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1. 发明申请

US20070260005A1 Silica-Containing Conjugated Diene Based Rubber Composition and Molding 审中-公开
标题翻译：含二氧化硅共轭二烯基橡胶组合物和成型
公开(公告)号：US20070260005A1
公开(公告)日：2007-11-08
申请号：US10577830
申请日：2004-10-29
申请人： Takeshi Karato , Yoshihiro Chino , Kazutaka Watanabe , Osamu Yatabe
发明人： Takeshi Karato , Yoshihiro Chino , Kazutaka Watanabe , Osamu Yatabe
IPC分类号： C08L21/00 , C08K3/36
CPC分类号： C08K3/36 , C08J3/215 , C08J2321/00 , C08L9/00 , C08L9/06 , C08L21/00 , C08L2205/02 , C08L2666/08
摘要： A silica-containing conjugated diene rubber composition comprising a conjugated diene rubber-silica mixture (A) containing at least 30 wt % of toluene insoluble components obtainable by co-coagulating an aqueous dispersion or solution of conjugated diene rubber (a) having a glass transition temperature of −120 to 0° C. with an aqueous dispersion of silica, blended with a conjugated diene rubber (b) having a glass transition temperature such that the difference in absolute value between the glass transition temperature of rubber (b) and that of rubber (a) is 3 to 100° C. According to the invention, it is possible to provide a rubber composition having highly balanced fuel efficiency, wet grip performance, mechanical strength, wear resistance and low temperature brittleness resistance; and suitably used for tire treads.
摘要翻译：含有共轭二烯橡胶 - 二氧化硅混合物（A）的含二氧化硅的共轭二烯橡胶组合物，其含有至少30重量％的甲苯不溶成分，可通过将具有玻璃化转变的共轭二烯橡胶（a）的水性分散体或溶液温度为-120〜0℃，与二氧化硅水分散体共混，共轭二烯橡胶（b）的玻璃化转变温度使得橡胶（b）的玻璃化转变温度与玻璃化转变温度之间的绝对值之差橡胶（a）为3〜100℃。根据本发明，可以提供具有高均衡燃料效率，湿抓地性能，机械强度，耐磨性和低温脆性的橡胶组合物。适用于轮胎胎面。

2. 发明申请

US20070037916A1 Diene rubber composition and process for producing the same 有权
标题翻译：二烯橡胶组合物及其制备方法
公开(公告)号：US20070037916A1
公开(公告)日：2007-02-15
申请号：US10543541
申请日：2004-01-30
申请人： Kazutaka Watanabe , Osamu Yatabe , Takeshi Karato , Yoshihiro Chino , Takahiko Fukahori
发明人： Kazutaka Watanabe , Osamu Yatabe , Takeshi Karato , Yoshihiro Chino , Takahiko Fukahori
IPC分类号： C08K3/34
CPC分类号： C08K3/36 , B60C1/00 , B60C1/0016 , B60C1/0025 , B60C15/06 , B60C2009/0021 , C08J3/215 , C08J2321/00 , C08L21/00 , C08L101/02 , C08L2666/02
摘要： The present invention is to provide a diene rubber composition and a cross-linked diene rubber thereof excellent in tensile strength, wear resistance and processability, keeping compatibility of both good fuel efficiency and high gripping property, and a production method thereof. What is characterized in the composition is that the composition is comprised of 100 parts by weight of a diene rubber having a molecular weight distribution expressed in terms of the ratio of the weight-average molecular weight to the number-average molecular weight of 1.1 to 30, 20 to 200 parts by weight of silica and a cationic polymer, and that a toluene-insoluble rubber content per gram of the silica within the range from 0.2 to 1 g, and diene cross-linked rubber thereof. What is characterized in the production method is that the method comprises steps of allowing rubber latex stabilized by an anionic emulsifying agent to react with an aqueous suspension of silica containing a cationic polymer and effecting co-coagulation of rubber in the rubber latex with the silica in the aqueous suspension within a specific pH range.
摘要翻译：本发明提供一种二烯橡胶组合物及其抗拉强度，耐磨性和加工性优异的交联二烯橡胶，兼具良好的燃料效率和高夹持性的兼容性及其制造方法。组合物的特征在于该组合物由100重量份的二烯橡胶组成，二烯橡胶的分子量分布以重均分子量与数均分子量的比率表示为1.1至30 ，20〜200重量份的二氧化硅和阳离子性聚合物，每克二氧化硅的甲苯不溶性橡胶含量在0.2〜1g的范围内，和二烯交联橡胶。制造方法的特征在于，该方法包括以下步骤：使由阴离子乳化剂稳定的橡胶胶乳与含有阳离子聚合物的二氧化硅水溶液悬浮液反应，并使橡胶胶乳中的橡胶与二氧化硅共混水性悬浮液在特定pH范围内。

