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1. 发明授权

US4243390A Process for dyeing or printing fibrous material using quaternary polymerized ammonium salts as assistants 失效
标题翻译：使用季铵盐作助剂染色或印刷纤维材料的方法
公开(公告)号：US4243390A
公开(公告)日：1981-01-06
申请号：US107115
申请日：1979-12-26
申请人： Paul Schafer , Hans-Ulrich Berendt , Jaroslav Haase
发明人： Paul Schafer , Hans-Ulrich Berendt , Jaroslav Haase
IPC分类号： D06P1/52 , C09B67/00 , D06P1/62
CPC分类号： D06P1/525 , D06P1/5242
摘要： A process for dyeing or printing organic fibrous material made e.g. of polyamide, polyester or polyacrylonitrile, and also of cellulose, said process comprising the use of a dyeing or printing assistant which contains a quaternary ammonium salt. The salt is a reaction product of a copolymer of maleic anhydride and ethylene, propylene or styrene, with a N,N-disubstituted n-alkylenediamine, a homopolymer of a vinylpyridine, or a quaternized copolymer of a vinylpyridine and styrene. The reaction product, the homopolymer, and the copolymer are quaternized with e.g. benzyl chloride. The ammonium salt can also be a homopolymer of a vinylbenzyl chloride which is quaternized with a tertiary monoamine. The fibrous material dyed or printed with e.g. direct or disperse dyes or with cationic dyes has excellent levelness, good penetration of the dye, and good wetfastness properties. It is also possible to obtain multi-shade effects by printing the material patchwise with a reserve paste and then dyeing it.
摘要翻译：用于染色或印刷有机纤维材料的方法，的聚酰胺，聚酯或聚丙烯腈，以及纤维素，所述方法包括使用含有季铵盐的染色或印刷助剂。该盐是马来酸酐与乙烯，丙烯或苯乙烯的共聚物与N，N-二取代的正构烷基二胺，乙烯基吡啶的均聚物或乙烯基吡啶和苯乙烯的季铵化共聚物的反应产物。反应产物，均聚物和共聚物用例如季铵化。苄基氯。铵盐也可以是乙烯基苄基氯的均聚物，其与叔单胺季铵化。用例如染色或印刷的纤维材料。直接或分散染料或阳离子染料具有优异的水平度，良好的染料渗透性和良好的耐湿性能。也可以通过用保留的糊剂贴片印刷材料然后染色来获得多色效果。

2. 发明授权

US4494956A Process for pad dyeing cellulosic textile materials 失效
公开(公告)号：US4494956A
公开(公告)日：1985-01-22
申请号：US559121
申请日：1983-12-07
申请人： Paul Schafer , Hans-Ulrich Berendt
发明人： Paul Schafer , Hans-Ulrich Berendt
IPC分类号： C08F283/06 , D06P1/613 , D06P1/38 , D06P1/52 , D06P1/607
CPC分类号： C08F283/06 , D06P1/6133
摘要： Cellulosic textile material is dyed with substantive dyes or preferably with reactive dyes. Dyeing is carried out by applying to the cellulosic material an aqueous dye liquor which contains, in addition to the dye, a graft polymer which is obtained from an adduct of an alkylene oxide, preferably propylene oxide, with an at least trihydric aliphatic alcohol, e.g. glycerol, and acrylamide or methacrylamide. The cellulosic material is then subjected to a heat treatment, e.g. by steaming or with microwaves, or is stored cold, to fix the dyes.This dye liquor increases the liquor pick-up and thus also increases the dye yield, while at the same time excellent levelness is achieved.

