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1. 发明申请

US20140287514A1 LUMINESCENT MICROPOROUS MATERIAL FOR DETECTION AND DISCRIMINATION OF LOW-LEVELS OF COMMON GASES AND VAPORS 审中-公开
标题翻译：用于检测和分辨低通量气体和蒸气的发光微孔材料
公开(公告)号：US20140287514A1
公开(公告)日：2014-09-25
申请号：US14215731
申请日：2014-03-17
申请人： Board of Regents, The University of Texas System
发明人： Simon M. Humphrey , Bradley J. Holliday
IPC分类号： C07F9/53 , G01N31/22
CPC分类号： C07F9/5345 , G01N21/64 , G01N31/223 , Y10T436/173845 , Y10T436/177692 , Y10T436/182 , Y10T436/203332 , Y10T436/204165 , Y10T436/204998 , Y10T436/207497 , Y10T436/21 , Y10T436/212 , Y10T436/214 , Y10T436/22
摘要： The present invention includes a sensing device and method detecting the presence of a chemical analyte, comprising: a surface; a continuous or discontinuous terbium(III)-triphenylphosphine oxide coordination polymer layer deposited on the surface, wherein the polymer layer is porous; and a luminescence detector, wherein one or more analytes that interact with the polymer layer luminesce at distinct wavelengths unique to each analyte.
摘要翻译：本发明包括检测化学分析物的存在的感测装置和方法，包括：表面; 沉积在表面上的连续或不连续的铽（III） - 三苯基膦氧化物配位聚合物层，其中聚合物层是多孔的; 和发光检测器，其中与聚合物层相互作用的一种或多种分析物在每种分析物独特的不同波长下发光。

2. 发明申请

US20080306251A1 RARE-EARTH AMIDATE COORDINATION COMPOUNDS 失效
标题翻译：稀土辅助化合物
公开(公告)号：US20080306251A1
公开(公告)日：2008-12-11
申请号：US11759973
申请日：2007-06-08
申请人： DAMIEN F. REARDON
发明人： DAMIEN F. REARDON
IPC分类号： C22B59/00
CPC分类号： C22B3/002 , C07F5/003 , C07F9/5345 , C22B59/00 , Y02P10/234
摘要： The invention is directed to a lanthamide chelate composition having a lanthamide, a charged amidate ligand, and a mono- or bidentate neutrally charged coordination compound, the composition being represented by structure I or structure II wherein Ln3+ designates lanthamide, R1 is alkyl, aryl, or heteroaryl; R2 is alkyl, aminoalkyl, aryl or heteroaryl; M is a neutrally charged monodentate coordination compound, M′ is a neutrally charged bidentate coordination compound, a=1 or 2; and wherein M and M′ comprise N, S, or O. It extends to the process of making the composition.
摘要翻译：本发明涉及具有花生酰胺，带电荷的酰胺化物配体和单或双齿中性带电配位化合物的花生酰胺螯合物组合物，该组合物由结构I或结构II表示，其中Ln3 +表示花氨酰胺，R1是烷基，芳基，或杂芳基; R2是烷基，氨基烷基，芳基或杂芳基; M是中性充电单齿配位化合物，M'是中性充电二齿配位化合物，a = 1或2; 并且其中M和M'包括N，S或O.它延伸到制备组合物的过程中。

3. 发明授权

US3422079A Coordination complexes of vinylphosphine oxides and metal salts,and polymers thereof 失效
标题翻译：乙氧基膦氧化物和金属盐的协调复合物及其聚合物
公开(公告)号：US3422079A
公开(公告)日：1969-01-14
申请号：US3422079D
申请日：1963-10-30
申请人： UNION CARBIDE CORP
发明人： WELCH FRANK J , PAXTON HERBERT J JR
IPC分类号： C07F9/53 , C08F30/02 , C08K5/5397 , C07F9/50 , C07F9/40 , C08F3/84
CPC分类号： C08K5/5397 , C07F9/5345 , C08F30/02

4. 发明授权

US09187505B2 Homoleptic rare earth triaryl complexes 有权
标题翻译：同位素稀土三芳基络合物
公开(公告)号：US09187505B2
公开(公告)日：2015-11-17
申请号：US14235285
申请日：2012-08-02
申请人： Oliver Thomas , Jörg Sundermeyer
发明人： Oliver Thomas , Jörg Sundermeyer
IPC分类号： C07F9/53 , C07F9/535 , C08G69/00 , C08G69/14 , C08G63/00 , C08G63/84 , C08F4/52 , C08F36/08 , C08F136/08 , C08F4/54 , C08G63/82
CPC分类号： C07F9/5345 , C07F9/5352 , C08F4/52 , C08F4/545 , C08F36/08 , C08F136/08 , C08G63/00 , C08G63/823 , C08G63/84 , C08G69/00 , C08G69/14
摘要： The invention relates to chelate-stabilized homleptic triaryl compounds based on phenylphosphoranes, to methods for preparing same and to the use thereof as catalysts. According to the invention, the object is achieved by homleptic rare earth triaryl complexes of the general formula (I), where SE=Sc, Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb or Lu; X═O, CRR′; R1, R2=phenyl; R, R′=mutually independently H, alkyl with n=10 C atoms, phenyl or trimethylsilyl.
摘要翻译：本发明涉及基于苯基磷烷的螯合稳定的亲和三芳基化合物，其制备方法及其作为催化剂的用途。根据本发明，通过通式（I）的亲水性稀土三芳基络合物，其中SE = Sc，Y，La，Ce，Pr，Nd，Pm，Sm，Eu，Gd，Tb，Dy， Ho，Er，Tm，Yb或Lu; X = O，CRR'; R1，R2 =苯基; R，R'=相互独立地为H，具有n = 10个C原子的烷基，苯基或三甲基甲硅烷基。

