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1. 发明申请

US20090203830A1 Thermoplastic Fluoropolymer Composition 有权
标题翻译：热塑性氟聚合物组合物
公开(公告)号：US20090203830A1
公开(公告)日：2009-08-13
申请号：US11995428
申请日：2006-06-27
申请人： Julio A. Abusleme , Giulio Brinati , Pier Antonio Guarda
发明人： Julio A. Abusleme , Giulio Brinati , Pier Antonio Guarda
IPC分类号： C08L27/20 , C08L27/14 , C08L27/18
CPC分类号： C08L27/16 , C08L27/18 , C08L71/00 , C08L2205/02 , C08L2205/03 , C08L2666/02 , C08L2666/14
摘要： The invention pertains to a thermoplastic fluoropolymer composition comprising: at least one thermoplastic partially fluorinated fluoropolymer having a melt flow index (MFI) of less than 10 g/10 min. as measured according to ASTM D-1238 under a piston load of 5 kg polymer A; from 0.05 to 5% by weight of A at least one (per)fluoropolyether, polymer B; and from 0 to 10% by weight of A of at least one per(halo)fluoropolymer polymer C. The addition of a (per)fluoropolyether B and, optionally, of a per(halo) fluoropolymer C advantageously enables improvement of rheological behavior of thermoplastic partially fluorinated fluoropolymer A, making possible processing in less severe conditions and yielding final parts with outstanding surface aspect and good homogeneity and coherency. Still objects of the inventions are the process for manufacturing said thermoplastic fluoropolymer composition and the articles thereof.
摘要翻译：本发明涉及一种热塑性含氟聚合物组合物，其包含：至少一种热塑性部分氟化含氟聚合物，其熔体流动指数（MFI）小于10g / 10min。根据ASTM D-1238在5kg聚合物A的活塞负载下测量; 0.05至5重量％的A至少一个（全）氟聚醚，聚合物B; 和0至10重量％的至少一个每（卤素）含氟聚合物C的A。加入（全）氟聚醚B和任选的全（卤）氟聚合物C有利地可以改善流变行为热塑性部分氟化氟聚合物A，使得在较不严格的条件下可能的处理并产生具有突出的表面方面和良好的均匀性和一致性的最终部件。本发明的另一个目的是制造所述热塑性含氟聚合物组合物及其制品的方法。

2. 发明申请

US20090171004A1 Thermoplastic Halopolymer Composition 有权
标题翻译：热塑性聚合物组合物
公开(公告)号：US20090171004A1
公开(公告)日：2009-07-02
申请号：US11995374
申请日：2006-06-27
申请人： Julio A. Abusleme , Giulio Brinati , Pier Antonio Guarda
发明人： Julio A. Abusleme , Giulio Brinati , Pier Antonio Guarda
IPC分类号： C08L27/12
CPC分类号： C08L27/16 , C08L27/18 , C08L71/00 , C08L2205/02 , C08L2205/03 , C08L2666/02
摘要： The invention pertains to a thermoplastic fluoropolymer composition comprising: at least one thermoplastic partially fluorinated fluoropolymer having a melt flow index (MFI) of less than 10 g/10 min, as measured according to ASTM D-1238 under a piston load of 5 kg polymer A; from 0.05 to 5% by weight of A at least one (per)fluoropolyether, polymer B; and from 0 to 10% by weight of A of at least one per(halo)fluoropolymer polymer C. The addition of a (per)fluoropolyether B and, optionally, of a per(halo)fluoropolymer C advantageously enables improvement of rheological behavior of thermoplastic partially fluorinated fluoropolymer A, making possible processing in less severe conditions and yielding final parts with outstanding surface aspect and good homogeneity and coherency. Still objects of the inventions are the process for manufacturing said thermoplastic fluoropolymer composition and the articles thereof.
摘要翻译：本发明涉及一种热塑性含氟聚合物组合物，其包含：至少一种热塑性部分氟化含氟聚合物，其熔体流动指数（MFI）小于10g / 10min，根据ASTM D-1238在5kg聚合物的活塞负荷下测量一个; 0.05至5重量％的A至少一个（全）氟聚醚，聚合物B; 和0至10重量％的至少一个每（卤素）含氟聚合物C的A。加入（全）氟聚醚B和任选的全（卤）氟聚合物C有利地可以改善流变行为热塑性部分氟化氟聚合物A，使得在较不严格的条件下可能的处理并产生具有突出的表面方面和良好的均匀性和一致性的最终部件。本发明的另一个目的是制造所述热塑性含氟聚合物组合物及其制品的方法。

