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    • 4. 发明授权
    • Process for producing dendrimer, building block compound, and process for producing thiophene compound
    • 树枝状大分子,结构单元化合物的制造方法,以及噻吩化合物的制造方法
    • US07531619B2
    • 2009-05-12
    • US10521689
    • 2003-07-14
    • Satoru ObaraKentaro Tada
    • Satoru ObaraKentaro Tada
    • C08G75/06C08G75/00C08G61/00C08G61/12
    • C08G83/003C07D333/18C08G61/126
    • A method for producing a dendrimer having a structural repeating unit which is represented by formula (1) and which contains a linear portion including a thienylene moiety and a branch portion Y formed of an optionally substituted trivalent organic group. The method is based on the convergent method and includes reaction step 1 of converting α-position hydrogen of the thiophene ring of a thienylene-moiety-containing compound (a) for forming end moieties to an active group V1 which undergoes Suzuki cross-coupling reaction, to thereby form compound (b); reaction step 2 of subjecting a compound (c) to Suzuki cross-coupling reaction with the compound (b), to thereby yield compound (d), the compound (c) having a linear portion and a branch portion Y and having, at the branch portion Y, two active groups V2 which undergo Suzuki cross-coupling reaction with the active group V1; reaction step 3 of converting α-position hydrogen of the thiophene ring of the thus-formed compound to an active group V1 which undergoes Suzuki cross-coupling reaction, and reacting the compound (c) with the active group V1, to thereby form a dendron of a subsequent generation; and a step of repeating the reaction step 3 in accordance with needs, to thereby form a dendrimer.
    • 一种制备具有由式(1)表示的结构重复单元并含有包含由任意取代的三价有机基团形成的亚噻吩基部分和分支部分Y的直链部分的树枝状聚合物的方法。 该方法基于收敛方法,包括将形成末端部分的含噻吩烯部分的化合物(a)的噻吩环的α-位氢转化为进行Suzuki交叉偶联反应的活性基团V1的反应步骤1 ,从而形成化合物(b); 使化合物(c)与化合物(b)进行Suzuki交叉偶联反应的反应步骤2,得到化合物(d),具有直链状部分和分支部分Y的化合物(c) 分支部分Y,与活性基团V1进行Suzuki交叉偶联反应的两个活性基团V2; 将由此形成的化合物的噻吩环的α-位氢转化为进行Suzuki交叉偶联反应的活性基团V1,并使化合物(c)与活性基团V1反应从而形成树突状物的反应步骤3 的后代 以及根据需要重复反应步骤3的步骤,从而形成树枝状聚合物。
    • 5. 发明申请
    • Process for producing dendrimer, building block compound, and process for producing thiophene compound
    • 树枝状大分子,结构单元化合物的制造方法,以及噻吩化合物的制造方法
    • US20060122364A1
    • 2006-06-08
    • US10521689
    • 2003-07-14
    • Satoru ObaraKentaro Tada
    • Satoru ObaraKentaro Tada
    • C08G75/32C07D409/14
    • C08G83/003C07D333/18C08G61/126
    • A method for producing a dendrimer having a structural repeating unit which is represented by formula (1) and which contains a linear portion including a thienylene moiety and a branch portion Y formed of an optionally substituted trivalent organic group. The method is based on the convergent method and includes reaction step 1 of converting α-position hydrogen of the thiophene ring of a thienylene-moiety-containing compound (a) for forming end moieties to an active group V1 which undergoes Suzuki cross-coupling reaction, to thereby form compound (b); reaction step 2 of subjecting a compound (c) to Suzuki cross-coupling reaction with the compound (b), to thereby yield compound (d), the compound (c) having a linear portion and a branch portion Y and having, at the branch portion Y, two active groups V2 which undergo Suzuki cross-coupling reaction with the active group V1; reaction step 3 of converting α-position hydrogen of the thiophene ring of the thus-formed compound to an active group V1 which undergoes Suzuki cross-coupling reaction, and reacting the compound (c) with the active group V1, to thereby form a dendron of a subsequent generation; and a step of repeating the reaction step 3 in accordance with needs, to thereby form a dendrimer.
    • 一种制备具有由式(1)表示的结构重复单元并含有包含由任意取代的三价有机基团形成的亚噻吩基部分和分支部分Y的直链部分的树枝状聚合物的方法。 该方法基于收敛方法,包括将形成末端部分的含噻吩烯部分的化合物(a)的噻吩环的α-位氢转化成活性基团V 1的反应步骤1 进行Suzuki交叉偶联反应,从而形成化合物(b); 使化合物(c)与化合物(b)进行Suzuki交叉偶联反应的反应步骤2,得到化合物(d),具有直链状部分和分支部分Y的化合物(c) 分支部分Y,与活性基团V 1进行Suzuki交叉偶联反应的两个活性基团V 2 2; 将由此形成的化合物的噻吩环的α-位氢转化成活性基团V 1的反应步骤3进行Suzuki交叉偶联反应,并使化合物(c)与活性 组V 1,从而形成下一代的树突; 以及根据需要重复反应步骤3的步骤,从而形成树枝状聚合物。
    • 7. 发明授权
    • IP telephone system, IP telephone apparatus and communications method
    • IP电话系统,IP电话机和通信方式
    • US07715367B2
    • 2010-05-11
    • US11183966
    • 2005-07-19
    • Toshiko NishidaKazuto KobayashiAkira MiyajimaKentaro TadaKiyoshi Toyoda
    • Toshiko NishidaKazuto KobayashiAkira MiyajimaKentaro TadaKiyoshi Toyoda
    • H04L12/66
    • H04M1/6016H04M1/2535H04M3/40H04M3/4211H04M7/006
    • An IP telephone system includes an IP telephone apparatus, a Web server and an ENUM server. The IP telephone apparatus is connected to an IP network. The Web server registers talk volume information corresponding to a telephone number assigned to the IP telephone apparatus. The ENUM server registers a NAPTR resource record in which a URI specifies link data related to the talk volume information registered in the Web server. In the IP telephone system, the IP telephone apparatus that has received a call transmits, to the ENUM server, a query for a NAPTR record corresponding to a targeted recipient phone number. The IP telephone apparatus then transmits, to the Web server, a request for the talk volume information corresponding to the targeted recipient phone number according to the returned NAPTR resource record, and adjusts the talk volume according to the returned talk volume information.
