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    • 6. 发明授权
    • Hardmask designs for dry etching FeRAM capacitor stacks
    • 硬掩模设计用于干蚀刻FeRAM电容器堆叠
    • US06534809B2
    • 2003-03-18
    • US09741479
    • 2000-12-19
    • Theodore MoiseStephen R. GilbertScott R. SummerfeltGuoqiang XingLuigi Colombo
    • Theodore MoiseStephen R. GilbertScott R. SummerfeltGuoqiang XingLuigi Colombo
    • H01L2994
    • H01L28/55H01L21/31122H01L21/31144H01L21/32136H01L21/32139
    • An embodiment of the instant invention is a ferroelectric capacitor formed over a semiconductor substrate, the ferroelectric capacitor comprising: a bottom electrode formed over the semiconductor substrate, the bottom electrode comprised of a bottom electrode material (304 of FIG. 4a); a top electrode formed over the bottom electrode and comprised of a first electrode material (306and 308 of FIG. 4a); a ferroelectric material (306 of FIG. 4a) situated between the top electrode and the bottom electrode; and a hardmask formed on the top electrode and comprising a bottom hardmask layer (402 of FIG. 4a) and a top hardmask layer (408 of FIG. 4a) formed on the bottom hardmask layer, the top hardmask layer able to with stand etchants used to etch the bottom electrode, the top electrode, and the ferroelectric material to leave the bottom hardmask layer substantially unremoved during the etch and the bottom hardmask layer being comprised of a conductive material which substantially acts as a hydrogen diffusion barrier.
    • 本发明的一个实施方案是形成在半导体衬底上的铁电电容器,所述铁电电容器包括:形成在所述半导体衬底上的底部电极,所述底部电极由底部电极材料(图4a的304)组成; 形成在底部电极上并由第一电极材料(图4a的306和308)组成的顶部电极; 位于顶部电极和底部电极之间的铁电材料(图4a的306) 以及形成在顶部电极上并包括底部硬掩模层(图4a的402)和形成在底部硬掩模层上的顶部硬掩模层(图4a的408)的硬掩模,所述顶部硬掩模层能够使用支架蚀刻剂 蚀刻底部电极,顶部电极和铁电材料以使蚀刻期间底部硬掩模层基本上不被去除,并且底部硬掩模层由基本上充当氢扩散阻挡层的导电材料构成。
    • 8. 发明申请
    • Ferroelectric capacitor stack etch cleaning methods
    • 铁电电容堆栈蚀刻清洗方法
    • US20060134808A1
    • 2006-06-22
    • US11016400
    • 2004-12-17
    • Scott SummerfeltLindsey HallK. UdayakumarTheodore Moise
    • Scott SummerfeltLindsey HallK. UdayakumarTheodore Moise
    • H01L21/00
    • H01L21/0206H01L21/02071H01L28/55H01L28/57H01L28/65H01L28/75
    • Methods (100) are provided for fabricating a ferroelectric capacitor structure including methods (128) for etching and cleaning patterned ferroelectric capacitor structures in a semiconductor device. The methods comprise etching (140, 200) portions of an upper electrode, etching (141, 201) ferroelectric material, and etching (142, 202) a lower electrode to define a patterned ferroelectric capacitor structure, and etching (143, 206) a portion of a lower electrode diffusion barrier structure. The methods further comprise ashing (144, 203) the patterned ferroelectric capacitor structure using a first ashing process, performing (145, 204) a wet clean process after the first ashing process, and ashing (146, 205) the patterned ferroelectric capacitor structure using a second ashing process directly after the wet clean process at a high temperature in an oxidizing ambient.
    • 提供了用于制造铁电电容器结构的方法(100),其包括用于在半导体器件中蚀刻和清洁图案化的铁电电容器结构的方法(128)。 所述方法包括:上电极的蚀刻(140,200)部分,蚀刻(141,201)铁电材料和蚀刻(142,202)下电极以限定图案化的铁电电容器结构,以及蚀刻(143,206)a 部分下部电极扩散阻挡结构。 所述方法还包括使用第一灰化处理灰化(144,203)所述图案化的铁电电容器结构,在第一灰化过程之后执行(145,204)湿式清洁处理,以及使用所述图案化铁电电容器结构灰化(146,205) 在氧化环境中的高温下在湿式清洁工艺之后直接进行第二次灰化处理。