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1. 发明申请

US20120177987A1 Composition of a Fluorinated Organic Carbonate and a Lewis Acid 审中-公开
标题翻译：氟化有机碳酸酯和路易斯酸的组成
公开(公告)号：US20120177987A1
公开(公告)日：2012-07-12
申请号：US13497333
申请日：2010-09-27
申请人： Jens Olschimke , Martin Bomkamp , Andreas Grossmann
发明人： Jens Olschimke , Martin Bomkamp , Andreas Grossmann
IPC分类号： H01M10/02 , C09K3/00
CPC分类号： C07D317/36 , C07D317/42
摘要： A method for handling fluorinated organic carbonates such that degradation reactions are minimized or even completely suppressed and hence initial purity of fluorinated organic carbonates is essentially maintained during handling. Compositions comprising a fluorinated organic carbonate with improved stability against degradation reactions. The compositions comprise equal to or less than 500 ppm of a Lewis acid.
摘要翻译：一种处理含氟有机碳酸酯的方法，使得降解反应被最小化或甚至完全抑制，因此氟化有机碳酸酯的初始纯度在处理过程中基本保持。包含具有改善的降解反应稳定性的含氟有机碳酸酯的组合物。所述组合物包含等于或小于500ppm的路易斯酸。

2. 发明申请

US20110160415A1 Method for manufacturing fluoropolymers 有权
标题翻译：氟聚合物的制造方法
公开(公告)号：US20110160415A1
公开(公告)日：2011-06-30
申请号：US13002781
申请日：2009-07-06
申请人： Giuseppe Marchionni , Vito Tortelli , Ivan Wlassics , Valeri Kapeliouchko
发明人： Giuseppe Marchionni , Vito Tortelli , Ivan Wlassics , Valeri Kapeliouchko
IPC分类号： C08F14/26 , C07D317/42
CPC分类号： C07D317/34 , C07D317/42 , C08F14/18 , C08F114/26 , C08F2/24
摘要： The invention pertains to a method for making a fluoropolymer comprising an aqueous emulsion polymerization of one or more fluorinated monomers wherein said aqueous emulsion polymerization is carried out in the presence of at least one cyclic fluorocompound of the following formula (I): wherein X1, X2, X3, equal or different from each other are independently selected among H, F, and C1-6 (per)fluoroalkyl groups, optionally comprising one or more catenary or non-catenary oxygen atoms; L represents a bond or a divalent group; RF is a divalent fluorinated C1-3 bridging group; Y is a hydrophilic function selected among anionic functionalities, cationic functionalities and non-ionic functionalities.
摘要翻译：本发明涉及一种制备含氟聚合物的方法，该方法包括一种或多种含氟单体的水乳液聚合，其中所述水乳液聚合在至少一种下式（I）的环状氟化合物的存在下进行：其中X1，X2 各自独立地选自H，F和C 1-6（全）氟烷基，任选地包含一个或多个悬链或非链状氧原子的X 3相同或不同。 L表示键或二价基团; RF是二价氟化C1-3桥联基团; Y是选自阴离子官能团，阳离子官能团和非离子官能团的亲水性功能。

3. 发明申请

US20110009660A1 Process for the removal of HF from HF containing organic carbonates 审中-公开
标题翻译：从含有机碳酸盐的HF中除去HF的方法
公开(公告)号：US20110009660A1
公开(公告)日：2011-01-13
申请号：US12933503
申请日：2009-03-26
申请人： Harald Krueger , Christoph Sommer , Alain Lambert , Phillip Schwerdt , Jens Olschimke , Dirk Seffer , Saskia Wedekind
发明人： Harald Krueger , Christoph Sommer , Alain Lambert , Phillip Schwerdt , Jens Olschimke , Dirk Seffer , Saskia Wedekind
IPC分类号： C07C68/08
CPC分类号： C07D317/42 , C07C68/08 , C07D317/36 , C07D317/38 , C07C69/96
摘要： Mixtures comprising organic carbonates, such as carbonates not substituted by fluorine, but especially fluorosubstituted organic carbonates, which are depleted in HF can be obtained from respective mixtures with a higher HF content by a step of stripping such mixture with an inert gas. For example, a reaction mixture comprising fluoroethylene carbonate and HF can be treated in this way. The mixture comprising organic carbonate which is depleted in HF can be distilled to obtain highly purified organic carbonate.
摘要翻译：通过用惰性气体汽提该混合物的步骤，可以从具有较高HF含量的各自混合物中获得包含有机碳酸酯的混合物，例如不被氟取代的碳酸酯，特别是氟代取代的有机碳酸酯。例如，可以以这种方式处理包含氟代碳酸亚乙酯和HF的反应混合物。含有HF的有机碳酸酯的混合物可以蒸馏得到高纯度的有机碳酸盐。

