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    • 1. 发明授权
    • Dewatering agent for sludge
    • 污泥脱水剂
    • US5525692A
    • 1996-06-11
    • US307571
    • 1994-12-28
    • Akiyoshi NagamotoHiroshi Oka
    • Akiyoshi NagamotoHiroshi Oka
    • C08F20/34B01D21/01C02F11/14C08F2/16C08F8/00C08F20/52C08F20/60
    • C02F11/14B01D21/01C08F220/60C08F8/00C08F220/56C08F2800/10
    • A novel process for preparing an acrylic polymer containing a tertiary amino group which is not quaternized or not salt formed and having a high molecular weight, characterized by reacting an aqueous solution of an acrylic monomer containing a tertiary amino group with carbonic acid gas to generate an acrylic monomer containing a tertiary ammonium carbonate, homopolymerizing the obtained monomer or copolymerizing the obtained monomer with the other vinyl monomer copolymerizable with the obtained monomer to give a polymer containing a structural unit of a tertiary ammonium carbonate, and decarboxylating the polymer with heating and/or reducing the pressure is provided, and particularly, an article containing a water-soluble vinyl polymer which contains at least 5% by mole of the above-mentioned structural unit of a tertiary amino group and whose intrinsic viscosity [.eta.] is at least 1 dl/g is available as an excellent dewatering agent for sludge.
    • PCT No.PCT / JP93 / 00850 Sec。 371日期1994年12月28日第 102(e)1994年12月28日PCT PCT 1993年6月23日PCT公布。 No.W095 / 00559 PCT出版物 日期1995年1月5日。一种制备含有叔氨基的丙烯酸聚合物的新方法,其不是季铵化的或不形成盐并具有高分子量,其特征在于使含有叔氨基的丙烯酸单体的水溶液 用碳酸气体生成含有碳酸铵的丙烯酸类单体,均聚所得单体或将所得单体与可与所得单体共聚的其它乙烯基单体共聚,得到含有碳酸铵的结构单元的聚合物和脱羧基 提供加热和/或降低压力的聚合物,特别是包含含有至少5摩尔%上述叔氨基结构单元的水溶性乙烯基聚合物并且其特性粘度[ eta]为至少1dl / g可用作污泥的优良脱水剂。
    • 3. 发明授权
    • Process for producing hydrogenation product of ring-opening polymer
    • 制备开环聚合物加氢产物的方法
    • US5202388A
    • 1993-04-13
    • US800231
    • 1991-11-29
    • Akira IioNoboru OshimaYosihiro OhiraMasao SakamotoHiroshi Oka
    • Akira IioNoboru OshimaYosihiro OhiraMasao SakamotoHiroshi Oka
    • C08F8/04C08G61/08
    • C08G61/08
    • A process for producing a hydrogenation product of ring-opening polymer by hydrogenating, in the presence of a hydrogenation catalyst, the non-aromatic carbon-to-carbon double bond present in a ring-opening polymer obtained by subjecting to ring-opening polymerization at least one norbornene derivative represented by general formula (I): ##STR1## wherein A and B independently represent hydrogen atoms or hydrocarbon groups having 1-10 carbon atoms, X and Y independently represent hydrogen atoms, halogen atoms or monovalent organic groups, and m is 0 or 1, alone or in combination with a monomer copolymerizable with said norbronene derivative, characterized by using, as the hydrogenation catalyst, a ruthenium compound represented by general formula (II):RuH.sub.k Q.sub.n T.sub.p Z.sub.q (11)wherein Q represents a halogen atom, T represents at least one atomic group selected from the group consisting of CO, NO and CH.sub.3 COCH.sub.2 COCH.sub.3, Z represents PR.sup.1 R.sup.2 R.sup.3 (R.sup.1, R.sub.2 and R.sup.3 independently represent alkyl groups, alkenyl groups or phenyl groups), k is 1 or 2, n is 0, 1 or 2, p is 1 or 2, and q is 2 or 3. This process enables hydrogenation with a small amount of a hydrogenation catalyst in a very high hydrogenation degree even when the polymer to be hydrogenated is a ring-opening polymer of a specific tetracyclodeodecene compound, and enables the hydrogenation reaction to be carried out easily.
