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1. 发明授权

US5525673A Hydroxyl and epoxy polymer, hydrolyzable silicone polymer, either containing flourine monomer 失效
标题翻译：羟基和环氧聚合物，可水解的硅氧烷聚合物，含有含氟单体
公开(公告)号：US5525673A
公开(公告)日：1996-06-11
申请号：US277429
申请日：1994-07-18
申请人： Akimasa Nakahata , Nobushige Numa , Masahiro Yamane , Osamu Isozaki , Noboru Nakai
发明人： Akimasa Nakahata , Nobushige Numa , Masahiro Yamane , Osamu Isozaki , Noboru Nakai
IPC分类号： C08L63/00 , C09D201/04 , C08F4/52 , C08F4/76 , C08F24/00 , C08F30/08
CPC分类号： C08L63/00 , C09D201/04
摘要： Disclosed are:1) a three-component resin composition comprising a hydroxyl group-containing compound (A), an epoxy group-containing compound (B) and a silane group-containing compound (C);2) a two-component resin composition comprising a hydroxyl group-containing compound (A) and silane group- and epoxy group-containing compound (D);3) a two-component resin composition comprising hydroxyl group- and silane group-containing compound (E) and epoxy group-containing compound (B); and4) two-component resin composition comprising hydroxyl group- and epoxy group-containing compound (F) and silane group-containing compound (C); wherein at least one of the components in each of the resin compositions 1) to 4) is (are) fluorine-containing resin;5) a curable composition comprising one of the resin compositions 1) to 4) and a metal chelate compound as curing catalyst; and6) coating compositions comprising such curing composition and when required a pigment.
摘要翻译：公开的是：1）包含含羟基的化合物（A），含环氧基的化合物（B）和含硅烷基的化合物（C）的三组分树脂组合物; 2）包含含羟基的化合物（A）和含硅烷基和含环氧基的化合物（D）的双组分树脂组合物; 3）包含含羟基和含硅烷基的化合物（E）和含环氧基的化合物（B）的双组分树脂组合物; 和4）包含含羟基和含环氧基的化合物（F）和含硅烷基化合物（C）的双组分树脂组合物; 其中，树脂组合物1）〜4）中的至少一种成分为含氟树脂， 5）包含树脂组合物1）至4）之一的可固化组合物和作为固化催化剂的金属螯合物; 和6）包含这种固化组合物和需要时颜料的涂料组合物。

2. 发明授权

US5260376A Resin composition, curable composition and coating composition 失效
标题翻译：树脂组合物，可固化组合物和涂料组合物
公开(公告)号：US5260376A
公开(公告)日：1993-11-09
申请号：US904257
申请日：1992-06-25
申请人： Akimasa Nakahata , Nobushige Numa , Masahiro Yamane , Osamu Isozaki , Noboru Nakai
发明人： Akimasa Nakahata , Nobushige Numa , Masahiro Yamane , Osamu Isozaki , Noboru Nakai
IPC分类号： C08L63/00 , C09D201/04 , C08L27/14 , C08L83/00
CPC分类号： C08L63/00 , C09D201/04
摘要： Disclosed are:1) a three-component resin composition comprising a hydroxyl group-containing compound (A), an epoxy group-containing compound (B) and a silane group-containing compound (C);2) a two-component resin composition comprising a hydroxyl group-containing compound (A) and silane group- and epoxy group-containing compound (D);3) a two component resin composition comprising hydroxyl group- and silane group-containing compound (E) and epoxy group-containing compound (B); and4) two-component resin composition comprising hydroxyl group- and epoxy group-containing compound (F) and silane group-containing compound (C); wherein at least one of the components in each of the resin compositions 1) to 4) is (are) fluorine-containing resin;5) a curable composition comprising one of the resin compositions 1) to 4) and a metal chelate compound as curing catalyst; and6) coating compositions comprising such curing composition and when required a pigment.
摘要翻译：公开的是：1）包含含羟基的化合物（A），含环氧基的化合物（B）和含硅烷基的化合物（C）的三组分树脂组合物; 2）包含含羟基的化合物（A）和含硅烷基和含环氧基的化合物（D）的双组分树脂组合物; 3）包含含羟基和含硅烷基的化合物（E）和含环氧基的化合物（B）的双组分树脂组合物; 和4）包含含羟基和含环氧基的化合物（F）和含硅烷基化合物（C）的双组分树脂组合物; 其中，树脂组合物1）〜4）中的至少一种成分为含氟树脂， 5）包含树脂组合物1）至4）之一的可固化组合物和作为固化催化剂的金属螯合物; 和6）包含这种固化组合物和需要时颜料的涂料组合物。