3. 发明授权

US4705526A Water-soluble or water-dispersible graft polymers and the preparation and use thereof 失效
标题翻译：水溶性或水分散性接枝聚合物及其制备和应用
公开(公告)号：US4705526A
公开(公告)日：1987-11-10
申请号：US876034
申请日：1986-06-19
申请人： Heinz Abel , Paul Schafer , Hans-Ulrich Berendt
发明人： Heinz Abel , Paul Schafer , Hans-Ulrich Berendt
IPC分类号： C08F283/00 , C08F283/02 , C08F299/04 , C08G63/676 , D06M13/02 , D06M13/184 , D06M13/203 , D06M13/322 , D06M13/402 , D06M13/41 , D06M15/263 , D06M101/00 , D06M101/02 , D06M101/06 , D06M101/08 , D06M101/10 , D06M101/16 , D06P1/613 , C08F283/01 , C08G63/66
CPC分类号： C08F283/02 , C08F299/04 , C08G63/676 , D06P1/613 , Y10S8/917 , Y10S8/918 , Y10S8/922 , Y10S8/924 , Y10S8/927
摘要： Water-soluble or water-dispersible graft polymers comprising i) as main chain, (1) a condensate of (A) (1) an aliphatic monoalcohol of 6 to 22 carbon atoms or (2) a fatty acid of 8 to 22 carbon atoms with (B) the reaction product of (a) an adduct of propylene adduct with at least trihydric aliphatic alcohol of 3 to 10 carbon atoms, (b) an aliphatic dicarboxylic acid of 4 to 10 carbon atoms, or an anhydride thereof, and (c) an aliphatic diol having an average molecular weight of not more than 1800 and ii) grafted ethylenically unsaturated polymerisable monomers, preferably acrylic acid or acrylamide, in the form of side chains at individual carbon atoms of said condensate.These graft polymers are particularly suitable for use as anticrease agents for dyeing, whitening, bleaching or washing textile materials, e.g. textiles containing cellulosic fibres, natural or synthetic polyamide fibres, polyacrylonitrile fibres or, in particular, for dyeing or whitening cotton or polyester fibres.
摘要翻译：包括i）作为主链的（1）（A）（1）碳原子数为6〜22的脂肪族一元醇或（2）碳原子数为8〜22的脂肪酸的缩合物的水溶性或水分散性接枝聚合物与（B）反应产物（a）丙烯加成物与至少三元碳原子数为3〜10的脂肪醇的加成物，（b）4-10个碳原子的脂肪族二羧酸或其酸酐，和 c）平均分子量不大于1800的脂肪族二醇和ii）在所述缩合物的各个碳原子处的侧链形式的接枝烯属不饱和可聚合单体，优选丙烯酸或丙烯酰胺。这些接枝聚合物特别适合用作染色，增白，漂白或洗涤织物材料的抗磨剂，例如。含有纤维素纤维，天然或合成聚酰胺纤维，聚丙烯腈纤维或特别是用于染色或增白棉或聚酯纤维的纺织品。

4. 发明授权

US4613335A Process for dyeing or printing cellulose-containing textile material with vat dye foam 失效
标题翻译：使用瓮染料泡沫染色或印刷含纤维素的纺织材料的方法
公开(公告)号：US4613335A
公开(公告)日：1986-09-23
申请号：US733346
申请日：1985-05-13
申请人： Hans-Ulrich Berendt , Paul Schafer
发明人： Hans-Ulrich Berendt , Paul Schafer
IPC分类号： D06P1/52 , D06P1/22 , D06P1/613 , D06P1/96 , D06P3/60
CPC分类号： D06P1/965 , D06P1/22 , D06P1/6133 , Y10S8/918
摘要： Textile cellulose material is dyed or in particular printed with vat dyes by applying to the cellulose material in the absence of air a foamed aqueous preparation which, in addition to the dye, alkalis, reducing agent, foam-forming agent, preferably also contains a homopolymer or copolymer of acrylamide or methacrylamide or in particular a graft polymer which is obtained from an adduct of an alkylene oxide, preferably propylene oxide, on an at least trihydric aliphatic alcohol, for example glycerol, and acrylamide or methacrylamide.The dyed or printed cellulose material is if desired subjected to a heat treatment, for example steaming, and is then oxidized to develop the color.The use of the foamed preparations makes it possible to obtain deep level dyeings and crisp prints without the use of thickeners; at the same time the textile materials thus obtained have excellent handle.
摘要翻译：纺织纤维素材料被染色或特别地用还原染料印刷，在没有空气的情况下通过施加到纤维素材料上的泡沫水性制剂，除了染料，碱，还原剂，发泡剂，优选还含有均聚物或丙烯酰胺或甲基丙烯酰胺的共聚物，或特别是由至少三元脂肪醇（例如甘油）和丙烯酰胺或甲基丙烯酰胺的烯化氧，优选环氧丙烷的加合物获得的接枝聚合物。染色或印刷的纤维素材料如果需要经受热处理，例如蒸汽，然后被氧化以显色。使用泡沫制剂使得可以在不使用增稠剂的情况下获得深层染色和清晰印刷; 同时由此获得的纺织材料具有优异的手感。

