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71. 发明授权

US08426509B2 Thermoplastic fluoropolymer composition 有权
标题翻译：热塑性氟聚合物组合物
公开(公告)号：US08426509B2
公开(公告)日：2013-04-23
申请号：US11995428
申请日：2006-06-27
申请人： Julio A. Abusleme , Giulo Brinati , Pier Antonio Guarda
发明人： Julio A. Abusleme , Giulo Brinati , Pier Antonio Guarda
IPC分类号： C08K5/06 , C08L27/16 , C08L27/18
CPC分类号： C08L27/16 , C08L27/18 , C08L71/00 , C08L2205/02 , C08L2205/03 , C08L2666/02 , C08L2666/14
摘要： The invention pertains to a thermoplastic fluoropolymer composition comprising: at least one thermoplastic partially fluorinated fluoropolymer having a melt flow index (MFI) of less than 10 g/10 min, as measured according to ASTM D-1238 under a piston load of 5 kg polymer A; from 0.05 to 5% by weight of A at least one (per)fluoropolyether, polymer B; and from 0 to 10% by weight of A of at least one per(halo)fluoropolymer polymer C. The addition of a (per)fluoropolyether B and, optionally, of a per(halo)fluoropolymer C advantageously enables improvement of rheological behavior of thermoplastic partially fluorinated fluoropolymer A, making possible processing in less severe conditions and yielding final parts with outstanding surface aspect and good homogeneity and coherency. Still objects of the inventions are the process for manufacturing said thermoplastic fluoropolymer composition and the articles thereof.
摘要翻译：本发明涉及一种热塑性含氟聚合物组合物，其包含：至少一种热塑性部分氟化含氟聚合物，其熔体流动指数（MFI）小于10g / 10min，根据ASTM D-1238在5kg聚合物的活塞负荷下测量一个; 0.05至5重量％的A至少一个（全）氟聚醚，聚合物B; 和0至10重量％的至少一个每（卤素）含氟聚合物C的A。加入（全）氟聚醚B和任选的全（卤）氟聚合物C有利地可以改善流变行为热塑性部分氟化氟聚合物A，使得在较不严格的条件下可能的处理并产生具有突出的表面方面和良好的均匀性和一致性的最终部件。本发明的另一个目的是制造所述热塑性含氟聚合物组合物及其制品的方法。

72. 发明授权

US08217119B2 Additives for halopolymers 有权
标题翻译：卤代烃添加剂
公开(公告)号：US08217119B2
公开(公告)日：2012-07-10
申请号：US12516086
申请日：2007-11-26
申请人： Julio A. Abusleme , Marco Avataneo , Giancarlo Perfetti
发明人： Julio A. Abusleme , Marco Avataneo , Giancarlo Perfetti
IPC分类号： C08L27/00 , C08L23/00
CPC分类号： C08L23/0892 , C08L23/00 , C08L27/00 , C08L51/08 , C08L53/00 , C08L71/02 , C08L2666/24 , C08L2666/22
摘要： Polymeric compositions comprising: 1) at least one thermoprocessable semicrystalline halo-polymer; 2) an additive in amounts between 0.01 and 10% by weight of 1) one or more (per)fluoropolyether polymers of formula: Q-O-[A-B]z-[A-B′]z′-A-Q′ (I) wherein: A=—(X)a—O-A′-(X′)b— wherein A′ is a perfluoropolyether chain; X, X′=—CF2—, —CF2CF2—, —CF(CF3)—; a, b=0 or 1; B derives from one or more olefins, of which at least one homopolymerizable by radical way, of formula: —[(CR1R2—CR3R4)j(CR5R6—CR7R8)j′]— (Ia) wherein j=1-30, j′=0-29, with the proviso that 2
摘要翻译：聚合物组合物包括：1）至少一种热可加工半结晶卤代聚合物; 2）0.01重量％至10重量％的添加剂，1）一种或多种式（QO- [AB] z- [AB'] z'-AQ'（I）的（全）氟聚醚聚合物，其中：A = - （X）a-OA' - （X'）b-其中A'是全氟聚醚链; X，X'= -CF 2 - ， - CF 2 CF 2 - ， - CF（CF 3） - ; a，b = 0或1; B衍生自一种或多种烯烃，其中至少一种可通过自由基方式可通过以下通式共聚合： - [（CR1R2-CR3R4）j（CR5R6-CR7R8）j'] - （Ia）其中j = 1-30，j' = 0-29，条件是2 <（j + j'）<30; R 1 -R 8 =卤素，H，C 1 -C 6（全）卤代烷基，C 1 -C 6烷基或C 1 -C 6氧基（全）氟烷基; B'=（Ia），但R 1 -R 8中的至少一个具有与B不同的含义，并且2＆nlE;（j + j'）<30; z≥2; z'为0或整数; z，z'使得（I）的数均分子量在500和500,000之间; Q，Q'= C1-C3全氟烷基; C1-C6烷基; 或功能性端基。

