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1. 发明授权

US4200585A Acid esters of propylene oxide poly-adducts 失效
标题翻译：环氧丙烷多加合物的酸酯
公开(公告)号：US4200585A
公开(公告)日：1980-04-29
申请号：US920588
申请日：1978-06-29
申请人： Alfred Berger , Hans-Ulrich Berendt
发明人： Alfred Berger , Hans-Ulrich Berendt
IPC分类号： C08G65/26 , C08G65/333 , C08G65/334 , D06P1/607 , C07C141/08
CPC分类号： D06P1/6076 , C08G65/2624 , C08G65/33396 , C08G65/3344 , Y10S8/922
摘要： Acid esters of propylene oxide poly-adducts and their salts, which are obtained by an addition reaction of(a) propylene oxide with(b) a polyfunction amine, which contains 2 to 9 carbon atoms and at least a second reactive amino group or at least one hydroxyl group, and esterification of the poly-adduct with(c) an oxy-acid which is at least dibasic or with a functional derivative of this acid and, if appropriate, by conversion of the resulting acid ester into a salt.These acid esters of propylene oxide poly-adducts are particularly effective as dyeing auxiliaries, especially as dispersing and levelling agents for dyeing synthetic fibres and primarily for dyeing linear polyester fibres.
摘要翻译：通过（a）环氧丙烷与（b）多官能胺，含有2至9个碳原子和至少第二反应性氨基的加成反应获得的环氧丙烷多加合物及其盐的酸酯，或至少一个羟基和多加成物与（c）至少二元酸或与该酸的官能衍生物的氧酸酯化，并且如果合适的话，通过将所得酸酯转化成盐来酯化。环氧丙烷多加合物的这些酸酯作为染色助剂特别有效，特别是用于染色合成纤维的分散和流平剂，主要用于染色线性聚酯纤维。

2. 发明授权

US4132525A Process for dyeing materials which contain synthetic fibres using polyadducts of propylene oxide and polyhydric alcohols 失效
标题翻译：使用环氧丙烷和多元醇的多加合物含有合成纤维的染色材料的方法
公开(公告)号：US4132525A
公开(公告)日：1979-01-02
申请号：US785897
申请日：1977-04-08
申请人： Alfred Berger , Hans-Ulrich Berendt
发明人： Alfred Berger , Hans-Ulrich Berendt
IPC分类号： D06P1/613 , D06P3/36 , D06P3/72 , D06P3/82 , D06P5/08 , C09B67/00 , D06P1/653
CPC分类号： D06P1/613 , D06P3/36 , D06P3/72 , D06P3/8214 , Y10S8/907 , Y10S8/908
摘要： Process for dyeing materials which contain synthetic fibres with dyes that are sparingly soluble to insoluble in water, in the presence of dyeing auxiliaries which are polyadducts of propylene oxide and a polyhydric aliphatic alcohol of at least 2 carbon atoms, wherein said adducts are soluble in water and contain sulphonic acid groups.The process of present invention is especially suitable for dyeing linear polyester fibres wherein level and strong dyeings are obtained which are in addition characterized by good fastness to rubbing.
摘要翻译：在具有至少2个碳原子的环氧丙烷和多元脂肪醇的聚合物的染色助剂的存在下，含有合成纤维的染料的方法，其中所述染料易溶于水，其中所述加合物可溶于水并含有磺酸基团。

3. 发明授权

US4975524A Graft polymers which are water-soluble or dispersible in water, their preparation and use 失效
标题翻译：水溶性或分散在水中的接枝聚合物，其制备和用途
公开(公告)号：US4975524A
公开(公告)日：1990-12-04
申请号：US414996
申请日：1989-09-29
申请人： Hans-Ulrich Berendt
发明人： Hans-Ulrich Berendt
IPC分类号： D06P1/642 , C08F283/06 , D06P1/52 , D06P1/613 , D06P3/60 , D06P5/20
CPC分类号： D06P5/2011 , C08F283/06 , D06P1/5214 , D06P1/6133 , D06P3/60
摘要： Graft polymers which are obtainable from(A) 2%-30% by weight of an addition product from alkylene oxide onto an aliphatic alcohol which is at least trihydric having 3 to 10 carbon atoms and(B) 70%-98% by weight of a grafted-on monomer mixture of(1) 20% to 50% by weight of an N-substituted or N-unsubstituted acrylamide or methacrylamide and(2) 50% to 80% by weight of an N-vinyl-substituted amide or of a vinyl ester, derived in each case from a saturated aliphatic monocarboxylic acid,where the sums of (A) and (B), and (1) and (2) in each case add up to 100%.These novel graft polymer are suitable as dyeing assistants, particularly as padding assistants or liquor binders when dyeing cellulose fibre materials.
摘要翻译：接枝聚合物可从（A）2重量％-30重量％的环氧烷加成产物至3至10个碳原子的脂族醇和（B）70重量％至98重量％（1）20重量％至50重量％的N-取代或N-未取代的丙烯酰胺或甲基丙烯酰胺的接枝单体混合物和（2）50重量％至80重量％的N-乙烯基取代的酰胺或每种情况下衍生自饱和脂族一元羧酸的乙烯基酯，其中（A）和（B）和（1）和（2）的总和在每种情况下加起来为100％。这些新型接枝聚合物适合用作染色助剂，特别是当染色纤维素纤维材料时，作为衬垫助剂或液体粘合剂。