5. 发明授权

US4602055A Process for pad dyeing cellulosic textile materials 失效
标题翻译：羊毛染色纤维素纺织材料的工艺
公开(公告)号：US4602055A
公开(公告)日：1986-07-22
申请号：US617443
申请日：1984-06-04
申请人： Paul Schafer , Hans-Ulrich Berendt
发明人： Paul Schafer , Hans-Ulrich Berendt
IPC分类号： C08F283/06 , D06P1/613 , C08G65/08 , C08K5/42 , C08L71/02
CPC分类号： C08F283/06 , D06P1/6133
摘要： Cellulosic textile material is dyed with substantive dyes or preferably with reactive dyes. Dyeing is carried out by applying to the cellulosic material an aqueous dye liquor which contains, in addition to the dye, a graft polymer which is obtained from an adduct of an alkylene oxide, preferably propylene oxide, with an at least trihydric aliphatic alcohol, e.g. glycerol, and acrylamide or methacrylamide. The cellulosic material is then subjected to a heat treatment, e.g. by steaming or with microwaves, or is stored cold, to fix the dyes.This dye liquor increases the liquor pick-up and thus also increases the dye yield, while at the same time excellent levelness is achieved.
摘要翻译：纤维素纺织材料用实质染料或优选与活性染料染色。染色是通过向纤维素材料施加含水染料液体而进行的，所述染料液除了染料之外还含有接枝聚合物，所述接枝聚合物由烯化氧，优选氧化丙烯的加合物与至少三元脂肪醇，例如，甘油，丙烯酰胺或甲基丙烯酰胺。然后对纤维素材料进行热处理，例如通过蒸或用微波，或冷藏，以固定染料。这种染液增加了液体吸收量，从而也增加了染料产率，同时实现了良好的水平度。

6. 发明授权

US4705525A Water-soluble or water-dispersible graft polymers, process for their preparation and the use thereof 失效
标题翻译：水溶性或水分散性接枝聚合物，其制备方法及其用途
公开(公告)号：US4705525A
公开(公告)日：1987-11-10
申请号：US876033
申请日：1986-06-19
申请人： Heinz Abel , Paul Schafer , Hans-Ulrich Berendt
发明人： Heinz Abel , Paul Schafer , Hans-Ulrich Berendt
IPC分类号： C08F283/00 , C08F283/06 , C11D3/37 , D06L1/14 , D06P1/613
CPC分类号： D06L1/14 , C08F283/06 , C11D3/3788 , D06P1/613 , Y10S8/917 , Y10S8/918 , Y10S8/922 , Y10S8/924 , Y10S8/927
摘要： Water-soluble or water-dispersible graft polymers which comprise (a) as main chain, a polyalkylene glycol, in particular polyethylene glycol, which is esterified at the two terminal hydroxyl groups with a long chain fatty acid of 8 to 26, preferably 10 to 22, carbon atoms, and (b) grafted ethylenically unsaturated monomers, preferably acrylic acid or acrylamide, in the form of side chains at individual carbon atoms of the polyalkylene glycol chain.These graft polymers are particularly suitable for use as anticrease agents for dyeing, whitening, bleaching or washing textile materials, e.g. textiles containing cellulosic fibres, natural or synthetic polyamide fibres, polyacrylonitrile fibres or, in particular, for dyeing or whitening cotton or polyester fibres.
摘要翻译：水溶性或水分散性接枝聚合物，其包含（a）主链，聚亚烷基二醇，特别是聚乙二醇，其在两末端羟基上被酯化，长链脂肪酸为8至26，优选10至 22，碳原子，和（b）接枝的烯属不饱和单体，优选丙烯酸或丙烯酰胺，以聚亚烷基二醇链的单个碳原子上的侧链形式。这些接枝聚合物特别适合用作染色，增白，漂白或洗涤织物材料的抗磨剂，例如。含有纤维素纤维，天然或合成聚酰胺纤维，聚丙烯腈纤维或特别是用于染色或增白棉或聚酯纤维的纺织品。

