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71. 发明申请

US20090269593A1 FUNCTIONALIZED, HYDROGEN-PASSIVATED SILICON SURFACES 失效
标题翻译：功能化，氢化硅表面
公开(公告)号：US20090269593A1
公开(公告)日：2009-10-29
申请号：US12407471
申请日：2009-03-19
申请人： James M. Tour , Michael P. Stewart
发明人： James M. Tour , Michael P. Stewart
IPC分类号： B32B9/04
CPC分类号： H01L21/02118 , H01L21/02282 , H01L21/288 , H01L21/312 , H01L21/3205 , Y10T428/31663
摘要： This invention is generally related to a method of making a molecule-surface interface comprising at least one surface comprising at least one material and at least one organic group wherein the organic group is adjoined to the surface and the method comprises contacting at least one organic group precursor with at least one surface wherein the organic group precursor is capable of reacting with the surface in a manner sufficient to adjoin the organic group and the surface.
摘要翻译：本发明通常涉及一种制备分子 - 表面界面的方法，该分子 - 表面界面包括至少一个包含至少一种材料和至少一种有机基团的表面，其中有机基团邻接于该表面，并且该方法包括使至少一种有机基团具有至少一个表面的前体，其中有机基团前体能够以足以邻接有机基团和表面的方式与表面反应。

72. 发明申请

US20090215953A1 SHORT, FUNCTIONALIZED, SOLUBLE CARBON NANOTUBES, METHODS OF MAKING SAME, AND POLYMER COMPOSITES MADE THEREFROM 有权
标题翻译：短功能化，可溶性碳纳米管，其制备方法及其制备的聚合物复合材料
公开(公告)号：US20090215953A1
公开(公告)日：2009-08-27
申请号：US12280523
申请日：2007-02-22
申请人： Wen-Fang Hwang , Zheyl Chen , James M. Tour
发明人： Wen-Fang Hwang , Zheyl Chen , James M. Tour
IPC分类号： C08K3/04 , D01F9/12 , C09K3/00
CPC分类号： B82Y30/00 , B82Y40/00 , C01B32/174 , C01B32/176 , C01B2202/02 , C01B2202/28
摘要： In some embodiments, the present invention relates to new processes to simultaneously shorten and functionalize raw or purified carbon nanotubes to improve their dispersity and processibility, and the short functionalized nanotubes that may be made by the processes. This present invention also relates to new compositions of matter using short functionalized carbon nanotubes with thermoset, thermoplastic polymers, high temperature polymers, and other materials; the processes for making such composite materials; and the products of said processes.
摘要翻译：在一些实施方案中，本发明涉及同时缩短和官能化原始或纯化的碳纳米管以提高其分散性和可加工性的新方法以及可通过该方法制备的短官能化纳米管。本发明还涉及使用具有热固性，热塑性聚合物，高温聚合物和其它材料的短官能化碳纳米管的物质的新组合物; 制造这种复合材料的方法; 和所述方法的产品。

73. 发明申请

US20080258179A1 Hybrid molecular electronic device for switching, memory, and sensor applications, and method of fabricating same 审中-公开
标题翻译：用于开关，存储器和传感器应用的混合分子电子器件及其制造方法
公开(公告)号：US20080258179A1
公开(公告)日：2008-10-23
申请号：US11157391
申请日：2005-06-21
申请人： James M. Tour , Harry F. Pang , Jianli He
发明人： James M. Tour , Harry F. Pang , Jianli He
IPC分类号： H01L29/78 , H01L21/336
CPC分类号： H01L51/0562 , B82Y10/00 , B82Y15/00 , B82Y30/00 , G01N27/4148
摘要： A hybrid molecular electronic device having switching, memory, and sensor application is disclosed. In one embodiment, the device resembles a conventional field-effect transistor (FET) formed on a silicon-on-insulator (SOI) substrate. Source and drain doped regions are formed in an upper surface of the SOI substrate, and a metallization layer which can serve as a gate contact is formed on a lower surface of the SOI substrate. A channel region spanning between the doped source and drain regions is left exposed, in order that a monolayer of molecules may be formed therein. Upon application of appropriate gating voltages to the gate contact, conduction between the source and drain regions can be modulated, possibly as a result of the reduction and oxidation of the molecules grafted to the gate region.
摘要翻译：公开了具有开关，存储器和传感器应用的混合分子电子器件。在一个实施例中，该器件类似于形成在绝缘体上硅（SOI）衬底上的常规场效应晶体管（FET）。源极和漏极掺杂区域形成在SOI衬底的上表面中，并且可以用作栅极接触的金属化层形成在SOI衬底的下表面上。在掺杂源极和漏极区域之间跨越的沟道区域被暴露，以便可以在其中形成单分子层。在向栅极接触施加适当的栅极电压时，源极和漏极区域之间的导电可以被调制，可能是由于接枝到栅极区域的分子的还原和氧化。

