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    • 2. 发明申请
    • CATALYTIC CONVERSION APPARATUS
    • 催化转换装置
    • US20090117017A1
    • 2009-05-07
    • US12295523
    • 2007-03-30
    • Jun LongKejia XuShuandi HouZhijian DaChaogang XieJiushun ZhangZhanzhu Zhang
    • Jun LongKejia XuShuandi HouZhijian DaChaogang XieJiushun ZhangZhanzhu Zhang
    • B01J8/04
    • C10G11/18B01J8/0055B01J8/0065B01J8/1827B01J8/26B01J2219/00038C10G2300/4093C10G2400/20Y02P30/40Y02P30/446
    • The present invention relates to a catalytic conversion apparatus, characterized in that said apparatus comprises at least one feed oil cracking riser reactor, a dense bed reactor, a disengager, and a stripper, wherein said stripper locates below said dense bed reactor and communicates directly with the lower part of the dense bed reactor or through a fluid-communicating channel, the outlet of at least one of said riser reactor(s) communicates with the lower part of said dense bed reactor or any part of said fluid-communicating channel, the outlet of said dense bed reactor communicates with the inlet of a gas-solid separating apparatus located in said disengager through said disengager and/or through an optional transporting channel, the catalyst outlet of said disengager communicates with at least one position selected from the upper part of said stripper, any part of said fluid-communicating channel, and the lower part of said dense bed reactor, through at least one catalyst transporting channel. The catalytic conversion apparatus according to the present invention sets up at least one riser reactor and a dense bed reactor to carry out further cracking of the intermediate products, produced from the feed oil by the cracking reaction in the riser, in the dense bed reactor. Moreover, the spent catalysts discharged from the outlet of the dense bed reactor can be introduced into the stripper via a specific catalyst transporting channel, so as to maintain higher activity and temperature of the catalyst in the dense bed reactor and be advantageous to deeper cracking of the intermediate products in the dense bed reactor so as to produce more light olefins, particularly propylene.
    • 催化转化装置技术领域本发明涉及一种催化转化装置,其特征在于,所述装置包括至少一个进料油裂解提升反应器,致密床反应器,分离器和汽提塔,其中所述汽提器位于所述致密床反应器下方并直接与 所述致密床反应器的下部或通过流体连通通道,所述提升管反应器中的至少一个的出口与所述致密床反应器的下部或所述流体连通通道的任何部分连通, 所述致密床反应器的出口通过所述分离器和/或通过可选的输送通道与位于所述分离器中的气固分离装置的入口连通,所述分离器的催化剂出口与选自上部的至少一个位置 的所述汽提器,所述流体连通通道的任何部分和所述致密床反应器的下部,通过至少一个催化剂运输 丁通道。 根据本发明的催化转化装置设置至少一个提升管反应器和致密床反应器,以进一步裂化由致密床反应器中的提升管中的裂化反应由进料油产生的中间产物。 此外,从致密床反应器出口排出的废催化剂可以通过特定的催化剂输送通道引入汽提塔,以保持催化剂在致密床反应器中的较高的活性和温度,并且有利于较深的开裂 在密床反应器中的中间产物,以产生更多的轻质烯烃,特别是丙烯。
    • 3. 发明申请
    • Catalytic Conversion Method Of Increasing The Yield Of Lower Olefin
    • 催化转化法提高低烯烃产量
    • US20080314799A1
    • 2008-12-25
    • US12158145
    • 2006-12-19
    • Zheng LiJun LongShuandi HouZhijian DaChaogang XieJiushun ZhangZhanzhu Zhang
    • Zheng LiJun LongShuandi HouZhijian DaChaogang XieJiushun ZhangZhanzhu Zhang
    • C10G11/05
    • C10G11/18C07C4/06C10G11/05Y02P20/52Y02P20/584C07C11/06C07C11/04
    • A catalytic conversion process for increasing the light olefin yields, which comprises bringing a hydrocarbon oil feedstock into contact with a catalytic conversion catalyst in a catalytic conversion reactor including one or more reaction zones to carry out the reaction, wherein the hydrocarbon oil feedstock is subjected to the catalytic conversion reaction in the presence of an inhibitor; and separating the reactant vapor optionally containing the inhibitor from the coke deposited catalyst, wherein a target product containing ethylene and propylene is obtained by separating the reactant vapor, and the coke deposited catalyst is stripped and regenerated for recycle use by being returned to the reactor. The process can weaken the further converting reaction of produced light olefins such as ethylene and propylene to 50-70% of the original level by injecting the inhibitor; thereby it can increase the yields of the target products. When vacuum gas oil is used as the feedstock, the yield of ethylene is as high as 8.73 wt % and that of propylene is as high as 29.30 wt %, increasing by 14.4% and 26.6% respectively comparing to those obtained without the inhibitor being injected.