3. 发明授权

US5408001A Hydroxyl and hydrolyzable groups-containing silicone resin with polyepoxy compound 失效
标题翻译：含羟基和可水解基团的硅氧烷树脂与聚环氧化合物
公开(公告)号：US5408001A
公开(公告)日：1995-04-18
申请号：US107580
申请日：1993-08-18
申请人： Akimasa Nakahata , Nobushige Numa , Masahiro Yamane , Osamu Isozaki , Noboru Nakai
发明人： Akimasa Nakahata , Nobushige Numa , Masahiro Yamane , Osamu Isozaki , Noboru Nakai
IPC分类号： C08L63/00 , C09D201/04 , C08L27/12 , C08L27/14 , C08L33/14 , C08L63/02
CPC分类号： C08L63/00 , C09D201/04
摘要： Disclosed are:1) a three-component resin composition comprising a hydroxyl group-containing compound (A), an epoxy group-containing compound (B) and a silane group-containing compound (C);2) a two-component resin composition comprising a hydroxyl group-containing compound (A) and silane group- and epoxy group-containing compound (D);3) a two-component resin composition comprising hydroxyl group- and silane group-containing compound (E) and epoxy group-containing compound (B); and4) two-component resin composition comprising hydroxyl group- and epoxy group-containing compound (F) and silane group-containing compound (C); wherein at least one of the components in each of the resin compositions 1) to 4) is (are) fluorine-containing resin;5) a curable composition comprising one of the resin compositions 1) to 4) and a metal chelate compound as curing catalyst; and6) coating compositions comprising such curing composition and when required a pigment.
摘要翻译：公开的是：1）包含含羟基的化合物（A），含环氧基的化合物（B）和含硅烷基的化合物（C）的三组分树脂组合物; 2）包含含羟基的化合物（A）和含硅烷基和含环氧基的化合物（D）的双组分树脂组合物; 3）包含含羟基和含硅烷基的化合物（E）和含环氧基的化合物（B）的双组分树脂组合物; 和4）包含含羟基和含环氧基的化合物（F）和含硅烷基化合物（C）的双组分树脂组合物; 其中，树脂组合物1）〜4）中的至少一种成分为含氟树脂， 5）包含树脂组合物1）至4）之一的可固化组合物和作为固化催化剂的金属螯合物; 和6）包含这种固化组合物和需要时颜料的涂料组合物。

4. 发明授权

US5418293A Dispersion-type resin composition, curable composition and coating composition 失效
标题翻译：分散型树脂组合物，固化性组合物和涂料组合物
公开(公告)号：US5418293A
公开(公告)日：1995-05-23
申请号：US117321
申请日：1993-09-07
申请人： Nobushige Numa , Akimasa Nakahata , Masahiro Yamane , Osamu Isozaki , Noboru Nakai
发明人： Nobushige Numa , Akimasa Nakahata , Masahiro Yamane , Osamu Isozaki , Noboru Nakai
IPC分类号： C08L27/12 , C08F2/08 , C08F2/14 , C08F2/44 , C09D127/12 , C09D127/16 , C08F259/08 , C08F259/00
CPC分类号： C08F2/08
摘要： The invention provides: 1) a dispersion-type resin composition including polymer particles insoluble in an organic solvent, the resin composition being prepared by polymerizing a radically polymerizable unsaturated monomer in the organic solvent in the presence of a fluorine-type resin containing silane group and epoxy group; 2) a resin composition including polymer particles insoluble in an organic solvent, the resin composition being prepared by polymerizing a radically polymerizable unsaturated monomer in the organic solvent in the presence of a dispersion stabilizer comprising at least one of a component (I) having silane group, and a component (II) having epoxy group, at least one of components (I) and (II) being a fluorine-containing resin; 3) a curable composition including one of the resin compositions 1) and 2) and a metal chelate compound; and 4) a coating composition including one of the curable composition and the resin compositions.
摘要翻译：本发明提供：1）一种分散型树脂组合物，其包含不溶于有机溶剂的聚合物颗粒，该树脂组合物是通过在含有硅烷基团的含氟型树脂和含硅烷基团的存在下使有机溶剂中的可自由基聚合的不饱和单体聚合而制备的，环氧基; 2）包含不溶于有机溶剂的聚合物颗粒的树脂组合物，所述树脂组合物通过在包含具有硅烷基的组分（I）中的至少一种的分散稳定剂的存在下在有机溶剂中聚合自由基聚合性不饱和单体而制备），和具有环氧基的组分（II），组分（I）和（II）中的至少一种是含氟树脂; 3）包含树脂组合物1）和2）和金属螯合物之一的可固化组合物; 和4）包含可固化组合物和树脂组合物之一的涂料组合物。

