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    • 6. 发明授权
    • Removal of metal cusp for improved contact fill
    • 去除金属尖端以改善接触填充
    • US06423626B1
    • 2002-07-23
    • US09334753
    • 1999-06-16
    • Anand SrinivasanGurtej SandhuSujit Sharan
    • Anand SrinivasanGurtej SandhuSujit Sharan
    • H01L214763
    • H01L21/76865H01L21/76844H01L21/76877H01L23/485H01L2924/0002H01L2924/00
    • Disclosed is a method for providing improved step coverage of contacts with conductive materials, and particularly metals. An initial conductive layer is deposited over an insulating layer either before or after contact opening formation. The deposition process tends to block the contact mouth with a metal overhang, or cusp. After both conductive layer deposition and contact formation a portion of the initial conductive layer is removed, thus removing at least a portion of the metal cusp and opening the contact mouth for further depositions. The invention has particular utility in connection with formation of metal plugs in high-aspect ratio contacts. Embodiments are disclosed wherein the cusp removal comprises mechanical planarization, etching with high viscosity chemicals, and facet etching.
    • 公开了一种用于提供与导电材料,特别是金属的接触的改进的台阶覆盖的方法。 在接触开口形成之前或之后,在绝缘层上沉积初始导电层。 沉积过程倾向于以金属悬垂或尖端阻塞接触嘴。 在导电层沉积和接触形成两者之后,去除初始导电层的一部分,从而去除金属尖端的至少一部分并打开接触口以进一步沉积。 本发明在高纵横比触点形成金属插头方面具有特殊的用途。 公开了其中尖端去除包括机械平面化,用高粘度化学品蚀刻和小面蚀刻的实施例。
    • 8. 发明申请
    • Methods of forming silicon dioxide layers, and methods of forming trench isolation regions
    • 形成二氧化硅层的方法以及形成沟槽隔离区的方法
    • US20060205175A1
    • 2006-09-14
    • US11362455
    • 2006-02-23
    • Sujit SharanGurtej Sandhu
    • Sujit SharanGurtej Sandhu
    • H01L21/76H01L21/31H01L21/469
    • H01L21/02164C23C16/045C23C16/402H01L21/02211H01L21/02274H01L21/31612H01L21/76224
    • A method of forming a silicon dioxide layer includes forming a high density plasma proximate a substrate, the plasma comprising silicon dioxide precursors; forming silicon dioxide from the precursors, the silicon dioxide being deposited over the substrate at a deposition rate; and while depositing, etching the deposited silicon dioxide with the plasma at an etch rate; a ratio of the deposition rate to the etch rate being at least about 4:1. Another method includes forming a high density plasma proximate a substrate; flowing gases into the plasma, at least some of the gases forming silicon dioxide; depositing the silicon dioxide formed from the gases over the substrate; and while depositing the silicon dioxide, maintaining a temperature of the substrate at greater than or equal to about 500° C. As an alternative, the method may include not cooling the substrate with a coolant gas while depositing the silicon dioxide.
    • 形成二氧化硅层的方法包括在基底附近形成高密度等离子体,所述等离子体包含二氧化硅前体; 从前体形成二氧化硅,二氧化硅以沉积速率沉积在衬底上; 并且在沉积时以蚀刻速率用等离子体蚀刻沉积的二氧化硅; 沉积速率与蚀刻速率的比率为至少约4:1。 另一种方法包括在基底附近形成高密度等离子体; 流入气体进入等离子体,形成二氧化硅的至少一些气体; 将由气体形成的二氧化硅沉积在衬底上; 并且同时沉积二氧化硅,将基底的温度保持在大于或等于约500℃。作为替代方案,该方法可以包括在沉积二氧化硅的同时不用冷却剂气体冷却基底。
    • 10. 发明申请
    • Method of forming refractory metal silicide
    • 形成难熔金属硅化物的方法
    • US20050109271A1
    • 2005-05-26
    • US10975714
    • 2004-10-27
    • Gurtej SandhuSujit Sharan
    • Gurtej SandhuSujit Sharan
    • H01L21/20H01L21/28H01L21/285H01L21/3205C30B23/00C30B25/00C30B28/12C30B28/14
    • H01L21/02667C30B1/02C30B29/34H01L21/2022H01L21/28061H01L21/28247H01L21/28518H01L21/32053H01L29/7842
    • A method of forming a crystalline phase material includes, a) providing a stress inducing material within or operatively adjacent a crystalline material of a first crystalline phase; and b) annealing the crystalline material of the first crystalline phase under conditions effective to transform it to a second crystalline phase. The stress inducing material preferably induces compressive stress within the first crystalline phase during the anneal to the second crystalline phase to lower the required activation energy to produce a more dense second crystalline phase. Example compressive stress inducing layers include SiO2 and Si3N4, while example stress inducing materials for providing into layers are Ge, W and Co. Where the compressive stress inducing material is provided on the same side of a wafer over which the crystalline phase material is provided, it is provided to have a thermal coefficient of expansion which is less than the first phase crystalline material. Where the compressive stress inducing material is provided on the opposite side of a wafer over which the crystalline phase material is provided, it is provided to have a thermal coefficient of expansion which is greater than the first phase crystalline material. Example and preferred crystalline phase materials having two phases are refractory metal silicides, such as TiSix.
    • 形成结晶相材料的方法包括:a)在第一结晶相的结晶材料内部或在其中邻近的第一结晶相中提供应力诱导材料; 和b)在有效地将其转变成第二结晶相的条件下退火第一结晶相的结晶材料。 应力诱导材料优选在与第二结晶相退火期间在第一结晶相内诱导压应力,以降低所需的活化能以产生更致密的第二结晶相。 示例性压缩应力诱导层包括SiO 2和Si 3 N 4,而用于提供层的应力诱导材料是Ge,W和Co 在压应力诱导材料设置在其上提供结晶相材料的晶片的相同侧上时,其被设置为具有小于第一相结晶材料的热膨胀系数。 在压应力诱导材料设置在提供结晶相材料的晶片的相对侧上的情况下,其被设置为具有大于第一相结晶材料的热膨胀系数。 具有两相的实例和优选结晶相材料是难熔金属硅化物,例如TiSi x x。