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1. 发明授权

US4873306A Urethanes containing fluorine and polysiloxane, process for their preparation and their use 失效
标题翻译：含氟和聚硅氧烷的聚氨酯，其制备方法及其应用
公开(公告)号：US4873306A
公开(公告)日：1989-10-10
申请号：US215202
申请日：1988-07-05
申请人： Frank Wehowsky , Martin Liebiger
发明人： Frank Wehowsky , Martin Liebiger
IPC分类号： C07F7/10 , C08G18/61 , C08G18/80 , C08G77/38 , C08G77/385 , C08G77/388 , C08G77/46 , D06M15/653 , D06M15/657
CPC分类号： C08G77/388 , C08G18/61 , C08G18/8087 , C08G77/385 , D06M15/653 , D06M15/657
摘要： The novel urethanes are composed essentially of fluoroalcohol-isocyanate adducts as the fluoro component and a polysiloxane component, the two components being combined in a structurally specific manner. The novel urethanes are prepared by reacting the fluoroalcohol-isocyanate adducts with the polysiloxane in a molar ratio of 1 to 2:1 at a temperature of 30.degree. to 130.degree. C. The novel urethanes are preferably used for finishing textiles, to which they also impart the property of a soft handle in addition to good hydrophobicity and oleophobicity. They are also suitable for finishing leather, skins and wood.
摘要翻译：新型氨基甲酸酯基本上由作为氟组分的氟代醇 - 异氰酸酯加合物和聚硅氧烷组分组成，两种组分以结构特异性方式组合。新型氨基甲酸酯通过使氟代醇 - 异氰酸酯加合物与聚硅氧烷在摩尔比为1至2:1的温度下在30至130℃下反应来制备。新型聚氨酯优选用于整理纺织品赋予柔软手感的性质以及良好的疏水性和疏油性。它们也适用于整理皮革，皮革和木材。

2. 发明授权

US5053537A Ammonium and iminium compounds 失效
标题翻译：氨和化合物
公开(公告)号：US5053537A
公开(公告)日：1991-10-01
申请号：US430740
申请日：1989-11-02
申请人： Jorg Gitzel , Hans-Tobias Macholdt , Frank Wehowsky , Gunther Prossel
发明人： Jorg Gitzel , Hans-Tobias Macholdt , Frank Wehowsky , Gunther Prossel
IPC分类号： C07C211/63 , C07D213/20 , C07D215/10 , C07F5/02
CPC分类号： C07D213/20 , C07C211/63 , C07D215/10 , C07F5/027
摘要： Ammonium compounds of the formula (I) ##STR1## in which at least one of the radicals R.sub.1 to R.sub.4 denotes a fluorine-containing alkyl radical having 4 to 30 carbon atoms and not more than three of the radicals R.sub.1 to R.sub.4 independently of one another denote hydrogen atoms or alkyl or hydroxyalkyl radicals having 1 to 30 carbon atoms, and R.sub.5 to R.sub.8 denote aryl, alkylaryl or halogenoaryl radicals or fluorine atoms, and iminium compounds of the formula (II) ##STR2## in which Q, together with the constituent ##STR3## forms a ring system having 4 to 17 carbon atoms, which can be interrupted by 1 to 4 hetero atoms and contain 2 to 9 double bonds, and which can be substituted by fluorine, chlorine, bromine or iodine atoms or alkyl (C.sub.1 -C.sub.6), alkoxy (C.sub.1 -C.sub.6), nitro or amino groups, R.sub.9 denotes a fluorine-containing alkyl (C.sub.1 -C.sub.30) radical, R.sub.10 denotes a hydrogen, fluorine, chlorine, bromine or iodine atom or an alkyl(C.sub.1 -C.sub.6), alkoxy (C.sub.1 -C.sub.6), nitro or amino group and the radicals R.sub.11 to R.sub.14 denote aryl radicals, alkylaryl radicals, halogenoaryl radicals or fluorine atoms, and mixtures of these compounds and processes for their preparation.
摘要翻译：式（I）的铵化合物其中至少一个基团R 1至R 4表示独立地具有4至30个碳原子且不超过3个基团R 1至R 4的含氟烷基彼此表示氢原子或具有1至30个碳原子的烷基或羟烷基，R5至R8表示芳基，烷基芳基或卤代芳基或氟原子，以及式（II）的亚铵化合物其中 Q与组分“IMAGE”一起形成具有4至17个碳原子的环系，其可被1至4个杂原子间隔并含有2至9个双键，并且可被氟，氯，溴或碘原子或烷基（C1-C6），烷氧基（C1-C6），硝基或氨基，R9表示含氟烷基（C1-C30）基，R10表示氢，氟，氯，溴或碘原子或烷基（C1-C6），烷氧基（C1-C6），硝基或氨基，基团R11至R14表示芳基自由基，烷基芳基，卤代芳基或氟原子，以及这些化合物的混合物及其制备方法。