5. 发明授权

US08975385B2 Rare-earth complex and uses thereof 有权
标题翻译：稀土配合物及其用途
公开(公告)号：US08975385B2
公开(公告)日：2015-03-10
申请号：US13387013
申请日：2010-07-15
申请人： Yasuchika Hasegawa , Tsuyoshi Kawai , Takuya Nakashima , Tetsuya Nakagawa , Kohei Miyata
发明人： Yasuchika Hasegawa , Tsuyoshi Kawai , Takuya Nakashima , Tetsuya Nakagawa , Kohei Miyata
IPC分类号： C07F5/00 , F21V9/16 , C07F9/53 , C07F9/572 , C07F9/58 , C07F9/655 , C09K11/06 , H01L51/00 , H05B33/14 , H01L51/50
CPC分类号： C07F9/5329 , C07F5/003 , C07F9/5345 , C07F9/572 , C07F9/58 , C07F9/65515 , C07F9/65522 , C07F9/65527 , C09K11/06 , C09K2211/1007 , C09K2211/1088 , C09K2211/182 , H01L51/0089 , H01L51/5016 , H05B33/14
摘要： The rare-earth complex of the present invention has high luminous efficiency, since it has a structure represented by the following general formula (I):
摘要翻译：本发明的稀土配合物具有高发光效率，因为它具有由以下通式（I）表示的结构：

6. 发明授权

US08545807B2 Near infrared high emission rare-earth complex 有权
标题翻译：近红外高发射稀土复合物
公开(公告)号：US08545807B2
公开(公告)日：2013-10-01
申请号：US12920244
申请日：2009-02-26
申请人： Yasuchika Hasegawa , Hideki Kawai , Tsuyoshi Kawai
发明人： Yasuchika Hasegawa , Hideki Kawai , Tsuyoshi Kawai
IPC分类号： A61K51/00 , A61M36/14
CPC分类号： C07F9/5345 , C07F5/003 , C09D11/037 , C09D11/50 , C09K11/06 , C09K2211/182
摘要： The present invention has been created to provide a near infrared high emission rare-earth complex having an excellent light-emitting property in the near infrared region. The near infrared high emission rare-earth complex of the present invention is characterized in that its structure is expressed by the following general formula (1): where Ln(III) represents a trivalent rare-earth ion; n is an integer equal to or greater than three; Xs represent either the same member or different members selected from a hydrogen atom, a deuterium atom, halogen atoms, C1-C20 groups, hydroxyl groups, nitro groups, amino groups, sulfonyl groups, cyano groups, silyl groups, phosphonic groups, diazo groups and mercapto groups; and Z represents a bidentate ligand.
摘要翻译：本发明的目的是提供一种在近红外区域具有优异的发光特性的近红外高发射稀土配合物。本发明的近红外高发射稀土配合物的特征在于其结构由以下通式（1）表示：其中Ln（III）表示三价稀土离子; n是等于或大于3的整数; Xs表示选自氢原子，氘原子，卤原子，C1-C20基，羟基，硝基，氨基，磺酰基，氰基，甲硅烷基，膦酸基，重氮基的相同成员或不同成员和巯基; Z表示双齿配体。

7. 发明授权

US08173271B2 Fluorescent rare earth complex, and light-emitting element, security medium and lighting device using the same 失效
标题翻译：荧光稀土复合体，发光元件，安全介质及使用其的照明装置
公开(公告)号：US08173271B2
公开(公告)日：2012-05-08
申请号：US12124786
申请日：2008-05-21
申请人： Hiroki Iwanaga , Fumihiko Aiga , Takahiro Sato
发明人： Hiroki Iwanaga , Fumihiko Aiga , Takahiro Sato
IPC分类号： C09K11/06 , H01L51/54
CPC分类号： C07F9/5345 , H01L51/004 , H01L51/0071 , H01L51/0089 , H01L51/5012 , Y10S428/917
摘要： The present invention provides a fluorescent rare earth complex having high solubility to a medium, showing fluorescence of high intensity and possessing excellent durability, and also provides a light-emitting element using that complex. The rare earth complex comprises a rare earth ion and a phosphine oxide ligand, and the phosphine oxide ligand contains a phosphorus atom connecting to at least one phenyl group. In the phenyl group, at least one of the meta-positions is substituted. It is also necessary that the para-position of the phenyl group be not substituted.
摘要翻译：本发明提供了一种对介质具有高溶解性的荧光稀土配合物，显示出高强度的荧光并且具有优异的耐久性，并且还提供了使用该复合物的发光元件。稀土配合物包含稀土离子和氧化膦配体，氧化膦配体含有连接至少一个苯基的磷原子。在苯基中，至少一个间位被取代。苯基的对位也不是取代的。