    • 一种开环聚合物的氢化产物的制备方法,在氢化催化剂的存在下,通过在通式(I)中进行开环聚合得到的开环聚合物中存在的非芳族碳 - 碳双键氢化, 由通式(I)表示的至少一种降冰片烯衍生物:其中A和B独立地表示氢原子或具有1-10个碳原子的烃基,X和Y独立地表示氢原子,卤素原子或一价有机基团 ,并且m为0或1,单独或与可与所述降冰片烯衍生物共聚的单体组合,其特征在于使用由通式(II)表示的钌化合物作为氢化催化剂:RuHkQnTpZq(11)其中Q表示卤素 原子,T表示选自CO,NO和CH 3 COCH 2 COCH 3中的至少一个原子团,Z表示PR1R2R3(R1,R2和R3独立地表示烷基,烯烃 基团或苯基),k为1或2,n为0,1或2,p为1或2,q为2或3.该方法可使用少量氢化催化剂进行非常高的氢化 氢化程度即使待氢化的聚合物是特定四环十二碳烯化合物的开环聚合物,并且能够容易地进行氢化反应。
    • 4. 发明授权
    • Process for producing tetrahydrofuran and 1,4-butanediol
    • 生产四氢呋喃和1,4-丁二醇的方法
    • US4268447A
    • 1981-05-19
    • US102658
    • 1979-12-12
    • Yoshinori YoshidaHiroshi Oka
    • Yoshinori YoshidaHiroshi Oka
    • C07C27/00C07C27/02C07C29/09C07C29/128C07C29/80C07C31/20C07C67/00C07D307/08
    • C07C29/095C07C29/1285C07D307/08
    • A process for producing simultaneously tetrahydrofuran and 1,4-butanediol in any desired proportion which comprises (a) reacting the acetic ester of 1,4-butanediol with a theoretical or smaller quantity, based on said acetic ester, of water (preferably 0.2-0.8 mole of water per mole of said acetic ester) in the presence of an acidic catalyst, (b) distilling, in the first distillation column, the reaction mixture to separate it into a distillate comprising tetrahydrofuran as major constituent and a bottom stream comprising as major constituent the acetic ester of 1,4-butanediol and (c) subjecting, in the second reaction-distillation column, at least a part of said bottom stream to a counter-current gas-liquid contact reaction with methanol, the quantity of said methanol being preferably 1-5 moles per mole of the acetate group of the acetic ester, in the presence of an acidic or basic catalyst and, simultaneously therewith, separating the reaction mixture into a bottom stream comprising 1,4-butanediol as major constituent and a distillate comprising methyl acetate as major constituent. By this process, methanol and catalyst can be economized to a great extent.
