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    • 2. 发明授权
    • Flame-retardant polyester fiber for artificial hair
    • 用于人造头发的阻燃聚酯纤维
    • US07501463B2
    • 2009-03-10
    • US10579994
    • 2004-11-24
    • Toshihiro KowakiToshiyuki MasudaHiroyuki Shinbayashi
    • Toshihiro KowakiToshiyuki MasudaHiroyuki Shinbayashi
    • C08K5/1515C08K5/52C08K5/09
    • D01F6/92
    • It is an object of the present invention to provide a polyester fiber for artificial hair which has an excellent spinning processability, maintains fiber properties possessed by conventional polyester fiber, and has excellent flame retardance, heat resistance, transparency and the like.A flame retardant polyester fiber for artificial hair which achieves the above object can be obtained by melt spinning a composition in which 5 to 30 parts by weight of (B) a brominated epoxy based flame retardant and 0.05 to 1 parts by weight of (C) a reaction accelerator is mixed with 100 parts by weight of (A) a polyester made of one or more of polyalkylene terephthalate or a copolymer polyester comprising polyalkylene terephthalate as a main component.
    • 本发明的目的是提供一种具有优异的纺丝加工性的人造毛发用聚酯纤维,保持常规聚酯纤维具有的纤维特性,并且具有优异的阻燃性,耐热性,透明性等。 实现上述目的的人造毛发用阻燃性聚酯纤维可以通过将(B)溴化环氧类阻燃剂为5〜30重量份,(C)的0.05〜1重量份, 将反应促进剂与100重量份的(A)由聚对苯二甲酸亚烷基酯或包含聚对苯二甲酸亚烷基酯作为主要成分的共聚物聚酯制成的聚酯混合。
    • 4. 发明申请
    • Flame-retardant polyester fiber for artificial hair
    • 用于人造头发的阻燃聚酯纤维
    • US20070155870A1
    • 2007-07-05
    • US10579994
    • 2004-11-24
    • Toshihiro KowakiToshiyuki MasudaHiroyuki Shinbayashi
    • Toshihiro KowakiToshiyuki MasudaHiroyuki Shinbayashi
    • C08K5/15
    • D01F6/92
    • It is an object of the present invention to provide a polyester fiber for artificial hair which has an excellent spinning processability, maintains fiber properties possessed by conventional polyester fiber, and has excellent flame retardance, heat resistance, transparency and the like. A flame retardant polyester fiber for artificial hair which achieves the above object can be obtained by melt spinning a composition in which 5 to 30 parts by weight of (B) a brominated epoxy based flame retardant and 0.05 to 1 parts by weight of (C) a reaction accelerator is mixed with 100 parts by weight of (A) a polyester made of one or more of polyalkylene terephthalate or a copolymer polyester comprising polyalkylene terephthalate as a main component.
    • 本发明的目的是提供一种具有优异的纺丝加工性的人造毛发用聚酯纤维,保持常规聚酯纤维具有的纤维特性,并且具有优异的阻燃性,耐热性,透明性等。 实现上述目的的人造毛发用阻燃性聚酯纤维可以通过将(B)溴化环氧类阻燃剂为5〜30重量份,(C)的0.05〜1重量份, 将反应促进剂与100重量份的(A)由聚对苯二甲酸亚烷基酯或包含聚对苯二甲酸亚烷基酯作为主要成分的共聚物聚酯制成的聚酯混合。
    • 5. 发明申请
    • Flame-retardant polyester-based fiber for artificial hair
    • 用于人造头发的阻燃聚酯基纤维
    • US20060194045A1
    • 2006-08-31
    • US10568693
    • 2004-08-16
    • Toshiyuki Masuda
    • Toshiyuki Masuda
    • D02G3/00C07F9/6574
    • D01F6/62D01F1/07D01F6/84Y10T428/2913
    • A polyester fiber having outstanding flame resistance, curl-setting property, melt-drip-proof property, transparency, devitrification resistance, and controlled gloss of fiber, while maintaining physical properties of usual polyester fibers, such as heat-resistance and tensile elongation and strength is provided. A flame retardant polyester fiber for artificial hair that can solve the problem may be obtained by melt-spinning a composition obtained by melt-kneading 2 to 20 parts by weight of organic cyclic phosphorus compounds and/or phosphoric ester amido compounds (B) into 100 parts by weight of a polyester (A) comprising one or more kinds of polyalkylene terephthalates and copolymerized polyesters having a polyalkylene terephthalate as a principal component, and a composition obtained by blending organic fine particles (C) and/or inorganic fine particles (D) into the above-mentioned composition.
    • 具有优异的阻燃性,卷曲性,耐熔滴性,透明性,耐失透性和光泽度的聚酯纤维,同时保持常规聚酯纤维的物理性能,如耐热性和拉伸伸长率和强度 被提供。 通过将2〜20重量份的有机环磷化合物和/或磷酸酯酰胺化合物(B)熔融捏合得到的组合物熔融纺丝成100,可以得到能够解决问题的人造毛发用阻燃性聚酯纤维 重量份包含一种或多种聚对苯二甲酸亚烷基酯和具有聚对苯二甲酸亚烷基酯作为主要成分的共聚聚酯的聚酯(A)和通过掺合有机细颗粒(C)和/或无机细颗粒(D)获得的组合物, 进入上述组合物。
    • 9. 发明授权
    • Room temperature curing composition
    • 室温固化组合物
    • US5668194A
    • 1997-09-16
    • US572581
    • 1995-12-14
    • Naotami AndoToshiyuki MasudaTakanori HatanoKazuya Nakayama
    • Naotami AndoToshiyuki MasudaTakanori HatanoKazuya Nakayama
    • C08F265/04C08F265/00C08F265/06C08F285/00C09D151/00H05K3/28C08L43/04
    • C09D151/003C08F265/06C08F285/00H05K3/285Y10S525/902
    • This invention relates to a room temperature curing composition for use in various coatings for interior and exterior sidings, automotive bodies, household electrical appliances and plastic substrates and particularly for coatings required to have weather resistance and durability. The room temperature curing composition of this invention comprises an emulsion obtained by a multi-stage polymerization of monomers, said emulsion comprising emulsion particles, the core of which is formed by polymerization of (A) a silyl group-containing vinyl monomer, (B) an alkyl or cycloalkyl methacrylate whose alkyl moiety contains not less than 4 carbon atoms, and (C) a non-hydrophilic vinyl monomer other than (B) and the outer shell of which is formed by polymerization of (A), (B), (C) and (D) a hydrophilic vinyl monomer. The room temperature curing composition of this invention features a high stability of silyl groups it contains and a remarkably improved film-forming property even after prolonged storage. Moreover, it is very satisfactory in mechanical stability, water resistance, durability and white enamel gloss.
    • 本发明涉及室温固化组合物,其用于室内和外侧各种涂料,汽车车身,家用电器和塑料基材,特别是用于具有耐候性和耐久性的涂层。 本发明的室温固化组合物包含通过单体多阶段聚合获得的乳液,所述乳液包含乳液颗粒,其核心通过(A)含甲硅烷基的乙烯基单体的聚合形成,(B) 烷基部分含有不少于4个碳原子的烷基或环烷基甲基丙烯酸酯,(C)除(B)以外的非亲水性乙烯基单体,其外壳由(A),(B), (C)和(D)亲水性乙烯基单体。 本发明的室温固化组合物特征在于其含有的甲硅烷基的稳定性高,即使在长时间储存​​后也具有显着改善的成膜性能。 此外,机械稳定性,耐水性,耐久性和白色搪瓷光泽度非常令人满意。