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1. 发明申请

US20100105584A1 Fluorinated Lubricants 有权
标题翻译：氟化润滑剂
公开(公告)号：US20100105584A1
公开(公告)日：2010-04-29
申请号：US12516048
申请日：2007-11-29
申请人： Marco Avataneo , Pier Antonio Guarda , Giuseppe Marchionni , Patrizia Maccone , Giovanni Boccaletti
发明人： Marco Avataneo , Pier Antonio Guarda , Giuseppe Marchionni , Patrizia Maccone , Giovanni Boccaletti
IPC分类号： C10M125/26 , C08F214/18 , C10M107/38 , C10M147/04 , C10M149/20
CPC分类号： C08F293/00 , C08F214/182 , C08F283/06 , C08F293/005 , C08L53/00 , C10M107/38 , C10M119/22 , C10M2201/0616 , C10M2201/1026 , C10M2201/1056 , C10M2203/045 , C10M2203/065 , C10M2203/1006 , C10M2203/1025 , C10M2203/1045 , C10M2205/0285 , C10M2207/1206 , C10M2207/2805 , C10M2209/1033 , C10M2213/043 , C10M2213/046 , C10M2213/0606 , C10M2213/0613 , C10M2213/0626 , C10M2215/121 , C10M2217/0456 , C10M2229/025 , C10N2210/01 , C10N2210/02 , C10N2220/021 , C10N2220/022 , C10N2230/06 , C10N2230/74 , C10N2240/06 , C10N2240/202 , C10N2250/10 , C10N2250/121 , C08L2666/02 , C08L2666/04
摘要： Fluorinated lubricants of formula: T-O[A-B]z-[A-B′]z′-A-T′ (I)wherein: A=—(X)a—O-A′-(X′)b wherein A′ is a perfluoropolyether chain comprising units (CF2O), (CF2CF2O), (CF2CF2CF2O), (CF2CF2CF2CF2O); X, X′═—CF2—, —CF2CF2—; a, b=0 or 1; B derives from olefins, of which at least one homopolymerizable by radical route, of formula: —[(CR1R2—CR3R4)j(CR5R6—CR7R8)j′]— (Ia) wherein j=1-5, j′=0-4 and 2
摘要翻译：氟化润滑剂，其结构式如下：TO [AB] z- [AB'] z'-AT'（I）其中：A = - （X）a-OA' - （X'）b其中A' （CF 2 CF 2 O），（CF 2 CF 2 CF 2 O），（CF 2 CF 2 CF 2 CF 2 O） X，X'= CF 2 - ， - CF 2 CF 2 - ; a，b = 0或1; B衍生自其中至少一种可通过自由基路线均聚的至少一种式： - [（CR1R2-CR3R4）j（CR5R6-CR7R8）j'] - （Ia）其中j = 1-5，j'= 0- 4和2 <（j + j'）<5; R1-R8 =卤素，H，C1-C6（全）卤代烷基，C1-C6烷基，C1-C6氧基（全） - 氟烷基; z≥2; z'为0或整数; z，z'使得式（I）的聚合物的数均分子量在500-500,000的范围内; B'=（Ia），但R 1 -R 8中的至少一个具有不同于B和2和nlE的含义;（j + j'）<5; T，T'= C 1 -C 3全氟烷基，C 1 -C 6烷基及其组合物。

2. 发明授权

US06197903B1 Preparation of sulphonic fluorinated polymer solutions 有权
标题翻译：磺化氟化聚合物溶液的制备
公开(公告)号：US06197903B1
公开(公告)日：2001-03-06
申请号：US09281913
申请日：1999-03-31
申请人： Patrizia Maccone , Alberto Zompatori
发明人： Patrizia Maccone , Alberto Zompatori
IPC分类号： C08F11418
CPC分类号： C08J3/091 , C08J2327/12
摘要： A process for preparing a solution and/or dispersion containing sulphonic (per)fluorinated ionomers having —SO3M functional groups, wherein M is selected from H, Li, Na, K, NR4 (R equal to or different from each other are selected from H, CH3, C2H5), characterized in that it dissolves the above defined ionomers at a temperature comprised between the room temperature and about 150° C., in a monophasic ternary mixture essentially constituted by water, by a C1-C4 alcohol and by a fluoro(poly)oxyalkylene having one hydrogen atom in at least a fluorinated end group; the dispersed polymer particle sizes are in the range 30-100 nm.
摘要翻译：一种制备含有具有-SO 3 M官能团的磺酸（全）氟化离聚物的溶液和/或分散体的方法，其中M选自H，Li，Na，K，NR4（R彼此相同或不同）选自H ，CH 3，C 2 H 5），其特征在于其在室温至约150℃之间的温度下，以基本上由水构成的单相三元混合物，C1-C4醇和氟在至少氟化端基中具有一个氢原子的（聚）氧化烯; 分散的聚合物粒径在30-100nm的范围内。

