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1. 发明申请

US20080308455A1 Catalyst and a Method for Cracking Hydrocarbons 审中-公开
标题翻译：催化剂和烃类裂化方法
公开(公告)号：US20080308455A1
公开(公告)日：2008-12-18
申请号：US11813056
申请日：2005-12-28
申请人： Jun Long , Wenbin Jiang , Mingde Xu , Huiping Tian , Yibin Luo , Xingtian Shu , Jiushun Zhang , Beiyan Chen , Haitao Song
发明人： Jun Long , Wenbin Jiang , Mingde Xu , Huiping Tian , Yibin Luo , Xingtian Shu , Jiushun Zhang , Beiyan Chen , Haitao Song
IPC分类号： C10G11/05
CPC分类号： C10G11/05 , B01J27/1853 , B01J29/46 , B01J35/0006 , B01J35/002 , B01J2229/42 , C10G11/02 , C10G47/16 , C10G2300/4018 , C10G2400/02
摘要： The invention discloses a catalyst and a method for cracking hydrocarbons. The catalyst comprises, calculated by dry basis, 10˜65 wt % ZSM-5 zeolite, 0˜60 wt % clay, 15˜60 wt % inorganic oxide binder, 0.5˜15 wt % one or more metal additives selected from the metals of Group VIIIB and 2˜25 wt % P additive, in which the metal additive is calculated by metal oxide and the P additive is calculated by P2O5. The method for cracking hydrocarbons using this catalyst increases the yield of FCC liquefied petroleum gas (LPG) and the octane number of FCC gasoline, as well as it increases the concentration of propylene in LPG dramatically.
摘要翻译：本发明公开了一种催化剂和一种裂化烃的方法。催化剂包括以干基计，10〜65重量％的ZSM-5沸石，0〜60重量％的粘土，15〜60重量％的无机氧化物粘合剂，0.5〜15重量％的一种或多种金属添加剂， ⅦB族和2〜25wt％P添加剂，其中金属添加剂由金属氧化物计算，P添加剂通过P2O5计算。使用该催化剂裂化烃的方法提高了FCC液化石油气（LPG）的产率和FCC汽油的辛烷值，并且显着提高了LPG中丙烯的浓度。

2. 发明授权

US08859791B2 Process for producing an alkylene oxide by olefin epoxidation 有权
标题翻译：通过烯烃环氧化制备烯化氧的方法
公开(公告)号：US08859791B2
公开(公告)日：2014-10-14
申请号：US13878659
申请日：2011-10-11
申请人： Hua Li , Min Lin , Xiaoju Wu , Wei Wang , Chijian He , Jizao Gao , Xingtian Shu , Shuanghua Wan , Bin Zhu
发明人： Hua Li , Min Lin , Xiaoju Wu , Wei Wang , Chijian He , Jizao Gao , Xingtian Shu , Shuanghua Wan , Bin Zhu
IPC分类号： C07D301/12 , C07D303/04
CPC分类号： C07D301/12 , C07D303/04
摘要： A process for producing an alkylene oxide by olefin epoxidation, wherein said process comprises the steps of: (1) in a first olefin epoxidation condition, in the presence of a first solid catalyst, a first mixed stream containing a solvent, an olefin and H2O2 is subjected to an epoxidation in one or more fixed bed reactors and/or one or more moving bed reactors until the conversion of H2O2 reaches 50%-95%, then, optionally, the resulting reaction mixture obtained in the step (1) is subjected to a separation to obtain a first stream free of H2O2 and a second stream containing the unreacted H2O2, and the olefin is introduced to the second stream to produce a second mixed stream, or optionally, the olefin is introduced to the reaction mixture obtained in the step (1) to produce a second mixed stream; (2) in a second olefin epoxidation condition, the reaction mixture obtained in the step (1) or the second mixed stream obtained in the step (1) and a second solid catalyst are introduced to one or more slurry bed reactors to conduct an epoxidation until the total conversion of H2O2 reaches 98% or more, with a proviso that said process for producing the alkylene oxide by olefin epoxidation has an selectivity for the alkylene oxide of 90% or more.The process of the present invention combines the slurry bed reactor with the fixed bed reactor and/or the moving bed reactor so as to overcome the disadvantages of the low conversion of H2O2 in the case that only the fixed bed reactor and/or the moving bed reactor are used, and the low selectivity for the target alkylene oxide in the case that only the slurry bed reactor is used.
摘要翻译：一种通过烯烃环氧化生产烯化氧的方法，其中所述方法包括以下步骤：（1）在第一烯烃环氧化条件下，在第一固体催化剂存在下，将含有溶剂，烯烃和H 2 O 2的第一混合物流在一个或多个固定床反应器和/或一个或多个移动床反应器中进行环氧化，直到H 2 O 2的转化率达到50％-95％，然后，任选地，将在步骤（1）中获得的所得反应混合物以分离以获得不含H 2 O 2的第一物流和含有未反应的H 2 O 2的第二物流，并将烯烃引入第二物流以产生第二混合物流，或任选地将烯烃引入到步骤（1）以产生第二混合流; （2）在第二烯烃环氧化条件下，将步骤（1）中获得的反应混合物或步骤（1）中获得的第二混合物流和第二固体催化剂引入一个或多个淤浆床反应器中进行环氧化直到H 2 O 2的总转化率达到98％以上，条件是通过烯烃环氧化生产环氧烷烃的方法对环氧烷烃的选择性为90％以上。本发明的方法将淤浆床反应器与固定床反应器和/或移动床反应器结合，以克服在只有固定床反应器和/或移动床的情况下H 2 O 2转化率低的缺点使用反应器，在仅使用浆料床反应器的情况下对目标烯化氧的选择性低。

