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1. 发明授权

US07780939B2 Sidewall derivatized carbon nanotubes 有权
标题翻译：侧壁衍生碳纳米管
公开(公告)号：US07780939B2
公开(公告)日：2010-08-24
申请号：US11408520
申请日：2006-06-13
申请人： John L. Margrave , Edward T. Mickelson , Robert Hauge , Peter Boul , Chad Huffman , Jie Liu , Richard E. Smalley , Ken Smith , Daniel T. Colbert
发明人： John L. Margrave , Edward T. Mickelson , Robert Hauge , Peter Boul , Chad Huffman , Jie Liu , Richard E. Smalley , Ken Smith , Daniel T. Colbert
IPC分类号： B82B1/00
CPC分类号： B01J21/18 , B01J23/74 , B01J23/755 , B01J35/006 , B01J35/06 , B82Y30/00 , B82Y40/00 , C01B32/174 , C01B2202/02 , C01B2202/06 , D01F11/121 , Y10S977/74 , Y10S977/748 , Y10S977/75 , Y10S977/843 , Y10S977/848
摘要： This invention is directed to chemical derivatives of carbon nanotubes wherein the carbon nanotubes have a diameter up to 3 nm. In one embodiment, this invention also provides a method for preparing carbon nanotubes having substituents attached to the side wall of the nanotube by reacting single-wall carbon nanotubes with fluorine gas and recovering fluorine derivatized carbon nanotubes, then reacting fluorine derivatized carbon nanotubes with a nucleophile. Some of the fluorine substituents are replaced by nucleophilic substitution. If desired, the remaining fluorine can be completely or partially eliminated to produce carbon nanotubes having substituents attached to the side wall of the nanotube. The substituents are dependent on the nucleophile, and preferred nucleophiles include alkyl lithium species such as methyl lithium.
摘要翻译：本发明涉及碳纳米管的化学衍生物，其中碳纳米管具有高达3nm的直径。在一个实施方案中，本发明还提供了通过使单壁碳纳米管与氟气反应并回收氟衍生的碳纳米管制备具有连接到纳米管侧壁的取代基的碳纳米管的方法，然后使氟衍生的碳纳米管与亲核试剂。一些氟取代基被亲核取代取代。如果需要，可以完全或部分地除去剩余的氟以产生具有连接到纳米管侧壁上的取代基的碳纳米管。取代基取决于亲核试剂，优选的亲核试剂包括烷基锂物质如甲基锂。

2. 发明申请

US20090169463A1 ARRAY OF FULLERENE NANOTUBES 失效
标题翻译： FULLERENE NANOTUBES的阵列
公开(公告)号：US20090169463A1
公开(公告)日：2009-07-02
申请号：US11507964
申请日：2006-08-22
申请人： Richard E. Smalley , Daniel T. Colbert , Hongjie Dai , Jie Liu , Andrew G. Rinzler , Jason H. Hafner , Kenneth A. Smith , Ting Guo , Pavel Nikolaev , Andreas Thess
发明人： Richard E. Smalley , Daniel T. Colbert , Hongjie Dai , Jie Liu , Andrew G. Rinzler , Jason H. Hafner , Kenneth A. Smith , Ting Guo , Pavel Nikolaev , Andreas Thess
IPC分类号： C01B31/00
CPC分类号： G11C13/025 , B01J19/081 , B01J19/087 , B01J19/10 , B01J19/121 , B01J19/126 , B01J19/129 , B01J21/185 , B01J23/74 , B01J23/755 , B01J23/8913 , B01J37/0238 , B01J37/349 , B01J2219/00078 , B01J2219/0892 , B82B3/00 , C01B32/152 , C01B32/162 , C01B32/17 , C01B2202/02 , D01F9/12 , D01F9/127 , D21H27/00 , G11B9/1418 , G11B9/1445 , G11B9/1472 , G11B9/149 , G11C13/0014 , G11C13/0019 , G11C2213/16 , G11C2213/71 , G11C2213/81 , H01G9/2059 , H01L31/0352 , H01L31/06 , H01L31/18 , H01M4/133 , H01M4/525 , H01M4/583 , H01M4/587 , H01M4/625 , H01M10/0525 , Y02E10/542 , Y02E60/122 , Y02P70/521 , Y02P70/54 , Y10S977/70 , Y10S977/742 , Y10S977/745 , Y10S977/748 , Y10S977/75 , Y10S977/753 , Y10S977/789 , Y10S977/842 , Y10S977/843 , Y10S977/845 , Y10S977/847 , Y10S977/848 , Y10S977/849 , Y10S977/882 , Y10S977/948 , Y10T428/24058 , Y10T428/2918 , Y10T428/292 , Y10T428/30
摘要： This invention relates generally to forming an array of fullerene nanotubes. In one embodiment, a macroscopic molecular array is provided comprising at least about 106 fullerene nanotubes in generally parallel orientation and having substantially similar lengths in the range of from about 5 to about 500 nanometers.
摘要翻译：本发明一般涉及形成富勒烯纳米管阵列。在一个实施方案中，提供了宏观分子阵列，其包括大致平行取向的至少约106个富勒烯纳米管，并且具有在约5至约500纳米范围内的基本相似的长度。

