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1. 发明授权

US06815475B2 Compositions comprising hydrogenated block copolymers and end-use applications thereof 有权
标题翻译：包含氢化嵌段共聚物及其最终用途的组合物
公开(公告)号：US06815475B2
公开(公告)日：2004-11-09
申请号：US10308429
申请日：2002-12-02
申请人： Robert J. Donald , Jerry L. Hahnfeld , Gary D. Parsons , Stephen F. Hahn , Rajen M. Patel , Calvin P. Esneault , Laura M. Phipps , James E. Pate, III
发明人： Robert J. Donald , Jerry L. Hahnfeld , Gary D. Parsons , Stephen F. Hahn , Rajen M. Patel , Calvin P. Esneault , Laura M. Phipps , James E. Pate, III
IPC分类号： C08L5302
CPC分类号： C08L53/025 , C08L2666/04 , C08L2666/02
摘要： Compositions comprising hydrogenated block copolymers can be successfully used in a variety of applications including films, profiles, sheets, pultruded articles, fibers, coated articles, injection molded articles and blow or rotational molded articles.
摘要翻译：包括氢化嵌段共聚物的组合物可以成功地用于各种应用，包括膜，型材，片材，拉挤制品，纤维，涂覆制品，注塑制品和吹塑或旋转模塑制品。

2. 发明授权

US06777082B2 Hydrogenated block copolymers having elasticity and articles made therefrom 有权
标题翻译：具有弹性的氢化嵌段共聚物和由其制成的制品
公开(公告)号：US06777082B2
公开(公告)日：2004-08-17
申请号：US10006082
申请日：2001-12-06
申请人： Rajen M. Patel , Pak-Wing S. Chum , Stephen F. Hahn , Leonie K. Walsh , Rexford A. Maugans , Selim Bensason , Thoi H. Ho , Calvin P. Esneault
发明人： Rajen M. Patel , Pak-Wing S. Chum , Stephen F. Hahn , Leonie K. Walsh , Rexford A. Maugans , Selim Bensason , Thoi H. Ho , Calvin P. Esneault
IPC分类号： C08L5300
CPC分类号： C08L51/06 , A61F13/4902 , C08L53/025 , D01F6/42 , D01F6/56 , D02G3/32 , D03D15/08 , Y10T428/2913 , Y10T428/2915 , Y10T428/2933 , C08L2666/24 , C08L2666/04 , C08L2666/02
摘要： The present invention relates to a fiber produced form a composition comprising at least one hydrogenated block copolymer and, optionally, at least one other polymer selected from the group consisting of a reactive tailored liquid polyurethane, an elastomeric or sulfonated ethylene/vinyl aromatic interpolymer, an elastomeric ethylene/C3-C20 &agr;-olefin interpolymer, an C3-C20 &agr;-olefin/conjugated diene interpolymer, an elastic polypropylene polymer, an enhanced polypropylene polymer, an elastomeric thermoplastic polyurethane, an elastic copolyester, a partially hydrogenated block copolymer, an elastic polyamide, a hydroxyl functionalized polyether (or polyetheramine), a styrene/conjugated diene interpolymer, and an elastomeric metallocene-catalyzed synthetic polymer or a blend or formulated system thereof.
摘要翻译：本发明涉及由包含至少一种氢化嵌段共聚物和任选的至少一种其它聚合物制备的纤维，所述其它聚合物选自反应性定制的液体聚氨酯，弹性体或磺化乙烯/乙烯基芳族互聚物，弹性体乙烯/ C 3 -C 20α-烯烃互聚物，C 3 -C 20α-烯烃/共轭二烯互聚物，弹性聚丙烯聚合物，增强聚丙烯聚合物，弹性体热塑性聚氨酯，弹性共聚酯，部分氢化嵌段共聚物，弹性体聚酰胺，羟基官能化聚醚（或聚醚胺），苯乙烯/共轭二烯互聚物和弹性体茂金属催化的合成聚合物或其共混物或配制体系。