4. 发明授权

US4731092A Process for printing or dyeing cellulose-containing textile material with reactive dyes in aqueous foam preparation containing acrylic graft co-polymer 失效
标题翻译：在包含丙烯酸接枝共聚物的含水泡沫制剂中用活性染料印染或染色含纤维素纺织材料的方法
公开(公告)号：US4731092A
公开(公告)日：1988-03-15
申请号：US40664
申请日：1987-04-20
申请人： Hans-Ulrich Berendt
发明人： Hans-Ulrich Berendt
IPC分类号： C08F283/06 , D06P1/52 , D06P1/96 , D06P3/66
CPC分类号： D06P3/66 , C08F283/06 , D06P1/5257 , D06P1/965 , Y10S8/918
摘要： Textile cellulose material is printed or dyed with reactive dyes with the aid of foam. The foam is applied by applying to the cellulose material a foamed, aqueous preparation which contains in addition to dyes and fixing alkalis(1) a foam-forming agent(2) a homopolymer or copolymer of acrylamide or methacrylamide or preferably a graft polymer which is obtained from an addition product of an alkylene oxide, preferably propylene oxide, on an at least trihydric aliphatic alcohol, e.g. glycerol, and acrylamide or methacrylamide, and(3) an anionic graft polymer which has as grafting base a copolymerization product from (A) an alkyl acrylate or methacrylate, the alkyl radical having at least 8 carbon atoms, with (B) a dicarboxylic acid diester of an ethylenically unsaturated aliphatic dicarboxylic acid and a polyethylene glycol, a terminal hydroxyl group of the diol having been etherified with a C.sub.1 -C.sub.4 -alkyl radical, and contains as graft constituent side chains which stem from grafted-on polymerizable monomers which contain hydrophilic groups.The cellulose material thus treated is then subjected to a heat treatment, for example steaming, to fix the dye.This very stable preparation produces without the use of thickenings a strong, level and crisp print which at the same time has an excellent handle.
摘要翻译：纺织纤维素材料借助泡沫印刷或染色活性染料。通过向纤维素材料施加发泡的含水制剂，其中除了染料和固定碱之外还包含发泡剂（2），丙烯酰胺或甲基丙烯酰胺或优选接枝聚合物的均聚物或共聚物，由至少三元脂肪醇的环氧烷，优选环氧丙烷的加成产物获得，例如甘油和丙烯酰胺或甲基丙烯酰胺，和（3）具有作为接枝碱的阴离子接枝聚合物，其由（A）丙烯酸烷基酯或甲基丙烯酸烷基酯，具有至少8个碳原子的烷基与（B）二羧酸烯键式不饱和脂族二羧酸和聚乙二醇的二酯，二醇的末端羟基与C1-C4-烷基醚化，并且含有作为接枝的侧链，其由含有亲水性的接枝聚合单体团体然后将如此处理的纤维素材料进行热处理，例如蒸煮以固定染料。这种非常稳定的制剂在不使用增稠剂的情况下产生强烈的水平和清晰的印刷品，同时具有优异的手感。

5. 发明授权

US4494956A Process for pad dyeing cellulosic textile materials 失效
公开(公告)号：US4494956A
公开(公告)日：1985-01-22
申请号：US559121
申请日：1983-12-07
申请人： Paul Schafer , Hans-Ulrich Berendt
发明人： Paul Schafer , Hans-Ulrich Berendt
IPC分类号： C08F283/06 , D06P1/613 , D06P1/38 , D06P1/52 , D06P1/607
CPC分类号： C08F283/06 , D06P1/6133
摘要： Cellulosic textile material is dyed with substantive dyes or preferably with reactive dyes. Dyeing is carried out by applying to the cellulosic material an aqueous dye liquor which contains, in addition to the dye, a graft polymer which is obtained from an adduct of an alkylene oxide, preferably propylene oxide, with an at least trihydric aliphatic alcohol, e.g. glycerol, and acrylamide or methacrylamide. The cellulosic material is then subjected to a heat treatment, e.g. by steaming or with microwaves, or is stored cold, to fix the dyes.This dye liquor increases the liquor pick-up and thus also increases the dye yield, while at the same time excellent levelness is achieved.