3. 发明授权

US08349756B2 Noble metal-containing titanosilicate material and its preparation method 有权
标题翻译：贵金属含钛硅酸盐材料及其制备方法
公开(公告)号：US08349756B2
公开(公告)日：2013-01-08
申请号：US12594008
申请日：2008-03-27
申请人： Min Lin , Chunfeng Shi , Jun Long , Bin Zhu , Xingtian Shu , Xuhong Mu , Yibin Luo , Xieqing Wang , Yingchun Ru
发明人： Min Lin , Chunfeng Shi , Jun Long , Bin Zhu , Xingtian Shu , Xuhong Mu , Yibin Luo , Xieqing Wang , Yingchun Ru
IPC分类号： B01J29/89
CPC分类号： B01J35/002 , B01J23/38 , B01J23/40 , B01J23/44 , B01J29/89 , B01J35/0046 , B01J35/006 , B01J2229/20 , C07D301/08 , Y02P20/52
摘要： A noble metal-containing titanosilicate material, characterized in that said material is represented with the oxide form of xTiO2.100SiO2.yEOm.zE, wherein x ranges from 0.001 to 50.0; (y+z) ranges from 0.0001 to 20.0 and y/z
摘要翻译：一种含贵金属的钛硅酸盐材料，其特征在于，所述材料用xTiO2.1··O·SiO 2·yO·m·zE的氧化物形式表示，其中x为0.001-50.0; （y + z）为0.0001〜20.0，y / z <5。 E表示选自Ru，Rh，Pd，Re，Os，Ir，Pt，Ag和Au中的一种或多种贵金属; m是满足E的氧化态的数。所述材料的晶粒含有中空结构或下垂结构。在所述材料中，增强了贵金属和钛硅酸盐之间的协同效应。与现有技术相比，在氧化反应中，反应产物的选择性，催化活性和稳定性明显增加。通过丙烯环氧化制备环氧丙烷的反应。