3. 发明授权

US07026509B2 Cyclic phosphazene compounds and use thereof as additives of perfluoropolyether oils 失效
标题翻译：环状磷腈化合物及其作为全氟聚醚油的添加剂的用途
公开(公告)号：US07026509B2
公开(公告)日：2006-04-11
申请号：US10366414
申请日：2003-02-14
申请人： Antonio Russo , Patrizia Maccone , Claudio Tonelli
发明人： Antonio Russo , Patrizia Maccone , Claudio Tonelli
IPC分类号： C10M107/38 , C09K15/32 , C07K9/547
CPC分类号： C08G65/3356 , C07F9/65815 , C07F9/65817 , C08G65/007 , C08G2650/48 , C08L71/02 , C10M137/06 , C10M153/04 , C10M169/04 , C10M2213/0606 , C10M2223/08 , C10M2225/04 , C10N2230/06 , C10N2250/10
摘要： Cyclic phosphazene compounds of formula (I): wherein: Q is a cyclic compound of formula: A is an end group of the —OCF2X, —OC2F4X, —OC3F6X type, wherein X=F, Cl, H; Rf and R′f are (per)fluoropolyoxyalkylene chains having a number average molecular weight in the range 280-5,000.
摘要翻译：式（I）的环状磷腈化合物：其中：Q是下式的环状化合物：A是-OCF 2 X X的末端基团，-OC 2 其中X = F，Cl，H; X，Y，X，X，X， R“F”和R“F”是数均分子量在280-5,000范围内的（全）氟代聚氧亚烷基链。

4. 发明授权

US6072020A Fluorinated polymer purification 有权
标题翻译：氟化聚合物纯化
公开(公告)号：US6072020A
公开(公告)日：2000-06-06
申请号：US340136
申请日：1999-06-28
申请人： Vincenzo Arcella , Giulio Brinati , Patrizia Maccone
发明人： Vincenzo Arcella , Giulio Brinati , Patrizia Maccone
IPC分类号： C08J3/00 , B01D61/14 , C08F6/06 , C08F6/16 , C08F14/18 , C08G63/00
CPC分类号： B01D61/142 , C08F6/06
摘要： Purification process of amorphous polymers comprising the following steps:a) the amorphous polymer is dissolved in a fluorinated solvent;b) the solution containing the polymer is microfiltered by semipermeable membranes having a porosity in the range 0.05-0.5 .mu.m, and the permeate forms the polymeric solution purified by contaminants in suspension;c) the permeate coming from b) is ultrafiltered/nanofiltered by membranes with porosity in the range 10-500 kDa, and the retentate is formed by the polymeric solution purified from the contaminants in solution.
摘要翻译：无定形聚合物的纯化方法包括以下步骤：a）将无定形聚合物溶解在氟化溶剂中; b）含有聚合物的溶液通过孔隙率在0.05-0.5μm范围内的半透膜进行微过滤，并且渗透物形成由悬浮液中的污染物纯化的聚合物溶液; c）来自b）的渗透物通过孔隙率在10-500kDa范围内的膜进行超滤/纳滤，并且通过从溶液中的污染物纯化的聚合溶液形成滞留物。