3. 发明授权

US08071187B2 Method for fabricating metallized ceramics substrate, metallized ceramics substrate fabricated by the method, and package 有权
标题翻译：用于制造金属化陶瓷衬底的方法，通过该方法制造的金属化陶瓷衬底和封装
公开(公告)号：US08071187B2
公开(公告)日：2011-12-06
申请号：US12161193
申请日：2007-01-23
申请人： Yasuyuki Yamamoto , Osamu Yatabe , Masakatsu Maeda
发明人： Yasuyuki Yamamoto , Osamu Yatabe , Masakatsu Maeda
IPC分类号： B29D22/00 , B32B7/02 , H01L23/15 , H05K5/06 , H05K7/02
CPC分类号： H01L23/15 , H01L23/10 , H01L2924/0002 , H01L2924/01079 , H05K1/092 , H05K3/4667 , H05K2201/0266 , H05K2201/0352 , Y10T428/131 , Y10T428/24355 , Y10T428/24917 , Y10T428/24926 , Y10T428/24942 , Y10T428/31 , H01L2924/00
摘要： A fabrication method for metallized a ceramics substrate including the steps of: forming a first conductive paste layer containing metallic powder on a sintered ceramics substrate; forming a second conductive paste layer containing metallic powder of which average particle diameter is different from that of metallic powder constituting the first conductive paste layer; and forming a first conductive layer and a second conductive paste layer. The surface roughness of the first conductive layer and the second conductive layer is different. By this method, it is possible to secure airtightness of the metallized ceramics substrate even if it is a multilayered substrate having a plurality of metallized layers.
摘要翻译：一种金属化陶瓷基板的制造方法，包括以下步骤：在烧结陶瓷基板上形成含有金属粉末的第一导电浆料层; 形成含有与构成第一导电糊层的金属粉末的平均粒径不同的金属粉末的第二导电膏层; 以及形成第一导电层和第二导电糊层。第一导电层和第二导电层的表面粗糙度不同。通过这种方法，即使是具有多个金属化层的多层基板，也可以确保金属化陶瓷基板的气密性。

4. 发明申请

US20100178461A1 METHOD FOR FABRICATING METALLIZED CERAMICS SUBSTRATE, METALLIZED CERAMICS SUBSTRATE FABRICATED BY THE METHOD, AND PACKAGE 有权
标题翻译：金属化陶瓷基板的制造方法，由该方法制成的金属化陶瓷基板和封装
公开(公告)号：US20100178461A1
公开(公告)日：2010-07-15
申请号：US12161193
申请日：2007-01-23
申请人： Yasuyuki Yamamoto , Osamu Yatabe , Masakatsu Maeda
发明人： Yasuyuki Yamamoto , Osamu Yatabe , Masakatsu Maeda
IPC分类号： B32B3/02 , B05D3/02
CPC分类号： H01L23/15 , H01L23/10 , H01L2924/0002 , H01L2924/01079 , H05K1/092 , H05K3/4667 , H05K2201/0266 , H05K2201/0352 , Y10T428/131 , Y10T428/24355 , Y10T428/24917 , Y10T428/24926 , Y10T428/24942 , Y10T428/31 , H01L2924/00
摘要： A fabrication method for metallized a ceramics substrate including the steps of: forming a first conductive paste layer containing metallic powder on a sintered ceramics substrate; forming a second conductive paste layer containing metallic powder of which average particle diameter is different from that of metallic powder constituting the first conductive paste layer; and forming a first conductive layer and a second conductive paste layer. The surface roughness of the first conductive layer and the second conductive layer is different. By this method, it is possible to secure airtightness of the metallized ceramics substrate even if it is a multilayered substrate having a plurality of metallized layers.
摘要翻译：一种金属化陶瓷基板的制造方法，包括以下步骤：在烧结陶瓷基板上形成含有金属粉末的第一导电浆料层; 形成含有与构成第一导电糊层的金属粉末的平均粒径不同的金属粉末的第二导电膏层; 以及形成第一导电层和第二导电糊层。第一导电层和第二导电层的表面粗糙度不同。通过这种方法，即使是具有多个金属化层的多层基板，也可以确保金属化陶瓷基板的气密性。

