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1. 发明授权

US5525673A Hydroxyl and epoxy polymer, hydrolyzable silicone polymer, either containing flourine monomer 失效
标题翻译：羟基和环氧聚合物，可水解的硅氧烷聚合物，含有含氟单体
公开(公告)号：US5525673A
公开(公告)日：1996-06-11
申请号：US277429
申请日：1994-07-18
申请人： Akimasa Nakahata , Nobushige Numa , Masahiro Yamane , Osamu Isozaki , Noboru Nakai
发明人： Akimasa Nakahata , Nobushige Numa , Masahiro Yamane , Osamu Isozaki , Noboru Nakai
IPC分类号： C08L63/00 , C09D201/04 , C08F4/52 , C08F4/76 , C08F24/00 , C08F30/08
CPC分类号： C08L63/00 , C09D201/04
摘要： Disclosed are:1) a three-component resin composition comprising a hydroxyl group-containing compound (A), an epoxy group-containing compound (B) and a silane group-containing compound (C);2) a two-component resin composition comprising a hydroxyl group-containing compound (A) and silane group- and epoxy group-containing compound (D);3) a two-component resin composition comprising hydroxyl group- and silane group-containing compound (E) and epoxy group-containing compound (B); and4) two-component resin composition comprising hydroxyl group- and epoxy group-containing compound (F) and silane group-containing compound (C); wherein at least one of the components in each of the resin compositions 1) to 4) is (are) fluorine-containing resin;5) a curable composition comprising one of the resin compositions 1) to 4) and a metal chelate compound as curing catalyst; and6) coating compositions comprising such curing composition and when required a pigment.
摘要翻译：公开的是：1）包含含羟基的化合物（A），含环氧基的化合物（B）和含硅烷基的化合物（C）的三组分树脂组合物; 2）包含含羟基的化合物（A）和含硅烷基和含环氧基的化合物（D）的双组分树脂组合物; 3）包含含羟基和含硅烷基的化合物（E）和含环氧基的化合物（B）的双组分树脂组合物; 和4）包含含羟基和含环氧基的化合物（F）和含硅烷基化合物（C）的双组分树脂组合物; 其中，树脂组合物1）〜4）中的至少一种成分为含氟树脂， 5）包含树脂组合物1）至4）之一的可固化组合物和作为固化催化剂的金属螯合物; 和6）包含这种固化组合物和需要时颜料的涂料组合物。

2. 发明授权

US5260376A Resin composition, curable composition and coating composition 失效
标题翻译：树脂组合物，可固化组合物和涂料组合物
公开(公告)号：US5260376A
公开(公告)日：1993-11-09
申请号：US904257
申请日：1992-06-25
申请人： Akimasa Nakahata , Nobushige Numa , Masahiro Yamane , Osamu Isozaki , Noboru Nakai
发明人： Akimasa Nakahata , Nobushige Numa , Masahiro Yamane , Osamu Isozaki , Noboru Nakai
IPC分类号： C08L63/00 , C09D201/04 , C08L27/14 , C08L83/00
CPC分类号： C08L63/00 , C09D201/04
摘要： Disclosed are:1) a three-component resin composition comprising a hydroxyl group-containing compound (A), an epoxy group-containing compound (B) and a silane group-containing compound (C);2) a two-component resin composition comprising a hydroxyl group-containing compound (A) and silane group- and epoxy group-containing compound (D);3) a two component resin composition comprising hydroxyl group- and silane group-containing compound (E) and epoxy group-containing compound (B); and4) two-component resin composition comprising hydroxyl group- and epoxy group-containing compound (F) and silane group-containing compound (C); wherein at least one of the components in each of the resin compositions 1) to 4) is (are) fluorine-containing resin;5) a curable composition comprising one of the resin compositions 1) to 4) and a metal chelate compound as curing catalyst; and6) coating compositions comprising such curing composition and when required a pigment.
摘要翻译：公开的是：1）包含含羟基的化合物（A），含环氧基的化合物（B）和含硅烷基的化合物（C）的三组分树脂组合物; 2）包含含羟基的化合物（A）和含硅烷基和含环氧基的化合物（D）的双组分树脂组合物; 3）包含含羟基和含硅烷基的化合物（E）和含环氧基的化合物（B）的双组分树脂组合物; 和4）包含含羟基和含环氧基的化合物（F）和含硅烷基化合物（C）的双组分树脂组合物; 其中，树脂组合物1）〜4）中的至少一种成分为含氟树脂， 5）包含树脂组合物1）至4）之一的可固化组合物和作为固化催化剂的金属螯合物; 和6）包含这种固化组合物和需要时颜料的涂料组合物。

