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    • 3. 发明授权
    • Flame-retardant polyester fiber for artificial hair
    • 用于人造头发的阻燃聚酯纤维
    • US07501463B2
    • 2009-03-10
    • US10579994
    • 2004-11-24
    • Toshihiro KowakiToshiyuki MasudaHiroyuki Shinbayashi
    • Toshihiro KowakiToshiyuki MasudaHiroyuki Shinbayashi
    • C08K5/1515C08K5/52C08K5/09
    • D01F6/92
    • It is an object of the present invention to provide a polyester fiber for artificial hair which has an excellent spinning processability, maintains fiber properties possessed by conventional polyester fiber, and has excellent flame retardance, heat resistance, transparency and the like.A flame retardant polyester fiber for artificial hair which achieves the above object can be obtained by melt spinning a composition in which 5 to 30 parts by weight of (B) a brominated epoxy based flame retardant and 0.05 to 1 parts by weight of (C) a reaction accelerator is mixed with 100 parts by weight of (A) a polyester made of one or more of polyalkylene terephthalate or a copolymer polyester comprising polyalkylene terephthalate as a main component.
    • 本发明的目的是提供一种具有优异的纺丝加工性的人造毛发用聚酯纤维,保持常规聚酯纤维具有的纤维特性,并且具有优异的阻燃性,耐热性,透明性等。 实现上述目的的人造毛发用阻燃性聚酯纤维可以通过将(B)溴化环氧类阻燃剂为5〜30重量份,(C)的0.05〜1重量份, 将反应促进剂与100重量份的(A)由聚对苯二甲酸亚烷基酯或包含聚对苯二甲酸亚烷基酯作为主要成分的共聚物聚酯制成的聚酯混合。
    • 4. 发明申请
    • Flame-retardant polyester fiber for artificial hair
    • 用于人造头发的阻燃聚酯纤维
    • US20070155870A1
    • 2007-07-05
    • US10579994
    • 2004-11-24
    • Toshihiro KowakiToshiyuki MasudaHiroyuki Shinbayashi
    • Toshihiro KowakiToshiyuki MasudaHiroyuki Shinbayashi
    • C08K5/15
    • D01F6/92
    • It is an object of the present invention to provide a polyester fiber for artificial hair which has an excellent spinning processability, maintains fiber properties possessed by conventional polyester fiber, and has excellent flame retardance, heat resistance, transparency and the like. A flame retardant polyester fiber for artificial hair which achieves the above object can be obtained by melt spinning a composition in which 5 to 30 parts by weight of (B) a brominated epoxy based flame retardant and 0.05 to 1 parts by weight of (C) a reaction accelerator is mixed with 100 parts by weight of (A) a polyester made of one or more of polyalkylene terephthalate or a copolymer polyester comprising polyalkylene terephthalate as a main component.
    • 本发明的目的是提供一种具有优异的纺丝加工性的人造毛发用聚酯纤维,保持常规聚酯纤维具有的纤维特性,并且具有优异的阻燃性,耐热性,透明性等。 实现上述目的的人造毛发用阻燃性聚酯纤维可以通过将(B)溴化环氧类阻燃剂为5〜30重量份,(C)的0.05〜1重量份, 将反应促进剂与100重量份的(A)由聚对苯二甲酸亚烷基酯或包含聚对苯二甲酸亚烷基酯作为主要成分的共聚物聚酯制成的聚酯混合。
    • 5. 发明申请
    • Flame-retardant polyester fibers for artificial hair
    • 用于人造头发的阻燃聚酯纤维
    • US20060194044A1
    • 2006-08-31
    • US10565744
    • 2004-07-25
    • Toshihiro KowakiToshiyuki MasudaHiroyuki ShinbayashiToyohiko Shiga
    • Toshihiro KowakiToshiyuki MasudaHiroyuki ShinbayashiToyohiko Shiga
    • D02G3/00C08K5/15
    • D01F6/62D01F1/07D01F6/92D06M15/53D06M2200/30Y10T428/2913Y10T428/2973Y10T428/2978Y10T428/298
    • There are provided a polyester fiber which maintains fiber properties such as heat resistance and strength and elongation possessed by a common polyester fiber, has excellent flame retardance, setting properties, transparence, devitrification resistance, stickiness reduction, and combing properties required for artificial hair, and has luster controlled according to need, and artificial hair using the same. Specifically, the present invention relates to a flame retardant polyester fiber for artificial hair, which is obtained by melt spinning a composition as a mixture of 100 parts by weight of (A) a polyester made of one or more of polyalkylene terephthalate and a copolymer polyester comprising polyalkylene terephthalate as a main component with 5 to 30 parts by weight of (B) a brominated epoxy flame retardant. The present invention also relates to the polyester fiber for artificial hair which has at least one modified cross-section, is a mixture with a fiber having a modified cross-section, and has a mixing ratio of the fiber having a round cross-section to the fiber having a modified cross-section is 8:2 to 1:9, and to the flame retardant polyester fiber for artificial hair which further comprises a hydrophilic fiber treating agent attached thereto, and thus has excellent smooth feeling, combing properties, and flame retardance.