5. 发明授权

US07619028B2 Diene rubber composition and process for producing the same 有权
标题翻译：二烯橡胶组合物及其制备方法
公开(公告)号：US07619028B2
公开(公告)日：2009-11-17
申请号：US10543541
申请日：2004-01-30
申请人： Kazutake Watanabe , Osamu Yatabe , Takeshi Karato , Yoshihiro Chino , Takahiko Fukahori
发明人： Kazutake Watanabe , Osamu Yatabe , Takeshi Karato , Yoshihiro Chino , Takahiko Fukahori
IPC分类号： C08K3/36 , C08J3/16
CPC分类号： C08K3/36 , B60C1/00 , B60C1/0016 , B60C1/0025 , B60C15/06 , B60C2009/0021 , C08J3/215 , C08J2321/00 , C08L21/00 , C08L101/02 , C08L2666/02
摘要： The present invention is to provide a diene rubber composition and a cross-linked diene rubber thereof excellent in tensile strength, wear resistance and processability, keeping compatibility of both good fuel efficiency and high gripping property, and a production method thereof. What is characterized in the composition is that the composition is comprised of 100 parts by weight of a diene rubber having a molecular weight distribution expressed in terms of the ratio of the weight-average molecular weight to the number-average molecular weight of 1.1 to 30, 20 to 200 parts by weight of silica and a cationic polymer, and that a toluene-insoluble rubber content per gram of the silica within the range from 0.2 to 1 g, and diene cross-linked rubber thereof. What is characterized in the production method is that the method comprises steps of allowing rubber latex stabilized by an anionic emulsifying agent to react with an aqueous suspension of silica containing a cationic polymer and effecting co-coagulation of rubber in the rubber latex with the silica in the aqueous suspension within a specific pH range.
摘要翻译：本发明提供一种二烯橡胶组合物及其抗拉强度，耐磨性和加工性优异的交联二烯橡胶，兼具良好的燃料效率和高夹持性的兼容性及其制造方法。组合物的特征在于该组合物由100重量份的二烯橡胶组成，二烯橡胶的分子量分布以重均分子量与数均分子量的比率表示为1.1至30 ，20〜200重量份的二氧化硅和阳离子性聚合物，每克二氧化硅的甲苯不溶性橡胶含量在0.2〜1g的范围内，和二烯交联橡胶。制造方法的特征在于，该方法包括以下步骤：使由阴离子乳化剂稳定的橡胶胶乳与含有阳离子聚合物的二氧化硅水溶液悬浮液反应，并使橡胶胶乳中的橡胶与二氧化硅共混水性悬浮液在特定pH范围内。