3. 发明授权

US4761456A Process for metallating nonconjugated diene-containing ethylene polymers and graft polymers prepared therefrom 失效
公开(公告)号：US4761456A
公开(公告)日：1988-08-02
申请号：US899183
申请日：1986-08-18
申请人： Gary K. Lund , Calvin P. Esneault
发明人： Gary K. Lund , Calvin P. Esneault
IPC分类号： C08F8/42
CPC分类号： C08F8/42
摘要： A process is provided for metallating ethylene polymers which have polymerized therein a minor amount of nonconjugated diene. Metallation is accomplished with a blend of three metallating reagents: (a) an alkyllithium compound; (b) a potassium alkoxide; and (c) a chelating tertiary diamine. The metallated polymers so prepared may be reacted with one or more anionically polymerizable monomers to form graft polymers or with a reagent such as carbon dioxide to form a functionalized polymer. When the anionically polymerizable monomer has two or more polymerizable sites, the metallated polymer is reacted with a modifying compound such as alpha-methylstyrene before it is reacted with the monomer(s). Certain of the graft polymers behave as thermoplastic elastomers whereas others are thermoplastic. The blend of metallating reagents may be used with any polymer having partial or complete unsaturation.

4. 发明授权

US4786689A Process for metallating nonconjugated diene-containing ethylene polymers and graft polymers prepared therefrom 失效
公开(公告)号：US4786689A
公开(公告)日：1988-11-22
申请号：US109331
申请日：1987-10-16
申请人： Gary K. Lund , Raymond L. Laakso, Jr. , Calvin P. Esneault , Brian W. Walther
发明人： Gary K. Lund , Raymond L. Laakso, Jr. , Calvin P. Esneault , Brian W. Walther
IPC分类号： C08F8/42 , C08F255/06 , C08F8/00
CPC分类号： C08F8/42
摘要： A process is provided for metallating ethylene polymers which have polymerized therein a minor amount of nonconjugated diene. Metallation is accomplished with a blend of three metallating reagents: (a) an alkyllithium compound; (b) a potassium alkoxide; and (c) a chelating tertiary diamine. The metallated polymers so prepared may be reacted with one or more anionically polymerizable monomers to form graft polymers or with a reagent such as carbon dioxide to form a functionalized polymer. When the anionically polymerizable monomer has two or more polymerizable sites, the metallated polymer is reacted with a modifying compound such as alpha-methylstyrene before it is reacted with the monomer(s). Certain of the graft polymers behave as thermoplastic elastomers whereas others are thermoplastic. The blend of metallating reagents may be used with any polymer having partial or complete unsaturation.

5. 发明授权

US4529715A Catalyst prepared from organomagnesium compound, carbon dioxide, reducing aluminum source, transition metal compound and zinc compound 失效
标题翻译：催化剂由有机镁化合物，二氧化碳，还原铝源，过渡金属化合物和锌化合物制备
公开(公告)号：US4529715A
公开(公告)日：1985-07-16
申请号：US542854
申请日：1983-10-17
申请人： Ricardo Fuentes, Jr. , Calvin P. Esneault
发明人： Ricardo Fuentes, Jr. , Calvin P. Esneault
IPC分类号： C08F4/60 , C08F10/00 , C08F4/62 , C08F4/64 , C08F4/68
CPC分类号： C08F10/00
摘要： A catalyst for polymerizing olefins is the product resulting from a mixture of (A) an organomagnesium material, (B) essentially anhydrous carbon dioxide, (C) a reducing halide source and (D) the reaction product or complex resulting from admixing a transition metal compound and an organozinc compound.
摘要翻译：用于聚合烯烃的催化剂是由（A）有机镁材料，（B）基本上无水的二氧化碳，（C）还原卤化物源和（D）由（A）混合过渡金属化合物和有机锌化合物。