5. 发明授权

US07405296B2 Additives for fluorinated oils 有权
标题翻译：氟化油添加剂
公开(公告)号：US07405296B2
公开(公告)日：2008-07-29
申请号：US11402930
申请日：2006-04-13
申请人： Antonio Russo , Patrizia Maccone
发明人： Antonio Russo , Patrizia Maccone
IPC分类号： C07D251/30 , C07D251/38 , C07D251/42 , C07D251/48 , C10M169/04
CPC分类号： C07D251/34 , C10M133/42 , C10M169/00 , C10M169/04 , C10M177/00 , C10M2213/0606 , C10M2213/0626 , C10M2215/222 , C10M2217/0456 , C10N2230/10 , C10N2230/12 , C10N2250/10 , C10N2270/00
摘要： Compounds of formula wherein Rf is a (per)fluoropolyoxyalkylene chain having a number average molecular weight in the range 500-10,000; W1, W2, equal to or different from each other, are —F or —CF3; T1 is equal to —CHAa—Ba (CH2CH2O)na— wherein Aa=H, CF3; Ba=O, S, NH; na=0 or an integer between 1 and 6; T2 is equal to —F, —CF3, —C2 F5, —(C2 F4) Cl, or a group of formula: Q1, Q2 equal to or different from each other, are a chain of formula -T1-l -CFW1—O—Rf—CFW2-T′2, wherein: T′2 is equal to —F, —CF3, —C2 F5, —(C2F4) Cl; or is a group of formula: wherein B is equal to O, S, NH; R1, R2, R3, R4, R5 equal to or different from each other are selected from H, F, NO2, CN, C1-C8 perfluoroalkyl, carboxyl, phenyl (Ph), O- Ph, NH-Ph, S-Ph; wherein B is equal to O, S, NH; R1, R2, R3, R4, R5 equal to or different from each other are selected from H, F, NO2, CN, C1-C8 perfluoroalkyl, carboxyl, phenyl (Ph), O- Ph, NH-Ph, S-Ph; with the proviso that at least one of Q1 and Q2a is equal to:
摘要翻译：下式化合物其中R ff是数均分子量在500-10,000范围内的（全）氟代聚氧亚烷基链; W 1，W 2，...等于或不同的基团是-F或-CF 3 N; T 1等于-CHA A 1 H 2 CH 2（CH 2 CH 2）2 CH 2 其中A a为H，CF 3 N; B = O，S，NH; na = 0或1和6之间的整数; T 2等于-F，-CF 3，-C 2 H 5， - （C 1 -C 3）或者每个等于或不同于下式的基团：Q 1，Q 2，...，N 2，另一方面，是一种式-T 1-1 -CFW-1 -F 1 -CFW 2 - - - SIPO < T'2，其中：T'2等于-F，-CF 3，-C 2， F 5， - （C 2 F 4）Cl; 或者是下式的基团：其中B等于O，S，NH; 等于或不同的R 1，R 2，R 3，R 4，R 5选自H，F，NO 2，CN，C 1 -C 8 全氟烷基，羧基，苯基（Ph），O- Ph，NH-Ph，S-Ph; 其中B等于O，S，NH; 等于或不同的R 1，R 2，R 3，R 4，R 5选自H，F，NO 2，CN，C 1 -C 8 全氟烷基，羧基，苯基（Ph），O- Ph，NH-Ph，S-Ph; 条件是Q 1和Q 2中的至少一个a等于：

6. 发明授权

US07399735B2 Perfluoropolyether additives 有权
标题翻译：全氟聚醚添加剂
公开(公告)号：US07399735B2
公开(公告)日：2008-07-15
申请号：US10849168
申请日：2004-05-20
申请人： Antonio Russo , Patrizia Maccone
发明人： Antonio Russo , Patrizia Maccone
IPC分类号： C10M107/38 , C10M149/00 , C07D213/62
CPC分类号： C10M169/044 , C08G65/007 , C10M147/04 , C10M169/00 , C10M169/041 , C10M177/00 , C10M2213/043 , C10M2213/0606 , C10M2215/221 , C10N2220/021 , C10N2250/10
摘要： Compounds formed of (per)fluoropolyether chains and end groups having a pyridine structure, with structural formula: T1-CW1—O—Rf—CW2-T2 (I) wherein T1, T2, equal to or different from each other, have the following meanings: F, CF3, C2F5, (C2F4)Cl; CH2—B—Y, CH(CF3)O—Y, wherein: B═O, S; wherein R1, R2, R3, R4, equal to or different from each other, are H, F, C1-C8 linear or branched perfluoroalkyl, NO2, CN; with the proviso that at least one of the two end groups T1, T2 is CH2—B—Y or CH(CF3)O—Y as above defined; W1, W2, equal to or different from each other, are —F, —CF3; Rf is a (per)fluoropolyoxyalkylene chain having a number average molecular weight from 400 to 10,000.
摘要翻译：由（全）氟代聚醚链和具有吡啶结构的端基形成的化合物，其结构式为：<？in-line-formula description =“In-line formula”end =“lead”？> T 1 （I）＆lt;＆lt;＆lt;＆lt;＆lt;＆lt;＆gt; 其中T 1，T 2，...彼此相同或不同的公式描述=“在线公式”end =“tail”？>具有以下含义： F，CF 3，C 2，F 5，（C 2 F 4））Cl; CH 2 -O-Y，CH（CF 3）O-Y，其中：B-O，S; 其中R 1，R 2，R 3，R 4等于或不同，分别为 H，F，C 1 -C 8直链或支链全氟烷基，NO 2，CN; 条件是两个端基T 1，T 2中的至少一个是CH 2 -2 -Y或CH（CF 3） 3）如上所定义; W 1，W 2，...等于或不同的基团是-F，-CF 3 N; Rf是数均分子量为400至10,000的（全）氟聚氧亚烷基链。