3. 发明授权

US6096795A (CO) polymerization process of fluorinated olefinic monomers in aqueous emulsion 失效
标题翻译：（CO）聚合方法
公开(公告)号：US6096795A
公开(公告)日：2000-08-01
申请号：US772865
申请日：1996-12-26
申请人： Julio A. Abusleme , Pier Antonio Guarda , Ralph J. De Pasquale
发明人： Julio A. Abusleme , Pier Antonio Guarda , Ralph J. De Pasquale
IPC分类号： C08F2/24 , C08F2/50 , C08J3/28
CPC分类号： C08F2/24 , C08F2/50 , C08J3/28
摘要： This invention relates fluorinated polymers having high structural regularity, characterized by a high maximum operating temperature and by improved mechanical and processability properties, prepared by a (co)polymerization process of fluorinated olefinic monomers, optionally in association with non-fluorinated olefins, in aqueous emulsion, in the presence of radical photoinitiators and of ultraviolet-visible radiation.
摘要翻译：本发明涉及具有高结构规整性的氟化聚合物，其特征在于最高工作温度和通过改进的机械和加工性能，其通过氟化烯烃单体（任选与非氟化烯烃缔合）在水乳液中的（共）聚合方法制备在存在自由基光引发剂和紫外 - 可见辐射的情况下。

4. 发明授权

US08399565B2 Thermoplastic halopolymer composition 有权
标题翻译：热塑性卤代聚合物组合物
公开(公告)号：US08399565B2
公开(公告)日：2013-03-19
申请号：US11995374
申请日：2006-06-27
申请人： Julio A. Abusleme , Giulo Brinati , Pier Antonio Guarda
发明人： Julio A. Abusleme , Giulo Brinati , Pier Antonio Guarda
IPC分类号： C08F214/26 , C08L27/16
CPC分类号： C08L27/16 , C08L27/18 , C08L71/00 , C08L2205/02 , C08L2205/03 , C08L2666/02
摘要： The invention pertains to a thermoplastic fluoropolymer composition comprising: at least one thermoplastic partially fluorinated fluoropolymer having a melt flow index (MFI) of less than 10 g/10 min, as measured according to ASTM D-1238 under a piston load of 5 kg polymer A; from 0.05 to 5% by weight of A at least one (per)fluoropolyether, polymer B; and from 0 to 10% by weight of A of at least one per(halo)fluoropolymer polymer C. The addition of a (per)fluoropolyether B and, optionally, of a per(halo)fluoropolymer C advantageously enables improvement of rheological behavior of thermoplastic partially fluorinated fluoropolymer A, making possible processing in less severe conditions and yielding final parts with outstanding surface aspect and good homogeneity and coherency. Still objects of the inventions are the process for manufacturing said thermoplastic fluoropolymer composition and the articles thereof.
摘要翻译：本发明涉及一种热塑性含氟聚合物组合物，其包含：至少一种热塑性部分氟化含氟聚合物，其熔体流动指数（MFI）小于10g / 10min，根据ASTM D-1238在5kg聚合物的活塞负荷下测量一个; 0.05至5重量％的A至少一个（全）氟聚醚，聚合物B; 和0至10重量％的至少一个每（卤素）含氟聚合物C的A。加入（全）氟聚醚B和任选的全（卤）氟聚合物C有利地可以改善流变行为热塑性部分氟化氟聚合物A，使得在较不严格的条件下可能的处理并产生具有突出的表面方面和良好的均匀性和一致性的最终部件。本发明的另一个目的是制造所述热塑性含氟聚合物组合物及其制品的方法。