4. 发明授权

US07745648B2 Process for preparing 4-fluoro-1,3-dioxolan-2-one 失效
标题翻译： 4-氟-1,3-二氧戊环-2-酮的制备方法
公开(公告)号：US07745648B2
公开(公告)日：2010-06-29
申请号：US11210868
申请日：2005-08-25
申请人： Olaf Boese , Dirk Seffer , Katja Peterkord
发明人： Olaf Boese , Dirk Seffer , Katja Peterkord
IPC分类号： C07D319/06
CPC分类号： C07D317/42
摘要： A process for preparing 4-fluoro-1,3-dioxolan-2-one comprising adding 4-fluoro-1,3-dioxolan-2-one to ethylene carbonate in an amount of from 3 to 20% by weight relative to the ethylene carbonate as a solvent for the ethylene carbonate, and introducing fluorine or a mixture containing fluorine in an inert gas is introduced into the resulting solution at 15 to 45° C.
摘要翻译：一种制备4-氟-1,3-二氧戊环-2-酮的方法，包括将相对于乙烯的3-20重量％的4-氟-1,3-二氧戊环-2-酮加入碳酸亚乙酯中碳酸酯作为碳酸亚乙酯的溶剂，并将氟或含氟的混合物在惰性气体中引入所得溶液中15至45℃。

5. 发明授权

US07709665B2 Processes for producing a fluorosulfonyl group-containing compound and a compound LED from the fluorosulfonyl group-containing compound 有权
标题翻译：从含氟磺酰基的化合物制备含氟磺酰基的化合物和化合物LED的方法
公开(公告)号：US07709665B2
公开(公告)日：2010-05-04
申请号：US11829579
申请日：2007-07-27
申请人： Takashi Okazoe , Atsushi Watakabe , Masahiro Ito , Kunio Watanabe , Takeshi Eriguchi , Kimiaki Kashiwagi , Shu-zhong Wang
发明人： Takashi Okazoe , Atsushi Watakabe , Masahiro Ito , Kunio Watanabe , Takeshi Eriguchi , Kimiaki Kashiwagi , Shu-zhong Wang
IPC分类号： C07D317/00
CPC分类号： C08F24/00 , C07D317/18 , C07D317/24 , C07D317/42
摘要： A fluorosulfonyl group-containing compound having a high polymerization reactivity, a process for its production, a sulfonyl group-containing polymerizable monomer led from the sulfonyl group-containing compound, and a polymer obtainable by polymerizing the sulfonyl group-containing polymerizable monomer, are provided.A compound (3) is fluorinated to form a compound (4), and then, the compound (4) is subjected to a decomposition reaction to produce a compound (5). A preferred compound (5-1) of the compound (5) is thermally decomposed to produce a compound (7-1) having a high polymerization reactivity. wherein RA is a bivalent organic group such as a fluoroalkylene group, RAF is a group having RA fluorinated, or the same group as RA, each of RB to RD which are independent of one another, is a hydrogen atom, etc., each of RBF to RDF is a fluorine atom, etc., RE is a monovalent organic group, REF is a group having RE fluorinated, or the same group as RE, E is a bivalent connecting group, EF is the same group as E, or a group having E fluorinated, EF1 is a group formed by scission of EF, each of X1 to X3 is a hydrogen atom, etc., and each of X1F to X3F is a fluorine atom, etc.
摘要翻译：提供具有高聚合反应性的含氟磺酰基的化合物，其制备方法，由含磺酰基的化合物引发的含磺酰基的可聚合单体和通过聚合含磺酰基的可聚合单体获得的聚合物。化合物（3）被氟化以形成化合物（4），然后使化合物（4）进行分解反应以制备化合物（5）。将化合物（5）的优选化合物（5-1）热分解，得到聚合反应性高的化合物（7-1）。其中RA是二价有机基团，例如氟代亚烷基，RAF是具有RA氟化的基团，或与RA相同的基团，每个RB与RD彼此独立，为氢原子等 RBF与RDF是氟原子等，RE是一价有机基团，REF是具有RE氟化的基团，或与RE相同的基团，E是二价连接基团，EF与E相同，或者具有E氟原子的基团，EF1是通过EF的断裂形成的基团，X1〜X3各自为氢原子等，X1F〜X3F各自为氟原子等。