    • 一种以任何所需比例同时生产四氢呋喃和1,4-丁二醇的方法,其包括(a)使基于所述乙酸酯的理论或更少量的1,4-丁二醇的乙酸酯与水反应(优选0.2- 在酸性催化剂存在下,将0.8摩尔水/摩尔的所述乙酸酯),(b)在第一蒸馏塔中蒸馏反应混合物以将其分离成包含四氢呋喃作为主要成分的馏出物和含有 主要成分是1,4-丁二醇的乙酸酯和(c)在第二反应 - 蒸馏塔中使至少一部分所述底部流与甲醇进行逆流气液接触反应,所述量 在酸性或碱性催化剂的存在下,每摩尔乙酸酯的乙酸酯基团,甲醇优选为1-5摩尔,同时将反应混合物分离成包含 主要成分为1,4-丁二醇,乙酸甲酯为主要成分的馏出物。 通过这个过程,甲醇和催化剂可以在很大程度上节约。
    • 6. 发明授权
    • Process for producing an alkylglycoside
    • 制备烷基糖苷的方法
    • US5886161A
    • 1999-03-23
    • US83110
    • 1998-05-22
    • Hiroshi OkaKenichi Tachi
    • Hiroshi OkaKenichi Tachi
    • C07H1/00B01J31/02C07B61/00C07H15/04C07G3/00
    • C07H15/04
    • The process for producing an alkylglycoside, wherein the amount of coarse sugar particles in alkylglycoside can be reduced without reducing reaction yield, is provided.The process for producing an alkylglycoside comprises,a) mixing a hydrated solid sugar with a higher alcohol;b) dehydrating the mixture at a reduced pressure at a temperature of lower than a melting point of the hydrated solid sugar until a water content of the solid sugar becomes not more than 0.5% by weight;c) heating the mixture to 90.degree.-140.degree. C. so that the proportion of particles having a particle diameter of 0.3 mm or more may be not more than 0.1% by weight of the solid sugar in the mixture at the end of this step;d) reacting the mixture with an acid catalyst added thereto at a temperature of 90.degree.-140.degree. C. at a pressure of 5-100 mmHg; ande) neutralizing the acid catalyst contained in the product mixture with an alkali after the reaction has been completed.
    • 提供了制备烷基糖苷的方法,其中可以在不降低反应产率的情况下降低烷基糖苷中的粗糖颗粒的量。 制备烷基糖苷的方法包括:a)将水合固体糖与高级醇混合; b)在低于水合固体糖的熔点的温度下在减压下使混合物脱水,直到固体糖的含水量不超过0.5重量%; c)将混合物加热至90-140℃,使得粒径在0.3mm以上的颗粒的比例可以在该步骤结束时在混合物中固体糖的重量比不超过0.1% ; d)使混合物与加入其中的酸催化剂在90-140℃的温度下在5-100mmHg的压力下反应; 和e)在反应完成后用碱中和产物混合物中所含的酸催化剂。
    • 8. 发明授权
    • Stable disc unit having reduced thickness
    • 具有减小厚度的稳定盘单元
    • US5128818A
    • 1992-07-07
    • US466010
    • 1990-01-16
    • Shigeki KoizumiHiroshi Oka
    • Shigeki KoizumiHiroshi Oka
    • G11B17/028G11B19/20G11B23/00H02K7/108
    • G11B17/0282G11B19/2009G11B23/0035H02K7/1085
    • A disc drive unit for rotating a data storage disc such as an optical disc or a magnetic disc comprising a turntable for supporting and rotating the disc, and a motor for rotating the turntable. The turntable also functions as a rotor of the motor. At least one driving magnet is mounted on the turntable in opposing relationship with at least one coil of the motor. At least one attraction magnet for securely holding the disc in position on the turntable is securely mounted thereon. One yoke functions as yokes, each of which must be provided for each of two kinds of magnets. When the turntable is made of a plastic, at least one attraction magnet and/or at least one driving magnet is defined by partially magnetizing the turntable at at least one predetermined region thereof. The turntable is securely attached to the bearings so that it rotates about a shaft having one end securely fixed to a stationary portion of the motor. When rotating the disc, one of the bearings is used as a member for securely holding the disc in position on the turntable.
    • 用于旋转诸如光盘或磁盘的数据存储盘的盘驱动单元,包括用于支撑和旋转盘的转盘和用于旋转转台的电动机。 转台也用作电机的转子。 至少一个驱动磁体以与电机的至少一个线圈相对的关系安装在转台上。 用于将盘牢固地保持在转台上的适当位置的至少一个吸引磁体牢固地安装在转台上。 一个磁轭用作磁轭,每个磁轭必须为两种磁体中的每一种提供。 当转盘由塑料制成时,至少一个吸引磁体和/或至少一个驱动磁体是通过在其至少一个预定区域部分磁化转台来限定的。 转盘牢固地连接到轴承上,使得其绕一轴旋转,该轴具有一端牢固地固定在马达的静止部分上。 当旋转盘时,其中一个轴承用作用于将盘牢固地保持在转盘上的适当位置的构件。