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1. 发明授权

US09175230B2 Cracking catalyst and a process for preparing the same 有权
标题翻译：裂化催化剂及其制备方法
公开(公告)号：US09175230B2
公开(公告)日：2015-11-03
申请号：US11658831
申请日：2005-07-14
申请人： Jun Long , Zhonghong Qiu , Youbao Lu , Jiushun Zhang , Zhijian Da , Huiping Tian , Yuxia Zhu , Wanhong Zhang , Zhenbo Wang
发明人： Jun Long , Zhonghong Qiu , Youbao Lu , Jiushun Zhang , Zhijian Da , Huiping Tian , Yuxia Zhu , Wanhong Zhang , Zhenbo Wang
IPC分类号： B01J29/00 , B01J29/80 , C10G11/05 , B01J29/06 , B01J29/08 , B01J21/04 , B01J27/16 , B01J29/40 , B01J29/70 , B01J29/85 , B01J37/00
CPC分类号： C10G11/05 , B01J21/04 , B01J27/16 , B01J29/06 , B01J29/084 , B01J29/40 , B01J29/70 , B01J29/80 , B01J29/85 , B01J37/0045 , B01J2229/42 , C10G2400/02
摘要： A cracking catalyst, which contains alumina, phosphorus and molecular sieve, with or without clay, wherein said alumina is η-alumina or a mixture of η-alumina and χ-alumina and/or γ-alumina, and wherein the catalyst contains, on the basis of the total amount of the catalyst, 0.5-50 wt % of η-alumina, 0-50 wt % of χ-alumina and/or γ-alumina, 10-70 wt % of molecular sieve, 0-75 wt % of clay, and 0.1-8 wt % of phosphorus, measured as P2O5. The catalyst not only has higher cracking activity and higher cracking ability for cracking heavy oil, but also improves significantly quality and yield of gasoline, LCO and LPG in cracking products.
摘要翻译：一种裂解催化剂，其含有氧化铝，磷和分子筛，具有或不具有粘土，其中所述氧化铝是氧化铝或氧化铝和氧化铝和χ-氧化铝和/或γ-氧化铝的混合物，并且其中所述催化剂含有，基于催化剂的总量，0.5-50重量％的氧化铝，0-50重量％的χ-氧化铝和/或γ-氧化铝，10-70重量％的分子筛，0- 75重量％的粘土和0.1-8重量％的磷，以P2O5测量。该催化剂不仅具有较高的裂解活性和较高的裂解重质油裂化能力，而且可显着提高裂化产物中汽油，LCO和LPG的质量和产率。

2. 发明授权

US08778170B2 Process for producing light olefins and aromatics 有权
标题翻译：轻质烯烃和芳族化合物的制备方法
公开(公告)号：US08778170B2
公开(公告)日：2014-07-15
申请号：US10592166
申请日：2005-03-08
申请人： Jun Long , Zhijian Da , Dadong Li , Xieqing Wang , Xingtian Shu , Jiushun Zhang , Hong Nie , Chaogang Xie , Zhigang Zhang , Wei Wang
发明人： Jun Long , Zhijian Da , Dadong Li , Xieqing Wang , Xingtian Shu , Jiushun Zhang , Hong Nie , Chaogang Xie , Zhigang Zhang , Wei Wang
IPC分类号： C10G51/02 , C10G51/04
CPC分类号： C10G69/04 , C07C4/06 , C07C5/05 , C07C5/11 , C10G11/18 , C10G69/02 , C10G69/06 , C10G69/14 , C10G2300/1044 , C10G2300/1055 , C10G2300/107 , C10G2300/1074 , C10G2300/1077 , C10G2300/301 , C10G2300/4006 , C10G2300/4018 , C10G2300/4093 , C10G2300/44 , C10G2300/807 , C10G2400/20 , C10G2400/30
摘要： A process for producing light olefins and aromatics, which comprises reacting a feedstock with a catalytic cracking catalyst in at least two reaction zones, wherein the reaction temperature of at least one reaction zone downstream of the first reaction zone is higher than that of the first reaction zone and its weight hourly space velocity is lower than that of the first reaction zone. The spent catalyst is separated, from the reaction product vapor, regenerated, and then returned to the reactor. The reaction product vapor is separated to obtain the desired products, light olefins and aromatics. This process efficiently produces light olefins such as propylene, ethylene, etc from heavy feedstocks, wherein the yield of propylene exceeds 20% by weight, and produces aromatics such as toluene, xylene, etc at the same time.
摘要翻译：一种用于生产轻质烯烃和芳族化合物的方法，其包括在至少两个反应区中使原料与催化裂化催化剂反应，其中第一反应区下游的至少一个反应区的反应温度高于第一反应的反应温度其重量时空速度低于第一反应区。将废催化剂与反应产物蒸气分离，再生，然后返回反应器。将反应产物蒸气分离以获得所需产物，轻质烯烃和芳族化合物。该方法从重质原料中有效地生产轻质烯烃如丙烯，乙烯等，其中丙烯的产率超过20重量％，同时产生芳烃如甲苯，二甲苯等。