3. 发明授权

US5408001A Hydroxyl and hydrolyzable groups-containing silicone resin with polyepoxy compound 失效
标题翻译：含羟基和可水解基团的硅氧烷树脂与聚环氧化合物
公开(公告)号：US5408001A
公开(公告)日：1995-04-18
申请号：US107580
申请日：1993-08-18
申请人： Akimasa Nakahata , Nobushige Numa , Masahiro Yamane , Osamu Isozaki , Noboru Nakai
发明人： Akimasa Nakahata , Nobushige Numa , Masahiro Yamane , Osamu Isozaki , Noboru Nakai
IPC分类号： C08L63/00 , C09D201/04 , C08L27/12 , C08L27/14 , C08L33/14 , C08L63/02
CPC分类号： C08L63/00 , C09D201/04
摘要： Disclosed are:1) a three-component resin composition comprising a hydroxyl group-containing compound (A), an epoxy group-containing compound (B) and a silane group-containing compound (C);2) a two-component resin composition comprising a hydroxyl group-containing compound (A) and silane group- and epoxy group-containing compound (D);3) a two-component resin composition comprising hydroxyl group- and silane group-containing compound (E) and epoxy group-containing compound (B); and4) two-component resin composition comprising hydroxyl group- and epoxy group-containing compound (F) and silane group-containing compound (C); wherein at least one of the components in each of the resin compositions 1) to 4) is (are) fluorine-containing resin;5) a curable composition comprising one of the resin compositions 1) to 4) and a metal chelate compound as curing catalyst; and6) coating compositions comprising such curing composition and when required a pigment.
摘要翻译：公开的是：1）包含含羟基的化合物（A），含环氧基的化合物（B）和含硅烷基的化合物（C）的三组分树脂组合物; 2）包含含羟基的化合物（A）和含硅烷基和含环氧基的化合物（D）的双组分树脂组合物; 3）包含含羟基和含硅烷基的化合物（E）和含环氧基的化合物（B）的双组分树脂组合物; 和4）包含含羟基和含环氧基的化合物（F）和含硅烷基化合物（C）的双组分树脂组合物; 其中，树脂组合物1）〜4）中的至少一种成分为含氟树脂， 5）包含树脂组合物1）至4）之一的可固化组合物和作为固化催化剂的金属螯合物; 和6）包含这种固化组合物和需要时颜料的涂料组合物。

4. 发明授权

US5418293A Dispersion-type resin composition, curable composition and coating composition 失效
标题翻译：分散型树脂组合物，固化性组合物和涂料组合物
公开(公告)号：US5418293A
公开(公告)日：1995-05-23
申请号：US117321
申请日：1993-09-07
申请人： Nobushige Numa , Akimasa Nakahata , Masahiro Yamane , Osamu Isozaki , Noboru Nakai
发明人： Nobushige Numa , Akimasa Nakahata , Masahiro Yamane , Osamu Isozaki , Noboru Nakai
IPC分类号： C08L27/12 , C08F2/08 , C08F2/14 , C08F2/44 , C09D127/12 , C09D127/16 , C08F259/08 , C08F259/00
CPC分类号： C08F2/08
摘要： The invention provides: 1) a dispersion-type resin composition including polymer particles insoluble in an organic solvent, the resin composition being prepared by polymerizing a radically polymerizable unsaturated monomer in the organic solvent in the presence of a fluorine-type resin containing silane group and epoxy group; 2) a resin composition including polymer particles insoluble in an organic solvent, the resin composition being prepared by polymerizing a radically polymerizable unsaturated monomer in the organic solvent in the presence of a dispersion stabilizer comprising at least one of a component (I) having silane group, and a component (II) having epoxy group, at least one of components (I) and (II) being a fluorine-containing resin; 3) a curable composition including one of the resin compositions 1) and 2) and a metal chelate compound; and 4) a coating composition including one of the curable composition and the resin compositions.
摘要翻译：本发明提供：1）一种分散型树脂组合物，其包含不溶于有机溶剂的聚合物颗粒，该树脂组合物是通过在含有硅烷基团的含氟型树脂和含硅烷基团的存在下使有机溶剂中的可自由基聚合的不饱和单体聚合而制备的，环氧基; 2）包含不溶于有机溶剂的聚合物颗粒的树脂组合物，所述树脂组合物通过在包含具有硅烷基的组分（I）中的至少一种的分散稳定剂的存在下在有机溶剂中聚合自由基聚合性不饱和单体而制备），和具有环氧基的组分（II），组分（I）和（II）中的至少一种是含氟树脂; 3）包含树脂组合物1）和2）和金属螯合物之一的可固化组合物; 和4）包含可固化组合物和树脂组合物之一的涂料组合物。

