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    • 2. 发明申请
    • POLYARYLENE BLOCK COPOLYMER AND USE THEREOF
    • 聚烯烃嵌段共聚物及其用途
    • US20090253015A1
    • 2009-10-08
    • US11817835
    • 2006-03-09
    • Toru OnoderaTakashi YamadaShigeru SasakiKatsuhiro SuenobuTakashi KamikawaNoriyuki Hida
    • Toru OnoderaTakashi YamadaShigeru SasakiKatsuhiro SuenobuTakashi KamikawaNoriyuki Hida
    • H01M8/10B01J41/12C08J5/22
    • H01M8/1058C08G61/12H01B1/122H01M8/1004H01M8/1023H01M8/1039H01M2300/0082Y02P70/56
    • Provided is a block copolymer comprising one or more segments having an acid group and one or more segments having substantially no acid group, wherein the segment having an acid group is represented by the following formula (1): wherein m represents an integer of 10 or more, Ar1, Ar2 and Ar3 each independently represent a divalent aromatic group, these divalent aromatic groups may be substituted by an alkyl group having 1-10 carbon atoms, an alkoxy group having 1-10 carbon atoms, an aryl group having 6-10 carbon atoms or an aryloxy group having 6-10 carbon atoms; at least one of Ar1 and Ar2 has an acid group, Ar3 may or may not have an acid group; Y represents —CO— or —SO2—, a plurality of Ys may be different from each other, and the segment having substantially no acid group has a repeating unit represented by the following formula (2): wherein n represents an integer of 10 or more, Ar4 and Ar5 each independently represent a divalent aromatic group, these divalent aromatic groups may be substituted by an alkyl group having 1-10 carbon atoms, an alkoxy group having 1-10 carbon atoms, an aryl group having 6-10 carbon atoms, an aryloxy group having 6-10 carbon atoms or a fluoro group; Z represents —CO—, or —SO2—, a plurality of Zs may be different from each other. It shows more excellent performance as a polymer electrolyte in fuel cells and the like.
    • 本发明提供含有一个或多个具有酸基和一个或多个基本上不含酸基的链段的嵌段共聚物,其中具有酸基的链段由下式(1)表示:其中m表示整数10或 更优选Ar 1,Ar 2和Ar 3各自独立地表示二价芳族基团,这些二价芳族基团可以被具有1-10个碳原子的烷基,具有1-10个碳原子的烷氧基,6-10 碳原子或具有6-10个碳原子的芳氧基; Ar 1和Ar 2中的至少一个具有酸基,Ar 3可以具有或不具有酸基; Y表示-CO-或-SO2-,多个Y可以彼此不同,并且基本上没有酸基的链段具有由下式(2)表示的重复单元:其中n表示整数10或 此外,Ar 4和Ar 5各自独立地表示二价芳族基团,这些二价芳基可以被具有1-10个碳原子的烷基,具有1-10个碳原子的烷氧基,具有6-10个碳原子的芳基取代 ,具有6-10个碳原子的芳氧基或氟基; Z表示-CO-或-SO 2 - ,多个Z可以彼此不同。 作为燃料电池等中的高分子电解质,表现出更优异的性能。
    • 6. 发明授权
    • Photovoltaic cell
    • 光伏电池
    • US08772763B2
    • 2014-07-08
    • US13502639
    • 2010-10-29
    • Ken YoshimuraKatsuhiro Suenobu
    • Ken YoshimuraKatsuhiro Suenobu
    • H01L21/48B82Y10/00H01L51/00C08G61/12H01L51/05H01L51/42
    • H01L51/0036B82Y10/00C08G61/122C08G61/123C08G61/126C08G2261/3223C08G2261/3246C08G2261/344C08G2261/364C08G2261/411C08G2261/91G06F19/00H01L51/0043H01L51/0046H01L51/0545H01L51/4253H01L2251/308Y02E10/549
    • The present invention provides a photovoltaic cell having a large short-circuit current density and a large photoelectric conversion efficiency.This photovoltaic cell comprises: a first electrode; a second electrode; an active layer between the first electrode and the second electrode; wherein the active layer contains a macromolecular compound having a structural unit represented by Formula (1): wherein Ar1 and Ar2 are the same as or different from each other and represent a trivalent aromatic hydrocarbon group or a trivalent heterocyclic group; X1 and X2 are the same as or different from each other and represent —O—, —S—, —C(═O)—, —S(═O)—, —SO2—, —C(R50)(R51)—, —Si(R3)(R4)—, —N(R5)—, —B(R6)—, —P(R7)—, or —P(═O)(R8)—; R50, R51, R3, R4, R5, R6, R7, and R8 are the same as or different from each other and represent a hydrogen atom, a halogen atom, or a monovalent organic group; and X1 and Ar2 are bonded with atoms adjacent to each other on a ring that constitutes Ar1, and X2 and Ar1 are bonded with atoms adjacent to each other on a ring that constitutes Ar2, wherein an inverse of the excitation energy of the macromolecular compound from a ground singlet state to a lowest excited singlet state that is calculated using the time-dependent density functional theory is 0.43 (eV−1) or more.