3. 发明授权

US5103048A Surface-active compounds having a perfluoroalkyl group and a nitrogen-containing aliphatic radical, a process for their preparation and their use 失效
标题翻译：具有全氟烷基的表面活性化合物和含氮的惰性气体，其制备方法及其使用
公开(公告)号：US5103048A
公开(公告)日：1992-04-07
申请号：US634023
申请日：1990-12-26
申请人： Wolfgang Knaup , Frank Wehowsky , Norbert Schmitt
发明人： Wolfgang Knaup , Frank Wehowsky , Norbert Schmitt
IPC分类号： B01F17/46 , B01F17/42 , C07C213/04 , C07C217/28 , C07C217/50 , C07C229/12 , C07C229/22 , C07C309/14 , C11D1/00
CPC分类号： C11D1/004 , C07C217/28 , C07C229/12 , C07C309/14
摘要： The new compounds have the formula below ##STR1## in which R.sub.f is a perfluoroalkyl radical having 4 to 20 carbon atoms,x is 1 to 4,y is 1 to 10,X is Br, Cl or I, andR.sup.1 and R.sup.2 are hydrogen or a C.sub.1 to C.sub.4 -alkyl radical or a water-solubilizing aliphatic radical, with the proviso that at least one of the two substituents R.sup.1 and R.sup.2 is a water-solubilizing aliphatic radical.The surface-active compounds described are prepared by reacting a suitable epoxide with a suitable amine. They are used in particular for the preparation of foaming agents.
摘要翻译：新化合物具有下式“IMAGE”，其中Rf为碳原子数4〜20的全氟烷基，x为1〜4，y为1〜10，X为Br，Cl或I，R 1和R 2为氢或C1至C4-烷基或水溶性脂肪族基团，条件是两个取代基R 1和R 2中的至少一个为水溶性脂族基团。所述的表面活性化合物通过使合适的环氧化物与合适的胺反应制备。它们特别用于制备发泡剂。