4. 发明授权

US08273930B2 Process for producing ethylene from ethanol combining the catalytic conversion of hydrocarbons 有权
标题翻译：从乙醇生产乙烯的方法，结合烃的催化转化
公开(公告)号：US08273930B2
公开(公告)日：2012-09-25
申请号：US12373585
申请日：2007-07-12
申请人： Zhiguo Wu , Wenhua Xie , Chaogang Xie , Qiang Liu , Xuhong Mu , Jiushun Zhang , Yibin Luo , Xingtian Shu , Chenghan Yan
发明人： Zhiguo Wu , Wenhua Xie , Chaogang Xie , Qiang Liu , Xuhong Mu , Jiushun Zhang , Yibin Luo , Xingtian Shu , Chenghan Yan
IPC分类号： C07C1/24
CPC分类号： C10G57/00 , C07C1/24 , C07C2529/08 , C10G11/05 , C10G2300/1033 , C10G2300/104 , C10G2300/1044 , C10G2300/1055 , C10G2300/107 , C10G2300/1074 , C10G2300/1077 , C10G2300/4018 , C10G2400/20 , Y02P20/52 , Y02P20/584 , C07C11/04
摘要： A process for producing ethylene from ethanol combining the catalytic conversion of hydrocarbons: an ethanol feedstock is contacted with a Y-zeolite containing catalyst to give a product stream, and a coked catalyst and an target product of ethylene are obtained after separating the reaction stream; a hydrocarbon feedstock is contacted with a Y-zeolite containing catalyst to give a product stream, a spent catalyst and an oil vapor are obtained after separating the reaction stream, and the oil vapor is further separated to give the products such as gas, gasoline and the like; a part or all of the coked catalyst and a part or all of the spent catalyst enter the regenerator for the coke-burning regeneration, and the regenerated catalyst is divided into two portions, wherein one portion returns to be contacted with the hydrocarbon feedstock, and the other portion, after cooling, returns to be contacted with ethanol feedstock. This process not only reasonably utilizes the excessive thermal energy of the hydrocarbon conversion, but also solves the problem of heat supply for the conversion of ethanol, thus ensuring the continuous catalytic conversion of ethanol and generating enormous economic benefits. For the catalytic conversion of the ethanol, the content of ethylene is 95 vol % or more in the gas product; and the conversion of ethylene is not less than 99%. For the catalytic conversion of the hydrocarbons, the yield for the light olefins increases slightly by at least 2 mol %.
摘要翻译：将乙烯的催化转化合成乙醇的方法：将乙醇原料与含Y-沸石的催化剂接触，得到产物流，分离出反应物流后得到结焦催化剂和乙烯目标产物; 将烃原料与含Y-沸石的催化剂接触，得到产物流，分离反应流后得到废催化剂和油蒸气，并进一步分离出油蒸汽，得到产物如气体，汽油和类似; 一部分或全部的焦化催化剂和一部分或全部废废催化剂进入再生器进行焦炭燃烧再生，再生催化剂分成两部分，其中一部分返回以与烃原料接触，和冷却后的另一部分返回与乙醇原料接触。这个过程不仅合理利用了烃转化的过量热能，而且解决了乙醇转化的供热问题，从而保证了乙醇的连续催化转化，产生了巨大的经济效益。对于乙醇的催化转化，气体产物中乙烯的含量为95体积％以上; 乙烯的转化率不低于99％。对于烃的催化转化，轻质烯烃的产率略微增加至少2摩尔％。