5. 发明授权

US5387646A Fluorine-type resin composition, curable composition and coating composition 失效
标题翻译：氟类树脂组合物，可固化组合物和涂料组合物
公开(公告)号：US5387646A
公开(公告)日：1995-02-07
申请号：US43984
申请日：1993-04-07
申请人： Akimasa Nakahata , Nobushige Numa , Masahiro Yamane , Osamu Isozaki , Noboru Nakai
发明人： Akimasa Nakahata , Nobushige Numa , Masahiro Yamane , Osamu Isozaki , Noboru Nakai
IPC分类号： C08L27/12 , C08G59/30 , C08G59/32 , C08G59/70 , C08L43/04 , C09D127/12 , C09D127/16 , C09D163/00 , C08L27/14 , C08L83/00
CPC分类号： C09D163/00 , C08G59/306 , C08G59/32 , C08G59/70 , C08L43/04
摘要： The invention provides:1) a fluorine-containing resin composition including:a) a fluorine-containing resin having (i) a hydrolyzable group attached directly to a silicon atom and/or a silanol group and (ii) an epoxy group in the molecule, orb) a mixture of a component (I) having a hydrolyzable group attached directly to a silicon atom and/or a silanol group and a component (II) having an epoxy group, such that at least one of the components (I) and (II) is a fluorine-containing resin;2) a curable composition including the resin composition and a metal chelate compound; and3) a coating composition including this resin composition or this curable composition.
摘要翻译：本发明提供：1）一种含氟树脂组合物，其包含：a）含有（i）直接与硅原子和/或硅烷醇基相连的水解基团和（ii）分子中的环氧基的含氟树脂或b）具有直接与硅原子直接连接的可水解基团的组分（I）和/或硅烷醇基的组分和具有环氧基的组分（II）的混合物，使得组分（I）中的至少一种和（II）是含氟树脂; 2）包含该树脂组合物和金属螯合物的可固化组合物; 和3）包含该树脂组合物或该可固化组合物的涂料组合物。

6. 发明授权

US5166265A Resin composition, curable composition and coating composition 失效
标题翻译：树脂组合物，可固化组合物和涂料组合物
公开(公告)号：US5166265A
公开(公告)日：1992-11-24
申请号：US486697
申请日：1990-03-01
申请人： Akimasa Nakahata , Nobushige Numa , Masahiro Yamane , Osamu Isozaki , Noboru Nakai
发明人： Akimasa Nakahata , Nobushige Numa , Masahiro Yamane , Osamu Isozaki , Noboru Nakai
IPC分类号： C08G59/00 , C08G59/18 , C08G59/20 , C08G59/40 , C08G59/62 , C08G59/68 , C08G59/70 , C08L63/00 , C09D163/00 , C09D201/04
CPC分类号： C08L63/00 , C09D201/04
摘要： Disclosed are:1) a three-component resin composition comprising a hydroxyl group-containing compound (A), an epoxy group-containing compound (B) and a silane group-containing compound (C);2) a two-component resin composition comprising a hydroxyl group-containing compound (A) and silane group- and epoxy group-containing compound (D);3) a two-component resin composition comprising hydroxyl group- and silane group-containing compound (E) and epoxy group-containing compound (B); and4) two-component resin composition comprising hydroxyl group- and epoxy group-containing compound (F) and silane group-containing compound (C); wherein at least one of the components in each of the resin compositions 1) to 4) is (are) fluorine-containing resin;5) a curable composition comprising one of the resin compositions 1) to 4) and a metal chelate compound as curing catalyst; and6) coating compositions comprising such curing composition and when required a pigment.
摘要翻译：公开的是：1）包含含羟基的化合物（A），含环氧基的化合物（B）和含硅烷基的化合物（C）的三组分树脂组合物; 2）包含含羟基的化合物（A）和含硅烷基和含环氧基的化合物（D）的双组分树脂组合物; 3）包含含羟基和含硅烷基的化合物（E）和含环氧基的化合物（B）的双组分树脂组合物; 和4）包含含羟基和含环氧基的化合物（F）和含硅烷基化合物（C）的双组分树脂组合物; 其中，树脂组合物1）〜4）中的至少一种成分为含氟树脂， 5）包含树脂组合物1）至4）之一的可固化组合物和作为固化催化剂的金属螯合物; 和6）包含这种固化组合物和需要时颜料的涂料组合物。