5. 发明授权

US5688838A Process for preparing hydrogen-containing fluoropolymers by suspension (co)polymerization 失效
标题翻译：通过悬浮（共）聚合制备含氢含氟聚合物的方法
公开(公告)号：US5688838A
公开(公告)日：1997-11-18
申请号：US508926
申请日：1995-07-28
申请人： Julio A. Abusleme , Pier Antonio Guarda , Ralph De Pasquale
发明人： Julio A. Abusleme , Pier Antonio Guarda , Ralph De Pasquale
IPC分类号： C08F14/24 , C08F2/18 , C08F2/48 , C08F2/50 , C08F14/00 , C08F14/18 , C08F14/26 , C08F210/02 , C08F2/46
CPC分类号： C08F14/18 , C08F210/02
摘要： Process for preparing hydrogen-containing fluoropolymers, wherein the corresponding olefinic monomers are (co) polymerized in an organic suspending medium in the presence of a radical photoinitiator and of ultraviolet-visible radiation at a temperature of from -60.degree. C. to +30.degree. C. Hydrogen-containing fluoropolymers are thus obtained having high second melting temperature and high maximum operating temperature, using as initiators non-hazardous products, which can be easily handled and kept also at room temperature.
摘要翻译：制备含氢含氟聚合物的方法，其中相应的烯属单体在有机悬浮介质中在自由基光引发剂的存在下和在-60℃至+ 30℃的温度下进行紫外 - 可见辐射（共）聚合因此，使用具有高的第二熔解温度和高的最高工作温度的含氢的含氟聚合物作为引发剂非危险产品，其可以容易地在室温下处理和保存。

6. 发明授权

US08426509B2 Thermoplastic fluoropolymer composition 有权
标题翻译：热塑性氟聚合物组合物
公开(公告)号：US08426509B2
公开(公告)日：2013-04-23
申请号：US11995428
申请日：2006-06-27
申请人： Julio A. Abusleme , Giulo Brinati , Pier Antonio Guarda
发明人： Julio A. Abusleme , Giulo Brinati , Pier Antonio Guarda
IPC分类号： C08K5/06 , C08L27/16 , C08L27/18
CPC分类号： C08L27/16 , C08L27/18 , C08L71/00 , C08L2205/02 , C08L2205/03 , C08L2666/02 , C08L2666/14
摘要： The invention pertains to a thermoplastic fluoropolymer composition comprising: at least one thermoplastic partially fluorinated fluoropolymer having a melt flow index (MFI) of less than 10 g/10 min, as measured according to ASTM D-1238 under a piston load of 5 kg polymer A; from 0.05 to 5% by weight of A at least one (per)fluoropolyether, polymer B; and from 0 to 10% by weight of A of at least one per(halo)fluoropolymer polymer C. The addition of a (per)fluoropolyether B and, optionally, of a per(halo)fluoropolymer C advantageously enables improvement of rheological behavior of thermoplastic partially fluorinated fluoropolymer A, making possible processing in less severe conditions and yielding final parts with outstanding surface aspect and good homogeneity and coherency. Still objects of the inventions are the process for manufacturing said thermoplastic fluoropolymer composition and the articles thereof.
摘要翻译：本发明涉及一种热塑性含氟聚合物组合物，其包含：至少一种热塑性部分氟化含氟聚合物，其熔体流动指数（MFI）小于10g / 10min，根据ASTM D-1238在5kg聚合物的活塞负荷下测量一个; 0.05至5重量％的A至少一个（全）氟聚醚，聚合物B; 和0至10重量％的至少一个每（卤素）含氟聚合物C的A。加入（全）氟聚醚B和任选的全（卤）氟聚合物C有利地可以改善流变行为热塑性部分氟化氟聚合物A，使得在较不严格的条件下可能的处理并产生具有突出的表面方面和良好的均匀性和一致性的最终部件。本发明的另一个目的是制造所述热塑性含氟聚合物组合物及其制品的方法。