6. 发明授权

US5741857A Blends of elastomer block copolymer and aliphatic .alpha.-olefin/monovinylidene aromatic monomer and/or hindered aliphatic vinylidene monomer interpolymer 失效
标题翻译：弹性体嵌段共聚物和脂族α-烯烃/单亚乙烯基芳族单体和/或受阻脂族亚乙烯基单体互聚物的共混物
公开(公告)号：US5741857A
公开(公告)日：1998-04-21
申请号：US732108
申请日：1996-10-15
申请人： Calvin P. Esneault , Morris S. Edmondson
发明人： Calvin P. Esneault , Morris S. Edmondson
IPC分类号： C08L23/00 , C08L23/06 , C08L23/08 , C08L25/02 , C08L25/08 , C08L53/00 , C08L53/02 , C08L25/04
CPC分类号： C08L53/00 , C08L23/06 , C08L23/0838 , C08L25/02 , C08L53/02 , C08L53/025 , C08L23/0815
摘要： A thermoplastic elastomeric blend composition comprising: (A) from 99 to 1 weight percent of a styrenic block copolymer; and (B) from 1 to 99 weight percent of an interpolymer of .alpha.-olefin and (1) at least one aliphatic .alpha.-olefin and (2)at least one vinylidene aromatic monomer or (2) at least one hindered aliphatic vinylidene monomer or (3) a combination of at least one vinylidene aromatic monomer and at least one hindered aliphatic vinylidene monomer, and fabricated articles made from such composition.
摘要翻译：一种热塑性弹性体共混物组合物，其包含：（A）99至1重量％的苯乙烯嵌段共聚物; 和（B）1至99重量％的α-烯烃互聚物和（1）至少一种脂族α-烯烃和（2）至少一种亚乙烯基芳族单体或（2）至少一种受阻脂族亚乙烯基单体或（3）至少一种亚乙烯基芳族单体和至少一种受阻脂族亚乙烯基单体的组合，以及由该组合物制成的制品。

7. 发明授权

US4707521A Process for metallating crystalline ethylene-nonconjugated diene polymers and graft polymers prepared therefrom 失效
标题翻译：用于金属化结晶乙烯 - 非共轭二烯聚合物和由其制备的接枝聚合物的方法
公开(公告)号：US4707521A
公开(公告)日：1987-11-17
申请号：US839301
申请日：1986-03-12
申请人： Calvin P. Esneault , Gary K. Lund
发明人： Calvin P. Esneault , Gary K. Lund
IPC分类号： C08F8/42 , C08F255/06
CPC分类号： C08F8/42 , C08F255/06 , Y02P20/582
摘要： A process is provided for metallating crystalline ethylene polymers which have polymerized therein a minor amount of at least one nonconjugated diene and, optionally, a minor amount of at least one 1-olefin. Metallation is accomplished with an alkyllithium compound and at least one activating reagent after a slurry of the copolymer in a nonreactive, saturated, nonpolar hydrocarbon solvent is first heated to a temperature greater than 80.degree. Centigrade to provide the polymer with an expanded settling volume greater than its original settling volume. Metallation may be accomplished either at that temperature or at a lower temperature following cooling of the slurry. The activating reagents include potassium alkoxides, and chelating tertiary diamines. The metallated polymers so prepared may be reacted with (a) one or more anionically polymerizable monomers to form graft polymers or (b) a reagent such as carbon dioxide to form a functionalized polymer.
摘要翻译：提供了一种金属化结晶乙烯聚合物的方法，其中聚合有少量至少一种非共轭二烯和任选的少量至少一种1-烯烃。在非反应性饱和非极性烃溶剂中的共聚物浆液首先被加热至高于80℃的温度之后，用烷基锂化合物和至少一种活化剂进行金属化，以使聚合物的膨胀沉降体积大于其原始定居量。金属化可以在该温度下或在冷却浆料后的较低温度下完成。活化试剂包括烷醇钾和螯合叔二胺。如此制备的金属化聚合物可以与（a）一种或多种阴离子可聚合单体反应形成接枝聚合物或（b）诸如二氧化碳的试剂以形成官能化聚合物。

8. 发明授权

US4544647A Catalyst prepared from organomagnesium compound, organic hydroxyl-containing compound, reducing halide source and transition metal compound 失效
标题翻译：由有机镁化合物，含有机羟基化合物，还原卤化物源和过渡金属化合物制备的催化剂
公开(公告)号：US4544647A
公开(公告)日：1985-10-01
申请号：US586577
申请日：1984-03-06
申请人： Ricardo Fuentes, Jr. , Calvin P. Esneault
发明人： Ricardo Fuentes, Jr. , Calvin P. Esneault
IPC分类号： C08F4/60 , C08F10/00 , C08F4/62 , C08F4/64 , C08F4/68
CPC分类号： C08F10/00
摘要： A catalyst for polymerizing olefins is the product resulting from mixing in an inert hydrocarbon diluent a mixture of (A) an organomagnesium material, (B) an organic hydroxyl-containing material, (C) a reducing halide source and (D) a transition metal compound.
摘要翻译：用于聚合烯烃的催化剂是通过在惰性烃稀释剂中混合（A）有机镁材料，（B）含有机羟基材料，（C）还原卤化物源和（D）过渡金属复合。