4. 发明授权

US5069994A Use of colorless, intensely fluorinated ammonium and iminium compounds as charge control agents for electrophotographic recording processes 失效
标题翻译：作为电子记录记录过程的充电控制剂，使用无色，强力氟化氨和铱化合物
公开(公告)号：US5069994A
公开(公告)日：1991-12-03
申请号：US430732
申请日：1989-11-02
申请人： Jorg Gitzel , Hans-Tobias Macholdt , Alexander Sieber , Frank Wehowsky , Gunther Prossel
发明人： Jorg Gitzel , Hans-Tobias Macholdt , Alexander Sieber , Frank Wehowsky , Gunther Prossel
IPC分类号： C09D5/03 , C09D5/46 , G03G9/09 , G03G9/097 , G03G9/113
CPC分类号： G03G9/09741 , C09D5/034 , G03G9/09766
摘要： The use of intensely fluorinated ammonium compounds of the general formula (I) ##STR1## in which R.sub.1 to R.sub.4 denote hydrogen atoms or organic radicals, at least one of the radicals R.sub.1 to R.sub.4 denoting a straight-chain or branched fluorine-containing alkyl radical or fluorine-containing alkenyl radical which contains 1 to 69 carbon atoms and 3 to 66 fluorine atoms and which may be substituted, and at most three of the radicals R.sub.1 to R.sub.4 are, independently of one another, hydrogen atoms, straight-chain or branched alkyl radicals or alkenyl radicals containing 1 to 30 carbon atoms, aryl radicals or aralkyl radicals, and X.sup.- denotes an organic or inorganic anion, and of intensely fluorinated iminium compounds of the general formula (II) ##STR2## in which R.sub.9 to R.sub.12 denote hydrogen atoms or organic radicals, at least one of the radicals R.sub.9 to R.sub.12 denoting a straight-chain or branched fluorine-containing alkyl radical or fluorine-containing alkenyl radical which contains 1 to 69 carbon atoms and 3 to 66 fluorine atoms and which may be substituted, and at most three of the radicals R.sub.9 to R.sub.12 denote, independently of one another, hydrogen, straight-chain or branched alkyl radicals or alkenyl radicals containing 1 to 30 carbon atoms, aryl or aralkyl radicals and Y.sup.- is an organic or inorganic anion, as colorless charge control agents having positive or negative control effect in toners and developers for electrophotographic recording processes.
摘要翻译：使用通式（I）的高度氟化的铵化合物，其中R 1至R 4表示氢原子或有机基团，基团R 1至R 4中的至少一个表示直链或支链的氟 - 含有1至69个碳原子和3至66个氟原子且可以被取代的烷基或含氟烯基，并且至少三个基团R 1至R 4彼此独立地为氢原子，含有1至30个碳原子的链或支链烷基或烯基，芳基或芳烷基，X表示有机或无机阴离子，以及通式（II）的强氟化亚胺化合物。（II）其中R9至R12表示氢原子或有机基团，表示含有1至69个碳原子的直链或支链含氟烷基或含氟烯基的基团R 9至R 12中的至少一个和3至66个氟原子并且其可以被取代，并且至少三个基团R 9至R 12彼此独立地表示氢，直链或支链烷基或含有1至30个碳原子的烯基，芳基或芳烷基和Y-是有机或无机阴离子，作为在调色剂和电子照相记录方法的显影剂中具有正或负控制效果的无色电荷控制剂。

5. 发明授权

US4782175A Urethanes composed of aliphatic fluoroalcohols, isocyanates and aromatic compounds, a process for their preparation and their use 失效
标题翻译：由脂族氟代醇，异氰酸酯和芳族化合物组成的聚氨酯，其制备方法及其用途
公开(公告)号：US4782175A
公开(公告)日：1988-11-01
申请号：US68924
申请日：1987-07-01
申请人： Frank Wehowsky , Rolf Kleber , Lothar Jaeckel
发明人： Frank Wehowsky , Rolf Kleber , Lothar Jaeckel
IPC分类号： C07C275/06 , C07C67/00 , C07C239/00 , C07C257/10 , C07C271/42 , C07C275/04 , C07C275/62 , C07C311/01 , C07C313/00 , C07C315/04 , C07C317/22 , C07C317/36 , C07C317/44 , C08G18/28 , C08G18/32 , D06M15/576 , C07C125/07 , C07C147/06
CPC分类号： C07C275/62 , C08G18/2885 , C08G18/3215 , D06M15/576
摘要： The molecule of the new urethanes contains an aliphatic fluoroalcohol, an isocyanate and an aromatic dihydroxy, diamino, aminohydroxy, aminocarboxy or hydroxycarboxy compound. They are prepared by reacting an aliphatic fluoroalcohol with a diisocyanate or triisocyanate to give the fluoroalcohol/isocyanate adduct and by reacting this adduct with said aromatic compound to give the desired urethanes composed of an aliphatic fluoroalcohol, an isocyanate and the bifunctional aromatic compound mentioned, and also be reacting a urethane of this type which also carries an active hydrogen atom on the bifunctional aromatic compound, with an isocyanate compound containing one or more isocyanate groups. The new urethanes are preferably used for imparting an oleophobic and hydrophobic finish to textiles and leather.
摘要翻译：新型氨基甲酸酯的分子含有脂族氟代醇，异氰酸酯和芳族二羟基，二氨基，氨基羟基，氨基羧基或羟基羧基化合物。它们通过使脂族氟代醇与二异氰酸酯或三异氰酸酯反应得到氟代醇/异氰酸酯加合物并通过使该加合物与所述芳族化合物反应得到所需的由脂族氟代醇，异氰酸酯和所述双官能芳族化合物组成的氨基甲酸酯，以及也可以使这种在双功能芳族化合物上带有活性氢原子的氨基甲酸酯与含有一个或多个异氰酸酯基团的异氰酸酯化合物反应。新的聚氨酯优选用于对纺织品和皮革赋予疏油和疏水整理剂。

