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1. 发明授权

US5525673A Hydroxyl and epoxy polymer, hydrolyzable silicone polymer, either containing flourine monomer 失效
标题翻译：羟基和环氧聚合物，可水解的硅氧烷聚合物，含有含氟单体
公开(公告)号：US5525673A
公开(公告)日：1996-06-11
申请号：US277429
申请日：1994-07-18
申请人： Akimasa Nakahata , Nobushige Numa , Masahiro Yamane , Osamu Isozaki , Noboru Nakai
发明人： Akimasa Nakahata , Nobushige Numa , Masahiro Yamane , Osamu Isozaki , Noboru Nakai
IPC分类号： C08L63/00 , C09D201/04 , C08F4/52 , C08F4/76 , C08F24/00 , C08F30/08
CPC分类号： C08L63/00 , C09D201/04
摘要： Disclosed are:1) a three-component resin composition comprising a hydroxyl group-containing compound (A), an epoxy group-containing compound (B) and a silane group-containing compound (C);2) a two-component resin composition comprising a hydroxyl group-containing compound (A) and silane group- and epoxy group-containing compound (D);3) a two-component resin composition comprising hydroxyl group- and silane group-containing compound (E) and epoxy group-containing compound (B); and4) two-component resin composition comprising hydroxyl group- and epoxy group-containing compound (F) and silane group-containing compound (C); wherein at least one of the components in each of the resin compositions 1) to 4) is (are) fluorine-containing resin;5) a curable composition comprising one of the resin compositions 1) to 4) and a metal chelate compound as curing catalyst; and6) coating compositions comprising such curing composition and when required a pigment.
摘要翻译：公开的是：1）包含含羟基的化合物（A），含环氧基的化合物（B）和含硅烷基的化合物（C）的三组分树脂组合物; 2）包含含羟基的化合物（A）和含硅烷基和含环氧基的化合物（D）的双组分树脂组合物; 3）包含含羟基和含硅烷基的化合物（E）和含环氧基的化合物（B）的双组分树脂组合物; 和4）包含含羟基和含环氧基的化合物（F）和含硅烷基化合物（C）的双组分树脂组合物; 其中，树脂组合物1）〜4）中的至少一种成分为含氟树脂， 5）包含树脂组合物1）至4）之一的可固化组合物和作为固化催化剂的金属螯合物; 和6）包含这种固化组合物和需要时颜料的涂料组合物。

2. 发明授权

US5260376A Resin composition, curable composition and coating composition 失效
标题翻译：树脂组合物，可固化组合物和涂料组合物
公开(公告)号：US5260376A
公开(公告)日：1993-11-09
申请号：US904257
申请日：1992-06-25
申请人： Akimasa Nakahata , Nobushige Numa , Masahiro Yamane , Osamu Isozaki , Noboru Nakai
发明人： Akimasa Nakahata , Nobushige Numa , Masahiro Yamane , Osamu Isozaki , Noboru Nakai
IPC分类号： C08L63/00 , C09D201/04 , C08L27/14 , C08L83/00
CPC分类号： C08L63/00 , C09D201/04
摘要： Disclosed are:1) a three-component resin composition comprising a hydroxyl group-containing compound (A), an epoxy group-containing compound (B) and a silane group-containing compound (C);2) a two-component resin composition comprising a hydroxyl group-containing compound (A) and silane group- and epoxy group-containing compound (D);3) a two component resin composition comprising hydroxyl group- and silane group-containing compound (E) and epoxy group-containing compound (B); and4) two-component resin composition comprising hydroxyl group- and epoxy group-containing compound (F) and silane group-containing compound (C); wherein at least one of the components in each of the resin compositions 1) to 4) is (are) fluorine-containing resin;5) a curable composition comprising one of the resin compositions 1) to 4) and a metal chelate compound as curing catalyst; and6) coating compositions comprising such curing composition and when required a pigment.
摘要翻译：公开的是：1）包含含羟基的化合物（A），含环氧基的化合物（B）和含硅烷基的化合物（C）的三组分树脂组合物; 2）包含含羟基的化合物（A）和含硅烷基和含环氧基的化合物（D）的双组分树脂组合物; 3）包含含羟基和含硅烷基的化合物（E）和含环氧基的化合物（B）的双组分树脂组合物; 和4）包含含羟基和含环氧基的化合物（F）和含硅烷基化合物（C）的双组分树脂组合物; 其中，树脂组合物1）〜4）中的至少一种成分为含氟树脂， 5）包含树脂组合物1）至4）之一的可固化组合物和作为固化催化剂的金属螯合物; 和6）包含这种固化组合物和需要时颜料的涂料组合物。