74. 发明申请

US20080213162A1 Amplification of Carbon Nanotubes Via Seeded-Growth Methods 失效
标题翻译：通过种子生长方法扩增碳纳米管
公开(公告)号：US20080213162A1
公开(公告)日：2008-09-04
申请号：US10575352
申请日：2004-10-14
申请人： Richard E. Smalley , Irene M. Marek , Robert H. Hauge , Andrew R. Barron , James M. Tour , Howard K. Schmidt , W. Edward Billups , Christopher A. Dyke , Valerie C. Moore , Elizabeth Whitsitt , Robin E. Anderson , Ramon Colorado , Michael P. Stewart , Douglas C. Ogrin
发明人： Richard E. Smalley , Irene M. Marek , Robert H. Hauge , Andrew R. Barron , James M. Tour , Howard K. Schmidt , W. Edward Billups , Christopher A. Dyke , Valerie C. Moore , Elizabeth Whitsitt , Robin E. Anderson , Ramon Colorado , Michael P. Stewart , Douglas C. Ogrin
IPC分类号： C09C1/44
CPC分类号： B82Y40/00 , B01J23/881 , B01J27/22 , B82Y30/00 , C01B3/0021 , C01B32/162 , C01B32/172 , C01B32/176 , C01B2202/02 , C01B2202/04 , C01B2202/06 , C01B2202/36 , Y02E60/325
摘要： The present invention is directed towards methods (processes) of providing large quantities of carbon nanotubes (CNTs) of defined diameter and chirality (i.e., precise populations). In such processes, CNT seeds of a pre-selected diameter and chirality are grown to many (e.g., hundreds) times their original length. This is optionally followed by cycling some of the newly grown material back as seed material for regrowth. Thus, the present invention provides for the large-scale production of precise populations of CNTs, the precise composition of such populations capable of being optimized for a particular application (e.g., hydrogen storage). The present invention is also directed to complexes of CNTs and transition metal catalyst precurors, such complexes typically being formed en route to forming CNT seeds.
摘要翻译：本发明涉及提供大量具有规定直径和手性（即，精确群体）的大量碳纳米管（CNT）的方法（方法）。在这种方法中，预先选择的直径和手性的CNT种子生长到其原始长度的许多（例如，数百）倍。随后可以将一些新生成的材料循环回种子材料再生。因此，本发明提供了大规模生产精确的碳纳米管群体，能够针对特定应用（例如，氢存储）优化的这些群体的精确组成。本发明还涉及CNT和过渡金属催化剂前体的复合物，这些络合物通常在形成CNT晶种途中形成。

75. 发明授权

US07384815B2 Process for attaching molecular wires and devices to carbon nanotubes and compositions thereof 有权
标题翻译：将分子线和器件连接到碳纳米管的方法及其组合物
公开(公告)号：US07384815B2
公开(公告)日：2008-06-10
申请号：US10632948
申请日：2003-08-01
申请人： James M. Tour , Jeffrey L. Bahr , Jiping Yang
发明人： James M. Tour , Jeffrey L. Bahr , Jiping Yang
IPC分类号： H01L51/30 , D01F9/12
CPC分类号： B82Y30/00 , B82Y40/00 , C01B32/174 , C01B2202/02 , C01B2202/06 , C01B2202/36 , C01P2002/72 , C01P2002/82 , C01P2002/84 , C01P2002/88 , C01P2004/04 , C01P2004/13 , C07C245/20 , C07C321/26 , C07C321/28 , C08K9/04 , C09C1/48 , C09C1/56 , C09C1/565 , H01G11/36 , Y02E60/13 , Y10S977/788 , Y10S977/847 , Y10T428/13 , Y10T428/30
摘要： The present invention is directed towards processes for covalently attaching molecular wires and molecular electronic devices to carbon nanotubes and compositions thereof. Such processes utilize diazonium chemistry to bring about this marriage of wire-like nanotubes with molecular wires and molecular electronic devices.
摘要翻译：本发明涉及将分子线和分子电子器件共价连接到碳纳米管及其组合物上的方法。这种方法利用重氮化学来引起线状纳米管与分子线和分子电子器件的这种结合。