6. 发明授权

US5002587A Copolymers which are water-soluble or dispersible in water, their preparation and use 失效
标题翻译：水溶性或分散在水中的共聚物，其制备和用途
公开(公告)号：US5002587A
公开(公告)日：1991-03-26
申请号：US414995
申请日：1989-09-29
申请人： Hans-Ulrich Berendt
发明人： Hans-Ulrich Berendt
IPC分类号： C08F20/52 , C08F26/00 , C08F220/56 , C08F226/02 , C08F226/08 , C08F283/06 , D06P1/52 , D06P1/613 , D06P3/60 , D06P5/20
CPC分类号： D06P5/2011 , C08F226/08 , C08F283/06 , D06P1/5214 , D06P1/5242 , D06P1/5257 , D06P1/6133 , D06P3/60 , Y10S8/918
摘要： Copolymers which are obtainable from(1) 20 to 50% by weight of an N-substituted or N-unsubstituted acrylamide or methacrylamide and(2) 50 to 80% by weight of an N-vinyl-substituted amide or of a vinyl ester, derived in each case from a saturated aliphatic monocarboxylic acid,the sum of (1) and (2) adding up to 100%.These novel copolymers are suitable as dyeing assistants, particularly as padding assistants or liquor binders in the dyeing of cellulose fibre materials.
摘要翻译：可从（1）20至50重量％的N-取代或N-未取代的丙烯酰胺或甲基丙烯酰胺获得的共聚物和（2）50至80重量％的N-乙烯基取代的酰胺或乙烯基酯，在每种情况下衍生自饱和脂族一元羧酸，（1）和（2）的总和相加至100％。这些新型共聚物适合作为染色助剂，特别是在纤维素纤维材料的染色中作为填料助剂或液体粘合剂。

7. 发明授权

US4496472A Process for bleaching cellulosic fibre materials using oligomers of phosphonic acid esters as stabilizers in alkaline, peroxide-containing bleaching liquors 失效
标题翻译：使用膦酸酯的低聚物作为碱性，含过氧化物的漂白液中的稳定剂漂白纤维素纤维材料的方法
公开(公告)号：US4496472A
公开(公告)日：1985-01-29
申请号：US450718
申请日：1982-12-17
申请人： Paul Schafer , Hans-Ulrich Berendt
发明人： Paul Schafer , Hans-Ulrich Berendt
IPC分类号： C11D7/54 , C11D3/39 , C11D7/36 , D06L3/02 , C09K3/00
CPC分类号： D06L3/021 , C11D3/394
摘要： Oligomers of the formula ##STR1## wherein Y.sub.1 is hydrogen or --CO--T.sub.1, R.sub.1 Q.sub.1 and T.sub.1 are alkyl and n.sub.1 is 1 to 16, or alkali metal salts thereof, are used as stabilizers in peroxide-containing alkaline liquors for bleaching cellulosic fibre materials.
摘要翻译：其中Y 1为氢或-CO-T 1，R 1 Q 1和T 1为烷基且n 1为1〜16的式[IMAGE]的低聚物或其碱金属盐用作漂白纤维素纤维的含过氧化物的碱性液体中的稳定剂材料