73. 发明申请

US20090171004A1 Thermoplastic Halopolymer Composition 有权
标题翻译：热塑性聚合物组合物
公开(公告)号：US20090171004A1
公开(公告)日：2009-07-02
申请号：US11995374
申请日：2006-06-27
申请人： Julio A. Abusleme , Giulio Brinati , Pier Antonio Guarda
发明人： Julio A. Abusleme , Giulio Brinati , Pier Antonio Guarda
IPC分类号： C08L27/12
CPC分类号： C08L27/16 , C08L27/18 , C08L71/00 , C08L2205/02 , C08L2205/03 , C08L2666/02
摘要： The invention pertains to a thermoplastic fluoropolymer composition comprising: at least one thermoplastic partially fluorinated fluoropolymer having a melt flow index (MFI) of less than 10 g/10 min, as measured according to ASTM D-1238 under a piston load of 5 kg polymer A; from 0.05 to 5% by weight of A at least one (per)fluoropolyether, polymer B; and from 0 to 10% by weight of A of at least one per(halo)fluoropolymer polymer C. The addition of a (per)fluoropolyether B and, optionally, of a per(halo)fluoropolymer C advantageously enables improvement of rheological behavior of thermoplastic partially fluorinated fluoropolymer A, making possible processing in less severe conditions and yielding final parts with outstanding surface aspect and good homogeneity and coherency. Still objects of the inventions are the process for manufacturing said thermoplastic fluoropolymer composition and the articles thereof.
摘要翻译：本发明涉及一种热塑性含氟聚合物组合物，其包含：至少一种热塑性部分氟化含氟聚合物，其熔体流动指数（MFI）小于10g / 10min，根据ASTM D-1238在5kg聚合物的活塞负荷下测量一个; 0.05至5重量％的A至少一个（全）氟聚醚，聚合物B; 和0至10重量％的至少一个每（卤素）含氟聚合物C的A。加入（全）氟聚醚B和任选的全（卤）氟聚合物C有利地可以改善流变行为热塑性部分氟化氟聚合物A，使得在较不严格的条件下可能的处理并产生具有突出的表面方面和良好的均匀性和一致性的最终部件。本发明的另一个目的是制造所述热塑性含氟聚合物组合物及其制品的方法。

74. 发明授权

US07381463B2 Metal substrates coated with fluoropolymers 有权
标题翻译：用氟聚合物涂覆的金属基材
公开(公告)号：US07381463B2
公开(公告)日：2008-06-03
申请号：US10208809
申请日：2002-08-01
申请人： Julio A. Abusleme , Giambattista Besana , Claudia Manzoni
发明人： Julio A. Abusleme , Giambattista Besana , Claudia Manzoni
IPC分类号： B32B15/08 , B32B27/20 , B32B27/28
CPC分类号： C09D127/12 , Y10T428/26 , Y10T428/3154 , Y10T428/31678 , Y10T428/31699
摘要： Metal substrates having a coating based on ethylene/chlorotrifluoroethylene (E/CTFE) having a TmII of 230° C.-264° C. and a MFI lower than 5 g/10′.
摘要翻译：金属基材具有基于乙烯/三氟氯乙烯（E / CTFE）的涂层，其具有230℃-264℃的T分子量和低于5克/ 10升的MFI。