5. 发明授权

US07923399B2 Zeolite-containing hydrocarbon-converting catalyst, the preparation process thereof, and a process for converting hydrocarbon oils with the catalyst 有权
标题翻译：含沸石的烃转化催化剂，其制备方法以及用催化剂转化烃油的方法
公开(公告)号：US07923399B2
公开(公告)日：2011-04-12
申请号：US11547209
申请日：2005-03-31
申请人： Jun Long , Zhijian Da , Huiping Tian , Zhenyu Chen , Weilin Zhang , Xingtian Shu , Jiushun Zhang , Yuxia Zhu , Yujian Liu
发明人： Jun Long , Zhijian Da , Huiping Tian , Zhenyu Chen , Weilin Zhang , Xingtian Shu , Jiushun Zhang , Yuxia Zhu , Yujian Liu
IPC分类号： B01J29/42
CPC分类号： B01J29/42 , B01J29/084 , B01J29/40 , B01J29/405 , B01J29/48 , B01J29/80 , B01J2229/42 , C10G11/05 , C10G2300/807 , C10G2400/20
摘要： A catalyst for converting hydrocarbons includes, based on the weight of the catalyst, 1-60% by weight of a zeolite, 0.1-10% by weight of an assistant catalytic component, 5-98% by weight of a thermotolerant inorganic oxide, and 0-70% by weight of a clay in terms of the oxide. The zeolite is a MFI-structured zeolite-containing phosphor and transition metal(s) or a mixture of the zeolite and a macroporous zeolite, which comprises, based on the weight of the mixture, 75-100% by weight of said MFI-structured zeolite containing phosphor and transition metal(s) and 0-25% by weight of the macroporous zeolite. In terms of the mass of the oxide, the MFI-structured zeolite containing phosphor and transition metal(s) has the following anhydrous chemical formula: (0-0.3)Na2O.(0.3-5.5)Al2O3.(1.0-10)P2O5.(0.7-15)M1xOy.(0.01-5)M2mOn(0-10)RE2O3.(70-97)SiO2 I or (0-0.3)Na2O.(0.3-5)Al2O3.(1.0-10)P2O5.(0.7-15)MpOq.(0-10)RE2O3.(70-98)SiO2 II The assistant catalytic component is one or more selected from the group consisting of the alkali earth metals, Group IVB metals, non-noble metals of Group VIII, and rare earth metals of the Periodic Table of the Elements. This catalyst has a higher ability to convert petroleum hydrocarbons and higher yields for propylene, ethylene, and light aromatics.
摘要翻译：用于转化烃的催化剂包括基于催化剂的重量，1-60重量％的沸石，0.1-10重量％的助催化组分，5-98重量％的耐热无机氧化物，和以氧化物换算0-70重量％的粘土。沸石是含有MFI结构的含沸石的磷光体和过渡金属或沸石与大孔沸石的混合物，其基于混合物的重量，包含所述MFI结构的75-100重量％含沸石的磷光体和过渡金属和0-25重量％的大孔沸石。就氧化物的质量而言，含有荧光粉和过渡金属的MFI结构的沸石具有以下无水化学式：（0-0.3）Na2O（0.3-5.5）Al2O3（1.0-10）P2O5。（0.7-15）M1xOy（0.01-5）M2mOn（0-10）RE2O3（70-97）SiO2 I或（0-0.3）Na2O（0.3-5）Al2O3（1.0-10）P2O5（ 0.7-15）MpOq。（0-10）RE2O3。（70-98）SiO2 II助催化剂组分是选自碱金属，ⅣB族金属，Ⅷ族非贵金属的一种或多种，元素周期表中的稀土金属。该催化剂具有较高的转化石油烃的能力和较高的丙烯，乙烯和轻质芳族化合物的产率。

6. 发明授权

US07713904B2 Composition for desulfurization 有权
标题翻译：脱硫组成
公开(公告)号：US07713904B2
公开(公告)日：2010-05-11
申请号：US10562965
申请日：2004-06-24
申请人： Baoning Zong , Jinyu Zheng , Wenhua Xie , Yong Xu , Xuhong Mu , Yibin Luo , Minggang Li , Xingtian Shu
发明人： Baoning Zong , Jinyu Zheng , Wenhua Xie , Yong Xu , Xuhong Mu , Yibin Luo , Minggang Li , Xingtian Shu
IPC分类号： B01J27/195 , B01J29/06
CPC分类号： B01J29/84 , B01J29/084 , B01J29/088 , B01J29/40 , B01J29/405 , B01J29/80 , B01J2229/42 , C10G45/12 , C10G47/20
摘要： This invention relates to a composition with desulfurization property, in which the desulfurization component is a kind of molecular sieves with incorporation of vanadium into the skeleton. The composition has high hydrothermal stability and the vanadium is hard to lose.
摘要翻译：本发明涉及具有脱硫性质的组合物，其中脱硫组分是一种将钒掺入骨架中的分子筛。该组合物具有很高的水热稳定性，钒难以失去。