3. 发明申请

US20080213162A1 Amplification of Carbon Nanotubes Via Seeded-Growth Methods 失效
标题翻译：通过种子生长方法扩增碳纳米管
公开(公告)号：US20080213162A1
公开(公告)日：2008-09-04
申请号：US10575352
申请日：2004-10-14
申请人： Richard E. Smalley , Irene M. Marek , Robert H. Hauge , Andrew R. Barron , James M. Tour , Howard K. Schmidt , W. Edward Billups , Christopher A. Dyke , Valerie C. Moore , Elizabeth Whitsitt , Robin E. Anderson , Ramon Colorado , Michael P. Stewart , Douglas C. Ogrin
发明人： Richard E. Smalley , Irene M. Marek , Robert H. Hauge , Andrew R. Barron , James M. Tour , Howard K. Schmidt , W. Edward Billups , Christopher A. Dyke , Valerie C. Moore , Elizabeth Whitsitt , Robin E. Anderson , Ramon Colorado , Michael P. Stewart , Douglas C. Ogrin
IPC分类号： C09C1/44
CPC分类号： B82Y40/00 , B01J23/881 , B01J27/22 , B82Y30/00 , C01B3/0021 , C01B32/162 , C01B32/172 , C01B32/176 , C01B2202/02 , C01B2202/04 , C01B2202/06 , C01B2202/36 , Y02E60/325
摘要： The present invention is directed towards methods (processes) of providing large quantities of carbon nanotubes (CNTs) of defined diameter and chirality (i.e., precise populations). In such processes, CNT seeds of a pre-selected diameter and chirality are grown to many (e.g., hundreds) times their original length. This is optionally followed by cycling some of the newly grown material back as seed material for regrowth. Thus, the present invention provides for the large-scale production of precise populations of CNTs, the precise composition of such populations capable of being optimized for a particular application (e.g., hydrogen storage). The present invention is also directed to complexes of CNTs and transition metal catalyst precurors, such complexes typically being formed en route to forming CNT seeds.
摘要翻译：本发明涉及提供大量具有规定直径和手性（即，精确群体）的大量碳纳米管（CNT）的方法（方法）。在这种方法中，预先选择的直径和手性的CNT种子生长到其原始长度的许多（例如，数百）倍。随后可以将一些新生成的材料循环回种子材料再生。因此，本发明提供了大规模生产精确的碳纳米管群体，能够针对特定应用（例如，氢存储）优化的这些群体的精确组成。本发明还涉及CNT和过渡金属催化剂前体的复合物，这些络合物通常在形成CNT晶种途中形成。