3. 发明授权

US5408001A Hydroxyl and hydrolyzable groups-containing silicone resin with polyepoxy compound 失效
标题翻译：含羟基和可水解基团的硅氧烷树脂与聚环氧化合物
公开(公告)号：US5408001A
公开(公告)日：1995-04-18
申请号：US107580
申请日：1993-08-18
申请人： Akimasa Nakahata , Nobushige Numa , Masahiro Yamane , Osamu Isozaki , Noboru Nakai
发明人： Akimasa Nakahata , Nobushige Numa , Masahiro Yamane , Osamu Isozaki , Noboru Nakai
IPC分类号： C08L63/00 , C09D201/04 , C08L27/12 , C08L27/14 , C08L33/14 , C08L63/02
CPC分类号： C08L63/00 , C09D201/04
摘要： Disclosed are:1) a three-component resin composition comprising a hydroxyl group-containing compound (A), an epoxy group-containing compound (B) and a silane group-containing compound (C);2) a two-component resin composition comprising a hydroxyl group-containing compound (A) and silane group- and epoxy group-containing compound (D);3) a two-component resin composition comprising hydroxyl group- and silane group-containing compound (E) and epoxy group-containing compound (B); and4) two-component resin composition comprising hydroxyl group- and epoxy group-containing compound (F) and silane group-containing compound (C); wherein at least one of the components in each of the resin compositions 1) to 4) is (are) fluorine-containing resin;5) a curable composition comprising one of the resin compositions 1) to 4) and a metal chelate compound as curing catalyst; and6) coating compositions comprising such curing composition and when required a pigment.
摘要翻译：公开的是：1）包含含羟基的化合物（A），含环氧基的化合物（B）和含硅烷基的化合物（C）的三组分树脂组合物; 2）包含含羟基的化合物（A）和含硅烷基和含环氧基的化合物（D）的双组分树脂组合物; 3）包含含羟基和含硅烷基的化合物（E）和含环氧基的化合物（B）的双组分树脂组合物; 和4）包含含羟基和含环氧基的化合物（F）和含硅烷基化合物（C）的双组分树脂组合物; 其中，树脂组合物1）〜4）中的至少一种成分为含氟树脂， 5）包含树脂组合物1）至4）之一的可固化组合物和作为固化催化剂的金属螯合物; 和6）包含这种固化组合物和需要时颜料的涂料组合物。

4. 发明授权

US5418293A Dispersion-type resin composition, curable composition and coating composition 失效
标题翻译：分散型树脂组合物，固化性组合物和涂料组合物
公开(公告)号：US5418293A
公开(公告)日：1995-05-23
申请号：US117321
申请日：1993-09-07
申请人： Nobushige Numa , Akimasa Nakahata , Masahiro Yamane , Osamu Isozaki , Noboru Nakai
发明人： Nobushige Numa , Akimasa Nakahata , Masahiro Yamane , Osamu Isozaki , Noboru Nakai
IPC分类号： C08L27/12 , C08F2/08 , C08F2/14 , C08F2/44 , C09D127/12 , C09D127/16 , C08F259/08 , C08F259/00
CPC分类号： C08F2/08
摘要： The invention provides: 1) a dispersion-type resin composition including polymer particles insoluble in an organic solvent, the resin composition being prepared by polymerizing a radically polymerizable unsaturated monomer in the organic solvent in the presence of a fluorine-type resin containing silane group and epoxy group; 2) a resin composition including polymer particles insoluble in an organic solvent, the resin composition being prepared by polymerizing a radically polymerizable unsaturated monomer in the organic solvent in the presence of a dispersion stabilizer comprising at least one of a component (I) having silane group, and a component (II) having epoxy group, at least one of components (I) and (II) being a fluorine-containing resin; 3) a curable composition including one of the resin compositions 1) and 2) and a metal chelate compound; and 4) a coating composition including one of the curable composition and the resin compositions.
摘要翻译：本发明提供：1）一种分散型树脂组合物，其包含不溶于有机溶剂的聚合物颗粒，该树脂组合物是通过在含有硅烷基团的含氟型树脂和含硅烷基团的存在下使有机溶剂中的可自由基聚合的不饱和单体聚合而制备的，环氧基; 2）包含不溶于有机溶剂的聚合物颗粒的树脂组合物，所述树脂组合物通过在包含具有硅烷基的组分（I）中的至少一种的分散稳定剂的存在下在有机溶剂中聚合自由基聚合性不饱和单体而制备），和具有环氧基的组分（II），组分（I）和（II）中的至少一种是含氟树脂; 3）包含树脂组合物1）和2）和金属螯合物之一的可固化组合物; 和4）包含可固化组合物和树脂组合物之一的涂料组合物。