75. 发明授权

US07262226B2 CTFE-based thermoprocessable compositions 有权
标题翻译：基于CTFE的热处理组合物
公开(公告)号：US07262226B2
公开(公告)日：2007-08-28
申请号：US10814339
申请日：2004-04-01
申请人： Julio A. Abusleme , Claudia Manzoni , Mattia Bassi
发明人： Julio A. Abusleme , Claudia Manzoni , Mattia Bassi
IPC分类号： C08J9/00 , C08F259/08
CPC分类号： C08J9/0061 , C08F259/08 , C08J2327/12 , C08J2427/00 , C08L27/12 , C08L27/18 , H01B3/441 , H01B3/443 , C08L2666/04
摘要： A thermoprocessable polymeric composition formed by ethylene/chlorotrifluoroethylene copolymers containing from 0.5 to 20% by moles of ethylene, optionally in combination with the chlorotrifluoroethylene homopolymer, wherein the composition contains in total from 90 to 99.5% by moles of chlorotrifluoroethylene and from 0.5-10% by moles of ethylene; said polymeric composition having a second melting temperature (TmII) higher than 185° C., preferably higher than 200° C.
摘要翻译：由乙烯/氯三氟乙烯共聚物形成的热可加工聚合物组合物，其含有0.5至20摩尔％的乙烯，任选与氯三氟乙烯均聚物组合，其中组合物含有总共90-99.5摩尔％的三氟氯乙烯和0.5-10％摩尔的乙烯; 所述聚合物组合物具有高于185℃，优选高于200℃的第二熔融温度（℃）。

76. 发明授权

US06476150B1 Crosslinkable modified fluorinated polymers 有权
标题翻译：可交联改性氟化聚合物
公开(公告)号：US06476150B1
公开(公告)日：2002-11-05
申请号：US09528198
申请日：2000-03-17
申请人： Julio A. Abusleme , Giambattista Besana , Giandomenico Vita
发明人： Julio A. Abusleme , Giambattista Besana , Giandomenico Vita
IPC分类号： C08J324
CPC分类号： C08K5/0025 , C08L27/12
摘要： The present invention is related to melt-processable thermally crosslinkable compositions consisting of I) thermoprocessable copolymers of ethylene (E) with tetrafluoroethylene (TFE) and/or chlorotrifluoroethylene (CTFE), and acrylic monomers of formula CH2═CH—CO—O—R2 (a); and II) one or more crosslinking agents.
摘要翻译：本发明涉及由I）乙烯（E）与四氟乙烯（TFE）和/或一氯三氟乙烯（CTFE）的热可加工共聚物和式CH 2 = CH-CO-O-R 2的丙烯酸单体组成的可熔融加工的热交联组合物（一个）; 和II）一种或多种交联剂。

77. 发明授权

US06417279B2 Thermoplastic fluorinated polymers 失效
标题翻译：热塑性氟化聚合物
公开(公告)号：US06417279B2
公开(公告)日：2002-07-09
申请号：US09781218
申请日：2001-02-13
申请人： Julio A. Abusleme , Claudia Manzoni
发明人： Julio A. Abusleme , Claudia Manzoni
IPC分类号： C08L2712
CPC分类号： C08L27/12 , C08L2205/02 , C08L2666/04
摘要： A composition comprising a polymer mixture A of polymers formed by: (a) from 10 to 70% by moles of ethylene (E), (b) from 30 to 90%, by moles of a fluorinated monomer selected from tetrafluoroethylene (TFE), chlorotrifluoroethylene (CTFE), or mixtures thereof, (c) from 0.1 to 30% by moles, with respect to the total amount of monomers (a) and (b), of one or more acrylic monomers; characterized in that the polymer mixture A comprises polymer fractions having a different content of the acrylic comonomer such that the elastic modulus at 23° C. (ASTM D1708) of said polymer mixture A is lower than at least 10% of the elastic modulus of a polymer formed by monomers a), b) and c) wherein the polymer fractions have substantially an equal content of the acrylic comonomer.
摘要翻译：一种组合物，其包含通过以下形成的聚合物混合物A：（a）10至70摩尔％的乙烯（E），（b）30至90摩尔的选自四氟乙烯（TFE），氯三氟乙烯（CTFE）或其混合物，（c）相对于单体（a）和（b）的总量为0.1至30摩尔％的一种或多种丙烯酸类单体;其特征在于，聚合物混合物A 包括具有不同含量的丙烯酸共聚单体的聚合物级分，使得所述聚合物混合物A的23℃下的弹性模量（ASTM D1708）低于由单体a）形成的聚合物的弹性模量的至少10％ b）和c）其中聚合物部分具有基本相等的丙烯酸共聚单体含量。