7. 发明申请

US20100105542A1 NOBLE METAL-CONTAINING TITANOSILICATE MATERIAL AND ITS PREPARATION METHOD 有权
标题翻译：含金属的钛酸盐材料及其制备方法
公开(公告)号：US20100105542A1
公开(公告)日：2010-04-29
申请号：US12594008
申请日：2008-03-27
申请人： Min Lin , Chunfeng Shi , Jun Long , Bin Zhu , Xingtian Shu , Xuhong Mu , Yibin Luo , Xieqing Wang , Yingchun Ru
发明人： Min Lin , Chunfeng Shi , Jun Long , Bin Zhu , Xingtian Shu , Xuhong Mu , Yibin Luo , Xieqing Wang , Yingchun Ru
IPC分类号： B01J29/068
CPC分类号： B01J35/002 , B01J23/38 , B01J23/40 , B01J23/44 , B01J29/89 , B01J35/0046 , B01J35/006 , B01J2229/20 , C07D301/08 , Y02P20/52
摘要： A noble metal-containing titanosilicate material, characterized in that said material is represented with the oxide form of xTiO2.100SiO2.yEOm.zE, wherein x ranges from 0.001 to 50.0; (y+z) ranges from 0.0001 to 20.0 and y/z
摘要翻译：一种含贵金属的钛硅酸盐材料，其特征在于，所述材料用xTiO2.1··O·SiO 2·yO·m·zE的氧化物形式表示，其中x为0.001-50.0; （y + z）为0.0001〜20.0，y / z <5。 E表示选自Ru，Rh，Pd，Re，Os，Ir，Pt，Ag和Au中的一种或多种贵金属; m是满足E的氧化态的数。所述材料的晶粒含有中空结构或下垂结构。在所述材料中，增强了贵金属和钛硅酸盐之间的协同效应。与现有技术相比，在氧化反应中，反应产物的选择性，催化活性和稳定性明显增加。通过丙烯环氧化制备环氧丙烷的反应。

8. 发明授权

US06475465B2 Titanium-silicalite molecular sieve and the method for its preparation 有权
标题翻译：钛 - 硅沸石分子筛及其制备方法
公开(公告)号：US06475465B2
公开(公告)日：2002-11-05
申请号：US09732100
申请日：2000-12-06
申请人： Min Lin , Xingtian Shu , Xieqing Wang , Bin Zhu
发明人： Min Lin , Xingtian Shu , Xieqing Wang , Bin Zhu
IPC分类号： C01B3700
CPC分类号： C01B37/005 , Y10S423/22
摘要： The present invention relates to a titanium-silicalite (TS-1) molecular sieve and the method for preparation of the same, wherein each crystallite of said titanium-silicalite molecular sieve has a hollow cavity with a radial length of 5-300 nm. The benzene adsorption capacity of the molecular sieve determined at 25° C. and P/P0=0.10 for 1 hour is at least 70 mg/g; and the method for preparation of said molecular sieve comprises an acid-treatment and then an organic-base treatment of the synthesized TS-1 molecular sieve, or only an organic-base treatment. The TS-1 molecular sieve of the present invention has a relatively high reactivity and activity stability in the catalytic oxidation.
摘要翻译：本发明涉及钛 - 硅沸石（TS-1）分子筛及其制备方法，其中所述钛 - 硅沸石分子筛的每个微晶具有径向长度为5-300nm的中空腔。在25℃和P / P0 = 0.10下测定1小时的分子筛的苯吸附能力为至少70mg / g; 并且所述分子筛的制备方法包括对所合成的TS-1分子筛进行酸处理，然后进行有机碱处理，或仅进行有机碱处理。本发明的TS-1分子筛在催化氧化中具有较高的反应活性和活性稳定性。