7. 发明授权

US09568250B2 Method for transferring heat 有权
标题翻译：传热方法
公开(公告)号：US09568250B2
公开(公告)日：2017-02-14
申请号：US13820781
申请日：2011-09-08
申请人： Pier Antonio Guarda , Gianfranco Spataro , Vincent Pierre Meunier
发明人： Pier Antonio Guarda , Gianfranco Spataro , Vincent Pierre Meunier
IPC分类号： F28D15/00 , C09K5/10
CPC分类号： F28D15/00 , C09K5/10
摘要： A process for transferring heat comprising the following steps: (1) transferring heat from a body to a first heat transfer system by means of a secondary loop passageway comprising a heat transfer fluid and, optionally, (2) transferring heat from a second heat transfer system to said body by means of said secondary loop passageway comprising said heat transfer fluid, wherein: said second heat transfer system being the same as or different from said first heat transfer system, said secondary loop passageway comprises at least one polymer sealant selected from a rubber seal and a plastic pipe; and said heat transfer fluid comprises one or more linear perfluoropolyethers having formula RF—(OCF2)n(OCF2CF2)m(OCF2(CF2)zCF2)p—ORF (I), wherein RF, equal or different at each occurrence, is a C1-C3 perfluoroalkyl group, m, n and p, equal to or different from each other, are integers comprised between 0 and 100, the sum m+n being higher than 0, and z is equal to 1 or 2, and wherein said heat transfer fluid is circulated through said secondary loop passageway in step (1) for transferring said heat from said body to said first heat transfer system and, optionally, in step (2) for transferring said heat from said second heat transfer system to said body.
摘要翻译：一种用于传递热量的方法，包括以下步骤：（1）借助于包括传热流体的二次回路通道和（2）从第二传热系统传递热量将热量从机体传递到第一传热系统系统通过包括所述传热流体的所述次级回路通道连接到所述主体，其中：所述第二传热系统与所述第一传热系统相同或不同，所述次级回路通道包括至少一种聚合物密封剂，其选自橡胶密封和塑料管; 并且所述传热流体包含具有式RF-（OCF 2）n（OCF 2 CF 2）m（OCF 2（CF 2）z CF 2）p-ORF（I）的一个或多个线性全氟聚醚，其中每次出现相等或不同的RF是C1 -C 3全氟烷基，m，n和p彼此相同或不同，为0〜100之间的整数，总和m + n高于0，z等于1或2，其中所述热传递流体在步骤（1）中循环通过所述次级回路通道，用于将所述热量从所述主体转移到所述第一传热系统，并且可选地在步骤（2）中用于将所述热量从所述第二传热系统转移到所述主体。

8. 发明授权

US08557952B2 Polyfunctional (per)fluoropolyethers 有权
标题翻译：多官能（全）氟聚醚
公开(公告)号：US08557952B2
公开(公告)日：2013-10-15
申请号：US13131240
申请日：2009-12-02
申请人： Giuseppe Marchionni , Silvia Petricci , Pier Antonio Guarda
发明人： Giuseppe Marchionni , Silvia Petricci , Pier Antonio Guarda
IPC分类号： C08G75/00 , C08G73/00
CPC分类号： C08G65/007
摘要： The invention pertains to novel (per)fluoropolyethers comprising at least one (per)fluoropolyoxyalkylene chain (chain Rf) comprising at least one recurring unit (R2) having formula: CF2—CF(CF2OSO2F)—O— (poly(fluorosulfate) PFPE) to a process for their manufacture, and to their use for providing functional (per)fluoropolyethers.
摘要翻译：本发明涉及包含至少一种（全）氟聚氧化烯链（链Rf）的新型（全）氟聚醚，其包含至少一个具有式CF 2 CF（CF 2 OSO 2 F）-O-（聚（氟硫酸酯）PFPE）的重复单元（R2）涉及其制造方法及其用于提供功能性（全）氟聚醚的用途。