78. 发明授权

US5654263A Ternary mixtures of solvents and their use for removing oily substances 失效
标题翻译：溶剂的三元混合物及其用于去除油性物质的用途
公开(公告)号：US5654263A
公开(公告)日：1997-08-05
申请号：US547331
申请日：1995-10-24
申请人： Julio A. Abusleme , Rossella Silvani , Patrizia Maccone
发明人： Julio A. Abusleme , Rossella Silvani , Patrizia Maccone
IPC分类号： B08B3/08 , C07C31/12 , C07C43/12 , C11D1/72 , C11D3/20 , C11D3/44 , C11D7/26 , C11D7/28 , C11D7/50 , C23G5/028 , C23G5/032
CPC分类号： C11D7/261 , C11D7/5018 , C23G5/032 , C11D7/28
摘要： Ternary mixtures, particularly suitable for removing oily substances having both an hyrogenated and fluorinated or mixed basis, essentially consisting of: (a) water; (b) terbutanol; (c) a fluoropolyoxyalkylene having hydrogenated end groups and/or hydrogenated repetitive units. Such mixtures have high flash point, are non toxic and with null depleting potential of the ozone and show a ternary diagram characterized by a wide monophasic zone, wherein the three components form limpid and stable solutions.
摘要翻译：三元混合物，特别适用于除去具有氢化和氟化或混合的基础的油性物质，基本上由以下组成：（a）水; （b）叔丁醇; （c）具有氢化端基和/或氢化重复单元的氟代聚氧化烯。这样的混合物具有高闪点，无毒，臭氧消耗潜力低，并且显示出以宽单相区为特征的三元图，其中三种组分形成清澈和稳定的溶液。

79. 发明授权

US5516863A (Co)polymerization process in aqueous emulsion of fluorinated olefinic monomers 失效
标题翻译：（Co）聚合方法在氟化烯烃单体的水乳液中
公开(公告)号：US5516863A
公开(公告)日：1996-05-14
申请号：US516685
申请日：1995-08-18
申请人： Julio A. Abusleme , Patrizia Maccone , Pasqua Colaianna
发明人： Julio A. Abusleme , Patrizia Maccone , Pasqua Colaianna
IPC分类号： C08F214/18 , C08F2/22 , C08F2/24 , C08F2/38 , C08F14/18 , C08F2/00
CPC分类号： C08F14/18 , C08F2438/01
摘要： Radical (co)polymerization process of fluorinated olefinic monomers, optionally in association with one or more non-fluorinated olefins, in which the monomers are (co)polymerized in aqueous emulsion, in the presence of a hydrogenated chain transfer agent selected from hydrogen, aliphatic hydrocarbons and fluorohydrocarbons C.sub.1 -C.sub.20 and of a branched chain aliphatic alcohol C.sub.3 -C.sub.12 characterized by a ratio between the number of hydroxyl groups and the number of methyl groups lower than or equal to 0.5.
摘要翻译：氟化烯烃单体的自由基（共）聚合方法，任选与一种或多种非氟化烯烃缔合，其中单体在水乳液中共聚合，在氢化链转移剂存在下，选自氢，脂族碳氢化合物和氟代烃C1-C20和支链脂族醇C3-C12，其特征在于羟基数与甲基数之比小于或等于0.5。

80. 发明授权

US5498682A Perfluorodioxoles, the preparation process thereof, and homopolymers and copolymers obtained therefrom 失效
公开(公告)号：US5498682A
公开(公告)日：1996-03-12
申请号：US270149
申请日：1994-07-01
申请人： Walter Navarrini , Vito Tortelli , Pasqua Colaianna , Julio A. Abusleme
发明人： Walter Navarrini , Vito Tortelli , Pasqua Colaianna , Julio A. Abusleme
IPC分类号： C07D317/42 , C08F34/00 , C08F34/02 , C08F134/02 , C08F214/26 , C08F234/02 , C10M107/24 , C10N50/10 , C08F14/18
CPC分类号： C07D317/42 , C08F214/262 , C08F2438/01
摘要： The invention relates to new thermoprocessable copolymers of tetrafluoroethylene constituted by perfluoromethylvinylether (0.5-13% by weight), a fluorinated dioxole (0.05-3%) and tetrafluoroethylene (difference to 100%), particularly useful for coating electric cables by melt extrusion. It relates also to new perfluorodioxoles of formula ##STR1## wherein R.sub.F is a C.sub.1 -C.sub.5 perfluoroalkyl radical; X.sub.1 and X.sub.2 are, independently from each other, F or CF.sub.3 ; and their homopolymers and copolymers, in particular thermoprocessable copolymers as defined above.

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