7. 发明申请

US20070032390A1 Additives for fluorinated oils 有权
标题翻译：氟化油添加剂
公开(公告)号：US20070032390A1
公开(公告)日：2007-02-08
申请号：US11402930
申请日：2006-04-13
申请人： Antonio Russo , Patrizia Maccone
发明人： Antonio Russo , Patrizia Maccone
IPC分类号： C10M169/04 , C07D251/30
CPC分类号： C07D251/34 , C10M133/42 , C10M169/00 , C10M169/04 , C10M177/00 , C10M2213/0606 , C10M2213/0626 , C10M2215/222 , C10M2217/0456 , C10N2230/10 , C10N2230/12 , C10N2250/10 , C10N2270/00
摘要： Compounds of formula wherein Rf is a (per)fluoropolyoxyalkylene chain having a number average molecular weight in the range 500-10,000; W1, W2, equal to or different from each other, are —F or —CF3; T1 is equal to —CHAa—Ba (CH2CH2O)na— wherein Aa=H, CF3; Ba=O, S, NH; na=0 or an integer between 1 and 6; T2 is equal to —F, —CF3, —C2 F5, —(C2 F4) Cl, or a group of formula: Q1, Q2 equal to or different from each other, are a chain of formula -T1-l -CFW1—O—Rf—CFW2-T′2, wherein: T′2 is equal to —F, —CF3, —C2 F5, —(C2F4) Cl; or is a group of formula: wherein B is equal to O, S, NH; R1, R2, R3, R4, R5 equal to or different from each other are selected from H, F, NO2, CN, C1-C8 perfluoroalkyl, carboxyl, phenyl (Ph), O—Ph, NH—Ph, S—Ph; with the proviso that at least one of Q1 and Q2 is equal to:
摘要翻译：下式化合物其中R ff是数均分子量在500-10,000范围内的（全）氟代聚氧亚烷基链; W 1，W 2，...等于或不同的基团是-F或-CF 3 N; T 1等于-CHA A 1 H 2 CH 2（CH 2 CH 2）2 CH 2 其中A a为H，CF 3 N; B = O，S，NH; na = 0或1和6之间的整数; T 2等于-F，-CF 3，-C 2 H 5， - （C 1 -C 3）或者每个等于或不同于下式的基团：Q 1，Q 2，...，N 2，另一方面，是一种式-T 1-1 -CFW-1 -F 1 -CFW 2 - - - SIPO < T'2，其中：T'2等于-F，-CF 3，-C 2， F 5， - （C 2 F 4）Cl; 或者是下式的基团：其中B等于O，S，NH; R 1，R 2，R 3，R 4，R 5等于相互或彼此不同，选自H，F，NO 2，CN，C 1 -C 8全氟烷基，羧基，苯基（ Ph），O-Ph，NH-Ph，S-Ph; 条件是Q 1和Q 2 2中的至少一个等于：

