy, aryloxy or aralkoxy, or R.sup.1 and R.sup.2 together form a ring andR.sup.3 is an at least disubstituted phenyl, pyridyl, furyl or thienyl radical which carries, at least at the two carbon atoms adjacent to the linkage point of the carbonyl group, the substituents A and B, which may be identical or different, and each of which is alkyl, alkoxy or alkylthio of 1 to 6 carbon atoms, cycloalkyl of 5 to 7 carbon atoms, phenyl or halogen, or R.sup.3 is .alpha.-naphthyl substituted by A and B at least in the 2- and 8-positions or is .beta.-naphthyl substituted by A and B at least in the 1- and 3-positions, a process for the preparation of these acylphosphine oxide compounds from acid halides of the general formula ##STR2## where X is chlorine or bromine, and a phosphine of the general formula ##STR3## and the use of these acylphosphine oxide compounds as photoinitiators in photopolymerizable surface coatings, finishes and printing inks.
摘要翻译：其中R1是烷基，环己基，环戊基，未被取代或被卤素，烷基或烷氧基取代的芳基，或含S或N的五元或六元杂环基的酰基氧化膦化合物，R 2具有R 1的含义（但R 1和R 2可以相同或不同）或者是烷氧基，芳氧基或芳烷氧基，或者R 1和R 2一起形成环，R 3是至少二取代的苯基，吡啶基，呋喃基或噻吩基至少在与羰基的连接点相邻的两个碳原子上具有可以相同或不同的取代基A和B的基团，并且各自为1-6个碳原子的烷基，烷氧基或烷硫基 5至7个碳原子的环烷基，苯基或卤素，或R3是至少在2-和8-位被A和B取代的α-萘基，或至少在1-位上由A和B取代的β-萘基，和3-位，这些酰基氧化物的制备方法 e化合物，其中X为氯或溴的通式为“IMAGE”的酰卤，以及通式为“IMAGE”的膦，以及这些酰基氧化膦化合物作为可光聚合表面涂料，表面处理剂和印刷油墨中的光引发剂的用途。

2. 发明授权

US4666952A Photopolmerizable mixtures containing tertiary amines as photoactivators 失效
标题翻译：含有叔胺作为光活化剂的光聚合混合物
公开(公告)号：US4666952A
公开(公告)日：1987-05-19
申请号：US645297
申请日：1984-08-29
申请人： Andreas Henne , Manfred Jacobi
发明人： Andreas Henne , Manfred Jacobi
IPC分类号： C08F2/00 , C08F2/50 , G03F7/004 , G03F7/031 , C08F20/20
CPC分类号： G03F7/031 , C08F2/50
摘要： Photopolymerizable mixtures comprising one or more photopolymerizable, olefinically unsaturated compounds and one or more photoinitiators or photosensitizers, with or without other conventional additives and/or assistants, contain, as an activator, a tertiary amine of the general formula (I) ##STR1## wherein R.sup.1 and R.sup.2 are each an unsubstituted alkyl, cycloalkyl or phenyl radical, hydroxyl or alkoxy, or R.sup.1 and R.sup.2 are bonded together to form a cyclic alkylene radical, R.sup.3 has the same meanings as R.sup.1 or R.sup.2 and may furthermore be hydrogen, acyloxy or substituted benzoyloxy, and R.sup.4 and R.sup.5 are each an unsubstituted or substituted alkyl, cycloalkyl or phenyl radical, or R.sup.4 and R.sup.5 are bonded together to form a cyclic alkylene or alkyleneoxyalkylene radical.
摘要翻译：包含一种或多种可光聚合的烯属不饱和化合物和一种或多种光引发剂或光敏剂的光聚合混合物含有或不含其它常规添加剂和/或助剂，作为活化剂含有通式（I）的叔胺（I） I）其中R 1和R 2各自是未取代的烷基，环烷基或苯基，羟基或烷氧基，或R 1和R 2结合在一起形成环状亚烷基，R 3具有与R 1或R 2相同的含义，并且还可以是氢，酰氧基或取代的苯甲酰氧基，R 4和R 5各自是未取代或取代的烷基，环烷基或苯基，或者R 4和R 5结合在一起形成环状亚烷基或亚烷氧基亚烷基。

