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    • 7. 发明申请
    • FLUORORESIN COMPOSITION AND COVERED ELECTRIC WIRE
    • 氟菊酯组合物和覆盖电线
    • US20110272173A1
    • 2011-11-10
    • US12674070
    • 2008-09-24
    • Keizo ShiotsukiHideki Konokenji IshiiKengo ItoKenjiro TanimotoTakahiro Kitahara
    • Keizo ShiotsukiHideki Konokenji IshiiKengo ItoKenjiro TanimotoTakahiro Kitahara
    • H01B3/30C08L27/20
    • C08J3/12C08F8/22C08J3/16C08J3/226C08J2327/18C08J2427/00C08L27/18C08L2205/02H01B3/445C08L2666/04
    • It is an object of the present invention to provide a fluororesin composition which hardly causes molding defects even when high-speed molding is performed in covering extrusion molding within a relatively broad molding temperature range and which can give covered electric wires, in particular foamed electric wires, excellent in surface smoothness.A fluororesin composition comprising a polytetrafluoroethylene [PTFE] having a standard specific gravity of 2.15 to 2.30 and a tetrafluoroethylene/hexafluoropropylene-based copolymer [FEP], the content of said PTFE being 0.01 to 3 parts by mass per 100 parts by mass of said FEP and the alkali metal content being not higher than 5 ppm on the resin composition solid matter basis, wherein said composition is obtained by a method comprising the step (1) of obtaining a cocoagulated fluororesin powder by mixing an aqueous dispersion containing said FEP and an aqueous dispersion containing said PTFE together, followed by coagulation, the step (2) of melt extruding the cocoagulated powder and the step (3) of subjecting the extrusion product to treatment for stabilizing unstable terminal groups in said PTFE and FEP.
    • 本发明的目的是提供即使在相对宽的成型温度范围内覆盖挤压成型进行高速成型时也难以引起成型缺陷的氟树脂组合物,其可以形成被覆电线,特别是发泡电线 表面平滑度优异。 一种含有标准比重为2.15〜2.30的聚四氟乙烯[PTFE]和四氟乙烯/六氟丙烯系共聚物[FEP]的氟树脂组合物,所述PTFE的含量相对于100质量份所述FEP为0.01〜3质量份 碱性金属含量在树脂组合物固体物质上不高于5ppm,其中所述组合物通过包括步骤(1)的方法获得,所述方法包括通过将含有所述FEP的水性分散体和水溶液 将所述PTFE分散在一起,然后凝固,熔融挤出可凝结粉末的步骤(2)和使挤出产物经受处理以稳定所述PTFE和FEP中的不稳定末端基团的步骤(3)。