9. 发明授权

US4526943A Process for polymerizing olefins in the presence of a catalyst prepared from organomagnesium compound, organic hydroxyl-containing compound, reducing halide source and transition metal compound 失效
标题翻译：在由有机镁化合物，含有机羟基化合物，还原卤化物源和过渡金属化合物制备的催化剂存在下聚合烯烃的方法
公开(公告)号：US4526943A
公开(公告)日：1985-07-02
申请号：US574754
申请日：1984-01-26
申请人： Ricardo Fuentes, Jr. , Calvin P. Esneault
发明人： Ricardo Fuentes, Jr. , Calvin P. Esneault
IPC分类号： C08F4/60 , C08F10/00 , C08F10/02 , C08F4/02
CPC分类号： C08F10/00 , C08F10/02
摘要： Olefins are polymerized in the presence of, as a catalyst therefor, the catalytic reaction product resulting from admixing(A) at least one hydrocarbon soluble organomagnesium material;(B) at least one organic hydroxyl-containing material;(C) at least one reducing halide source; and(D) at least one transition metal (Tm) compound.
摘要翻译：在作为催化剂的存在下，将烯烃聚合为通过混合（A）至少一种可溶于烃的有机镁材料而产生的催化反应产物; （B）至少一种含有机羟基的材料; （C）至少一种还原卤素源; 和（D）至少一种过渡金属（Tm）化合物。

10. 发明授权

US4794145A Process for metallating nonconjugated diene-containing ethylene polymers and graft polymers prepared therefrom 失效
标题翻译：用于金属化非共轭二烯的乙烯聚合物和由其制备的接枝聚合物的方法
公开(公告)号：US4794145A
公开(公告)日：1988-12-27
申请号：US109332
申请日：1987-10-16
申请人： Gary K. Lund , Raymond L. Laakso, Jr. , Calvin P. Esneault , Brian W. Walther
发明人： Gary K. Lund , Raymond L. Laakso, Jr. , Calvin P. Esneault , Brian W. Walther
IPC分类号： C08F8/42 , C08F255/06 , C08F255/00
CPC分类号： C08F8/42
摘要： A process is provided for metallating ethylene polymers which have polymerized therein a minor amount of nonconjugated diene. Metallation is accomplished with a blend of three metallating reagents: (a) an alkyllithium compound; (b) a potassium alkoxide; and (c) a chelating tertiary diamine. The metallated polymers so prepared may be reacted with one or more anionically polymerizable monomers to form graft polymers or with a reagent such as carbon dioxide to form a functionalized polymer. When the anionically polymerizable monomer has two or more polymerizable sites, the metallated polymer is reacted with a modifying compound such as alpha-methylstyrene before it is reacted with the monomer(s). Certain of the graft polymers behave as thermoplastic elastomers whereas others are thermoplastic. The blend of metallating reagents may be used with any polymer having partial or complete unsaturation.
摘要翻译：提供了一种金属化乙烯聚合物的方法，其中聚合有少量非共轭二烯。金属化是用三种金属化试剂的混合物完成的：（a）烷基锂化合物; （b）醇钾; 和（c）螯合叔胺。如此制备的金属化聚合物可以与一种或多种阴离子可聚合单体反应以形成接枝聚合物或与诸如二氧化碳的试剂形成官能化聚合物。当阴离子聚合单体具有两个或更多个可聚合位点时，金属化聚合物在与单体反应之前与诸如α-甲基苯乙烯的改性化合物反应。某些接枝聚合物表现为热塑性弹性体，而另一些则是热塑性弹性体。金属化试剂的混合物可以与具有部分或完全不饱和度的任何聚合物一起使用。

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