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    • 4. 发明授权
    • Process for preparing high internal phase ratio emulsions and latexes
derived thereof
    • 制备高内相比乳液和衍生自其的胶乳的方法
    • US5688842A
    • 1997-11-18
    • US630187
    • 1996-04-10
    • James E. Pate, IIINanette E. LutenskeJames PetersRonald R. Pelletier
    • James E. Pate, IIINanette E. LutenskeJames PetersRonald R. Pelletier
    • B01F3/08B01F15/04B01J13/00C08J3/03C08J3/09C08J3/02
    • B01J13/0086B01J13/00C08J3/03C08J3/09Y10S516/929
    • The present invention is a method of preparing a high internal phase ratio emulsion without phase inversion comprising the steps of: a) continuously merging into a disperser and in the presence of an emulsifying and a stabilizing amount of a surfactant, a continuous phase liquid stream having a flow rate R.sub.1, and a disperse phase liquid stream having a flow rate R.sub.2 ; and b) mixing the merged streams with a sufficient amount of shear, and with R.sub.2 :R.sub.1 sufficiently constant, to form the high internal phase ratio emulsion without phase inversion or stepwise distribution of an internal phase into an external phase; wherein R.sub.2 :R.sub.1 encompasses a range, the lower limit of which range being defined by a point where the volume average particle size of the high internal phase ratio emulsion begins to show an inverse dependence on R.sub.2 :R.sub.1, and wherein the upper limit of which range is just less than an R.sub.2 :R.sub.1 where a phase inversion of the high internal phase ratio emulsion takes place. Monodisperse submicron particles can be prepared using the process of the present invention. Useful latexes can be prepared from these high internal phase ratio emulsions.
    • 本发明是一种制备不含相转化的高内相比乳液的方法,包括以下步骤:a)连续合并到分散器中,并在乳化剂和稳定剂量的表面活性剂存在下,连续相液体流具有 流量R1和具有流量R2的分散相液体流; 和b)将合并的流与足够量的剪切混合,并使R2:R1充分恒定,以形成高内相比乳液,而不会内相逐步分配到外相中; 其中R2:R1包含一个范围,其下限限定在高内相比乳液的体积平均粒径开始显示与R2:R1的反相关性的点,其中其上限 范围小于R2:R1,其中发生高内相比乳液的相转化。 可以使用本发明的方法制备单分散亚微米颗粒。 可以从这些高内相比乳液制备有用的胶乳。