6. 发明授权

US4709074A Urethanes containing perfluoroalkyl and epichlorohydrin groups 失效
标题翻译：含有全氟烷基和表氯醇基团的聚氨酯
公开(公告)号：US4709074A
公开(公告)日：1987-11-24
申请号：US901247
申请日：1986-08-28
申请人： Heinrich Bathelt , Winfried Ehrl , Frank Wehowsky , Rolf Kleber , Werner Lotz , Wolfgang Glenz , Hubert Herdt , Lothar Jackel , Jan-Hilbert Mast , Karl Hintermeier , Manfred Muller
发明人： Heinrich Bathelt , Winfried Ehrl , Frank Wehowsky , Rolf Kleber , Werner Lotz , Wolfgang Glenz , Hubert Herdt , Lothar Jackel , Jan-Hilbert Mast , Karl Hintermeier , Manfred Muller
IPC分类号： C09K3/18 , B27K3/38 , C07C67/00 , C07C239/00 , C07C271/28 , C08G65/32 , C09K3/00 , C14C9/00 , D06M13/02 , D06M13/224 , D06M13/322 , D06M13/342 , D06M13/345 , D06M13/425 , D06M13/428 , D06M13/463 , D06M101/00 , D06M101/02 , D06M101/10 , D06M101/12 , C07C125/073
CPC分类号： D06M13/428 , C14C9/00 , B27K2240/70 , B27K3/38 , B27K3/50
摘要： The novel urethanes correspond to the formula I below ##STR1## in which a denotes a number from 5 to 17 and b denotes a number from 1 to 7. These urethanes are prepared by reacting the corresponding perfluoroalkylethanol/epichlorohydrin adducts with toluelene diisocyanates. The novel aqueous dispersions are essentially composed of the novel urethanes, cationic or betaine emulsifiers and non-ionic emulsifiers, water-insoluble carboxylic and/or dicarboxylic acid esters and alkanediols or polyalkanediols which can be etherified on one or both sides, in water.The novel urethanes and the novel aqueous dispersions are used to impart an oleophobic and hydrophobic finish to textiles, leather and furs. They are also suitable for the treatment of unpainted timber, for example unpainted furniture.
摘要翻译：新型氨基甲酸酯对应于下面的式I，其中a表示5至17的数，b表示1至7的数。这些氨基甲酸酯通过相应的全氟烷基乙醇/表氯醇加合物与甲苯二异氰酸酯反应制备。新型水性分散体基本上由新型氨基甲酸酯，阳离子或甜菜碱乳化剂和非离子乳化剂，水不溶性羧酸和/或二羧酸酯和烷二醇或聚烷二醇组成，其可以在水中在一侧或两侧进行醚化。新型氨基甲酸酯和新型水性分散体用于对纺织品，皮革和毛皮赋予疏油和疏水整理剂。它们也适用于未涂漆的木材的处理，例如未上漆的家具。

7. 发明授权

US5648528A Saturated fluoroalkylamines and their derivatives, and mixtures thereof 失效
标题翻译：饱和氟烷基胺及其衍生物及其混合物
公开(公告)号：US5648528A
公开(公告)日：1997-07-15
申请号：US476725
申请日：1995-06-07
申请人： Gunter Prossel , Wolfgang Knaup , Frank Wehowsky
发明人： Gunter Prossel , Wolfgang Knaup , Frank Wehowsky
IPC分类号： B01J23/40 , C07B61/00 , C07C211/15 , C07C215/12 , C07C229/12 , C07C303/32 , C07C309/13 , C07C309/14 , C07C229/00
CPC分类号： C07C211/15 , C07C229/12 , C07C309/13
摘要： New saturated fluoroalkylamines and carboxyalkylbetaines and alkylsulfobetaines derived therefrom, and mixtures containing the new fluoroalkylamines and mixtures containing the new fluorobetaines are described. The saturated fluoroalkylamines conform to the formula below ##STR1## in which n is an integer from 3 to 17 and R.sup.1 and R.sup.2 are C.sub.1 to C.sub.4 -alkyl, C.sub.1 to C.sub.4 -hydroxyalkyl or hydrogen, with the proviso that only one of the two substituents R.sup.1 and R.sup.2 is hydrogen. The carboxyalkylbetaines and sulfobetaines and the mixtures thereof are highly effective products for reducing the surface tension of water/air systems and the interfacial tension of water/hydrocarbon systems.
摘要翻译：描述了新的饱和氟代烷基胺和羧基烷基甜菜碱和由其衍生的烷基磺基甜菜碱，以及含有新的氟代烷基胺和含有新的氟代甜菜碱的混合物的混合物。饱和氟烷基胺符合下面的式，其中n是3至17的整数，R 1和R 2是C 1至C 4 - 烷基，C 1至C 4 - 羟烷基或氢，条件是两个取代基中只有一个 R1和R2是氢。羧基烷基甜菜碱和磺基甜菜碱及其混合物是降低水/空气体系的表面张力和水/烃体系的界面张力的高效产品。