3. 发明授权

US08597500B2 Process for converting inferior feedstock to high quality fuel oil 有权
标题翻译：将劣质原料转化为优质燃料油的方法
公开(公告)号：US08597500B2
公开(公告)日：2013-12-03
申请号：US12921436
申请日：2009-03-13
申请人： Youhao Xu , Lishun Dai , Zhigang Zhang , Shouye Cui , Jianhong Gong , Chaogang Xie , Jun Long , Hong Nie , Zhijian Da , Jiushun Zhang , Tao Liu , Anguo Mao
发明人： Youhao Xu , Lishun Dai , Zhigang Zhang , Shouye Cui , Jianhong Gong , Chaogang Xie , Jun Long , Hong Nie , Zhijian Da , Jiushun Zhang , Tao Liu , Anguo Mao
IPC分类号： C10G11/00
CPC分类号： C10G55/06 , C10G11/18 , C10G67/0409 , C10G69/04 , C10G2300/1033 , C10G2300/104 , C10G2300/1044 , C10G2300/1055 , C10G2300/107 , C10G2300/1077 , C10G2300/203 , C10G2300/205 , C10G2300/308 , C10G2300/4018 , C10G2300/4025 , C10G2300/4093 , C10G2300/44 , C10G2400/02 , C10G2400/04 , C10G2400/06 , C10G2400/28
摘要： A catalytic conversion process to convert inferior feedstock to high quality fuel oil and propylene is disclosed. Inferior feedstock is introduced into first and second reactor zone, wherein first step and second step reactions occur by contacting with catalytic conversion catalyst. Product vapors include fluid catalytic cracking gas oil (FGO) which is introduced into a hydrotreating unit and/or extraction unit to obtain hydrotreated FGO and/or extracted FGO. Hydrotreated FGO and/or extracted FGO returns to the first reactor zone and/or another catalytic cracking unit to obtain propylene and gasoline. The extracted oil of said FGO is rich in double ring aromatics and the raffinate of said FGO is rich in chain alkane and cycloalkane. More particularly, the invention utilizes petroleum oil resources efficiently for decreasing the yield of dry gas and coke significantly.
摘要翻译：公开了将劣质原料转化为高质量燃料油和丙烯的催化转化方法。将不良原料引入第一和第二反应器区，其中通过与催化转化催化剂接触进行第一步和第二步反应。产物蒸气包括流化催化裂化瓦斯油（FGO），其被引入加氢处理单元和/或提取单元以获得加氢处理的FGO和/或提取的FGO。加氢处理的FGO和/或提取的FGO返回到第一反应器区和/或另一个催化裂化单元以获得丙烯和汽油。所述FGO的提取油富含双环芳族化合物，所述FGO的残油富含链烷烃和环烷烃。更具体地说，本发明有效地利用石油资源，显着降低干气和焦炭的产率。