8. 发明授权

US07141140B2 Aqueous compositions of perfluoropolyether phosphates and use thereof to confer oleo-repellence to paper 有权
标题翻译：全氟聚醚磷酸盐的水性组合物及其用于赋予纸的疏油性的用途
公开(公告)号：US07141140B2
公开(公告)日：2006-11-28
申请号：US10340730
申请日：2003-01-13
申请人： Patrizia Maccone , Fiorenza D'Aprile , Mario Visca
发明人： Patrizia Maccone , Fiorenza D'Aprile , Mario Visca
IPC分类号： D21H19/12 , D21H17/10
CPC分类号： D21H19/28 , C08G65/007 , C08G65/327
摘要： Aqueous compositions of (per)fluoropolyether phosphates of formula: T—O—[Rf—CFY—L—O]P(O)(O−Z+)(OH); (A) and/or (OH)m(O−Z+)2-mP(O)[O—L—YFC—O—Rf—CFY—L—O—P(O)(O−Z+)]m′——[O—L—YFC—O—Rf—CFY—L—O]P(O)(O−Z+)2-m(OH)m (B) and use thereof to confer oleo-repellence to the paper by means of the size-press method.
摘要翻译：（全）氟聚醚磷酸酯的水性组合物，其结构如下：<？in-line-formula description =“In-line Formulas”end =“lead”→TO- [R ff -CFY-LO] （O）（O）（O） - （OH）; （A）<？in-line-formula description =“In-line Formulas”end =“tail”？>和/或<？in-line-formula description =“In-line Formulas”end =“lead”？> （OH）m（O） - （O） - （O） - （O） - （O）（O） - （O） - - - - - - - - - - - - - - - - - -YFC-OR f Y Y LO LO LO]]]]] SUB SUB SUB SUB SUB SUB SUB SUB SUB SUB SUB SUB SUB SUB SUB SUB SUB SUB SUB SUB SUB SUB SUB SUB SUB SUB SUB SUB SUB SUB （OH）m（<<<<<<<<

9. 发明授权

US07081440B2 Additives for perfluoropolyether oils 有权
公开(公告)号：US07081440B2
公开(公告)日：2006-07-25
申请号：US10417135
申请日：2003-04-17
申请人： Walter Navarrini , Patrizia Maccone
发明人： Walter Navarrini , Patrizia Maccone
IPC分类号： C10M131/10 , C10M133/32 , C10M147/00
CPC分类号： C08G65/007 , C08G65/33386 , C10M147/04 , C10M169/041 , C10M2211/063 , C10M2213/04 , C10N2220/021 , C10N2230/08 , C10N2230/10
摘要： Use as stabilizers of perfluoropolyether oils at high temperatures, higher than 200° C., of compounds not containing phosphor and having the general formula (A):

10. 发明授权

US06559192B2 Semipermeable porous membranes of semi-crystalline fluoropolymers 有权
标题翻译：半结晶含氟聚合物半透膜多孔膜
公开(公告)号：US06559192B2
公开(公告)日：2003-05-06
申请号：US10083294
申请日：2002-02-27
申请人： Patrizia Maccone , Paolo Fossati
发明人： Patrizia Maccone , Paolo Fossati
IPC分类号： C08J928
CPC分类号： B01D71/32 , B01D67/003 , B01D69/02 , B01D2323/12
摘要： Semipermeable porous membranes having an average pore diameter in the range 0.01-3 &mgr;m, and porosity in the range 30%-90%, based on semi-crystalline fluoropolymers and the respective preparation process, wherein the semi-crystalline fluoropolymers comprise: (a) from 10 to 70% by moles of ethylene, (b) from 30 to 90% by moles of a fluorinated monomer selected from tetrafluoroethylene, chlorotrifluoroethylene, or mixtures thereof, (c) from 0.1 to 30% by moles, with respect to the total amount of monomers (a) and (b), of a hydrogenated monomer of formula: CH2═CH—(CH2)n—R1 (I) wherein R1=—OR2, or —(O)tC(O)pR2 wherein t and p are integers equal to 0.1 and R2 is a linear or branched C1-C20 alkyl, or a cycloalkyl, optionally containing heteroatoms and/or chlorine atoms, preferably heteroatoms are O or N; R2 can optionally contain one or more functional groups, preferably selected from OH, COOH, epoxy, ester and ether group; R2 can optionally contain double bonds, or it can be H; n is an integer in the range 0-10.
摘要翻译：基于半结晶含氟聚合物和相应的制备方法，平均孔径在0.01-3μm范围内，孔隙率在30％-90％范围内的半透性多孔膜，其中半结晶含氟聚合物包括：（a） 10至70摩尔％的乙烯，（b）30至90摩尔％的选自四氟乙烯，氯三氟乙烯或其混合物的氟化单体，（c）0.1至30摩尔％单体（a）和（b）的单体量，其中R1 = -OR2或 - （O）tC（O）pR2其中t和p为等于0.1的整数，R2为直链或支链任选含有杂原子和/或氯原子，优选杂原子的C 1 -C 20烷基或环烷基是O或N; R2可以任选地含有一个或多个官能团，优选选自OH，COOH，环氧基，酯和醚基团; R2可以任选地含有双键，或者它可以是H; n是0-10的整数。

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