8. 发明授权

US5648527A Saturated fluoroalkylamines and their derivatives, and mixtures thereof 失效
公开(公告)号：US5648527A
公开(公告)日：1997-07-15
申请号：US480647
申请日：1995-06-07
申请人： Gunter Prossel , Wolfgang Knaup , Frank Wehowsky
发明人： Gunter Prossel , Wolfgang Knaup , Frank Wehowsky
IPC分类号： B01J23/40 , C07B61/00 , C07C211/15 , C07C215/12 , C07C229/12 , C07C303/32 , C07C309/13 , C07C309/14 , C07C51/14
CPC分类号： C07C211/15 , C07C229/12 , C07C309/13
摘要： New saturated fluoroalkylamines and carboxyalkylbetaines and alkylsulfobetaines derived therefrom, and mixtures containing the new fluoroalkylamines and mixtures containing the new fluorobetaines are described. The saturated fluoroalkylamines conform to the formula below ##STR1## in which n is an integer from 3 to 17 and R.sup.1 and R.sup.2 are C.sub.1 to C.sub.4 -alkyl, C.sub.1 to C.sub.4 -hydroxyalkyl or hydrogen, with the proviso that only one of the two substituents R.sup.1 and R.sup.2 is hydrogen. The carboxyalkylbetaines and sulfobetaines and the mixtures thereof are highly effective products for reducing the surface tension of water/air systems and the interfacial tension of water/hydrocarbon systems.

9. 发明授权

US4960543A Urethane made from aliphatic fluorinated alcohols, isocyanates and substituted aromatic compounds, a process for their preparation, and their use 失效
标题翻译：由脂肪族氟化醇，异氰酸酯和取代的芳族化合物制成的聚氨酯，其制备方法及其用途
公开(公告)号：US4960543A
公开(公告)日：1990-10-02
申请号：US289913
申请日：1988-12-27
申请人： Frank Wehowsky , Rolf Kleber , Lothar Jaeckel
发明人： Frank Wehowsky , Rolf Kleber , Lothar Jaeckel
IPC分类号： C07C271/28 , C07C271/36 , C07C271/38 , C07C271/42 , C07C275/14 , C07C275/28 , C07C275/62 , C08G18/28 , C08G18/32 , D06M13/02 , D06M13/322 , D06M13/402 , D06M13/425 , D06M13/428 , D06M13/432 , D06M13/438 , D06M15/576
CPC分类号： C07C275/14 , C07C271/28 , C07C275/62 , C08G18/2885 , C08G18/3215 , D06M15/576
摘要： Urethanes made from aliphatic fluorinated alochols, isocyanates and substituted aromatic compounds, a process for their preparation, and their use.The novel urethanes are synthesized from an aliphatic fluorinated alcohol, an isocyanate and a specific substituted phenol or aniline compound. They are prepared by reacting an aliphatic fluorinated alcohol with a di- or triisocyanate to form a fluorinated alcohol/isocyanate adduct and reacting this adduct with a certain substituted phenol or aniline to form the urethanes intended. The novel urethanes are preferably used for oleophobic and hydrophobic finishing of textiles and leather.
摘要翻译：由脂肪族氟化环醇，异氰酸酯和取代的芳族化合物制成的聚氨酯，其制备方法及其用途。该新型聚氨酯由脂肪族氟化醇，异氰酸酯和特定的取代苯酚或苯胺化合物合成。它们通过使脂族氟化醇与二异氰酸酯或三异氰酸酯反应以形成氟化醇/异氰酸酯加合物并使该加合物与某些取代的苯酚或苯胺反应以形成预期的聚氨酯。新型聚氨酯优选用于纺织品和皮革的疏油和疏水整理。