6. 发明申请

US20100183898A1 METALLIZED SUBSTRATE AND METHOD FOR PRODUCING THE SAME 有权
标题翻译：金属化基板及其制造方法
公开(公告)号：US20100183898A1
公开(公告)日：2010-07-22
申请号：US12602828
申请日：2008-06-10
申请人： Tetsuo Imai , Osamu Yatabe , Masakatsu Maeda
发明人： Tetsuo Imai , Osamu Yatabe , Masakatsu Maeda
IPC分类号： B32B15/01 , B05D3/02 , C25D5/50 , C25D5/54
CPC分类号： H01L23/498 , B22F7/04 , B22F2998/00 , C22C5/02 , C22C5/04 , C22C19/03 , C22C27/04 , C22C32/0047 , C23C18/32 , C23C18/54 , C25D5/48 , C25D5/50 , H01L21/4853 , H01L23/15 , H01L23/49811 , H01L24/45 , H01L24/48 , H01L24/85 , H01L2224/45015 , H01L2224/45124 , H01L2224/45144 , H01L2224/48227 , H01L2224/48599 , H01L2224/48644 , H01L2224/48699 , H01L2224/48744 , H01L2224/85444 , H01L2924/01005 , H01L2924/01006 , H01L2924/01007 , H01L2924/01011 , H01L2924/01013 , H01L2924/01014 , H01L2924/01015 , H01L2924/01027 , H01L2924/01028 , H01L2924/01033 , H01L2924/01042 , H01L2924/01046 , H01L2924/01074 , H01L2924/01078 , H01L2924/01079 , H01L2924/09701 , H01L2924/15787 , H01L2924/20752 , Y10T428/12889 , H01L2924/00014 , B22F9/04 , H01L2924/00
摘要： A metallized substrate having, disposed in the order mentioned: a ceramics substrate; a high-melting point metal layer; a base nickel plating layer; a layered nickel-phosphorous plating layer; a diffusion-inhibiting plating layer; and a gold plating layer. The base nickel plating layer being any one of a nickel plating layer, a nickel-boron plating layer, or a nickel-cobalt plating layer. The diffusion-inhibiting plating layer being any one of a columnar nickel-phosphorous plating layer, a palladium-phosphorous plating layer, or a palladium plating layer. According to the above composition, even after heating the semiconductor chips in a mounted state, the metallized substrate can make the connection strength of wire bonding favorable.
摘要翻译：金属化基板，具有按照以下顺序设置的陶瓷基板; 高熔点金属层; 基底镍镀层; 层状镍 - 磷电镀层; 扩散抑制镀层; 和镀金层。基底镀镍层是镀镍层，镍 - 硼镀层或镍钴镀层中的任意一种。扩散抑制镀层是柱状镍 - 磷镀层，钯 - 磷镀层或钯镀层中的任一种。根据上述组成，即使在安装状态下加热半导体芯片之后，金属化基板也可以使引线接合的连接强度有利。

7. 发明申请

US20060143938A1 Rubber composition containing silica and method for production therof 审中-公开
标题翻译：含二氧化硅的橡胶组合物及其制备方法
公开(公告)号：US20060143938A1
公开(公告)日：2006-07-06
申请号：US10562975
申请日：2004-06-29
申请人： Takeshi Karato , Kazuhiro Hikida , Takahiko Fukahori , Yoshihiro Chino , Kazutaka Watanabe , Osamu Yatabe , Tsunetoshi Sugimura , Shinji Tokunaga
发明人： Takeshi Karato , Kazuhiro Hikida , Takahiko Fukahori , Yoshihiro Chino , Kazutaka Watanabe , Osamu Yatabe , Tsunetoshi Sugimura , Shinji Tokunaga
IPC分类号： F26B5/14
CPC分类号： C08J3/215 , B60C1/0016 , C08J2321/00 , C08K3/36 , C08L21/00
摘要： A silica-containing rubber composition produced by filtering slurry of silica-containing rubber crumbs obtained by co-coagulating a mixture of rubber latex and silica to give a moisture content of 80 wt % or less, dehydrating by a dehydrator having a compression function, then, drying. According to the present invention, a silica-containing rubber composition with improved silica dispersibility can be provided.
摘要翻译：通过将橡胶胶乳和二氧化硅的混合物共混而得到的含二氧化硅的橡胶屑的浆料过滤，得到含水率为80重量％以下的二氧化硅橡胶组合物，通过具有压缩功能的脱水机脱水，，干燥。根据本发明，可以提供具有改善的二氧化硅分散性的含二氧化硅的橡胶组合物。