4. 发明授权

US07485595B2 Molecular sieve-containing catalyst for cracking hydrocarbons and a method for preparing the same 有权
标题翻译：用于裂化烃的分子筛催化剂及其制备方法
公开(公告)号：US07485595B2
公开(公告)日：2009-02-03
申请号：US10855386
申请日：2004-05-28
申请人： Jun Long , Yuxia Zhu , Huiping Tian , Yujian Liu , Zhenyu Chen , Yaoqing Guo , Zhijian Da , Jiushun Zhang , Mingyuan He
发明人： Jun Long , Yuxia Zhu , Huiping Tian , Yujian Liu , Zhenyu Chen , Yaoqing Guo , Zhijian Da , Jiushun Zhang , Mingyuan He
IPC分类号： B01J29/04 , B01J29/87 , B01J29/06 , B01J21/00 , B01J29/00 , B01J29/08 , B01J21/16 , B01J23/00 , B01J23/32 , B01J23/02 , B01J23/06 , B01J23/70
CPC分类号： B01J29/088 , B01J29/061 , B01J29/146 , B01J29/166 , B01J37/0045 , B01J37/16 , B01J2229/18 , B01J2229/20 , B01J2229/42 , C10G11/05
摘要： A molecular sieve-containing catalyst for cracking hydrocarbons, comprising molecular sieve, refractory inorganic oxide, clay and a metal component, wherein the amount of said molecular sieve is from 1 to 90% by weight, the refractory inorganic oxide is from 2 to 80% by weight, the clay is from 2 to 80% by weight, and the metal component is from 0.1 to 30% by weight, calculated as the oxide of said metal having its maximum valence state, based on the total amount of the catalyst, wherein said metal component exists essentially in a reduction state and is one or more metals selected from the group consisting of metals of Group IIIA (other than aluminum), and metals of Group IVA, VA, IB, IIB, VB, VIB and VIIB, and non-noble metals of Group VIII of the periodic table. The catalyst has higher cracking activity and higher sulfur reduction activity.
摘要翻译：一种分子筛催化剂，用于裂解烃，包括分子筛，耐火无机氧化物，粘土和金属组分，其中所述分子筛的量为1至90重量％，耐火无机氧化物为2至80重量％，粘土为2〜80重量％，金属成分为0.1〜30重量％，以所述金属的最高化合价的氧化物计，基于催化剂的总量计，其中，所述金属组分基本上以还原状态存在，并且是选自IIIA族金属（铝以外）中的一种或多种金属，以及IVA，VA，IB，IIB，VB，VIB和VIIB族的金属，以及周期表第Ⅷ族的非贵金属。该催化剂具有较高的裂解活性和较高的硫还原活性。

5. 发明授权

US07435332B2 Process for cracking hydrocarbon oils 有权
标题翻译：裂解烃油的工艺
公开(公告)号：US07435332B2
公开(公告)日：2008-10-14
申请号：US10949298
申请日：2004-09-27
申请人： Jun Long , Huiping Tian , Yujian Liu , Yuxia Zhu , Zhenyu Chen , Yaoqing Guo , Zhijian Da , Jiushun Zhang , Mingyuan He
发明人： Jun Long , Huiping Tian , Yujian Liu , Yuxia Zhu , Zhenyu Chen , Yaoqing Guo , Zhijian Da , Jiushun Zhang , Mingyuan He
IPC分类号： C10G11/00 , C10G9/00
CPC分类号： C10G11/05 , C10G11/04
摘要： This invention relates to a process for cracking hydrocarbon oils. The process comprises contacting a hydrocarbon oil with a catalyst that has been contacted with an atmosphere containing a reducing gas, separating cracked products and the catalyst, and regenerating the catalyst. The catalyst is a cracking catalyst containing a metal component, or a catalyst mixture of a cracking catalyst containing a metal component and a cracking catalyst free of metal component. The catalyst is contacted with the atmosphere containing a reducing gas at a temperature of 100 to 900° C. for at least 1 second, and the amount of the atmosphere containing a reducing gas is not less than 0.03 cubic meters of reducing gas per ton of the cracking catalyst containing a metal component per minute, at a pressure of 0.1-0.5 MPa in the reduction reactor. The process has enhanced capability for desulfurizing and cracking heavy oils.
摘要翻译：本发明涉及一种裂解烃油的方法。该方法包括使烃油与已经与含有还原气体的气氛接触的催化剂接触，分离裂化产物和催化剂，并再生催化剂。催化剂是含有金属组分的裂化催化剂，或含有金属组分的裂化催化剂和不含金属组分的裂化催化剂的催化剂混合物。催化剂与含有还原气体的气氛在100〜900℃的温度下接触1秒以上，含有还原气体的气氛量不低于0.03立方米/ 裂化催化剂在还原反应器中以0.1-0.5MPa的压力每分钟含有金属组分。该工艺提高脱硫和重油的能力。