5. 发明授权

US5387646A Fluorine-type resin composition, curable composition and coating composition 失效
标题翻译：氟类树脂组合物，可固化组合物和涂料组合物
公开(公告)号：US5387646A
公开(公告)日：1995-02-07
申请号：US43984
申请日：1993-04-07
申请人： Akimasa Nakahata , Nobushige Numa , Masahiro Yamane , Osamu Isozaki , Noboru Nakai
发明人： Akimasa Nakahata , Nobushige Numa , Masahiro Yamane , Osamu Isozaki , Noboru Nakai
IPC分类号： C08L27/12 , C08G59/30 , C08G59/32 , C08G59/70 , C08L43/04 , C09D127/12 , C09D127/16 , C09D163/00 , C08L27/14 , C08L83/00
CPC分类号： C09D163/00 , C08G59/306 , C08G59/32 , C08G59/70 , C08L43/04
摘要： The invention provides:1) a fluorine-containing resin composition including:a) a fluorine-containing resin having (i) a hydrolyzable group attached directly to a silicon atom and/or a silanol group and (ii) an epoxy group in the molecule, orb) a mixture of a component (I) having a hydrolyzable group attached directly to a silicon atom and/or a silanol group and a component (II) having an epoxy group, such that at least one of the components (I) and (II) is a fluorine-containing resin;2) a curable composition including the resin composition and a metal chelate compound; and3) a coating composition including this resin composition or this curable composition.
摘要翻译：本发明提供：1）一种含氟树脂组合物，其包含：a）含有（i）直接与硅原子和/或硅烷醇基相连的水解基团和（ii）分子中的环氧基的含氟树脂或b）具有直接与硅原子直接连接的可水解基团的组分（I）和/或硅烷醇基的组分和具有环氧基的组分（II）的混合物，使得组分（I）中的至少一种和（II）是含氟树脂; 2）包含该树脂组合物和金属螯合物的可固化组合物; 和3）包含该树脂组合物或该可固化组合物的涂料组合物。

6. 发明授权

US5166265A Resin composition, curable composition and coating composition 失效
标题翻译：树脂组合物，可固化组合物和涂料组合物
公开(公告)号：US5166265A
公开(公告)日：1992-11-24
申请号：US486697
申请日：1990-03-01
申请人： Akimasa Nakahata , Nobushige Numa , Masahiro Yamane , Osamu Isozaki , Noboru Nakai
发明人： Akimasa Nakahata , Nobushige Numa , Masahiro Yamane , Osamu Isozaki , Noboru Nakai
IPC分类号： C08G59/00 , C08G59/18 , C08G59/20 , C08G59/40 , C08G59/62 , C08G59/68 , C08G59/70 , C08L63/00 , C09D163/00 , C09D201/04
CPC分类号： C08L63/00 , C09D201/04
摘要： Disclosed are:1) a three-component resin composition comprising a hydroxyl group-containing compound (A), an epoxy group-containing compound (B) and a silane group-containing compound (C);2) a two-component resin composition comprising a hydroxyl group-containing compound (A) and silane group- and epoxy group-containing compound (D);3) a two-component resin composition comprising hydroxyl group- and silane group-containing compound (E) and epoxy group-containing compound (B); and4) two-component resin composition comprising hydroxyl group- and epoxy group-containing compound (F) and silane group-containing compound (C); wherein at least one of the components in each of the resin compositions 1) to 4) is (are) fluorine-containing resin;5) a curable composition comprising one of the resin compositions 1) to 4) and a metal chelate compound as curing catalyst; and6) coating compositions comprising such curing composition and when required a pigment.
摘要翻译：公开的是：1）包含含羟基的化合物（A），含环氧基的化合物（B）和含硅烷基的化合物（C）的三组分树脂组合物; 2）包含含羟基的化合物（A）和含硅烷基和含环氧基的化合物（D）的双组分树脂组合物; 3）包含含羟基和含硅烷基的化合物（E）和含环氧基的化合物（B）的双组分树脂组合物; 和4）包含含羟基和含环氧基的化合物（F）和含硅烷基化合物（C）的双组分树脂组合物; 其中，树脂组合物1）〜4）中的至少一种成分为含氟树脂， 5）包含树脂组合物1）至4）之一的可固化组合物和作为固化催化剂的金属螯合物; 和6）包含这种固化组合物和需要时颜料的涂料组合物。