8. 发明授权

US08309164B2 Metallized substrate and method for producing the same 有权
标题翻译：金属化基板及其制造方法
公开(公告)号：US08309164B2
公开(公告)日：2012-11-13
申请号：US12602828
申请日：2008-06-10
申请人： Tetsuo Imai , Osamu Yatabe , Masakatsu Maeda
发明人： Tetsuo Imai , Osamu Yatabe , Masakatsu Maeda
IPC分类号： B05D3/10 , B05D5/12 , B05D5/00
CPC分类号： H01L23/498 , B22F7/04 , B22F2998/00 , C22C5/02 , C22C5/04 , C22C19/03 , C22C27/04 , C22C32/0047 , C23C18/32 , C23C18/54 , C25D5/48 , C25D5/50 , H01L21/4853 , H01L23/15 , H01L23/49811 , H01L24/45 , H01L24/48 , H01L24/85 , H01L2224/45015 , H01L2224/45124 , H01L2224/45144 , H01L2224/48227 , H01L2224/48599 , H01L2224/48644 , H01L2224/48699 , H01L2224/48744 , H01L2224/85444 , H01L2924/01005 , H01L2924/01006 , H01L2924/01007 , H01L2924/01011 , H01L2924/01013 , H01L2924/01014 , H01L2924/01015 , H01L2924/01027 , H01L2924/01028 , H01L2924/01033 , H01L2924/01042 , H01L2924/01046 , H01L2924/01074 , H01L2924/01078 , H01L2924/01079 , H01L2924/09701 , H01L2924/15787 , H01L2924/20752 , Y10T428/12889 , H01L2924/00014 , B22F9/04 , H01L2924/00
摘要： A metallized substrate having, disposed in the order mentioned: a ceramics substrate; a high-melting point metal layer; a base nickel plating layer; a layered nickel-phosphorous plating layer; a diffusion-inhibiting plating layer; and a gold plating layer. The base nickel plating layer being any one of a nickel plating layer, a nickel-boron plating layer, or a nickel-cobalt plating layer. The diffusion-inhibiting plating layer being any one of a columnar nickel-phosphorous plating layer, a palladium-phosphorous plating layer, or a palladium plating layer. According to the above composition, even after heating the semiconductor chips in a mounted state, the metallized substrate can make the connection strength of wire bonding favorable.
摘要翻译：金属化基板，具有按照以下顺序设置的陶瓷基板; 高熔点金属层; 基底镍镀层; 层状镍 - 磷电镀层; 扩散抑制镀层; 和镀金层。基底镀镍层是镀镍层，镍 - 硼镀层或镍钴镀层中的任意一种。扩散抑制镀层是柱状镍 - 磷镀层，钯 - 磷镀层或钯镀层中的任一种。根据上述组成，即使在安装状态下加热半导体芯片之后，金属化基板也可以使引线接合的连接强度有利。