4. 发明申请

US20080210370A1 MACROSCOPIC ORDERED ASSEMBLY OF CARBON NANOTUBES 审中-公开
标题翻译：碳纳米管的大型订购总成
公开(公告)号：US20080210370A1
公开(公告)日：2008-09-04
申请号：US11840033
申请日：2007-08-16
申请人： Richard E. Smalley , Daniel T. Colbert , Ken A. Smith , Deron A. Walters , Michael J. Casavant , Chad B. Huffman , Boris I. Yakobson , Robert H. Hauge , Rajesh Kumar Saini , Wan-Ting Chiang , Xiao Chuan Qin
发明人： Richard E. Smalley , Daniel T. Colbert , Ken A. Smith , Deron A. Walters , Michael J. Casavant , Chad B. Huffman , Boris I. Yakobson , Robert H. Hauge , Rajesh Kumar Saini , Wan-Ting Chiang , Xiao Chuan Qin
IPC分类号： C01B31/02 , B32B37/00 , B05D3/00 , B01J19/00 , B03C1/32
CPC分类号： B82Y40/00 , B82Y10/00 , B82Y30/00 , C01B32/168 , C01B2202/02 , C01B2202/08 , H01J2201/30469 , Y10S977/75 , Y10S977/845 , Y10S977/847 , Y10T156/10
摘要： The present invention is directed to the creation of macroscopic materials and objects comprising aligned nanotube segments. The invention entails aligning single-wall carbon nanotube (SWNT) segments that are suspended in a fluid medium and then removing the aligned segments from suspension in a way that macroscopic, ordered assemblies of SWNT are formed. The invention is further directed to controlling the natural proclivity or nanotube segments to self assemble into or ordered structures by modifying the environment of the nanotubes and the history of that environment prior to and during the process. The materials and objects are “macroscopic” in that they are large enough to be seen without the aid of a microscope or of the dimensions of such objects. These macroscopic ordered SWNT materials and objects have the remarkable physical, electrical, and chemical properties that SWNT exhibit on the microscopic scale because they are comprised of nanotubes, each of which is aligned in the same direction and in contact with its nearest neighbors. An ordered assembly of closest SWNT also serves as a template for growth of more and larger ordered assemblies. An ordered assembly further serves as a foundation for post processing treatments that modify the assembly internally to specifically enhance selected material properties such as shear strength, tensile strength, compressive strength, toughness, electrical conductivity, and thermal conductivity.
摘要翻译：本发明涉及包括对准的纳米管段的宏观材料和物体的产生。本发明需要将悬浮在流体介质中的单壁碳纳米管（SWNT）段对准，然后以形成SWNT的宏观有序组件的方式从悬浮液中除去对准的段。本发明进一步涉及通过在工艺之前和期间修改纳米管的环境和该环境的历史来控制天然倾向或纳米管段自组装成或有序的结构。材料和物体是“宏观的”，因为它们足够大以便在没有显微镜或这些物体的尺寸的情况下被看到。这些宏观有序的SWNT材料和物体具有卓越的物理，电学和化学性质，SWNT在微观尺度上显示，因为它们由纳米管组成，其中每个纳米管沿相同方向对齐并与其最近的邻近物接触。最近的SWNT的有序组件也可以作为增加更多和更大订单组件的模板。订购的组件还用作后处理处理的基础，其在内部改变组件以特异性地增强选定的材料性能，例如剪切强度，抗拉强度，抗压强度，韧性，导电性和导热性。