    • 提供一种聚酯纤维,其保持了普通聚酯纤维具有的耐热性,强度和伸长率等纤维性能,具有优异的阻燃性,凝固性,透明性,耐失透性,粘着性降低和人造毛发所需的梳理性能, 根据需要控制光泽,使用同样的人造头发。 具体地说,本发明涉及一种人造毛发用阻燃性聚酯纤维,其通过将(A)由聚对苯二甲酸亚烷基酯和共聚物聚酯中的一种或多种制成的聚酯组成的100重量份的混合物熔融纺丝, 以(B)溴化环氧阻燃剂为5〜30重量份,以聚对苯二甲酸亚烷基酯为主要成分。 本发明还涉及具有至少一个改性横截面的人造毛发用聚酯纤维,是具有改性横截面的纤维的混合物,并且具有圆形横截面的纤维与 具有改进的横截面的纤维是8:2至1:9,并且对于还包含附着在其上的亲水性纤维处理剂的人造毛发用阻燃性聚酯纤维,因此具有优异的平滑感,梳理性和火焰 延迟。
    • 6. 发明申请
    • Flame retardant polyester fiber for artificial hair
    • 用于人造头发的阻燃聚酯纤维
    • US20060154062A1
    • 2006-07-13
    • US11345952
    • 2006-02-02
    • Toshihiro KowakiToshiyuki MasudaHiroyuki ShinbayashiToyohiko Shiga
    • Toshihiro KowakiToshiyuki MasudaHiroyuki ShinbayashiToyohiko Shiga
    • D02G3/00C08F20/00
    • C08K5/0066C08L63/00C08L67/02Y10T428/2913Y10T428/2927Y10T428/2973Y10T428/2978Y10T428/298C08L2666/22
    • There are provided a polyester fiber which maintains fiber properties such as heat resistance and strength and elongation possessed by a common polyester fiber, has excellent flame retardance, setting properties, transparence, devitrification resistance, stickiness reduction, and combing properties required for artificial hair, and has luster controlled according to need, and artificial hair using the same. Specifically, the present invention relates to a flame retardant polyester fiber for artificial hair, which is obtained by melt spinning a composition as a mixture of 100 parts by weight of (A) a polyester made of one or more of polyalkylene terephthalate and a copolymer polyester comprising polyalkylene terephthalate as a main component with 5 to 30 parts by weight of (B) a brominated epoxy flame retardant. The present invention also relates to the polyester fiber for artificial hair which has at least one modified cross-section, is a mixture with a fiber having a modified cross-section, and has a mixing ratio of the fiber having a round cross-section to the fiber having a modified cross-section is 8:2 to 1:9, and to the flame retardant polyester fiber for artificial hair which further comprises a hydrophilic fiber treating agent attached thereto, and thus has excellent smooth feeling, combing properties, and flame retardance.
    • 提供一种聚酯纤维,其保持了普通聚酯纤维具有的耐热性,强度和伸长率等纤维性能,具有优异的阻燃性,凝固性,透明性,耐失透性,粘着性降低和人造毛发所需的梳理性能, 根据需要控制光泽,使用同样的人造头发。 具体地说,本发明涉及一种人造毛发用阻燃性聚酯纤维,其通过将(A)由聚对苯二甲酸亚烷基酯和共聚物聚酯中的一种或多种制成的聚酯组成的100重量份的混合物熔融纺丝, 以(B)溴化环氧阻燃剂为5〜30重量份,以聚对苯二甲酸亚烷基酯为主要成分。 本发明还涉及具有至少一个改性横截面的人造毛发用聚酯纤维,是具有改性横截面的纤维的混合物,并且具有圆形横截面的纤维与 具有改进的横截面的纤维是8:2至1:9,并且对于还包含附着在其上的亲水性纤维处理剂的人造毛发用阻燃性聚酯纤维,因此具有优异的平滑感,梳理性和火焰 延迟。
    • 7. 发明授权
    • Polyester based fiber and artificial hair using the same
    • 聚酯纤维和人造头发使用相同
    • US07332563B2
    • 2008-02-19
    • US10482646
    • 2002-07-18
    • Toshiyuki MasudaToyohiko ShigaToshihiro Kowaki
    • Toshiyuki MasudaToyohiko ShigaToshihiro Kowaki
    • C08G63/183
    • D01F6/92
    • The object of the invention is to provide polyester-based fiber which maintains physical properties of usual polyester fiber, such as heat resistance, strength and elongation and is excellent in setting ability with controlled gloss of the fiber, artificial hair using the same, a method of producing polyester-based fiber, and a method of producing artificial hair by using the same. To achieve the object, a composition obtained by melt-kneading polyalkylene terephthalate or a copolymerized polyester (A) based on polyalkylene terephthalate, polyarylate (B) and a phosphite compound (C) is melt-spun to form fiber. In the case of melt-kneading, the ester exchange reaction of components (A) and (B) is prevented due to the inhibitory effect of the component (C) on the ester exchange reaction, the heat resistance and physical properties of the fiber are not deteriorated, and a matte effect is brought about by formation of protrusions on the surface of the fiber.