7. 发明授权

US5609918A Method of forming a top coat 失效
标题翻译：形成面漆的方法
公开(公告)号：US5609918A
公开(公告)日：1997-03-11
申请号：US477613
申请日：1995-06-07
申请人： Sachio Yamaguchi, deceased , Akimasa Nakahata , Satoshi Ikushima , Yasumasa Okumura , Haruhiko Aida , Shigeo Nishiguchi , Osamu Isozaki
发明人： Sachio Yamaguchi, deceased , Akimasa Nakahata , Satoshi Ikushima , Yasumasa Okumura , Haruhiko Aida , Shigeo Nishiguchi , Osamu Isozaki
IPC分类号： B05D7/00 , C09D133/06 , C09D163/00 , C09D201/02 , B05D1/36
CPC分类号： B05D7/53 , C09D133/066 , C09D133/068 , C09D163/00 , C09D201/02
摘要： The invention provides a method of forming a top coat by forming in sequence a colored base coat on a substrate and a clear coat, the method being characterized in that at least one of the colored base coat and the clear coat is formed by a curable coating composition consisting essentially of:(a) (a-1) a resin having a hydroxyl group, a carboxyl group and an epoxy group in the same molecule, or (a-2) a mixture of a hydroxyl- and carboxyl-containing resin with a polyepoxide;(b) a silicon compound having, per molecule, at least one silanol group and/or at least one hydrolyzable group directly bound to a silicon atom; and(c) an organic solvent.
摘要翻译：本发明提供一种通过在基材上形成有色底涂层和透明涂层来形成顶涂层的方法，其特征在于，着色底涂层和透明涂层中的至少一个通过可固化涂层形成组合物基本上由以下组成：（a）（a-1）在同一分子中具有羟基，羧基和环氧基的树脂，或（a-2）含羟基和羧基的树脂与聚环氧化物（b）每分子具有至少一个硅烷醇基和/或至少一个与硅原子直接结合的可水解基团的硅化合物; 和（c）有机溶剂。

8. 发明授权

US5449717A Coating composition 失效
标题翻译：涂料组成
公开(公告)号：US5449717A
公开(公告)日：1995-09-12
申请号：US42517
申请日：1993-04-05
申请人： Tetsuya Yokoyama , Mitsuhiro Fukuda , Akimasa Nakahata , Yasushi Nakao , Motoshi Yabuta
发明人： Tetsuya Yokoyama , Mitsuhiro Fukuda , Akimasa Nakahata , Yasushi Nakao , Motoshi Yabuta
IPC分类号： C08F214/18 , C08F14/18 , C08F290/00 , C08F299/08 , C08L61/20 , C09D127/12 , C09D137/00 , C09D143/04 , C09D155/00 , C09D157/00 , C09D161/20 , C08L43/04 , C08L61/00
CPC分类号： C09D143/04 , C08L61/20
摘要： A coating composition which consists essentially of:(A) a copolymer comprising 5 to 40 wt. % of an alkoxysilane-containing vinyl monomer which is a compound represented by the formula ##STR1## wherein A is ##STR2## R.sub.1 is a hydrogen atom or methyl group, R.sub.2 is a bivalent aliphatic saturated hydrocarbon group having 1 to 6 carbon atoms, R.sub.3 and R.sub.4 are the same or different and are each a phenyl group, alkyl group having 1 to 6 carbon atoms or alkoxy group having 1 to 10 carbon atoms, R.sub.5 is an alkyl group having 1 to 10 carbon atoms, m is 0 or 1, and n is an integer of 1 to 100, 5 to 50 wt. % of a hydroxyl-containing vinyl monomer and 30 to 70 wt. % of a fluorine-containing vinyl monomer, and (B) an amino resin in an amount of 5 to 50 wt. % based on the total amount of solids in the copolymer (A) and the amino resin (B).
摘要翻译：一种涂料组合物，其基本上由以下组成：（A）包含5至40wt。％为由式（I）表示的化合物的烷氧基硅烷的乙烯基单体，其中A为氢原子或甲基，R 2为具有1至6个碳原子的二价脂族饱和烃基原子，R 3和R 4相同或不同，分别为苯基，碳原子数1〜6的烷基或碳原子数1〜10的烷氧基，R 5为碳原子数1〜10的烷基，m为0 或1，n为1〜100的整数，5〜50重量％％的含羟基的乙烯基单体和30至70wt。％的含氟乙烯基单体，和（B）5〜50重量％的氨基树脂。基于共聚物（A）和氨基树脂（B）中的固体总量的％。