6. 发明申请

US20100056752A1 Fluorinated 1,3-Dioxolane Compounds, Fluorinated Polymers of the Compounds, and Optical or Electrical Materials Comprising the Polymers 有权
标题翻译：氟化1,3-二氧杂环戊烷化合物，化合物的氟化聚合物和包含聚合物的光学或电学材料
公开(公告)号：US20100056752A1
公开(公告)日：2010-03-04
申请号：US12614948
申请日：2009-11-09
申请人： Yoshiyuki Okamoto , Yasuhiro Koike
发明人： Yoshiyuki Okamoto , Yasuhiro Koike
IPC分类号： C08G65/22 , C07D317/44
CPC分类号： C07D317/46 , C07D317/42 , C07D317/44
摘要： A production method of fluorinated compounds, for producing a compound represented by formula (3) in a fluorine-based solution in a flow of fluorine gas after reaction of at least one type of compounds represented by formula (1) and at least one type of compounds represented by formula (2). Similarly, fluorinated compounds represented by formula (4) prepared by the fluorination of compounds obtained by the reaction of formula (1) and formula (2)′. The fluorinated polymers obtained by the polymerizations of formula (3) and (4) compounds are useful as an optical or electrical materials. wherein R1, R2, R3, R4, Rff1, Rff2, Rff3, Rff4, X, Y, Z, and n are defined in the specification respectively.
摘要翻译：一种含氟化合物的制备方法，用于在由式（1）表示的至少一种类型的化合物与至少一种类型的化合物反应之后的氟气流中的氟基溶液中制备由式（3）表示的化合物由式（2）表示的化合物。类似地，通过氟化通过式（1）和式（2）'的反应获得的化合物氟化制备的由式（4）表示的氟化化合物。通过式（3）和（4）化合物的聚合获得的氟化聚合物可用作光学或电气材料。其中R1，R2，R3，R4，Rff1，Rff2，Rff3，Rff4，X，Y，Z和n分别在规范中定义。

7. 发明申请

US20090082586A1 PROCESS FOR PREPARING MONOCHLOROETHYLENE CARBONATE AND SUBSEQUENT CONVERSION TO VINYLENE CARBONATE 失效
标题翻译：制备单氯乙烯碳酸酯和后续碳酸亚乙酯的方法
公开(公告)号：US20090082586A1
公开(公告)日：2009-03-26
申请号：US12236765
申请日：2008-09-24
申请人： Marco Lerm , Joerg Lotz , Klaus Stadtmueller
发明人： Marco Lerm , Joerg Lotz , Klaus Stadtmueller
IPC分类号： C07C69/96
CPC分类号： C07D317/40 , C07D317/42
摘要： Processes for preparing monochloroethylene carbonate include reacting ethylene carbonate with chlorine gas in a liquid phase under irradiation of UV light and introducing a separate feed of an inert gas into the liquid phase. Monochloroethylene carbonate may be subsequently converted to vinylene carbonate.
摘要翻译：制备单氯代亚乙基碳酸酯的方法包括在UV光照射下在液相中使碳酸亚乙酯与氯气反应，并将惰性气体的单独进料引入液相。随后可将一氯代碳酸亚乙酯转化为碳酸亚乙烯酯。