9. 发明申请

US20130244131A1 Fuel cell modules 审中-公开
标题翻译：燃料电池模块
公开(公告)号：US20130244131A1
公开(公告)日：2013-09-19
申请号：US13989283
申请日：2011-11-28
申请人： Vincenzo Arcella , Giuseppe Marchionni , Ugo De Patto , Pier Antonio Guarda
发明人： Vincenzo Arcella , Giuseppe Marchionni , Ugo De Patto , Pier Antonio Guarda
IPC分类号： H01M8/10
CPC分类号： H01M8/1006 , H01M8/0232 , H01M8/0254 , H01M8/1004 , H01M2008/1095
摘要： A method for the preparation of corrugated fuel cell units from a composite laminate comprising an ion conductive membrane having first and second surface; a first electrocatalyst layer in contact with the first surface of the membrane; a second electrocatalyst layer in contact with the second surface of the membrane; a first metallic mesh in contact with said first electrocatalyst layer and a second metallic mesh in contact with said second electrocatalyst layer.
摘要翻译：一种由复合层压制备波纹燃料电池单元的方法，包括具有第一和第二表面的离子传导膜; 与膜的第一表面接触的第一电催化剂层; 与所述膜的第二表面接触的第二电催化剂层; 与所述第一电催化剂层接触的第一金属网和与所述第二电催化剂层接触的第二金属网。

10. 发明授权

US07629483B2 Peroxidic perfluoropolyethers 有权
标题翻译：过氧化全氟聚醚
公开(公告)号：US07629483B2
公开(公告)日：2009-12-08
申请号：US12099293
申请日：2008-04-08
申请人： Giuseppe Marchionni , Pier Antonio Guarda
发明人： Giuseppe Marchionni , Pier Antonio Guarda
IPC分类号： C07C309/06
CPC分类号： C08G65/32 , C08G65/007
摘要： Peroxidic perfluoropolyethers having formula: X1—O(CF2O)n1(CF2CF2O)m1(CF2(CF2)zCF2O)p1(O)h—X2 (I) wherein: X1 and X2, equal to or different from each other, are chain end groups selected among —CF2COF, —COF, —SO2F; n1, m1, p1 and h are integers such that the number average molecular weight is in the range 700-100,000; z=1 or 2; with the proviso that: the m1/n1 ratio is between 0.2 and 10; the p1/(n1+m1) ratio is lower than 0.05; the h/(n1+m1+p1) ratio is such that the PO content, defined as grams of active oxygen/100 g of compound, is in the range 0.8-4.5, preferably 1.4-3.8; the perfluorooxyalkylene units being statistically distributed along the polymeric chain.
摘要翻译：具有式：X1-O（CF2O）n1（CF2CF2O）m1（CF2（CF2）zCF2O）p1（O）h-X2（I）的过氧化全氟聚醚其中：X 1和X 2彼此相同或不同，为链末端 -CF 2 COF，-COF，-SO 2 F中选择的基团; n1，m1，p1和h是数均分子量在700-100,000范围内的整数; z = 1或2; 条件是：m1 / n1比在0.2和10之间; p1 /（n1 + m1）比低于0.05; h /（n1 + m1 + p1）的比例使得定义为活性氧克数/ 100g化合物的PO含量在0.8-4.5，优选1.4-3.8的范围内; 全氟氧化烯单元沿着聚合物链统计分布。

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