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    • 5. 发明授权
    • Method for forming metal film
    • 金属膜形成方法
    • US08357284B2
    • 2013-01-22
    • US12977592
    • 2010-12-23
    • Akira SusakiTsutomu NakadaHideki Tateishi
    • Akira SusakiTsutomu NakadaHideki Tateishi
    • C25D5/12C25D5/10C25D5/34C25D5/38C25D5/44
    • C25D3/38C25D3/12C25D5/38C25D5/42C25D5/44
    • A metal film-forming method is capable of forming a metal film on a surface of a base metal film, formed on a surface of a substrate, with sufficient adhesion to the base metal film even when a natural oxide film is formed on the surface of the base metal film. The metal film-forming method includes: preparing a substrate having a base metal film formed on a surface; and carrying out electroplating of the substrate using the base metal film as a cathode and another metal as an anode while immersing the substrate in a solution containing a metal complex and a reducing material, both dissolved in a solvent, to form a metal film, deriving from a metal contained in the metal complex, on the surface of the base metal film.
    • 金属膜形成方法能够在形成在基板表面上的基底金属膜的表面上形成金属膜,即使当在基体金属膜的表面上形成自然氧化膜时,也能够对基底金属膜具有足够的粘合力 贱金属膜。 金属膜形成方法包括:制备在表面上形成有贱金属膜的基板; 并且使用基底金属膜作为阴极和另一种金属作为阳极进行基板的电镀,同时将基板浸入含有溶解在溶剂中的金属络合物和还原材料的溶液中以形成金属膜,得到 从包含在金属络合物中的金属在基底金属膜的表面上。
    • 7. 发明申请
    • Substrate Processing Apparatus
    • 基板加工装置
    • US20070289604A1
    • 2007-12-20
    • US11587974
    • 2005-04-27
    • Yukio FukunagaAkira SusakiJunji KunisawaHiroyuki UeyamaShohei ShimaAkira FukunagaHideki TateishiJunko Mine
    • Yukio FukunagaAkira SusakiJunji KunisawaHiroyuki UeyamaShohei ShimaAkira FukunagaHideki TateishiJunko Mine
    • C23G1/02B08B3/00G05D23/00G05D99/00
    • H01L21/76838H01L21/02063H01L21/02068H01L21/67253
    • To provide an apparatus and a method capable of supplying a gas containing an evaporated reducing organic compound while strictly controlling the flow rate thereof to process a surface of a metal on a substrate without causing any deterioration of various types of films forming a semiconductor element with a simple apparatus configuration. The apparatus includes a process chamber 10 for keeping a substrate W therein, the process chamber 10 being gastight, an evacuation control system 20 for controlling the pressure in the process chamber 10, and a process gas supply system 30 for supplying a process gas containing a reducing organic compound to the process chamber 10. The process gas supply system 30 has an evaporator 32 keeping liquid material of the reducing organic compound therein and having an evaporating liquid surface S, a process gas pipe 18 for directing the process gas containing the reducing organic compound evaporated in the evaporator 32 into the process chamber 10, and a throttle element 40 disposed in the process gas pipe 18 for controlling the flow rate of the process gas to be supplied to the process chamber 10 by adjusting the opening of the throttle element 40. The opening of the throttle element 40 is so set that the pressure variation in the evaporator 32 can be maintained within a prescribed range.
    • 提供一种能够提供含有蒸发还原性有机化合物的气体的装置和方法,同时严格控制其流速来处理基板上的金属表面,而不会导致形成半导体元件的各种类型的膜的劣化 简单的设备配置。 该装置包括用于将基板W保持在其中的处理室10,气密的处理室10,用于控制处理室10中的压力的​​抽空控制系统20以及用于提供含有 将有机化合物还原成处理室10。 工艺气体供给系统30具有:蒸发器32,其中还原有机化合物的液体材料保持在其中并具有蒸发的液体表面S;一个工艺气体管道18,用于将含有在蒸发器32中蒸发的还原性有机化合物的工艺气体引导到过程 设置在处理气体管道18中的节流元件40,用于通过调节节流元件40的开口来控制供给处理室10的处理气体的流量。 节流元件40的开度被设定为使得蒸发器32中的压力变化可以保持在规定范围内。