10. 发明授权

US4775488A Aqueous anionic dispersion 失效
标题翻译：水性阴离子分散体
公开(公告)号：US4775488A
公开(公告)日：1988-10-04
申请号：US850592
申请日：1986-04-11
申请人： Karl Hintermeier , Heinrich Bathelt , Frank Wehowsky , Hans Wagener , Manfred Seidel , Manfred Muller , Klaus Kaschub
发明人： Karl Hintermeier , Heinrich Bathelt , Frank Wehowsky , Hans Wagener , Manfred Seidel , Manfred Muller , Klaus Kaschub
IPC分类号： B01J13/00 , B01F17/22 , B01F17/42 , C09K3/18 , D06M13/02 , D06M13/144 , D06M13/165 , D06M13/322 , D06M13/325 , D06M13/335 , D06M13/402 , D06M13/408 , D06M13/428 , D06M13/00
CPC分类号： D06M13/428
摘要： An agent effective for oleophobizing and hydrophobizing textiles is an aqueous anionic dispersion which comprises water and(A) 5 to 25% by weight of a reaction product which contains at least one bis-(2-fluoroalkyl-ethoxy-carbonylamino)-toluene of the formula ##STR1## wherein n is a number from 5 to 15 and Y is --H or --F, and wherein said reaction product is prepared by reacting 2-perfluoroalkylethanol of the formulaYCF.sub.2 --(CF.sub.2).sub.n --CH.sub.2 CH.sub.2 OH with tolylene diisocyanate in a molar ratio of (1.8 to 2):1 in the presence of 2 to 5% by weight of N-methylpyrrolidone, relative to the perfluoroalkylethanol,(B) 1 to 14% by weight of at least one emulsifier of the formulaYCF.sub.2 (CF.sub.2).sub.p --CH.sub.2 CH.sub.2 O--CO--NH--CH.sub.2 CH.sub.2 --SSO.sub.3 X wherein p is a number from 5 to 15, Y is --H or --F, and X is a monovalent cation,(C) 1 to 14% by weight of at least one nonionic emulsifier of the formulaYCF.sub.2 --(CF.sub.2).sub.q --CH.sub.2 CH.sub.2 --(OCH.sub.2 CH.sub.2).sub.r --OH wherein Y is --H or --F, q is a number from 5 to 15, r is a number from 0 to 10, and(D) 5 to 30% by weight of a solvent or solvent mixture, with the proviso that the sum of the amounts of components (B) and (C) is 2 to 15%.
摘要翻译：用于疏油和疏水化纺织品的试剂是水性阴离子分散体，其包含水和（A）5至25重量％的反应产物，其含有至少一种双（2-氟烷基 - 乙氧基 - 羰基氨基） - 甲苯其中n为5至15的数，Y为-H或-F，并且其中所述反应产物通过使式YCF2-（CF2）n的2-全氟烷基乙醇反应来制备，其中所述反应产物是通过使式YCF2（CF2）nCH2CH2OCO + -CH 2 CH 2 OH与甲苯二异氰酸酯的摩尔比为（1.8至2）：1，相对于全氟烷基乙醇为2至5重量％的N-甲基吡咯烷酮，（B）1至14重量％的至少一种式中YCF2（CF2）p-CH2CH2O-CO-NH-CH2CH2-SSO3X的乳化剂，其中p为5至15的数，Y为-H或-F，X为单价阳离子，（C）1至14 重量％的至少一种式YCF2-（CF2）q-CH2CH2-（OCH2CH2）r-OH的非离子乳化剂，其中Y为-H或-F，q为5至15的数，r为 0〜10，（ D）5至30重量％的溶剂或溶剂混合物，条件是组分（B）和（C）的量的总和为2至15％。

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