3. 发明授权

US4298738A Acylphosphine oxide compounds their preparation and use 失效
标题翻译：酰基氧化膦化合物的制备和使用
公开(公告)号：US4298738A
公开(公告)日：1981-11-03
申请号：US148665
申请日：1980-05-12
申请人： Peter Lechtken , Ingolf Buethe , Manfred Jacobi , Werner Trimborn
发明人： Peter Lechtken , Ingolf Buethe , Manfred Jacobi , Werner Trimborn
IPC分类号： C07F9/32 , C07F9/40 , C07F9/46 , C07F9/48 , C07F9/53 , C08F2/50 , C08F4/00 , C08F4/32 , G03F7/029
CPC分类号： C07F9/4065 , C07F9/3252 , C07F9/46 , C07F9/48 , C07F9/4841 , C07F9/5337 , G03F7/029
摘要： Acylphosphine oxide compounds of the general formula ##STR1## where R.sup.1 is alkyl, cyclohexyl, cyclopentyl, aryl which is unsubstituted or substituted by halogen, alkyl or alkoxy, or an S-containing or N-containing five-membered or six-membered heterocyclic radical,R.sup.2 has one of the meanings of R.sup.1 (but R.sup.1 and R.sup.2 may be identical or different) or is alkoxy, aryloxy or aralkoxy, or R.sup.1 and R.sup.2 together form a ring andR.sup.3 is an at least disubstituted phenyl, pyridyl, furyl or thienyl radical which carries, at least at the two carbon atoms adjacent to the linkage point of the carbonyl group, the substituents A and B, which may be identical or different, and each of which is alkyl, alkoxy or alkythio of 1 to 6 carbon atoms, cycloalkyl of 5 to 7 carbon atoms, phenyl or halogen, or R.sup.3 is .alpha.-naphthyl substituted by A and B at least in the 2- and 8-positions or is .beta.-naphthyl substituted by A and B at least in the 1- and 3-positions, a process for the preparation of these acylphosphine oxide compounds from acid halides of the general formula ##STR2## where X is chlorine or bromine, and a phosphine of the general formula ##STR3## and the use of these acylphosphine oxide compounds as photoinitiators in photopolymerizable surface coatings, finishes and printing inks.
摘要翻译：其中R1是烷基，环己基，环戊基，未被取代或被卤素，烷基或烷氧基取代的芳基，或含S或N的五元或六元杂环基的酰基氧化膦化合物，R 2具有R 1的含义（但R 1和R 2可以相同或不同）或者是烷氧基，芳氧基或芳烷氧基，或者R 1和R 2一起形成环，R 3是至少二取代的苯基，吡啶基，呋喃基或噻吩基至少在与羰基的连接点相邻的两个碳原子上具有可以相同或不同的取代基A和B的基团，并且各自为1至6个碳原子的烷基，烷氧基或链烯基 5至7个碳原子的环烷基，苯基或卤素，或R3是至少在2-和8-位被A和B取代的α-萘基，或至少在1-位上由A和B取代的β-萘基，和3-位，这些酰基氧化膦的制备方法其中X是氯或溴的通式为“IMAGE”的酰卤，以及通式为“IMAGE”的膦，以及这些酰基氧化膦化合物作为可光聚合表面涂料，表面处理剂和印刷油墨中的光引发剂的用途。