7. 发明授权

US4612016A Process for dyeing cellulosic textile materials 失效
标题翻译：染色纤维素纺织材料的方法
公开(公告)号：US4612016A
公开(公告)日：1986-09-16
申请号：US706226
申请日：1985-02-27
申请人： Carl A. Jaeger , Hans-Ulrich Berendt , Paul Schafer
发明人： Carl A. Jaeger , Hans-Ulrich Berendt , Paul Schafer
IPC分类号： D06P1/52 , D06P1/607 , D06P1/613 , D06P3/60 , D06B1/02 , D06P3/62
CPC分类号： D06P1/6133 , D06P1/5257 , Y10S8/918
摘要： Cellulosic textile material is dyed with substantive dyes or preferably with reactive dyes. Dyeing is carried out by applying to the cellulosic material, by a non-pad method, an aqueous dye liquor which contains, in addition to the dye, a graft polymer which is obtained from an adduct of an alkylene oxide, preferably propylene oxide, with an at least trihydric aliphatic alcohol, e.g. glycerol, and acrylamide or methacrylamide. The cellulosic material is then subjected to a heat treatment, e.g. by steaming or with microwaves, or is preferably stored cold, to fix the dyes.This dyeing process affords dyeings with excellent penetration of the fabric and with level depth of shade from edge to edge.
摘要翻译：纤维素纺织材料用实质染料或优选与活性染料染色。染色是通过对非纤维素方法施加到纤维素材料上而进行的，该染料液除了染料之外还含有接枝聚合物，该接枝聚合物是由烯化氧，优选环氧丙烷的加合物与至少三元脂肪醇，例如甘油，丙烯酰胺或甲基丙烯酰胺。然后对纤维素材料进行热处理，例如通过蒸或用微波，或优选储存冷，以固定染料。这种染色工艺提供了具有优异的织物渗透性和从边缘到边缘的色调水平深度的染色。

8. 发明授权

US4496472A Process for bleaching cellulosic fibre materials using oligomers of phosphonic acid esters as stabilizers in alkaline, peroxide-containing bleaching liquors 失效
标题翻译：使用膦酸酯的低聚物作为碱性，含过氧化物的漂白液中的稳定剂漂白纤维素纤维材料的方法
公开(公告)号：US4496472A
公开(公告)日：1985-01-29
申请号：US450718
申请日：1982-12-17
申请人： Paul Schafer , Hans-Ulrich Berendt
发明人： Paul Schafer , Hans-Ulrich Berendt
IPC分类号： C11D7/54 , C11D3/39 , C11D7/36 , D06L3/02 , C09K3/00
CPC分类号： D06L3/021 , C11D3/394
摘要： Oligomers of the formula ##STR1## wherein Y.sub.1 is hydrogen or --CO--T.sub.1, R.sub.1 Q.sub.1 and T.sub.1 are alkyl and n.sub.1 is 1 to 16, or alkali metal salts thereof, are used as stabilizers in peroxide-containing alkaline liquors for bleaching cellulosic fibre materials.
摘要翻译：其中Y 1为氢或-CO-T 1，R 1 Q 1和T 1为烷基且n 1为1〜16的式[IMAGE]的低聚物或其碱金属盐用作漂白纤维素纤维的含过氧化物的碱性液体中的稳定剂材料