    • IP电话系统包括IP电话设备,Web服务器和ENUM服务器。 IP电话设备连接到IP网络。 Web服务器登记与分配给IP电话设备的电话号码对应的通话音量信息。 ENUM服务器注册NAPTR资源记录,其中URI指定与在Web服务器中注册的通话量信息相关的链接数据。 在IP电话系统中,已经接收到呼叫的IP电话设备向ENUM服务器发送对应于目标接收方电话号码的NAPTR记录的查询。 然后,IP电话设备根据返回的NAPTR资源记录向Web服务器发送对应于目标接收方电话号码的通话量信息的请求,并根据返回的通话音量信息调整通话音量。
    • 9. 发明授权
    • Radiation-sensitive negative-type resist composition for pattern formation method
    • 用于图案形成方法的辐射敏感负型抗蚀剂组合物
    • US07329480B2
    • 2008-02-12
    • US10526383
    • 2003-08-29
    • Nobuji SakaiKentaro Tada
    • Nobuji SakaiKentaro Tada
    • G03F7/038G03F7/004
    • G03F7/038G03F7/0045
    • The radiation-sensitive negative-type resist composition for pattern formation containing an epoxy resin, a radiation-sensitive cationic polymerization initiator, and a solvent for dissolving the epoxy resin therein, characterized in that the resist composition, through drying, forms a resist film having a softening point falling within range of 30 to 120 C and that the epoxy resin is represented by formula (1): (wherein R1 represents a moiety derived from an organic compound having k active hydrogen atoms (k represents an integer of 1 to 100); each of n1, n2, through nk represents 0 or an integer of 1 to 100; the sum of n1, n2, through nK falls within a range of 1 to 100; and each of “A”s, which may be identical to or different from each other, represents an oxycyclohexane skeleton represented by formula (2): (wherein X represents any of groups represented by formulas (3) to (5): and at least two groups represented by formula (3) are contained in one molecule of the epoxy resin))
    • 包含环氧树脂,辐射敏感性阳离子聚合引发剂和用于溶解环氧树脂的溶剂的用于图案形成的辐射敏感性负型抗蚀剂组合物,其特征在于,所述抗蚀剂组合物通过干燥形成抗蚀剂膜, 软化点在30〜120℃的范围内,环氧树脂由式(1)表示:(其中R1表示衍生自具有k个活性氢原子的有机化合物的部分(k表示1〜100的整数) n 1,n 2,n 2,n 2,n 2各自表示0或1〜100的整数,n< 1 2,N 2,N 2,N 2,N 2,N 2,N 2,N 2, 彼此表示由式(2)表示的氧环己烷骨架:(其中X表示由式(3)至(5)表示的基团中的任一个:和由f (3)包含在环氧树脂的一分子中))
    • 10. 发明申请
    • Radiation-sensitive negative-type resist composition for pattern formation method
    • 用于图案形成方法的辐射敏感负型抗蚀剂组合物
    • US20060172222A1
    • 2006-08-03
    • US10526383
    • 2003-08-29
    • Nobuji SakaiKentaro Tada
    • Nobuji SakaiKentaro Tada
    • G03C1/76
    • G03F7/038G03F7/0045
    • The radiation-sensitive negative-type resist composition for pattern formation containing an epoxy resin, a radiation-sensitive cationic polymerization initiator, and a solvent for dissolving the epoxy resin therein, characterized in that the resist composition, through drying, forms a resist film having a softening point falling within range of 30 to 120 C. and that the epoxy resin is represented by formula (1): (wherein R1 represents a moiety derived from an organic compound having k active hydrogen atoms (k represents an integer of 1 to 100); each of n1, n2, through nk represents 0 or an integer of 1 to 100; the sum of n1, n2, through nK falls within a range of 1 to 100; and each of “A”s, which may be identical to or different from each other, represents an oxycyclohexane skeleton represented by formula (2): (wherein X represents any of groups represented by formulas (3) to (5): and at least two groups represented by formula (3) are contained in one molecule of the epoxy resin)).
    • 包含环氧树脂,辐射敏感性阳离子聚合引发剂和用于溶解环氧树脂的溶剂的用于图案形成的辐射敏感性负型抗蚀剂组合物,其特征在于,所述抗蚀剂组合物通过干燥形成抗蚀剂膜, 软化点在30〜120℃的范围内,环氧树脂由式(1)表示:(其中R1表示衍生自具有k个活性氢原子的有机化合物的部分(k表示1〜100的整数) ); n 1,n 2,...,n 2中的每一个表示0或1至100的整数; n 1 ,N 2,N 2,N 2,N 2,N 2,N 2, 表示由式(2)表示的氧环己烷骨架:(式中,X表示由式(3)〜(5)表示的基团中的任一种, 式(3)包含在环氧树脂的一个分子中))。