5. 发明授权

US5387646A Fluorine-type resin composition, curable composition and coating composition 失效
标题翻译：氟类树脂组合物，可固化组合物和涂料组合物
公开(公告)号：US5387646A
公开(公告)日：1995-02-07
申请号：US43984
申请日：1993-04-07
申请人： Akimasa Nakahata , Nobushige Numa , Masahiro Yamane , Osamu Isozaki , Noboru Nakai
发明人： Akimasa Nakahata , Nobushige Numa , Masahiro Yamane , Osamu Isozaki , Noboru Nakai
IPC分类号： C08L27/12 , C08G59/30 , C08G59/32 , C08G59/70 , C08L43/04 , C09D127/12 , C09D127/16 , C09D163/00 , C08L27/14 , C08L83/00
CPC分类号： C09D163/00 , C08G59/306 , C08G59/32 , C08G59/70 , C08L43/04
摘要： The invention provides:1) a fluorine-containing resin composition including:a) a fluorine-containing resin having (i) a hydrolyzable group attached directly to a silicon atom and/or a silanol group and (ii) an epoxy group in the molecule, orb) a mixture of a component (I) having a hydrolyzable group attached directly to a silicon atom and/or a silanol group and a component (II) having an epoxy group, such that at least one of the components (I) and (II) is a fluorine-containing resin;2) a curable composition including the resin composition and a metal chelate compound; and3) a coating composition including this resin composition or this curable composition.
摘要翻译：本发明提供：1）一种含氟树脂组合物，其包含：a）含有（i）直接与硅原子和/或硅烷醇基相连的水解基团和（ii）分子中的环氧基的含氟树脂或b）具有直接与硅原子直接连接的可水解基团的组分（I）和/或硅烷醇基的组分和具有环氧基的组分（II）的混合物，使得组分（I）中的至少一种和（II）是含氟树脂; 2）包含该树脂组合物和金属螯合物的可固化组合物; 和3）包含该树脂组合物或该可固化组合物的涂料组合物。

6. 发明授权

US5166265A Resin composition, curable composition and coating composition 失效
标题翻译：树脂组合物，可固化组合物和涂料组合物
公开(公告)号：US5166265A
公开(公告)日：1992-11-24
申请号：US486697
申请日：1990-03-01
申请人： Akimasa Nakahata , Nobushige Numa , Masahiro Yamane , Osamu Isozaki , Noboru Nakai
发明人： Akimasa Nakahata , Nobushige Numa , Masahiro Yamane , Osamu Isozaki , Noboru Nakai
IPC分类号： C08G59/00 , C08G59/18 , C08G59/20 , C08G59/40 , C08G59/62 , C08G59/68 , C08G59/70 , C08L63/00 , C09D163/00 , C09D201/04
CPC分类号： C08L63/00 , C09D201/04
摘要： Disclosed are:1) a three-component resin composition comprising a hydroxyl group-containing compound (A), an epoxy group-containing compound (B) and a silane group-containing compound (C);2) a two-component resin composition comprising a hydroxyl group-containing compound (A) and silane group- and epoxy group-containing compound (D);3) a two-component resin composition comprising hydroxyl group- and silane group-containing compound (E) and epoxy group-containing compound (B); and4) two-component resin composition comprising hydroxyl group- and epoxy group-containing compound (F) and silane group-containing compound (C); wherein at least one of the components in each of the resin compositions 1) to 4) is (are) fluorine-containing resin;5) a curable composition comprising one of the resin compositions 1) to 4) and a metal chelate compound as curing catalyst; and6) coating compositions comprising such curing composition and when required a pigment.
摘要翻译：公开的是：1）包含含羟基的化合物（A），含环氧基的化合物（B）和含硅烷基的化合物（C）的三组分树脂组合物; 2）包含含羟基的化合物（A）和含硅烷基和含环氧基的化合物（D）的双组分树脂组合物; 3）包含含羟基和含硅烷基的化合物（E）和含环氧基的化合物（B）的双组分树脂组合物; 和4）包含含羟基和含环氧基的化合物（F）和含硅烷基化合物（C）的双组分树脂组合物; 其中，树脂组合物1）〜4）中的至少一种成分为含氟树脂， 5）包含树脂组合物1）至4）之一的可固化组合物和作为固化催化剂的金属螯合物; 和6）包含这种固化组合物和需要时颜料的涂料组合物。