4. 发明授权

US4054682A Photopolymerizable composition containing a thioether sensitizer 失效
标题翻译：含有硫醚增感剂的光聚合组合物
公开(公告)号：US4054682A
公开(公告)日：1977-10-18
申请号：US757382
申请日：1977-01-06
申请人： Werner Kuesters , Rolf Osterloh , Manfred Jacobi
发明人： Werner Kuesters , Rolf Osterloh , Manfred Jacobi
IPC分类号： C08F2/00 , C08F2/50 , C09D4/00 , C09D11/101 , G03F7/031 , G03F7/038 , C08F2/46 , C08F4/00
CPC分类号： C09D11/101 , C08F2/50 , G03F7/031 , Y10S430/108 , Y10S430/122 , Y10T428/31525 , Y10T428/31529
摘要： A photopolymerizable composition containing olefinically unsaturated compounds, optional conventional additives and, as photoinitiator, a mixture of a thioether of the general formula (I): ##STR1## where R.sup.4 is phenyl, naphthyl, thienyl, furyl or styryl which may be substituted by one or more identical or different R.sup.5 's,R.sup.5 is phenyl, benzoyl, halogen, alkyl of 1 to 5 carbon atoms, alkyl having an --O--group and 1 to 5 carbon atoms, alkyl having an --S--group and 1 to 5 carbon atoms, alkoxyalkyl of 2 to 5 carbon atoms, alkaryl of 7 to 11 carbon atoms, aralkyl of 7 to 11 carbon atoms, NO.sub.2, CN, COOH or COOR.sup.6, R.sup.6 being an alkyl of 1 to 5 carbon atoms,A is the alkylene group C.sub.n H.sub.2n (n = an integer of 1 to 5) which may be substituted by one or more R.sup.4 's and/or R.sup.5 's, andR.sup.1, r.sup.2 and R.sup.3 may be identical or different and are each H, an R.sup.4 or an R.sup.5,and an organic amine.The photopolymerizable composition is suitable for the production of coatings and printing inks which can be cured by ultraviolet radiation.
摘要翻译：含有烯属不饱和化合物的可光聚合组合物，任选的常规添加剂和作为光引发剂的通式（I）的硫醚的混合物：其中R 4是苯基，萘基，噻吩基，呋喃基或苯乙烯基，其可以是被一个或多个相同或不同的R5取代，R5是苯基，苯甲酰基，卤素，1-5个碳原子的烷基，具有-O-基和1-5个碳原子的烷基，具有-S-基团的烷基和1〜 2至5个碳原子的烷氧基烷基，7至11个碳原子的烷芳基，7至11个碳原子的芳烷基，NO 2，CN，COOH或COOR 6，R 6是1至5个碳原子的烷基，A是可以被一个或多个R 4和/或R 5取代的亚烷基C n H 2n（n = 1〜5的整数），R 1，R 2和R 3可以相同或不同，各自为H，R4或R5，有机胺。

5. 发明授权

US4719297A Acylphosphine compounds and their use as photoinitiators 失效
标题翻译：酰基膦化合物及其作为光引发剂的用途
公开(公告)号：US4719297A
公开(公告)日：1988-01-12
申请号：US673218
申请日：1984-11-20
申请人： Andreas Henne , Anton Hesse , Manfred Jacobi , Guenter Wallbillich , Bernd Bronstert
发明人： Andreas Henne , Anton Hesse , Manfred Jacobi , Guenter Wallbillich , Bernd Bronstert
IPC分类号： C08K5/00 , C07F9/30 , C07F9/36 , C07F9/38 , C07F9/40 , C07F9/58 , C08F2/00 , C08F2/48 , C08F2/50 , C08K5/49 , C08K5/51 , C08K5/5313 , C08K5/5398 , C08L33/00 , C08L33/02 , C08L67/00 , G03F7/029 , C07F9/32 , C07F9/65
CPC分类号： C08K5/5398 , C07F9/307 , C07F9/36 , C07F9/4065 , C08F2/50 , C08K5/5313 , G03F7/029
摘要： Acylphosphine compounds of the formula I ##STR1## where X is oxygen, sulfur or an electron pair, R.sup.1 is R.sub.4 or OR.sup.4, R.sup.2 is --OM, where M is a monovalent cation, R.sup.3 is aryl which is substituted at least at the two positions ortho to the carbonyl group, and R.sup.4 is hydrogen, alkyl or aryl, are very effective photoinitiators for photopolymerizable materials, such as coating compositions, finishes, printing inks, unsaturated polyesters, recording media and preferably aqueous polymer dispersions or solutions.
摘要翻译：式I的酰基膦化合物其中X是氧，硫或电子对，R1是R4或OR4，R2是-OM，其中M是一价阳离子，R3是至少在两个位置被取代的芳基羰基的邻位，R4是氢，烷基或芳基，是光聚合材料如涂料组合物，表面处理剂，印刷油墨，不饱和聚酯，记录介质，优选含水聚合物分散体或溶液的非常有效的光引发剂。