5. 发明授权

US07419624B1 Methods for producing composites of fullerene nanotubes and compositions thereof 有权
标题翻译：富勒烯纳米管复合材料的制备方法及其组成
公开(公告)号：US07419624B1
公开(公告)日：2008-09-02
申请号：US11507974
申请日：2006-08-22
申请人： Richard E. Smalley , Daniel T. Colbert , Hongjie Dai , Jie Liu , Andrew G. Rinzler , Jason H. Hafner , Ken Smith , Ting Guo , Pavel Nikolaev , Andreas Thess
发明人： Richard E. Smalley , Daniel T. Colbert , Hongjie Dai , Jie Liu , Andrew G. Rinzler , Jason H. Hafner , Ken Smith , Ting Guo , Pavel Nikolaev , Andreas Thess
IPC分类号： B82B1/00
CPC分类号： G11C13/025 , B01J19/081 , B01J19/087 , B01J19/10 , B01J19/121 , B01J19/126 , B01J19/129 , B01J21/185 , B01J23/74 , B01J23/755 , B01J23/8913 , B01J37/0238 , B01J37/349 , B01J2219/00078 , B01J2219/0892 , B82B3/00 , C01B32/152 , C01B32/162 , C01B32/17 , C01B2202/02 , D01F9/12 , D01F9/127 , D21H27/00 , G11B9/1418 , G11B9/1445 , G11B9/1472 , G11B9/149 , G11C13/0014 , G11C13/0019 , G11C2213/16 , G11C2213/71 , G11C2213/81 , H01G9/2059 , H01L31/0352 , H01L31/06 , H01L31/18 , H01M4/133 , H01M4/525 , H01M4/583 , H01M4/587 , H01M4/625 , H01M10/0525 , Y02E10/542 , Y02E60/122 , Y02P70/521 , Y02P70/54 , Y10S977/70 , Y10S977/742 , Y10S977/745 , Y10S977/748 , Y10S977/75 , Y10S977/753 , Y10S977/789 , Y10S977/842 , Y10S977/843 , Y10S977/845 , Y10S977/847 , Y10S977/848 , Y10S977/849 , Y10S977/882 , Y10S977/948 , Y10T428/24058 , Y10T428/2918 , Y10T428/292 , Y10T428/30
摘要： This invention relates generally to a method for producing composites of fullerene nanotubes and compositions thereof. In one embodiment, the present invention involves a method of producing a composite material that includes a matrix and a fullerene nanotube material embedded within said matrix. In another embodiment, a method of producing a composite material containing fullerene nanotube material is disclosed. This method includes the steps of preparing an assembly of a fibrous material; adding the fullerene nanotube material to the fibrous material; and adding a matrix material precursor to the fullerene nanotube material and the fibrous material.
摘要翻译：本发明一般涉及富勒烯纳米管复合材料的制造方法及其组合物。在一个实施方案中，本发明涉及一种生产复合材料的方法，所述复合材料包括嵌入所述基质内的基质和富勒烯纳米管材料。在另一个实施方案中，公开了一种制备含有富勒烯纳米管材料的复合材料的方法。该方法包括准备纤维材料组件的步骤; 将富勒烯纳米管材料添加到纤维材料中; 并向所述富勒烯纳米管材料和所述纤维材料添加基质材料前体。

6. 发明申请

US20080063587A1 Selective Functionalization Of Carbon Nanotubes 失效
标题翻译：碳纳米管的选择性功能化
公开(公告)号：US20080063587A1
公开(公告)日：2008-03-13
申请号：US10566073
申请日：2004-07-29
申请人： Michael S. Strano , Monica Usrey , Paul Barone , Christopher A. Dyke , James M. Tour , W. Carter Kittrell , Robert H. Hauge , Richard E. Smalley
发明人： Michael S. Strano , Monica Usrey , Paul Barone , Christopher A. Dyke , James M. Tour , W. Carter Kittrell , Robert H. Hauge , Richard E. Smalley
IPC分类号： D01F9/12 , B01D57/02 , C07C245/20
CPC分类号： D01F11/14 , B82Y30/00 , B82Y40/00 , C01B32/172 , C01B32/174 , C01B2202/02 , C01B2202/22 , C01P2002/82 , C01P2002/84 , C01P2004/13 , C01P2004/133 , C01P2004/64 , C09C1/44 , C09C1/48 , C09C1/56 , Y10S977/734 , Y10S977/742 , Y10S977/745 , Y10S977/748
摘要： The present invention is directed toward methods of selectively functionalizing carbon nanotubes of a specific type or range of types, based on their electronic properties, using diazonium chemistry. The present invention is also directed toward methods of separating carbon nanotubes into populations of specific types or range(s) of types via selective functionalization and electrophoresis, and also to the novel compositions generated by such separations.
摘要翻译：本发明涉及使用重氮化学，基于其电子性质，选择性官能化特定类型或范围类型的碳纳米管的方法。本发明还涉及通过选择性官能化和电泳将碳纳米管分离成特定类型或范围的种类的方法，以及通过这种分离产生的新型组合物的方法。