7. 发明授权

US5609918A Method of forming a top coat 失效
标题翻译：形成面漆的方法
公开(公告)号：US5609918A
公开(公告)日：1997-03-11
申请号：US477613
申请日：1995-06-07
申请人： Sachio Yamaguchi, deceased , Akimasa Nakahata , Satoshi Ikushima , Yasumasa Okumura , Haruhiko Aida , Shigeo Nishiguchi , Osamu Isozaki
发明人： Sachio Yamaguchi, deceased , Akimasa Nakahata , Satoshi Ikushima , Yasumasa Okumura , Haruhiko Aida , Shigeo Nishiguchi , Osamu Isozaki
IPC分类号： B05D7/00 , C09D133/06 , C09D163/00 , C09D201/02 , B05D1/36
CPC分类号： B05D7/53 , C09D133/066 , C09D133/068 , C09D163/00 , C09D201/02
摘要： The invention provides a method of forming a top coat by forming in sequence a colored base coat on a substrate and a clear coat, the method being characterized in that at least one of the colored base coat and the clear coat is formed by a curable coating composition consisting essentially of:(a) (a-1) a resin having a hydroxyl group, a carboxyl group and an epoxy group in the same molecule, or (a-2) a mixture of a hydroxyl- and carboxyl-containing resin with a polyepoxide;(b) a silicon compound having, per molecule, at least one silanol group and/or at least one hydrolyzable group directly bound to a silicon atom; and(c) an organic solvent.
摘要翻译：本发明提供一种通过在基材上形成有色底涂层和透明涂层来形成顶涂层的方法，其特征在于，着色底涂层和透明涂层中的至少一个通过可固化涂层形成组合物基本上由以下组成：（a）（a-1）在同一分子中具有羟基，羧基和环氧基的树脂，或（a-2）含羟基和羧基的树脂与聚环氧化物（b）每分子具有至少一个硅烷醇基和/或至少一个与硅原子直接结合的可水解基团的硅化合物; 和（c）有机溶剂。

8. 发明授权

US5583246A Lactone-modified organopolysiloxane compound and a process for its preparation 失效
标题翻译：内酯改性的有机聚硅氧烷化合物及其制备方法
公开(公告)号：US5583246A
公开(公告)日：1996-12-10
申请号：US573545
申请日：1995-12-15
申请人： Haruhiko Aida , Noboru Nakai , Osamu Isozaki
发明人： Haruhiko Aida , Noboru Nakai , Osamu Isozaki
IPC分类号： C08G77/445 , C07F7/04 , C08G77/02 , C08G77/42 , C09D183/04 , C09D183/06 , C07F7/18 , C07F7/08
CPC分类号： C08G77/02 , C07F7/04
摘要： The invention provides a lactone-modified organopolysiloxane compound represented by the formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are the same or different and each represents a methyl group, an ethyl group, a n-propyl group, an isopropyl group or a group represented by the formula ##STR2## wherein R.sub.5 is a methyl group, an ethyl group, a n-propyl group or an isopropyl group, X is a saturated divalent hydrocarbon group having 2 to 14 carbon atoms, and m is an integer of 1 to 3, provided that at least one of R.sub.1, R.sub.2, R.sub.3 and R.sub.4 is a group represented by the formula ##STR3## wherein R.sub.5, X and m are as defined above, and n is an integer of 1 to 100. The polysiloxane compound of the invention is excellent in compatibility with various organic resins.
摘要翻译：本发明提供由式（I）表示的内酯改性的有机聚硅氧烷化合物，其中R 1，R 2，R 3和R 4相同或不同，并且各自表示甲基，乙基，正丙基，异丙基或由下式表示的基团：其中R 5为甲基，乙基，正丙基或异丙基，X为碳原子数2〜14的饱和二价烃基，m为其中R 1，R 2，R 3和R 4中的至少一个是由下式表示的基团：其中R 5，X和m定义同上，n为1至100的整数。本发明的聚硅氧烷化合物与各种有机树脂的相容性优异。