8. 发明授权

US4243390A Process for dyeing or printing fibrous material using quaternary polymerized ammonium salts as assistants 失效
标题翻译：使用季铵盐作助剂染色或印刷纤维材料的方法
公开(公告)号：US4243390A
公开(公告)日：1981-01-06
申请号：US107115
申请日：1979-12-26
申请人： Paul Schafer , Hans-Ulrich Berendt , Jaroslav Haase
发明人： Paul Schafer , Hans-Ulrich Berendt , Jaroslav Haase
IPC分类号： D06P1/52 , C09B67/00 , D06P1/62
CPC分类号： D06P1/525 , D06P1/5242
摘要： A process for dyeing or printing organic fibrous material made e.g. of polyamide, polyester or polyacrylonitrile, and also of cellulose, said process comprising the use of a dyeing or printing assistant which contains a quaternary ammonium salt. The salt is a reaction product of a copolymer of maleic anhydride and ethylene, propylene or styrene, with a N,N-disubstituted n-alkylenediamine, a homopolymer of a vinylpyridine, or a quaternized copolymer of a vinylpyridine and styrene. The reaction product, the homopolymer, and the copolymer are quaternized with e.g. benzyl chloride. The ammonium salt can also be a homopolymer of a vinylbenzyl chloride which is quaternized with a tertiary monoamine. The fibrous material dyed or printed with e.g. direct or disperse dyes or with cationic dyes has excellent levelness, good penetration of the dye, and good wetfastness properties. It is also possible to obtain multi-shade effects by printing the material patchwise with a reserve paste and then dyeing it.
摘要翻译：用于染色或印刷有机纤维材料的方法，的聚酰胺，聚酯或聚丙烯腈，以及纤维素，所述方法包括使用含有季铵盐的染色或印刷助剂。该盐是马来酸酐与乙烯，丙烯或苯乙烯的共聚物与N，N-二取代的正构烷基二胺，乙烯基吡啶的均聚物或乙烯基吡啶和苯乙烯的季铵化共聚物的反应产物。反应产物，均聚物和共聚物用例如季铵化。苄基氯。铵盐也可以是乙烯基苄基氯的均聚物，其与叔单胺季铵化。用例如染色或印刷的纤维材料。直接或分散染料或阳离子染料具有优异的水平度，良好的染料渗透性和良好的耐湿性能。也可以通过用保留的糊剂贴片印刷材料然后染色来获得多色效果。

9. 发明授权

US5028237A Dyeing process using graft polymers which are water soluble or dispersible in water as dyeing assistants 失效
标题翻译：使用水溶性或分散在水中作为染色助剂的接枝聚合物的染色方法
公开(公告)号：US5028237A
公开(公告)日：1991-07-02
申请号：US587386
申请日：1990-09-25
申请人： Hans-Ulrich Berendt
发明人： Hans-Ulrich Berendt
IPC分类号： D06P1/642 , C08F283/06 , D06P1/52 , D06P1/613 , D06P3/60 , D06P5/20
CPC分类号： D06P5/2011 , C08F283/06 , D06P1/5214 , D06P1/6133 , D06P3/60
摘要： Graft polymers which are obtainable from(A) 2-30% by weight of an addition product from alkylene oxide onto an aliphatic alcohol which is at least trihydric having 3 to 10 carbon atoms and(B) 70-98% by weight of a grafted-on monomer mixture of(1) 20 to 50% by weight of an N-substituted or N-unsubstituted acrylamide or methacrylamide and(2) 50 to 80% by weight of an N-vinyl-substituted amide or of a vinyl ester, derived in each case from a saturated aliphatic monocarboxylic acid,where the sums of (A) and (B), and (1) and (2) in each case add up to 100%.These novel graft polymers are suitable as dyeing assistants, particularly as padding assistants or liquor binders when dyeing cellulose fibre materials.

10. 发明授权

US4880564A Antifoams for aqueous systems and their use 失效
标题翻译：含水系统的消泡剂及其用途
公开(公告)号：US4880564A
公开(公告)日：1989-11-14
申请号：US99034
申请日：1987-09-21
申请人： Heinz Abel , Christian Guth , Hans-Ulrich Berendt
发明人： Heinz Abel , Christian Guth , Hans-Ulrich Berendt
IPC分类号： B01D19/04
CPC分类号： B01D19/0404
摘要： Antifoams are described which contain p0 (1) an alkaline earth metal salt of a C.sub.10 -C.sub.24 -fatty acid,(2) a dialkyl ester of an unsaturated dicarboxylic acid,(3) a mineral oil,(4) a non-ionic emulsifier,(5) an anionic emulsifier and(6) an alkylenediamide,as well as liquid formulations containing such antifoams and their use in a defoaming method for aqueous systems.
摘要翻译：描述了消泡剂，其含有p0（1）C10-C24-脂肪酸的碱土金属盐，（2）不饱和二羧酸的二烷基酯，（3）矿物油，（4）非离子型乳化剂，（5）阴离子乳化剂和（6）亚烷基二胺，以及含有这种消泡剂的液体制剂及其在水系统的消泡方法中的用途。

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