9. 发明授权

US5908669A Aqueous colored coating composition 失效
标题翻译：水性着色涂料组合物
公开(公告)号：US5908669A
公开(公告)日：1999-06-01
申请号：US947157
申请日：1997-10-08
申请人： Yukiko Hayashi , Keita Ono , Akimasa Nakahata , Mitsuhiro Fukuda
发明人： Yukiko Hayashi , Keita Ono , Akimasa Nakahata , Mitsuhiro Fukuda
IPC分类号： B05D7/24 , B05D5/06 , B05D7/00 , C09D5/00 , C09D5/02 , C09D133/02 , C09D133/04 , C09D143/04 , B05D1/02
CPC分类号： C09D5/021 , B05D5/06 , C09D143/04 , B05D7/53
摘要： This invention is directed to an aqueous colored coating composition which is applied with a spray device having a fine-orifice nozzle(s), the composition comprising a neutralized acrylic copolymer containing an alkoxysilyl group and a carboxyl group and a coloring pigment.
摘要翻译：本发明涉及一种水性着色涂料组合物，其涂有具有细孔喷嘴的喷雾装置，该组合物包含含有烷氧基甲硅烷基和羧基的中和丙烯酸共聚物和着色颜料。

10. 发明授权

US5830581A Method for formation of coating film 失效
标题翻译：涂膜形成方法
公开(公告)号：US5830581A
公开(公告)日：1998-11-03
申请号：US843595
申请日：1997-04-16
申请人： Yutaka Masuda , Akimasa Nakahata , Yoshiyuki Yukawa , Motoshi Yabuta
发明人： Yutaka Masuda , Akimasa Nakahata , Yoshiyuki Yukawa , Motoshi Yabuta
IPC分类号： B05D5/06 , B32B15/08 , B05D3/02
CPC分类号： B05D5/068 , Y10T428/31692 , Y10T428/31699 , Y10T428/31855 , Y10T428/31935
摘要： The present invention provides a method for forming a multi-layer coating film by applying a colored clear coating (B) containing a color pigment and/or a glittering material, on the film of a leafing type aluminum flake-containing metallic coating (A), wherein the colored clear coating (B) also contains a polymer formed from an unsaturated monomer having a phosphoric acid group represented by --O--PO(OH)(R.sub.1) (wherein R.sub.1 is a hydroxyl group, a phenyl group or a C.sub.1-20 alkyl group) and a hydroxyl group-containing unsaturated monomer. The method can form a multi-layer coating film improved in interlayer adhesivity between the metallic coating film and the colored clear coating film, without reducing the excellent effects and metallic feeling provided by a metallic coating film containing leafing type aluminum flake.
摘要翻译：本发明提供一种通过将含有着色颜料和/或闪光材料的着色透明涂层（B）涂覆在含叶片状铝箔金属涂层（A）的膜上形成多层涂膜的方法，，其中着色透明涂层（B）还含有由具有由-O-PO（OH）（R1）表示的磷酸基的不饱和单体形成的聚合物（其中R1是羟基，苯基或C1- 20烷基）和含羟基的不饱和单体。该方法可以形成改善金属涂膜和着色透明涂膜之间的层间粘合性的多层涂膜，而不会降低由含叶片型铝片的金属涂膜提供的优异的效果和金属感。

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