    • 本发明提供一种具有大的短路电流密度和大的光电转换效率的光伏电池。 该光伏电池包括:第一电极; 第二电极; 在第一电极和第二电极之间的有源层; 其中活性层含有具有由式(1)表示的结构单元的高分子化合物:其中Ar1和Ar2彼此相同或不同,表示三价芳族烃基或三价杂环基; X1和X2彼此相同或不同,表示-O - , - S - , - C(= O) - , - S(= O) - , - SO2-,-C(R50) - , - Si(R 3)(R 4) - , - N(R 5) - , - (R 6) - , - (R 7) - 或-P(= O) R50,R51,R3,R4,R5,R6,R7和R8彼此相同或不同,表示氢原子,卤素原子或一价有机基团; 并且X1和Ar2与构成Ar1的环彼此相邻的原子键合,并且X2和Ar1与构成Ar2的环彼此相邻的原子键合,其中大分子化合物的激发能从 使用时间依赖密度函数理论计算的最低激发单线态的地面单线态为0.43(eV-1)以上。
    • 7. 发明申请
    • PHOTOVOLTAIC CELL
    • 光伏电池
    • US20120205641A1
    • 2012-08-16
    • US13502639
    • 2010-10-29
    • Ken YoshimuraKatsuhiro Suenobu
    • Ken YoshimuraKatsuhiro Suenobu
    • H01L51/46G06F17/10H01L51/30
    • H01L51/0036B82Y10/00C08G61/122C08G61/123C08G61/126C08G2261/3223C08G2261/3246C08G2261/344C08G2261/364C08G2261/411C08G2261/91G06F19/00H01L51/0043H01L51/0046H01L51/0545H01L51/4253H01L2251/308Y02E10/549
    • The present invention provides a photovoltaic cell having a large short-circuit current density and a large photoelectric conversion efficiency.This photovoltaic cell comprises: a first electrode; a second electrode; an active layer between the first electrode and the second electrode; wherein the active layer contains a macromolecular compound having a structural unit represented by Formula (1): wherein Ar1 and Ar2 are the same as or different from each other and represent a trivalent aromatic hydrocarbon group or a trivalent heterocyclic group; X1 and X2 are the same as or different from each other and represent —O—, —S—, —C(═O)—, —S(═O)—, —SO2—, —C(R50)(R51)—, —Si(R3)(R4)—, —N(R5)—, —B(R6)—, —P(R7)—, or —P(═O)(R8)—; R50, R51, R3, R4, R5, R6, R7, and R8 are the same as or different from each other and represent a hydrogen atom, a halogen atom, or a monovalent organic group; and X1 and Ar2 are bonded with atoms adjacent to each other on a ring that constitutes Ar1, and X2 and Ar1 are bonded with atoms adjacent to each other on a ring that constitutes Ar2, wherein an inverse of the excitation energy of the macromolecular compound from a ground singlet state to a lowest excited singlet state that is calculated using the time-dependent density functional theory is 0.43 (eV−1) or more.
    • 本发明提供一种具有大的短路电流密度和大的光电转换效率的光伏电池。 该光伏电池包括:第一电极; 第二电极; 在第一电极和第二电极之间的有源层; 其中活性层含有具有由式(1)表示的结构单元的高分子化合物:其中Ar1和Ar2彼此相同或不同,表示三价芳族烃基或三价杂环基; X1和X2彼此相同或不同,表示-O - , - S - , - C(= O) - , - S(= O) - , - SO2-,-C(R50) - , - Si(R 3)(R 4) - , - N(R 5) - , - (R 6) - , - (R 7) - 或-P(= O) R50,R51,R3,R4,R5,R6,R7和R8彼此相同或不同,表示氢原子,卤素原子或一价有机基团; 并且X1和Ar2与构成Ar1的环彼此相邻的原子键合,并且X2和Ar1与构成Ar2的环彼此相邻的原子键合,其中大分子化合物的激发能从 使用时间依赖密度函数理论计算的最低激发单线态的地面单线态为0.43(eV-1)以上。