8. 发明申请

US20050100511A1 Photoactive lanthanide complexes with phosphine oxides, phosphine oxide-sulfides, pyridine N-oxides, and phosphine oxide-pyridine N-oxides, and devices made with such complexes 失效
公开(公告)号：US20050100511A1
公开(公告)日：2005-05-12
申请号：US11011668
申请日：2004-12-14
申请人： Vladimir Grushin , Norman Herron , Viacheslav Petrov , Nora Radu , Ying Wang
发明人： Vladimir Grushin , Norman Herron , Viacheslav Petrov , Nora Radu , Ying Wang
IPC分类号： H01L51/50 , C07C49/92 , C07D213/26 , C07D213/89 , C07D217/08 , C07F5/00 , C07F9/53 , C07F19/00 , C09K11/06 , A61K49/00
CPC分类号： C09K11/06 , C07F9/5345 , C09K2211/10 , C09K2211/1003 , C09K2211/1007 , C09K2211/1011 , C09K2211/1014 , C09K2211/1018 , C09K2211/1029 , C09K2211/1044 , C09K2211/182 , Y10S428/917
摘要： The present invention is generally directed to luminescent lanthanide compounds with phosphine oxide, phosphine oxide-sulfide, pyridine N-oxide, and phosphine oxide-pyridine N-oxide ligands. It also relates to electronic devices in which the active layer includes a lanthanide complex.

9. 发明申请

US20040086444A1 Production of metal chalcogenide nanoparticles 审中-公开
标题翻译：金属硫族化物纳米粒子的生产
公开(公告)号：US20040086444A1
公开(公告)日：2004-05-06
申请号：US10415269
申请日：2003-12-18
发明人： Mark Green
IPC分类号： C01B019/04
CPC分类号： C30B7/00 , C07F9/5345 , C30B29/46 , C30B29/605 , H01S5/327
摘要： A process for preparing a capped metal sulfide, selenide or telluride nanoparticle containing one or a mixture of metals; which process comprises contacting, in an inert organic solvent and in the presence of a polar Lewis base capping ligand, a source of the metal(s) and a source of sulfur, selenium or tellurium, wherein the capping ligand and the source of the metal(s) are soluble in said inert organic solvent. Trialkylphosphine oxide capped mercury sulfide, selenide or telluride nanoparticles may be produced by the process of the invention and are useful as amplifiers in optical cables.
摘要翻译：一种制备包含一种或多种金属的金属硫化物，硒化物或碲化物纳米颗粒的方法; 该方法包括在惰性有机溶剂中和极性路易斯碱封端配体的存在下使金属源和硫，硒或碲的源接触，其中封端配体和金属源一种或多种可溶于所述惰性有机溶剂中。三烷基氧化膦封端的硫化汞，硒化物或碲化物纳米颗粒可以通过本发明的方法制备，并且可用作光缆中的放大器。

10. 发明申请

US20030144487A1 Photoactive lanthanide complexes with phosphine oxides, phosphine oxide-sulfides, pyridine N-oxides, and phosphine oxide-pyridine N-oxides, and devices made with such complexes 失效
标题翻译：与氧化膦，氧化膦 - 硫化物，吡啶N-氧化物和氧化膦 - 吡啶N-氧化物的光活性镧系元素络合物和由这种配合物制成的器件
公开(公告)号：US20030144487A1
公开(公告)日：2003-07-31
申请号：US10185484
申请日：2002-06-27
发明人： Vladimir Grushin , Norman Herron , Viacheslav Alexandrovich Petrov , Nora Sabina Radu , Ying Wang
IPC分类号： C07F005/00
CPC分类号： C09K11/06 , C07F9/5345 , C09K2211/10 , C09K2211/1003 , C09K2211/1007 , C09K2211/1011 , C09K2211/1014 , C09K2211/1018 , C09K2211/1029 , C09K2211/1044 , C09K2211/182 , Y10S428/917
摘要： The present invention is generally directed to luminescent lanthanide compounds with phosphine oxide, phosphine oxide-sulfide, pyridine N-oxide, and phosphine oxide-pyridine N-oxide ligands. It also relates to electronic devices in which the active layer includes a lanthanide complex.
摘要翻译：本发明一般涉及具有氧化膦，氧化膦 - 硫化物，吡啶N-氧化物和氧化膦 - 吡啶N-氧化物配体的发光镧系元素化合物。它还涉及其中活性层包括镧系元素络合物的电子器件。

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