7. 发明授权

US07338915B1 Ropes of single-wall carbon nanotubes and compositions thereof 失效
标题翻译：单壁碳纳米管的绳索及其组成
公开(公告)号：US07338915B1
公开(公告)日：2008-03-04
申请号：US09722950
申请日：2000-11-27
申请人： Richard E. Smalley , Daniel T. Colbert , Ting Guo , Andrew G. Rinzler , Pavel Nikolaev , Andreas Thess
发明人： Richard E. Smalley , Daniel T. Colbert , Ting Guo , Andrew G. Rinzler , Pavel Nikolaev , Andreas Thess
IPC分类号： C01B31/00
CPC分类号： B82Y30/00 , B82Y15/00 , B82Y40/00 , C01B32/162 , C01B2202/02 , C01B2202/22 , C01B2202/36 , Y02P20/134 , Y10S428/903 , Y10S977/742 , Y10S977/743 , Y10S977/75 , Y10S977/751 , Y10S977/842 , Y10S977/844 , Y10S977/938 , Y10T428/2913 , Y10T442/50 , Y10T442/624
摘要： This invention provides a method of making single-wall carbon nanotubes by laser vaporizing a mixture of carbon and one or more Group VIII transition metals. Single-wall carbon nanotubes preferentially form in the vapor and the one or more Group VIII transition metals catalyzed growth of the single-wall carbon nanotubes. In one embodiment of the invention, one or more single-wall carbon nanotubes are fixed in a high temperature zone so that the one or more Group VIII transition metals catalyze further growth of the single-wall carbon nanotube that is maintained in the high temperature zone. In another embodiment, two separate laser pulses are utilized with the second pulse timed to be absorbed by the vapor created by the first pulse.
摘要翻译：本发明提供了一种通过激发汽化碳和一种或多种第八族过渡金属的混合物来制备单壁碳纳米管的方法。单壁碳纳米管优先在蒸气中形成，并且一个或多个VIII族过渡金属催化单壁碳纳米管的生长。在本发明的一个实施方案中，一个或多个单壁碳纳米管固定在高温区域中，使得一种或多种第VIII族过渡金属催化保持在高温区域中的单壁碳纳米管的进一步生长。在另一个实施例中，利用两个单独的激光脉冲，第二脉冲定时被第一脉冲产生的蒸气吸收。

8. 发明授权

US07262266B2 Copolymerization of polybenzazoles and other aromatic polymers with carbon nanotubes 失效
标题翻译：聚苯并唑和其他芳族聚合物与碳纳米管的共聚合
公开(公告)号：US07262266B2
公开(公告)日：2007-08-28
申请号：US10972560
申请日：2004-10-25
申请人： Wen-Fang Hwang , Richard E. Smalley , Robert H. Hauge
发明人： Wen-Fang Hwang , Richard E. Smalley , Robert H. Hauge
IPC分类号： C08G81/00
CPC分类号： C08J5/18 , B82Y30/00 , C08G73/18 , C08G73/22 , C08J2379/06 , D01F6/74 , D01F6/94 , Y10S977/75 , Y10S977/753 , Y10S977/783
摘要： The present invention is generally directed to the block copolymerization of rigid rod polymers with carbon nanotubes (CNTs), the CNTs generally being shortened, to form nanotube block copolymers. The present invention is also directed to fibers and other shaped articles made from the nanotube block copolymers of the present invention.
摘要翻译：本发明一般涉及刚性棒状聚合物与碳纳米管（CNTs）的嵌段共聚合，CNT通常被缩短以形成纳米管嵌段共聚物。本发明还涉及由本发明的纳米管嵌段共聚物制成的纤维和其它成型制品。