9. 发明授权

US4604099A Process for printing cellulose-containing textile material with foam-containing reactive dyes and addition of (meth) acrylamide polymers 失效
标题翻译：用含泡沫的活性染料印刷含纤维素的纺织材料和加入（甲基）丙烯酰胺聚合物的方法
公开(公告)号：US4604099A
公开(公告)日：1986-08-05
申请号：US694189
申请日：1985-01-23
申请人： Hans-Ulrich Berendt , Paul Schafer
发明人： Hans-Ulrich Berendt , Paul Schafer
IPC分类号： D06P1/613 , D06P1/96 , D06P3/66 , D06P1/52
CPC分类号： D06P1/6133 , D06P1/965 , D06P3/66 , Y10S8/918
摘要： Textile cellulose material is printed with a reactive dye by applying to the cellulose material a foamed aqueous preparation which, in addition to the dye, contains foaming agent and a homopolymer or copolymer of acrylamide or methacrylamide or preferably a graft polymer obtained from an adduct of an alkylene oxide, preferably propylene oxide, on an at least trihydric aliphatic alcohol, for example glycerol, and acrylamide or methacrylamide.The printed cellulose material is then subjected to a heat treatment, for example steaming, to fix the dye.This foamed printing color produces without the use of thickenings a deep, level and crisp print which also has excellent handle.
摘要翻译：纺织纤维素材料通过向纤维素材料施加泡沫水性制剂而印刷有活性染料，发泡水性制剂除了染料之外还含有发泡剂和丙烯酰胺或甲基丙烯酰胺的均聚物或共聚物，或优选由环氧烷，优选环氧丙烷，至少三元脂肪醇，例如甘油，丙烯酰胺或甲基丙烯酰胺。然后将印刷的纤维素材料进行热处理，例如蒸汽以固定染料。这种泡沫印刷颜色产生而不使用增厚的深度，水平和清晰的印刷品，其也具有优异的手感。

10. 发明授权

US4453946A Dyeing assistant and use thereof in dyeing synthetic fibre material 失效
标题翻译：染色助剂及其在染色合成纤维材料中的应用
公开(公告)号：US4453946A
公开(公告)日：1984-06-12
申请号：US370762
申请日：1982-04-22
申请人： Heinz Abel , Paul Schafer , Hans-Ulrich Berendt
发明人： Heinz Abel , Paul Schafer , Hans-Ulrich Berendt
IPC分类号： D06L3/12 , D06P1/642 , D06P1/667
CPC分类号： D06P1/6421 , D06L3/1264
摘要： The invention relates to a dyeing assistant comprising at least(A) an O-cyanoethylated compound of the formulaR(O--CH.sub.2 CH.sub.2 CN).sub.n, (1)wherein R is an n-valent aliphatic, cycloaliphatic or araliphatic radical, and n is 1 to 5,(B) an anionic surfactant(C) a non-ionic surfactant and optionally at least one of the following components(D) an aliphatic alcohol containing 5 to 18 carbon atoms, a siloxane-oxyalkylene copolymer or a mixture thereof, and(E) a polar solvent.This assistant is used in particular for dyeing synthetic fibre material, preferably polyester fibres, to improve levelness and crockfastness and to increase the dye yield.
摘要翻译：本发明涉及一种染色助剂，其至少包含（A）式R（O-CH 2 CH 2 CN）n的O-氰乙基化化合物，（1）其中R是n价脂肪族，脂环族或芳脂族基，n为1 至（5），（B）阴离子表面活性剂（C）非离子表面活性剂和任选的至少一种以下组分（D）含有5至18个碳原子的脂族醇，硅氧烷 - 氧化烯共聚物或其混合物，和（E）极性溶剂。该助剂特别用于染色合成纤维材料，优选聚酯纤维，以提高水平度和耐克度，并提高染色产率。

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