9. 发明授权

US5951963A Phosphorous containing zeolite having MFI type structure 失效
标题翻译：含有MFI型结构的含磷沸石
公开(公告)号：US5951963A
公开(公告)日：1999-09-14
申请号：US46630
申请日：1998-03-24
申请人： Mingyuan He , Xiaoming Yang , Xingtian Shu , Jinge Luo
发明人： Mingyuan He , Xiaoming Yang , Xingtian Shu , Jinge Luo
IPC分类号： B01J29/85 , C01B39/10 , C01B39/46
CPC分类号： B01J29/85 , C01B39/10 , B01J2229/16 , B01J2229/183 , B01J2229/32 , Y10S423/22 , Y10S423/30
摘要： The present invention discloses a phosphorus-containing zeolite having MFI type structure. The anhydrous composition (based on the mole ratios of oxides) of the above zeolite is0.01-0.3Na.sub.2 O.Al.sub.2 O.sub.3.0.2-1.5P.sub.2 O.sub.5.30-90SiO.sub.2Said zeolite possesses a X-ray diffraction pattern listed in Table 1. The pore volume ratio of 1.0-10 nm mesopore to 10-membered ring pore is no less than 0.5. The crystal particle size of said zeolite is in the range of 0.8-2.0 micron. Said zeolite exhibits superior hydrothermal stability in catalytic conversion of hydrocarbons. Especially, when said zeolite is applied in catalytic cracking of hydrocarbons, it will enhance the crackability of large molecules, improve gasoline octane value and stability, and reduce the sulfur content in the gasoline as well.
摘要翻译：本发明公开了具有MFI型结构的含磷沸石。上述沸石的无水组成（基于氧化物的摩尔比）为0.01-0.3Na2O.Al2O3.0.2-1.5P2O5.30-90SiO2所述沸石具有表1中列出的X射线衍射图。孔体积 1.0-10nm中孔与10元环孔的比例不小于0.5。所述沸石的晶体粒度在0.8-2.0微米的范围内。所述沸石在烃的催化转化中表现出优异的水热稳定性。特别是当所述沸石用于烃的催化裂化时，会提高大分子的裂解性，提高汽油辛烷值和稳定性，并降低汽油中的硫含量。

10. 发明授权

US08778170B2 Process for producing light olefins and aromatics 有权
标题翻译：轻质烯烃和芳族化合物的制备方法
公开(公告)号：US08778170B2
公开(公告)日：2014-07-15
申请号：US10592166
申请日：2005-03-08
申请人： Jun Long , Zhijian Da , Dadong Li , Xieqing Wang , Xingtian Shu , Jiushun Zhang , Hong Nie , Chaogang Xie , Zhigang Zhang , Wei Wang
发明人： Jun Long , Zhijian Da , Dadong Li , Xieqing Wang , Xingtian Shu , Jiushun Zhang , Hong Nie , Chaogang Xie , Zhigang Zhang , Wei Wang
IPC分类号： C10G51/02 , C10G51/04
CPC分类号： C10G69/04 , C07C4/06 , C07C5/05 , C07C5/11 , C10G11/18 , C10G69/02 , C10G69/06 , C10G69/14 , C10G2300/1044 , C10G2300/1055 , C10G2300/107 , C10G2300/1074 , C10G2300/1077 , C10G2300/301 , C10G2300/4006 , C10G2300/4018 , C10G2300/4093 , C10G2300/44 , C10G2300/807 , C10G2400/20 , C10G2400/30
摘要： A process for producing light olefins and aromatics, which comprises reacting a feedstock with a catalytic cracking catalyst in at least two reaction zones, wherein the reaction temperature of at least one reaction zone downstream of the first reaction zone is higher than that of the first reaction zone and its weight hourly space velocity is lower than that of the first reaction zone. The spent catalyst is separated, from the reaction product vapor, regenerated, and then returned to the reactor. The reaction product vapor is separated to obtain the desired products, light olefins and aromatics. This process efficiently produces light olefins such as propylene, ethylene, etc from heavy feedstocks, wherein the yield of propylene exceeds 20% by weight, and produces aromatics such as toluene, xylene, etc at the same time.
摘要翻译：一种用于生产轻质烯烃和芳族化合物的方法，其包括在至少两个反应区中使原料与催化裂化催化剂反应，其中第一反应区下游的至少一个反应区的反应温度高于第一反应的反应温度其重量时空速度低于第一反应区。将废催化剂与反应产物蒸气分离，再生，然后返回反应器。将反应产物蒸气分离以获得所需产物，轻质烯烃和芳族化合物。该方法从重质原料中有效地生产轻质烯烃如丙烯，乙烯等，其中丙烯的产率超过20重量％，同时产生芳烃如甲苯，二甲苯等。

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