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    • 4. 发明授权
    • Fluoropolymers containing organo-silanes and methods of making the same
    • 含有机硅烷的含氟聚合物及其制备方法
    • US06710123B1
    • 2004-03-23
    • US09869454
    • 2001-06-28
    • Ramin Amin-SanayeiClaude Christophe Granel
    • Ramin Amin-SanayeiClaude Christophe Granel
    • C08L2712
    • C08F230/08
    • A fluoropolymer is described which is a polymer reaction product of a fluoropolymer comprising a polymer reaction product of a) at least one first alkylene co-monomer containing at least one fluorine atom; b) optionally at least one monomer selected from 1) at least one second alkylene containing at least one fluorine atom; 2) at least one alkyl alkenyl ether containing at least one fluorine atom; 3) at least one aliphatic or cyclic ketone containing at least one fluorinated alpha-alpha position; or 4) non-fluorinated alkene, alkyl alkenyl ether, or alkenyl ester; and c) at least one sterically hindered alkenyl or alkenyl ether organo silane co-monomer with or without at least one fluorine substituent. The fluoropolymer can be subsequently cross-linked or further reacted. Methods of making the fluoropolymer are further disclosed as well as applications of the fluoropolymers.
    • 描述了含氟聚合物,其是包含a)至少一种含有至少一个氟原子的至少一种第一亚烷基共聚单体的聚合物反应产物的含氟聚合物的聚合物反应产物; b)任选的至少一种选自1)至少一种含有至少一个氟原子的第二亚烷基的单体; 2)至少一个含有至少一个氟原子的烷基烯基醚; 3)至少一种含有至少一个氟化α-α位的脂族或环酮; 或4)非氟化烯烃,烷基烯基醚或烯基酯; 和c)至少一个具有或不具有至少一个氟取代基的空间位阻烯基或烯基醚有机硅烷共聚单体。 氟聚合物可以随后交联或进一步反应。 进一步公开制备氟聚合物的方法以及含氟聚合物的应用。
    • 9. 发明授权
    • Thermoplastic fluorinated polymers
    • 热塑性氟化聚合物
    • US06417279B2
    • 2002-07-09
    • US09781218
    • 2001-02-13
    • Julio A. AbuslemeClaudia Manzoni
    • Julio A. AbuslemeClaudia Manzoni
    • C08L2712
    • C08L27/12C08L2205/02C08L2666/04
    • A composition comprising a polymer mixture A of polymers formed by: (a) from 10 to 70% by moles of ethylene (E), (b) from 30 to 90%, by moles of a fluorinated monomer selected from tetrafluoroethylene (TFE), chlorotrifluoroethylene (CTFE), or mixtures thereof, (c) from 0.1 to 30% by moles, with respect to the total amount of monomers (a) and (b), of one or more acrylic monomers; characterized in that the polymer mixture A comprises polymer fractions having a different content of the acrylic comonomer such that the elastic modulus at 23° C. (ASTM D1708) of said polymer mixture A is lower than at least 10% of the elastic modulus of a polymer formed by monomers a), b) and c) wherein the polymer fractions have substantially an equal content of the acrylic comonomer.
    • 一种组合物,其包含通过以下形成的聚合物混合物A:(a)10至70摩尔%的乙烯(E),(b)30至90摩尔的选自四氟乙烯(TFE), 氯三氟乙烯(CTFE)或其混合物,(c)相对于单体(a)和(b)的总量为0.1至30摩尔%的一种或多种丙烯酸类单体;其特征在于,聚合物混合物A 包括具有不同含量的丙烯酸共聚单体的聚合物级分,使得所述聚合物混合物A的23℃下的弹性模量(ASTM D1708)低于由单体a)形成的聚合物的弹性模量的至少10% b)和c)其中聚合物部分具有基本相等的丙烯酸共聚单体含量。