9. 发明授权

US07204970B2 Single-wall carbon nanotubes from high pressure CO 有权
标题翻译：单壁碳纳米管由高压CO
公开(公告)号：US07204970B2
公开(公告)日：2007-04-17
申请号：US10730630
申请日：2003-12-08
申请人： Richard E. Smalley , Ken A. Smith , Daniel T. Colbert , Pavel Nikolaev , Michael J. Bronikowski , Robert K. Bradley , Frank Rohmund
发明人： Richard E. Smalley , Ken A. Smith , Daniel T. Colbert , Pavel Nikolaev , Michael J. Bronikowski , Robert K. Bradley , Frank Rohmund
IPC分类号： C01B11/02
CPC分类号： B01J4/002 , B01J3/04 , B01J3/042 , B01J19/121 , B01J19/26 , B01J2219/0875 , B82Y30/00 , B82Y40/00 , C01B32/162 , C01B2202/02 , C01B2202/36 , D01F9/1278 , Y10S977/75 , Y10S977/751 , Y10S977/843 , Y10S977/845 , Y10S977/951 , Y10T428/30
摘要： The present invention discloses the process of supplying high pressure (e.g., 30 atmospheres) CO that has been preheated (e.g., to about 1000° C.) and a catalyst precursor gas (e.g., Fe(CO)5) in CO that is kept below the catalyst precursor decomposition temperature to a mixing zone. In this mixing zone, the catalyst precursor is rapidly heated to a temperature that results in (1) precursor decomposition, (2) formation of active catalyst metal atom clusters of the appropriate size, and (3) favorable growth of SWNTs on the catalyst clusters. Preferably a catalyst cluster nucleation agency is employed to enable rapid reaction of the catalyst precursor gas to form many small, active catalyst particles instead of a few large, inactive ones. Such nucleation agencies can include auxiliary metal precursors that cluster more rapidly than the primary catalyst, or through provision of additional energy inputs (e.g., from a pulsed or CW laser) directed precisely at the region where cluster formation is desired. Under these conditions SWNTs nucleate and grow according to the Boudouard reaction. The SWNTs thus formed may be recovered directly or passed through a growth and annealing zone maintained at an elevated temperature (e.g., 1000° C.) in which tubes may continue to grow and coalesce into ropes.
摘要翻译：本发明公开了提供已被预热（例如，约1000℃）的高压（例如30个大气压）的CO和催化剂前体气体（例如Fe（CO）5） >）在CO中，其保持低于催化剂前体分解温度至混合区。在该混合区中，将催化剂前体快速加热到导致（1）前体分解的温度，（2）形成适当尺寸的活性催化剂金属原子簇，和（3）在催化剂簇上的SWNT的有利生长。优选使用催化剂簇成核剂来使催化剂前体气体快速反应以形成许多小的活性催化剂颗粒，而不是几个大的非活性催化剂颗粒。这样的成核机构可以包括比主要催化剂更快地聚集的辅助金属前体，或者通过提供精确地指向需要簇形成的区域的额外的能量输入（例如来自脉冲或CW激光）。在这些条件下，SWNT根据Boudouard反应成核并生长。如此形成的SWNT可以直接回收或通过保持在高温（例如1000℃）的生长和退火区域，其中管可以继续生长并聚结成绳索。

10. 发明授权

US07138100B2 Process for making single-wall carbon nanotubes utilizing refractory particles 有权
$Process for making single-wall carbon nanotubes utilizing refractory particles$
公开(公告)号：US07138100B2
公开(公告)日：2006-11-21
申请号：US10300135
申请日：2002-11-20
申请人： Richard E. Smalley , Robert H. Hauge
发明人： Richard E. Smalley , Robert H. Hauge
IPC分类号： D01C5/00
CPC分类号： B82Y30/00 , D01F9/1278 , Y10S977/842
摘要： A continuous gas-phase method for producing single-wall carbon nanotubes at high catalyst productivity and high yield is disclosed. The method involves the use of a novel in-situ formed catalyst to initiate and grow single-wall carbon nanotubes using a carbon-containing feedstock in a high temperature and pressure process. The catalyst comprises in-situ-generated transition metal particles in contact with in-situ-generated refractory particles. The population of nucleating sites for single-wall carbon nanotubes is enhanced due to the ease of formation of a population of refractory particles. These, in turn, improve the nucleation and stability of the transition metal particles that grow on them. The larger number of transition metal particles translate into a larger number of sites for single-wall carbon nanotube production. The higher catalyst yields provide a means for obtaining higher purity single-wall carbon nanotubes.

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