7. 发明授权

US06780902B2 Water-based coating composition 失效
标题翻译：水性涂料组合物
公开(公告)号：US06780902B2
公开(公告)日：2004-08-24
申请号：US10149435
申请日：2002-06-24
申请人： Yuji Hirose , Noboru Nakai , Reiziro Nishida , Nobushige Numa
发明人： Yuji Hirose , Noboru Nakai , Reiziro Nishida , Nobushige Numa
IPC分类号： C08K320
CPC分类号： C09D163/00 , C08G59/12 , C09D167/00 , C08L2666/04 , C08L33/00
摘要： The present invention provides an aqueous coating composition comprising a carboxyl-containing, acrylic-modified polyester resin (B) neutralized and dispersed in an aqueous medium, the polyester resin (B) being obtainable by reacting a carboxyl-containing acrylic resin (c) with an epoxy-modified polyester resin (A) prepared by esterification of a carboxyl-containing polyester resin (a) having a number average molecular weight of 1,000 to 30,000 and an acid value of 5 to 200 mg KOH/g with a 1,2-epoxy-containing low-molecular-weight epoxy compound (b) having a number average molecular weight of 1,200 or less.
摘要翻译：本发明提供一种水性涂料组合物，其包含中和并分散在水性介质中的含羧基的丙烯酸改性聚酯树脂（B），所述聚酯树脂（B）可通过使含羧基的丙烯酸树脂（c）与通过使数均分子量为1,000〜30,000，酸值为5〜200mgKOH / g的含羧基的聚酯树脂（a）与1,2-二羟基苯乙烯酯进行酯化而制备的环氧改性聚酯树脂（A）含环氧基的低分子量环氧化合物（b）的数均分子量为1200以下。

8. 发明授权

US5492968A Resin compositions and a method of curing the same 失效
标题翻译：树脂组合物及其固化方法
公开(公告)号：US5492968A
公开(公告)日：1996-02-20
申请号：US335379
申请日：1994-11-03
申请人： Noboru Nakai , Osamu Isozaki , Naozumi Iwasawa
发明人： Noboru Nakai , Osamu Isozaki , Naozumi Iwasawa
IPC分类号： C08G59/40 , C07F7/08 , C07F7/18 , C08G59/00 , C08G59/02 , C08G59/04 , C08G59/30 , C08G59/32 , C08G59/70 , C08K5/00 , C08K5/07 , C08K5/1515 , C08K5/5415 , C08L33/06 , C08L43/04 , C08L63/00 , C08L75/04 , C08L101/06 , C09D133/06 , C09D133/14 , C09D143/04 , C09D163/00 , C08F8/00
CPC分类号： C08L63/00 , C07F7/0836 , C07F7/0858 , C07F7/0859 , C07F7/182 , C07F7/1836 , C07F7/1844 , C07F7/1896 , C08G59/02 , C08G59/04 , C08G59/306 , C08G59/3254 , C08G59/70 , C08K5/00 , C08K5/0091 , C08K5/07 , C08K5/1515 , C08K5/5415 , C08L101/06 , C08L75/04 , C09D133/064 , C09D133/068 , C09D143/04 , C09D163/00 , C08L33/068 , C08L43/04
摘要： A resin composition comprising a) a high molecular weight compound containing an average of 2 or more hydroxyl groups and an average of 2 or more epoxy groups per molecule and having a number average molecular weight of 3,000 to 200,000; b) a silane compound having an average of 1 or more alkoxysilane, silanol and acyloxysilane groups per molecule and having a number average molecular weight of 104 to 200,000; and c) a metal chelate compound, is curable at a relatively low temperature to yield a film having excellent resistance to weathering.
摘要翻译：一种树脂组合物，其包含a）每分子平均含有2个或更多个羟基并且平均具有2个或更多个环氧基并且数均分子量为3,000至200,000的高分子量化合物; b）每分子平均具有1个或更多个烷氧基硅烷，硅烷醇和酰氧基硅烷基团并且数均分子量为104至200,000的硅烷化合物; 和c）金属螯合化合物在相对低的温度下可固化，得到具有优异耐候性的膜。