6. 发明授权

US4134813A Photopolymerizable composition and its use 失效
标题翻译：光聚合组合物及其用途
公开(公告)号：US4134813A
公开(公告)日：1979-01-16
申请号：US858744
申请日：1977-12-08
申请人： Werner Kuesters , Rolf Osterloh , Manfred Jacobi
发明人： Werner Kuesters , Rolf Osterloh , Manfred Jacobi
IPC分类号： C08F2/50 , C09D11/101 , G03F7/031 , C08F2/46 , C08F4/00 , C08F8/18
CPC分类号： C09D11/101 , G03F7/031 , Y10S430/124 , Y10S525/922 , Y10T428/31529 , Y10T428/31699
摘要： A photopolymerizable composition which contains one or more olefinically unsaturated compounds and from 0.2 to 20% by weight (based on the unsaturated compound(s)) of a photoinitiator, with or without conventional additives, the photoinitiator being a mixture of one or more aromatic carbonyl compounds of the general formula (A) ##STR1## where Ar is an ortho-arylene radical which may or may not be substituted by one or more radicals R.sup.1 to R.sup.4, R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are identical or different and each is H, alkyl or 1 to 5 carbon atoms, phenyl, halogen, alkoxy of 1 to 5 carbon atoms, alkaryl of 7 to 11 carbon atoms, aralkyl of 7 to 11 carbon atoms or --CO.sub.2 R.sup.9, where R.sup.9 is alkyl of 1 to 5 carbon atoms, and n is 0 or 1, and an amine, with or without an aromatic carbonyl compound which differs from (A).This photopolymerizable composition is particularly suitable for the manufacture of photopolymer printing plates and UV-curing printing inks.
摘要翻译：含有一种或多种烯属不饱和化合物和0.2-20％重量（基于不饱和化合物）光引发剂的可光聚合组合物，具有或不含常规添加剂的光引发剂是一种或多种芳族羰基通式（A）的化合物（A）其中Ar是可以被一个或多个基团R 1至R 4，R 1，R 2，R 3和R 4可被或不被其取代的邻亚芳基相同或不同，各自为H，烷基或1至5个碳原子，苯基，卤素，1至5个碳原子的烷氧基，7至11个碳原子的烷芳基，7至11个碳原子的芳烷基或-CO 2 R 9，其中R 9为烷基， 5个碳原子，n为0或1，以及与（A）不同的具有或不具有芳族羰基化合物的胺。

7. 发明授权

US4131529A Photoinitiators for photopolymerizable coating compositions 失效
标题翻译：光聚合涂料组合物的光引发剂
公开(公告)号：US4131529A
公开(公告)日：1978-12-26
申请号：US796546
申请日：1977-05-13
申请人： Rolf Osterloh , Manfred Jacobi , Werner Kuesters
发明人： Rolf Osterloh , Manfred Jacobi , Werner Kuesters
IPC分类号： C08F2/50 , C08F299/04 , C09D4/00 , C09D11/10 , C08F2/46 , C08F4/00
CPC分类号： C08F299/0435 , C08F2/50 , C08K5/0008 , C08K5/0025 , C09D11/101 , C09D4/00 , Y10T428/31525 , Y10T428/31645 , Y10T428/31649
摘要： Photopolymerizable coating compositions contain, as the binder, olefinically unsaturated compounds having a boiling point above 50.degree. C, together with from 0.5 to 15% by weight of photoinitiators, based on the binder. The photoinitiators are a mixture of an aromatic carbonyl compound A, which is a derivative of benzoin or benzil, which has at least one carbon-oxygen single bond in the .alpha.-position relative to the carbonyl group, an aromatic carbonyl compound B which is derived from benzophenone, fluorenone, anthraquinone, xanthene, thioxanthone or acridone, and an amine C of the general formula ##STR1## where R', R" and R"' are H, alkyl of 1 to 10 carbon atoms, cycloalkyl of 3 to 10 carbon atoms, aryl, hydroxyalkyl of 1 to 8 carbon atoms or alkoxyalkyl of 2 to 4 carbon atoms, but at most 2 substituents are H and at most 2 substituents are aromatic.These coating compositions may be used for finishing various substrates, as fillers or as printing inks.
摘要翻译：作为粘合剂，可光聚合涂料组合物含有沸点高于50℃的烯属不饱和化合物和0.5至15重量％的基于粘合剂的光引发剂。光引发剂是芳族羰基化合物A，其是苯偶姻或苯偶酰的衍生物，其相对于羰基在α位具有至少一个碳 - 氧单键，衍生自芳族羰基化合物B 来自二苯甲酮，芴酮，蒽醌，呫吨，噻吨酮或吖啶酮，以及通式为“IMAGE”的胺C，其中R'，R“和R”'为H，1至10个碳原子的烷基，3 至10个碳原子，芳基，1至8个碳原子的羟烷基或2至4个碳原子的烷氧基烷基，但最多2个取代基是H，并且最多2个取代基是芳族的。