6. 发明授权

US09309467B2 Integrated process for hydrogenation and catalytic cracking of hydrocarbon oil 有权
标题翻译：碳氢化合物氢化和催化裂解的综合工艺
公开(公告)号：US09309467B2
公开(公告)日：2016-04-12
申请号：US12809516
申请日：2008-12-19
申请人： Yongcan Gao , Chaogang Xie , Chuanfeng Niu , Jiushun Zhang , Lishun Dai , Hong Nie , Dadong Li , Jun Long , Jianguo Ma , Yan Cui
发明人： Yongcan Gao , Chaogang Xie , Chuanfeng Niu , Jiushun Zhang , Lishun Dai , Hong Nie , Dadong Li , Jun Long , Jianguo Ma , Yan Cui
IPC分类号： C10G11/18 , C10G51/06 , C10G69/04
CPC分类号： C10G11/18 , C10G11/182 , C10G51/06 , C10G69/04 , C10G2300/1037 , C10G2300/107 , C10G2300/1077 , C10G2300/301 , C10G2300/4006 , C10G2300/4012 , C10G2300/70 , C10G2300/807 , C10G2400/02 , C10G2400/04 , C10G2400/28
摘要： Disclosed is a combination process for improved hydrotreating and catalytic cracking of hydrocarbon oils, including: contacting residual oil, catalytic cracking cycle oil, and optional distillate oil with a hydrotreating catalyst under hydrotreating conditions in the presence of hydrogen followed by separation of the reaction products to obtain gas, hydrogenated naphtha, hydrogenated diesel oil, and hydrogenated tail oil; contacting the hydrogenated tail oil and optional normal catalytic cracking feedstock oil with a cracking catalyst under catalytic cracking conditions followed by separation of the reaction products to obtain dry gas, hydrogenated naphtha, liquefied petroleum gas, catalytic cracked gasoline, catalytic cracked diesel oil, and catalytic cracking cycle oil; wherein the hydrogenated tail oil and/or normal catalytic cracking feedstock oil are separated into at least two fractions, the light and the heavy fractions or normal catalytic cracking heavy feedstock oil and normal catalytic cracking light feedstock oil, prior to contacting the hydrogenated tail oil and/or normal catalytic cracking feedstock oil with the cracking catalyst. The process according to the present invention is especially suitable for conversion of hydrocarbon oils to produce more products of gasoline or diesel oil.
摘要翻译：公开了用于改进烃油的加氢处理和催化裂化的组合方法，包括：在加氢处理条件下在氢气存在下，用加氢处理催化剂将残油，催化裂化循环油和任选的馏出油接触，然后将反应产物分离获得气体，氢化石脑油，氢化柴油和氢化尾油; 在催化裂化条件下使氢化尾油和任选的常规催化裂化原料油与裂化催化剂接触，然后分离反应产物，得到干燥气体，氢化石脑油，液化石油气，催化裂化汽油，催化裂化柴油和催化剂开裂循环油; 其中所述氢化尾油和/或常规催化裂化原料油在将氢化尾油与氢化尾油接触之前分离成至少两个馏分，轻馏分或重馏分或正常催化裂化重原料油和常规催化裂化轻原料油， /或正常催化裂化原料油与裂化催化剂。根据本发明的方法特别适用于烃油的转化以产生更多的汽油或柴油的产物。

