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    • 8. 发明申请
    • MICROCAPSULE-TYPE LATENT CURING AGENT
    • 微胶囊型固化剂
    • US20100324170A1
    • 2010-12-23
    • US12672806
    • 2008-03-18
    • Kazunobu Kamiya
    • Kazunobu Kamiya
    • C08K9/00C12P21/02C08G59/14
    • C08K5/0091C08G59/70C08L63/00Y10T428/2982Y10T428/2984Y10T428/2991Y10T428/2993Y10T428/2995
    • An aluminum chelate-based latent curing agent having excellent latency and thermal response includes a latent curing agent in which an aluminum chelating agent is retained in a porous resin obtained by interfacial polymerization of a polyfunctional isocyanate compound, and an enzyme-treated gelatin film coating such latent curing agent. This microcapsule-type latent curing agent can be produced by dissolving an aluminum chelating agent and a polyfunctional isocyanate compound in a volatile organic solvent, charging the obtained solution into a gelatin-containing aqueous phase, carrying out interfacial polymerization by heating and stirring, and subjecting the gelatin to an enzyme treatment by adding an enzyme to the obtained polymerization reaction mixture.
    • 具有优异潜在性和热响应性的铝螯合物潜固​​化剂包括其中铝螯合剂保留在通过多官能异氰酸酯化合物的界面聚合获得的多孔树脂中的潜在性固化剂,以及经酶处理的明胶膜包衣 潜在固化剂。 这种微胶囊型潜在性固化剂可以通过将铝螯合剂和多官能异氰酸酯化合物溶解在挥发性有机溶剂中,将所得溶液装入含明胶的水相中,通过加热和搅拌进行界面聚合,并且 所述明胶通过向所得聚合反应混合物中加入酶进行酶处理。
    • 9. 发明申请
    • LATENT CURING AGENT
    • 专利固化剂
    • US20090209669A1
    • 2009-08-20
    • US11813825
    • 2005-08-04
    • Kazunobu Kamiya
    • Kazunobu Kamiya
    • C08J9/00
    • C08G18/706C08G18/8029C08G18/8093C08G59/4028C08G59/70
    • An aluminum chelating agent-based latent curing agent is provided that can rapidly cure thermosetting epoxy resins at relatively low temperatures. A method for producing the aluminum chelating agent-based latent curing agent is also provided that enables relatively facile control of the curing conditions therefor. The latent curing agent holds an aluminum chelating agent in a porous resin obtained by the interfacial polymerization of a polyfunctional isocyanate compound, and when the latent curing agent is incorporated in a curable epoxy resin composition for differential scanning calorimetric (DSC) measurement, the DSC exothermic peak temperature of the curable epoxy resin composition for DSC measurement that contains the latent curing agent that has been treated by immersion in a nonaqueous polar solvent can be brought to not less than the DSC exothermic peak temperature of the curable epoxy resin composition for DSC measurement that incorporates the latent curing agent that has not been subjected to the immersion treatment.
    • 提供了一种铝螯合剂型潜在固化剂,可以在相对较低的温度下快速固化热固性环氧树脂。 还提供了一种制备基于铝螯合剂的潜在性固化剂的方法,其能够相对容易地控制其固化条件。 潜在性固化剂在通过多官能异氰酸酯化合物的界面聚合获得的多孔树脂中保持铝螯合剂,并且当将潜在性固化剂引入用于差示扫描量热(DSC)测量的可固化环氧树脂组合物中时,DSC放热 包含通过浸渍在非水极性溶剂中处理的潜在性固化剂的DSC测定用固化性环氧树脂组合物的峰值温度可以不低于用于DSC测定的固化性环氧树脂组合物的DSC放热峰温度, 掺入未进行浸渍处理的潜在性固化剂。
    • 10. 发明申请
    • Latent hardener
    • 潜在硬化剂
    • US20070010636A1
    • 2007-01-11
    • US10569277
    • 2004-08-30
    • Kazunobu KamiyaMakoto Yoshinari
    • Kazunobu KamiyaMakoto Yoshinari
    • C08L63/00C08K3/10
    • C08G59/70C08G18/0852C08G18/58C08G18/79C08G59/188H05K3/323
    • A latent curing agent that can cure a thermosetting epoxy resin in a relatively short period of time and at a relatively low temperature has a structure in which an aluminum chelating agent is held by a porous resin carrier obtained through interfacial polymerization of a polyfunctional isocyanate compound. The aluminum chelating agent is preferably a complex compound comprising β-ketoenolate anion ligands coordinated to aluminum. The latent curing agent can be produced by dissolving the aluminum chelating agent and the polyfunctional isocyanate compound in a volatile organic solvent, adding the resulting solution to an aqueous phase containing a dispersing agent, and stirring the resulting mixture to cause interfacial polymerization of the isocyanate compound while the mixture is being heated.
    • 在相当短的时间和相对低的温度下可固化热固性环氧树脂的潜在性固化剂具有其中通过多官能异氰酸酯化合物的界面聚合获得的多孔树脂载体保持铝螯合剂的结构。 铝螯合剂优选为包含与铝配位的β-酮酸酯阴离子配体的络合物。 潜在性固化剂可以通过将铝螯合剂和多官能异氰酸酯化合物溶解在挥发性有机溶剂中,将所得溶液加入到含有分散剂的水相中,并搅拌所得混合物以引起异氰酸酯化合物的界面聚合 同时混合物被加热。