    • 一种用于增加轻质烯烃产率的催化转化方法,其包括在包含一个或多个反应区的催化转化反应器中使烃油原料与催化转化催化剂接触以进行反应,其中烃油原料经受 在抑制剂存在下的催化转化反应; 以及将任选地含有抑制剂的反应物蒸气与焦炭沉积催化剂分离,其中通过分离反应物蒸气获得含有乙烯和丙烯的目标产物,并将焦炭沉积的催化剂通过返回到反应器中被汽提并再生再循环使用。 该方法可以通过注射抑制剂来削弱生产的轻质烯烃如乙烯和丙烯的进一步转化反应,达到原始水平的50-70%; 从而可以提高目标产品的产量。 当使用减压瓦斯油作为原料时,乙烯的产率高达8.73重量%,丙烯的产率高达29.30重量%,分别比不注入抑制剂的那些获得的增加了14.4%和26.6% 。
    • 5. 发明授权
    • Catalytic conversion method of increasing the yield of lower olefin
    • 提高低级烯烃产率的催化转化方法
    • US08608944B2
    • 2013-12-17
    • US12158145
    • 2006-12-19
    • Zheng LiJun LongShuandl HouZhijian DaChaogang XieJiushun ZhangZhanzhu Zhang
    • Zheng LiJun LongShuandl HouZhijian DaChaogang XieJiushun ZhangZhanzhu Zhang
    • C10G47/32C10G11/04C10G49/08
    • C10G11/18C07C4/06C10G11/05Y02P20/52Y02P20/584C07C11/06C07C11/04
    • A catalytic conversion process for increasing the light olefin yields, which comprises bringing a hydrocarbon oil feedstock into contact with a catalytic conversion catalyst in a catalytic conversion reactor including one or more reaction zones to carry out the reaction, wherein the hydrocarbon oil feedstock is subjected to the catalytic conversion reaction in the presence of an inhibitor; and separating the reactant vapor optionally containing the inhibitor from the coke deposited catalyst, wherein a target product containing ethylene and propylene is obtained by separating the reactant vapor, and the coke deposited catalyst is stripped and regenerated for recycle use by being returned to the reactor. The process can weaken the further converting reaction of produced light olefins such as ethylene and propylene to 50-70% of the original level by injecting the inhibitor; thereby it can increase the yields of the target products. When vacuum gas oil is used as the feedstock, the yield of ethylene is as high as 8.73 wt % and that of propylene is as high as 29.30 wt %, increasing by 14.4% and 26.6% respectively comparing to those obtained without the inhibitor being injected.
    • 一种用于增加轻质烯烃产率的催化转化方法,其包括在包含一个或多个反应区的催化转化反应器中使烃油原料与催化转化催化剂接触以进行反应,其中烃油原料经受 在抑制剂存在下的催化转化反应; 以及将任选地含有抑制剂的反应物蒸气与焦炭沉积催化剂分离,其中通过分离反应物蒸气获得含有乙烯和丙烯的目标产物,并将焦炭沉积的催化剂通过返回到反应器中被汽提并再生再循环使用。 该方法可以通过注射抑制剂来削弱生产的轻质烯烃如乙烯和丙烯的进一步转化反应,达到原始水平的50-70%; 从而可以提高目标产品的产量。 当使用减压瓦斯油作为原料时,乙烯的产率高达8.73重量%,丙烯的产率高达29.30重量%,分别比不注入抑制剂的那些获得的增加了14.4%和26.6% 。