9. 发明申请

US20100015468A1 METHOD FOR MANUFACTURING METALLIZED ALUMINUM NITRIDE SUBSTRATE 审中-公开
标题翻译：制造金属化氮化铝衬底的方法
公开(公告)号：US20100015468A1
公开(公告)日：2010-01-21
申请号：US12519571
申请日：2007-12-21
申请人： Yasuyuki Yamamoto , Masakatsu Maeda , Osamu Yatabe
发明人： Yasuyuki Yamamoto , Masakatsu Maeda , Osamu Yatabe
IPC分类号： B32B15/04 , B05D3/02
CPC分类号： H05K3/38 , C04B41/009 , C04B41/52 , C04B41/90 , C04B2111/00844 , H01L21/4867 , H01L23/3735 , H01L2924/0002 , H01L2924/09701 , H05K1/0306 , H05K1/092 , H05K3/248 , H05K2201/0347 , H05K2201/035 , Y10T428/12576 , C04B35/581 , C04B41/4517 , C04B41/4539 , C04B41/5133 , C04B41/4541 , C04B41/5144 , C04B41/5127 , C04B41/522 , C04B41/5116 , H01L2924/00
摘要： A method for manufacturing metallized aluminum nitride substrate. The method includes: Step A for forming a high-melting point metal layer over a sintered aluminum nitride substrate; Step B for forming over the high-melting point metal layer an intermediate metal layer of at least one selected from the group of: nickel, copper, copper-silver, copper-tin, and gold by plate processing; and Step C for forming a surface metal layer containing silver as a main component over the intermediate metal layer by coating a silver paste whose glass component content is 1 mass % or less and firing under nonoxidizing atmosphere. By this method, it is capable of forming a glass component-free silver layer which is adhered at a high degree of adhesion strength onto the high-melting point metal layer formed over the aluminum nitride substrate as a top face by thick-film method using a silver paste which makes thick-membrane forming easier.
摘要翻译：金属化氮化铝基板的制造方法。该方法包括：步骤A，用于在烧结的氮化铝衬底上形成高熔点金属层; 步骤B，通过板加工在高熔点金属层上形成选自镍，铜，铜 - 银，铜 - 锡和金中的至少一种的中间金属层; 以及步骤C，通过涂覆玻璃成分含量为1质量％以下的银膏，在非氧化性气氛下进行烧成，在中间金属层上形成含有银为主要成分的表面金属层。通过该方法，能够通过厚膜法以高膜法形成以高粘合强度粘附在形成在氮化铝基板上的高熔点金属层上的无玻璃成分的银层，使得较厚膜形成更容易的银糊。

10. 发明授权

US07625971B2 Silica-loaded granular rubber and process for producing the same 失效
标题翻译：二氧化硅颗粒状橡胶及其制造方法
公开(公告)号：US07625971B2
公开(公告)日：2009-12-01
申请号：US10568393
申请日：2004-08-19
申请人： Shinji Tokunaga , Tsunetoshi Sugimura , Kazutaka Watanabe , Osamu Yatabe , Takeshi Karato , Takahiko Fukahori , Yoshihiro Chino
发明人： Shinji Tokunaga , Tsunetoshi Sugimura , Kazutaka Watanabe , Osamu Yatabe , Takeshi Karato , Takahiko Fukahori , Yoshihiro Chino
IPC分类号： C08K3/36 , C08J3/16 , C08C1/14
CPC分类号： C08J3/12 , B01J2/10 , C08J3/128 , C08J2321/00 , C08J2383/04 , C08K3/36 , Y10T428/2982 , C08L21/00
摘要： Disclosed are silica-filled rubber granules comprised of a cocoagulation product of rubber and silica, which are extremely less powdery and excellent in handling and kneading, as well as an industrially advantageous process for producing same. The silica-filled rubber granules of the present invention are dried granules of a cocoagulation product of rubber and silica particles, which are characterized in that an average particle diameter (D50) in terms of the sieve analysis is 300˜3000 μm and the weight ratio of the granules within the range of D50±(D50×0.5) is at least 50% by weight. The silica-filled rubber granules are produced by supplying a cake of a cocoagulation product of silica and rubber having a water content of 40˜80% by weight to a drier provided with an indirect-heating type container having stirring wing blades, and then drying the cake while stirring it with the stirring wing blade.
摘要翻译：公开了由橡胶和二氧化硅的可凝固产物组成的二氧化硅填充的橡胶颗粒，其粉末非常少，处理和捏合性优异，以及其工业上有利的制备方法。本发明的二氧化硅填充橡胶颗粒是橡胶和二氧化硅颗粒的可凝固产物的干燥颗粒，其特征在于，筛分分析中的平均粒径（D50）为300〜3000μm，重量比的颗粒在D50±（D50x0.5）的范围内至少为50重量％。二氧化硅填充的橡胶颗粒通过将具有40-80重量％水含量的二氧化硅和橡胶的可凝固产物的饼块供给到具有搅拌翼片的间接加热型容器的干燥器中，然后干燥在搅拌翼片的同时搅拌它。

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