7. 发明授权

US09259711B2 Catalyst for upgrading inferior acid-containing crude oil, process for manufacturing the same, and application thereof 有权
标题翻译：用于升级劣质含酸原油的催化剂，其制造方法及其应用
公开(公告)号：US09259711B2
公开(公告)日：2016-02-16
申请号：US12993637
申请日：2009-01-09
申请人： Jun Long , Jiushun Zhang , Huiping Tian , Yuxia Zhu
发明人： Jun Long , Jiushun Zhang , Huiping Tian , Yuxia Zhu
IPC分类号： C10G11/04 , B01J21/14 , B01J21/16 , B01J23/02 , B01J35/10 , B01J37/03 , B01J37/30 , C10G29/04 , C10G45/04
CPC分类号： B01J21/14 , B01J21/16 , B01J23/02 , B01J35/1019 , B01J35/1042 , B01J35/1047 , B01J35/1061 , B01J37/03 , B01J37/30 , C10G11/04 , C10G29/04 , C10G45/04
摘要： The present invention relates to a mesopore material of a catalyst for upgrading acid-containing crude oil. Said mesopore material is an amorphous material containing alkaline earth oxide, silica and alumina, and has an anhydrous chemical formula of (0-0.3)Na2O.(1-50)MO.(6-58)Al2O3.(40-92)SiO2, based on the weight percent of the oxides, wherein M is one or more selected from Mg, Ca and Ba. Said mesopore material has a specific surface area of 200-400 m2/g, a pore volume of 0.5-2.0 ml/g, an average pore diameter of 8-20 nm, and a most probable pore size of 5-15 nm. The present invention further relates to a process for manufacturing said mesopore material and the use thereof. The catalyst prepared from the mesopore material provided in the present invention is suitable for the catalytic upgrading of inferior acid-containing crude oil and for the removal of organic acids, carbon residues and metals in the crude oil, and thus has very good economic benefits.
摘要翻译：本发明涉及一种用于升级含酸原油的催化剂的中孔材料。所述中孔材料是含有碱土金属氧化物，二氧化硅和氧化铝的无定形材料，具有无水化学式（0-0.3）Na2O（1-50）MO。（6-58）Al2O3。（40-92）SiO2 ，基于氧化物的重量百分数，其中M是选自Mg，Ca和Ba中的一种或多种。所述中孔材料的比表面积为200-400m2 / g，孔体积为0.5-2.0ml / g，平均孔径为8-20nm，最可能的孔径为5-15nm。本发明还涉及一种制造所述中孔材料的方法及其用途。由本发明提供的中孔材料制备的催化剂适用于劣质含酸原油的催化提质和原油中有机酸，碳残余物和金属的去除，具有非常好的经济效益。

8. 发明授权

US09163182B2 Process for cracking hydrocarbon oils 有权
标题翻译：裂解烃油的工艺
公开(公告)号：US09163182B2
公开(公告)日：2015-10-20
申请号：US12027123
申请日：2008-02-06
申请人： Jun Long , Yuxia Zhu , Huiping Tian , Yujian Liu , Zhenyu Chen , Yaoqing Guo , Zhijian Da , Jiushun Zhang , Mingyuan He
发明人： Jun Long , Yuxia Zhu , Huiping Tian , Yujian Liu , Zhenyu Chen , Yaoqing Guo , Zhijian Da , Jiushun Zhang , Mingyuan He
IPC分类号： C10G51/02 , C10G11/14 , C10G11/05 , C10G11/16 , C10G11/18
CPC分类号： C10G11/14 , C10G11/05 , C10G11/16 , C10G11/182 , C10G2300/205 , C10G2300/4006 , C10G2300/4012 , C10G2300/701 , C10G2400/04
摘要： A novel process for cracking olefins including contacting a hydrocarbon oil with a catalyst in a riser reactor having multiple reaction zones under cracking reaction conditions; separating reaction products and the catalyst; regenerating at least a part of spent catalyst obtained, contacting a part of the regenerated catalyst with the hydrocarbon in the first reaction zone; contacting the other part of the spent catalyst and/or regenerated catalyst in at least one reaction zone after the first reaction zone with the products obtained in previous reaction zones.
摘要翻译：一种用于裂化烯烃的新方法，包括在裂化反应条件下具有多个反应区的提升管反应器中使烃油与催化剂接触; 分离反应产物和催化剂; 再生至少一部分所获得的废催化剂，使部分再生催化剂与第一反应区中的烃接触; 在第一反应区之后的至少一个反应区与先前反应区中获得的产物接触废催化剂和/或再生催化剂的另一部分。