9. 发明授权

US5079312A Process for preparing polysiloxane-containing resin 失效
标题翻译：制备含多羟基树脂的方法
公开(公告)号：US5079312A
公开(公告)日：1992-01-07
申请号：US522401
申请日：1990-05-11
申请人： Osamu Isozaki , Noboru Nakai , Koichiro Murata
发明人： Osamu Isozaki , Noboru Nakai , Koichiro Murata
IPC分类号： C08F30/08 , C08F283/12 , C08F290/00 , C08F299/08 , C08G77/20 , C08G77/22 , C08G77/42
CPC分类号： C08F283/124 , C08G77/20
摘要： The invention provides a process for preparing a polysiloxane-containing resin which comprises copolymerizing a polysiloxane-type macromonomer with a vinyl monomer, characterized in that the polysiloxane-type macromonomer is one prepared by reacting about 70 to about 99.999 mole % of a compound (A) represented by the formula ##STR1## wherein R.sub.1 represents aliphatic hydrocarbon group having 1 to 8 carbon atoms or phenyl group, and R.sub.2, R.sub.3 and R.sub.4 each represent alkoxyl group having 1 to 4 carbon atoms or hydroxyl group with about 30 to about 0.001 mole % of a compound (B) represented by the formula ##STR2## wherein R.sub.5 represents hydrogen atom or methyl group, R.sub.6, R.sub.7 and R.sub.8 each represent hydroxyl group, alkoxyl group having 1 to 4 carbon atoms or aliphatic hydrocarbon group having 1 to 8 carbon atoms with the proviso that R.sub.6, R.sub.7 and R.sub.8 can not be aliphatic hydrocarbon groups having 1 to 8 carbon atoms at the same time, and n is an integer of 1 to 6, the polysiloxane-type macromonomer having at least two free functional groups selected from hydroxyl groups and alkoxyl groups per molecule, and the macromonomer having a number-average molecular weight of about 400 to about 100,000.
摘要翻译：本发明提供一种制备含聚硅氧烷的树脂的方法，其包括将聚硅氧烷型大分子单体与乙烯基单体共聚，其特征在于，所述聚硅氧烷型大分子单体是通过使约70-约99.999摩尔％的化合物（A ），其中R 1表示具有1至8个碳原子的脂族烃基或苯基，R 2，R 3和R 4各自表示具有1至4个碳原子的烷氧基或羟基，其中约30至约0.001摩尔％的由式（II）表示的化合物（B），其中R5表示氢原子或甲基，R6，R7和R8各自表示羟基，具有1至4个碳原子的烷氧基或脂族烃具有1至8个碳原子的基团，条件是R 6，R 7和R 8不能同时为具有1至8个碳原子的脂族烃基，n为1至6的整数，聚硅氧烷型大分子量具有至少两个选自每个分子的羟基和烷氧基的游离官能团，并且大分子单体的数均分子量为约400至约100,000。

10. 发明授权

US4965312A Nonaqueous vehicle composition for coating materials 失效
标题翻译：用于涂料的非水性载体组合物
公开(公告)号：US4965312A
公开(公告)日：1990-10-23
申请号：US924477
申请日：1986-10-29
申请人： Noboru Nakai , Osamu Isozaki , Susumu Midogohchi
发明人： Noboru Nakai , Osamu Isozaki , Susumu Midogohchi
IPC分类号： C08F2/14 , C08F2/00 , C08F2/08 , C08F2/18 , C08F2/24 , C08F2/44 , C08L83/04 , C09D133/06 , C09D157/00 , C09D183/04 , C09D201/00
CPC分类号： C09D133/06 , C09D157/00 , C09D183/04 , C08L83/04
摘要： A vehicle composition for coating materials is disclosed. The vehicle composition includes an organic liquid, finely divided particles of a vinyl polymer dispersed in the organic liquid and a polymer of alkoxysiloxane having an alkoxy group of 3 to 5 carbon atoms dissolved in the organic liquid. The vehicle composition is prepared by polymerizing at least one vinyl monomer in the organic liquid which has the alkoxysiloxane polymer dissolved therein, the organic liquid being capable of dissolving the vinyl monomer but incapable of dissolving the vinyl polymer obtained therefrom.
摘要翻译：公开了一种用于涂料的载体组合物。车辆组合物包括有机液体，分散在有机液体中的细分散的乙烯基聚合物颗粒和溶解在有机液体中的具有3至5个碳原子的烷氧基的烷氧基硅氧烷的聚合物。载体组合物通过使溶解有烷氧基硅氧烷聚合物的有机液体中的至少一种乙烯基单体聚合而制备，有机液体能够溶解乙烯基单体，但不能溶解由其获得的乙烯基聚合物。

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