8. 发明授权

US4447520A Acylphosphine oxides and their use 失效
标题翻译：酰基氧化膦及其用途
公开(公告)号：US4447520A
公开(公告)日：1984-05-08
申请号：US409555
申请日：1982-08-19
申请人： Andreas Henne , Anton Hesse , Manfred Jacobi , Gunnar Schornick , Rudolf Vyvial , Klaus Holoch
发明人： Andreas Henne , Anton Hesse , Manfred Jacobi , Gunnar Schornick , Rudolf Vyvial , Klaus Holoch
IPC分类号： C08F2/00 , C07F9/53 , C08F2/50 , C08F4/00 , C08K5/5397 , G03F7/029 , G03C1/68
CPC分类号： G03F7/029 , C07F9/5337 , C08F2/50 , C08K5/5397 , Y10S430/124
摘要： Acylphosphine oxides of the general formula ##STR1## where R.sup.1 is methyl or ethyl, R.sup.2 is a branched or straight-chain alkyl radical or chlorine, alkoxy or hydrogen, R.sup.3 and R.sup.4 are identical or different, and are each alkyl, alkoxy, alkylthio or chlorine and R.sup.5 is hydrogen, chlorine, alkoxy, alkylthio or alkyl, may be used as photoinitiators in photopolymerizable materials.
摘要翻译：其中R1是甲基或乙基，R2是支链或直链烷基或氯，烷氧基或氢的酰基氧化膦，其中R 1是甲基或乙基，R 3和R 4是相同或不同的，并且各自是烷基，烷氧基，烷硫基或氯和R 5是氢，氯，烷氧基，烷硫基或烷基，可用作可光聚合材料中的光引发剂。

9. 发明授权

US4144156A Manufacture of unsymmetric monoacetals of aromatic 1,2-diketones employable as photoiniatiators 失效
标题翻译：制造可用作光合剂的芳族1,2-二酮的不对称单缩醛
公开(公告)号：US4144156A
公开(公告)日：1979-03-13
申请号：US787569
申请日：1977-04-14
申请人： Werner Kuesters , Manfred Jacobi , Rolf Osterloh
发明人： Werner Kuesters , Manfred Jacobi , Rolf Osterloh
IPC分类号： C08F2/50 , C08F299/04 , G03F7/031 , C08F2/46 , C08F4/00
CPC分类号： G03F7/031 , C07C45/68 , C08F2/50 , C08F299/0435 , Y10S430/114 , Y10S525/922 , Y10T428/31511 , Y10T428/3179
摘要： Unsymmetrical monoketals of aromatic 1,2-diketones ##STR1## wherein R.sup.1 and R.sup.2 are different radicals, are manufactured by reacting the corresponding aromatic 1,2-diketones, in an organic solvent, with an acid ester (R.sup.1).sub.n X as alkylating agent and an alcoholate (R.sup.2 O).sub.m Me, where n and m are integers from 1 to 3, X is an acid radical and Me is a metal of main groups 1 to 3 of the periodic table of the elements. The resulting diketone monoacetals are particularly suitable for use as photoinitiators in photopolymerizable compositions.
摘要翻译：通过使有机溶剂中的相应芳族1,2-二酮与作为烷基化剂的酸酯（R1）nX反应制备芳族1,2-二酮的不对称单键，其中R 1和R 2是不同的基团，醇化物（R 2 O）mMe，其中n和m为1至3的整数，X为酸基，Me为元素周期表的主要基团1至3的金属。所得的二酮单缩醛特别适用于光聚合组合物中的光引发剂。

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