8. 发明申请

US20090048424A1 FLUOROSULFONYL GROUP-CONTAINING MONOMER AND ITS POLYMER, AND SULFONIC ACID GROUP-CONTAINING POLYMER 审中-公开
标题翻译：含氟基团的单体及其聚合物和含有磺酸基团的聚合物
公开(公告)号：US20090048424A1
公开(公告)日：2009-02-19
申请号：US12186947
申请日：2008-08-06
申请人： Atsushi WATAKABE , Hiromasa YAMAMOTO , Masao IWAYA , Susumu SAITO
发明人： Atsushi WATAKABE , Hiromasa YAMAMOTO , Masao IWAYA , Susumu SAITO
IPC分类号： C08G75/20 , C07D317/10
CPC分类号： C07D317/42 , C08G75/23
摘要： To provide a fluorosulfonyl group-containing monomer having a high polymerization reactivity and plural fluorosulfonyl groups. Further, to provide a fluorosulfonyl group-containing polymer and a sulfonic acid group-containing polymer, obtained by using the monomer.A perfluoro(2-methylene-1,3-dioxolane) derivative which is represented by the following formula (3) and which has two fluorosulfonyl groups, and its production process and its synthetic intermediate. A fluorosulfonyl group-containing polymer having monomer units represented by the following formula (3U) obtained by polymerizing the compound (3) by itself or with a comonomer, and a sulfonic acid group-containing polymer having the following units (5U) obtained by hydrolyzing a fluorosulfonyl group of the polymer. In the following formulae, each of Rf1 and Rf2 which are independent of each other, is a C1-8 perfluoroalkylene group which may have an etheric oxygen atom between carbon atoms.
摘要翻译：提供具有高聚合反应性的氟代磺酰基单体和多个氟磺酰基。此外，提供通过使用该单体获得的含氟磺酰基的聚合物和含磺酸基的聚合物。由下式（3）表示并具有两个氟磺酰基的全氟（2-亚甲基-1,3-二氧戊环）衍生物及其制备方法及其合成中间体。具有由下述通式（3U）表示的具有单体单元的含氟磺酰基的聚合物，其单独或共聚单体与共聚单体聚合得到的含有磺酸基的聚合物和通过水解聚合物的氟磺酰基。在下式中，R 1和R f 2彼此独立的是碳原子之间可以具有醚性氧原子的C1-8全氟亚烷基。

9. 发明申请

US20060194936A1 Novel fluorinated compound and fluoropolymer 审中-公开
标题翻译：新型氟化合物和含氟聚合物
公开(公告)号：US20060194936A1
公开(公告)日：2006-08-31
申请号：US11414300
申请日：2006-05-01
申请人： Takeshi Eriguchi , Takashi Okazoe , Eisuke Murotani , Masahiro Ito , Kunio Watanabe
发明人： Takeshi Eriguchi , Takashi Okazoe , Eisuke Murotani , Masahiro Ito , Kunio Watanabe
IPC分类号： C08F16/24
CPC分类号： C07D317/42 , C08F24/00 , G02B6/02033 , G02B2006/1219
摘要： The present invention provides a fluoropolymer having excellent mechanical strength and transparency, having a high glass transition point suitable for high-temperature use, and having a high refractive index. The present invention provides a novel compound represented by the following formula (1) and a fluoropolymer comprising monomer unit (2) formed by the polymerization of such a compound. RAF, RBF, RCF, RDF: each independently is a fluorine atom, a chlorine atom, a perfluoro monovalent saturated hydrocarbon group or a perfluoro(partially chlorinated monovalent saturated hydrocarbon) group, provided that at least one of RAF, RBF, RCF and RDF is a perfluoro(partially chlorinated monovalent saturated hydrocarbon) group.
摘要翻译：本发明提供一种具有优异的机械强度和透明性的氟聚合物，具有适合于高温使用的高玻璃化转变点，并具有高折射率。本发明提供由下式（1）表示的新化合物和通过这种化合物的聚合形成的含有单体单元（2）的含氟聚合物。 R AF，BF，R CF，R DF各自独立地是氟原子，氯原子，全氟一价饱和烃基或全氟（部分氯化的一价饱和烃）基团中的至少一个，条件是R AF，BF 2，R CF，和/或DF是全氟（部分氯化的一价饱和烃）基团。

10. 发明申请

US20060036102A1 Process for preparing 4-fluoro-1,3-dioxolan-2-one 失效
标题翻译： 4-氟-1,3-二氧戊环-2-酮的制备方法
公开(公告)号：US20060036102A1
公开(公告)日：2006-02-16
申请号：US11210868
申请日：2005-08-25
申请人： Olaf Boese , Dirk Seffer , Katja Peterkord
发明人： Olaf Boese , Dirk Seffer , Katja Peterkord
IPC分类号： C07D317/08
CPC分类号： C07D317/42
摘要： A process for preparing 4-fluoro-1,3-dioxolan-2-one comprising adding 4-fluoro-1,3-dioxolan-2-one to ethylene carbonate in an amount of from 3 to 20% by weight relative to the ethylene carbonate as a solvent for the ethylene carbonate, and introducing fluorine or a mixture containing fluorine in an inert gas is introduced into the resulting solution at 15 to 45° C.
摘要翻译：一种制备4-氟-1,3-二氧戊环-2-酮的方法，包括将相对于乙烯的3-20重量％的4-氟-1,3-二氧戊环-2-酮加入碳酸亚乙酯中碳酸酯作为碳酸亚乙酯的溶剂，并将氟或含氟的混合物在惰性气体中引入所得溶液中15至45℃。

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