    • 本发明的目的是提供保持常规聚酯纤维的物理性能如耐热性,强度和伸长率的聚酯基纤维,并且具有优异的固化能力和光泽受控的光泽,使用其的人造毛发,方法 的生产聚酯类纤维的方法,以及使用该纤维的人造毛发的制造方法。 为了达到上述目的,通过将聚对苯二甲酸亚烷基酯或基于聚对苯二甲酸亚烷基酯,聚芳酯(B)和亚磷酸酯化合物(C)的共聚聚酯(A))熔融捏合而获得的组合物进行熔融纺丝以形成纤维。 在熔融捏合的情况下,由于组分(C)对酯交换反应的抑制作用,组分(A)和(B)的酯交换反应被阻止,纤维的耐热性和物理性能是 不劣化,并且通过在纤维的表面上形成突起而产生无光泽效果。
    • 9. 发明申请
    • Flame-retardant polyester fiber and artificial hair comprising the same
    • 阻燃聚酯纤维和包含其的人造毛发
    • US20050245647A1
    • 2005-11-03
    • US10505300
    • 2003-02-19
    • Toshiyuki MasudaToyohiko ShigaToshihiro Kowaki
    • Toshiyuki MasudaToyohiko ShigaToshihiro Kowaki
    • A41G3/00A41G5/00D01F1/07D01F6/92C08K5/49
    • D01F6/92A41G3/0083D01F1/07
    • A flame resistant polyester fiber, while maintaining physical properties, such as heat resistance, tensile strength and elongation, etc. of usual polyester fibers, having excellent flame resistance and excellent setting property, and furthermore having controlled gloss of fiber is provided. A composition obtained by melt kneading of a polyester (A) comprising polyalkylene terephthalates, and one or more kinds of copolymerized polyesters having polyalkylene terephthalate as a principal component; a polymer alloy (B) consisting of polyalkylene terephthalates and polyarylates; phosphorus based flame resistant agents (C); and phosphite based compounds (D), and organic fine particles (E) and/or inorganic fine particles (F) are mixed thereto to obtain a composition. The obtained composition is melt spun to obtain a flame resistant polyester fiber in which the above-mentioned problems are solved, and to obtain artificial hair using the fiber.
    • 提供了一种阻燃聚酯纤维,同时保持了具有优异的阻燃性和优异的固化性的普通聚酯纤维的物理性能,如耐热性,拉伸强度和伸长率等,并且还具有光泽受控的光泽。 通过熔融捏合包含聚对苯二甲酸亚烷基酯的聚酯(A)和一种或多种以聚对苯二甲酸亚烷基酯为主要成分的共聚聚酯得到的组合物; 由聚对苯二甲酸亚烷基酯和聚芳酯组成的聚合物合金(B) 磷基阻燃剂(C); 和亚磷酸酯类化合物(D)和有机微粒(E)和/或无机微粒(F)混合,得到组合物。 将得到的组合物进行熔融纺丝以获得其中解决上述问题的耐火聚酯纤维,并使用该纤维获得人造毛发。
    • 10. 发明授权
    • Artificial hair made of flame-retardant polyester
    • 人造头发由阻燃聚酯制成
    • US08545981B2
    • 2013-10-01
    • US13482499
    • 2012-05-29
    • Toshiyuki MasudaHiroyuki Shinbayashi
    • Toshiyuki MasudaHiroyuki Shinbayashi
    • D02G3/16C08K5/353C08K5/1515
    • C08L67/04D01F1/07D01F6/92D06M15/643D06M2200/30Y10T428/2962
    • The artificial hair of the present invention comprising a flame-retardant polyester-based fiber that is formed of a composition obtained by melt-kneading, the composition comprising: 100 parts by weight of polyester (A); 5 parts by weight to 30 parts by weight of a bromine-containing flame retardancy agent (B); and 0.5 parts by weight to 10 parts by weight of an antimony compound (C) having an average particle diameter ranging from 1.5 μm to 15 μm, wherein the polyester (A) is made of at least one polymer selected from the group consisting of polyalkylene terephthalate and copolyester, where the copolyester contains polyalkylene terephthalate as a main component, and 0.01% omf to 1% omf of a polyorganosiloxane-based fiber treating agent (E) is deposited on the flame-retardant polyester-based fiber. The artificial fiber has excellent combing smoothness, and the excellent flame retardancy.
    • 本发明的人造毛发包含由通过熔融捏合得到的组合物形成的阻燃聚酯类纤维,所述组合物包含:100重量份的聚酯(A); 5重量份至30重量份的含溴阻燃剂(B); 和0.5重量份至10重量份的平均粒径为1.5μm至15μm的锑化合物(C),其中聚酯(A)由至少一种选自聚亚烷基 对苯二甲酸酯和共聚酯,其中共聚酯包含聚对苯二甲酸亚烷基酯作为主要成分,并且在阻燃聚酯基纤维上沉积0.01%至1%omf的聚有机硅氧烷基纤维处理剂(E)。 人造纤维具有优异的梳理平滑性和优异的阻燃性。