9. 发明授权

US08088335B2 Catalytic conversion apparatus 有权
标题翻译：催化转化装置
公开(公告)号：US08088335B2
公开(公告)日：2012-01-03
申请号：US12295523
申请日：2007-03-30
申请人： Jun Long , Kejia Xu , Shuandi Hou , Zhijian Da , Chaogang Xie , Jiushun Zhang , Zhanzhu Zhang
发明人： Jun Long , Kejia Xu , Shuandi Hou , Zhijian Da , Chaogang Xie , Jiushun Zhang , Zhanzhu Zhang
IPC分类号： B01J8/18 , F27B15/00
CPC分类号： C10G11/18 , B01J8/0055 , B01J8/0065 , B01J8/1827 , B01J8/26 , B01J2219/00038 , C10G2300/4093 , C10G2400/20 , Y02P30/40 , Y02P30/446
摘要： A conversion apparatus for catalytic cracking a hydrocarbon feed to light hydrocarbon comprises at least one riser reactor, a dense bed reactor, a disengager, and a stripper. A dense bed reactor which is separated from disengage, is employed to enforce further cracking hydrocarbon to light olefins, with low methane yield. Moreover, the spent catalysts discharged from the outlet of the dense bed reactor can be introduced into the stripper via a specific catalyst transporting channel, to maintain catalyst concentration in the dense bed reactor that can be advantageous to deeper cracking of the intermediate products to produce more light olefins, particularly propylene.
摘要翻译：用于将烃进料催化裂化成轻质烃的转化装置包括至少一个提升管反应器，致密床反应器，脱分离器和剥离器。使用与脱离分离的致密床反应器用于进一步将烃裂解成轻质烯烃，甲烷产率低。此外，从致密床反应器的出口排出的废催化剂可以通过特定的催化剂输送通道引入汽提塔中，以保持致密床反应器中的催化剂浓度，这有利于中间产物的更深裂化以产生更多轻质烯烃，特别是丙烯。

10. 发明申请

US20080308455A1 Catalyst and a Method for Cracking Hydrocarbons 审中-公开
标题翻译：催化剂和烃类裂化方法
公开(公告)号：US20080308455A1
公开(公告)日：2008-12-18
申请号：US11813056
申请日：2005-12-28
申请人： Jun Long , Wenbin Jiang , Mingde Xu , Huiping Tian , Yibin Luo , Xingtian Shu , Jiushun Zhang , Beiyan Chen , Haitao Song
发明人： Jun Long , Wenbin Jiang , Mingde Xu , Huiping Tian , Yibin Luo , Xingtian Shu , Jiushun Zhang , Beiyan Chen , Haitao Song
IPC分类号： C10G11/05
CPC分类号： C10G11/05 , B01J27/1853 , B01J29/46 , B01J35/0006 , B01J35/002 , B01J2229/42 , C10G11/02 , C10G47/16 , C10G2300/4018 , C10G2400/02
摘要： The invention discloses a catalyst and a method for cracking hydrocarbons. The catalyst comprises, calculated by dry basis, 10˜65 wt % ZSM-5 zeolite, 0˜60 wt % clay, 15˜60 wt % inorganic oxide binder, 0.5˜15 wt % one or more metal additives selected from the metals of Group VIIIB and 2˜25 wt % P additive, in which the metal additive is calculated by metal oxide and the P additive is calculated by P2O5. The method for cracking hydrocarbons using this catalyst increases the yield of FCC liquefied petroleum gas (LPG) and the octane number of FCC gasoline, as well as it increases the concentration of propylene in LPG dramatically.
摘要翻译：本发明公开了一种催化剂和一种裂化烃的方法。催化剂包括以干基计，10〜65重量％的ZSM-5沸石，0〜60重量％的粘土，15〜60重量％的无机氧化物粘合剂，0.5〜15重量％的一种或多种金属添加剂， ⅦB族和2〜25wt％P添加剂，其中金属添加剂由金属氧化物计算，P添加剂通过P2O5计算。使用该催化剂裂化烃的方法提高了FCC液化石油气（LPG）的产率和FCC汽油的辛烷值，并且显着提高了LPG中丙烯的浓度。

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