9. 发明授权

US5008328A Aqueous organosilicon resin coating compositions 失效
标题翻译：水性有机硅树脂涂料组合物
公开(公告)号：US5008328A
公开(公告)日：1991-04-16
申请号：US313367
申请日：1989-02-21
申请人： Noboru Nakai , Osamu Isozaki
发明人： Noboru Nakai , Osamu Isozaki
IPC分类号： C08G77/14 , C08G77/22 , C08G77/28 , C08G77/388 , C09D183/04 , C09D183/06 , C09D183/08
CPC分类号： C09D183/08 , C08G77/388 , C09D183/06
摘要： This invention provides an aqueous organosilicon resin coating composition comprising:(I) an aqueous organosilicon resin which is a condensation product and which contains a quaternary ammonium base, the condensation product being prepared from (i) an organosilicon compound represented by the formulaR.sup.1.sub.a Si(OR.sup.2).sub.4-a (A) wherein R.sup.1 is hydrocarbon group having 1 to 12 carbon atoms, R.sup.2 is hydrocarbon group having 1 to 8 carbon atoms and a is 0, 1 or 2, and/or a low condensate thereof and (ii) an organosilicon compound represented by the formula ##STR1## wherein R.sup.3 is hydrogen atom or methyl group, R.sup.4 is bivalent hydrocarbon group having 1 to 8 carbon atoms and R.sup.2 is as defined above, and/or a low condensate thereof and,(II) an aqueous medium.
摘要翻译：本发明提供一种水性有机硅树脂涂料组合物，其包含：（I）水性有机硅氧烷树脂，其为缩合产物并且含有季铵碱，所述缩合产物由（i）由式R 1a a（OR 2）表示的有机硅化合物）4-a（A）其中R 1是具有1至12个碳原子的烃基，R 2是具有1至8个碳原子的烃基，a是0,1或2，和/或其低缩合物和（ii）由式（B）表示的有机硅化合物，其中R 3为氢原子或甲基，R 4为碳原子数为1〜8的二价烃基，R 2如上所定义，和/或低级缩合物，（II））水性介质。

10. 发明授权

US4772672A Curable compositions and method of curing same 失效
标题翻译：固化组合物及其固化方法
公开(公告)号：US4772672A
公开(公告)日：1988-09-20
申请号：US47392
申请日：1987-05-08
申请人： Osamu Isozaki , Noboru Nakai
发明人： Osamu Isozaki , Noboru Nakai
IPC分类号： C08F4/06 , C08F230/08 , C08K5/00 , C08F4/52 , C08F24/00
CPC分类号： C08K5/0091 , C08F230/08
摘要： The present invention provides a curable composition characterized in that the composition comprises a copolymer comprising as monomer components an oxirane-containing vinyl monomer and a specific alkoxysilane-containing vinyl monomer, and as a crosslinking curing agent at least one of an aluminum chelate compound and a zirconium chelate compound having neither of hydroxyl and alkoxyl directly combined with zirconium. The invention also provides a curing method characterized in that the composition is cured at a temperature of up to 100.degree. C. in the presence of water.
摘要翻译：本发明提供一种可固化组合物，其特征在于该组合物包含含有环氧乙烷的乙烯基单体和含特定烷氧基硅烷的乙烯基单体作为单体成分的共聚物，作为交联固化剂，可以使用铝螯合物和没有羟基和烷氧基直接与锆结合的锆螯合物。本发明还提供一种固化方法，其特征在于该组合物在水存在下在高达100℃的温度下固化。

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