76. 发明申请

US20080063587A1 Selective Functionalization Of Carbon Nanotubes 失效
标题翻译：碳纳米管的选择性功能化
公开(公告)号：US20080063587A1
公开(公告)日：2008-03-13
申请号：US10566073
申请日：2004-07-29
申请人： Michael S. Strano , Monica Usrey , Paul Barone , Christopher A. Dyke , James M. Tour , W. Carter Kittrell , Robert H. Hauge , Richard E. Smalley
发明人： Michael S. Strano , Monica Usrey , Paul Barone , Christopher A. Dyke , James M. Tour , W. Carter Kittrell , Robert H. Hauge , Richard E. Smalley
IPC分类号： D01F9/12 , B01D57/02 , C07C245/20
CPC分类号： D01F11/14 , B82Y30/00 , B82Y40/00 , C01B32/172 , C01B32/174 , C01B2202/02 , C01B2202/22 , C01P2002/82 , C01P2002/84 , C01P2004/13 , C01P2004/133 , C01P2004/64 , C09C1/44 , C09C1/48 , C09C1/56 , Y10S977/734 , Y10S977/742 , Y10S977/745 , Y10S977/748
摘要： The present invention is directed toward methods of selectively functionalizing carbon nanotubes of a specific type or range of types, based on their electronic properties, using diazonium chemistry. The present invention is also directed toward methods of separating carbon nanotubes into populations of specific types or range(s) of types via selective functionalization and electrophoresis, and also to the novel compositions generated by such separations.
摘要翻译：本发明涉及使用重氮化学，基于其电子性质，选择性官能化特定类型或范围类型的碳纳米管的方法。本发明还涉及通过选择性官能化和电泳将碳纳米管分离成特定类型或范围的种类的方法，以及通过这种分离产生的新型组合物的方法。

77. 发明授权

US09831424B2 Nanoporous metal-oxide memory 有权
公开(公告)号：US09831424B2
公开(公告)日：2017-11-28
申请号：US14809770
申请日：2015-07-27
申请人： James M. Tour , Gunuk Wang , Yang Yang
发明人： James M. Tour , Gunuk Wang , Yang Yang
IPC分类号： H01L27/108 , H01L45/00 , H01L27/24
CPC分类号： H01L45/08 , H01L27/2472 , H01L45/1233 , H01L45/146 , H01L45/1633
摘要： A nanoporous (NP) memory may include a non-porous layer and a nanoporous layer sandwiched between the bottom and top electrodes. The memory may be free of diodes, selectors, and/or transistors that may be necessary in other memories to mitigate crosstalk. The nanoporous material of the nanoporous layer may be a metal oxide, metal chalcogenide, or a combination thereof. Further, the memory may lack any additional components. Further, the memory may be free from requiring an electroformation process to allow switching between ON/OFF states.

78. 发明授权

US09572834B2 Use of carbon nanomaterials with antioxidant properties to treat oxidative stress 有权
标题翻译：使用具有抗氧化性能的碳纳米材料来治疗氧化应激
公开(公告)号：US09572834B2
公开(公告)日：2017-02-21
申请号：US14114007
申请日：2012-04-26
申请人： James M. Tour , Jacob Berlin , Daniela Marcano , Ashley Leonard , Thomas A. Kent , Robia G. Pautler , Brittany Bitner , Taeko Inoue
发明人： James M. Tour , Jacob Berlin , Daniela Marcano , Ashley Leonard , Thomas A. Kent , Robia G. Pautler , Brittany Bitner , Taeko Inoue
IPC分类号： A61K31/335 , A61K9/00 , A61K38/00 , A61K47/00 , A61K33/44 , B82Y5/00 , A61K45/06 , A61K47/48 , A61K31/713
CPC分类号： A61K33/44 , A61K9/0019 , A61K31/713 , A61K45/06 , A61K47/60 , A61K47/6925 , B82Y5/00 , A61K2300/00
摘要： In some embodiments, the present invention provides methods of treating oxidative stress in a subject by administering a therapeutic composition to the subject. In some embodiments, the therapeutic composition comprises a carbon nanomaterial with anti-oxidant activity. In some embodiments, the anti-oxidant activity of the carbon nanomaterial corresponds to ORAC values between about 200 to about 15,000. In some embodiments, the administered carbon nanomaterials include at least one of single-walled nanotubes, double-walled nanotubes, triple-walled nanotubes, multi-walled nanotubes, ultra-short nanotubes, graphene, graphene nanoribbons, graphite, graphite oxide nanoribbons, carbon black, oxidized carbon black, hydrophilic carbon clusters, and combinations thereof. In some embodiments, the carbon nanomaterial is an ultra-short single-walled nanotube that is functionalized with a plurality of solubilizing groups. In some embodiments, the carbon nanomaterial is a polyethylene glycol functionalized hydrophilic carbon cluster (PEG-HCC). In some embodiments, the administered therapeutic compositions of the present invention may also include an active agent or targeting agent associated with the carbon nanomaterial. Additional embodiments of the present invention pertain to the aforementioned carbon nanomaterial compositions for treating oxidative stress.
摘要翻译：在一些实施方案中，本发明提供了通过向受试者施用治疗组合物来治疗受试者的氧化应激的方法。在一些实施方案中，治疗组合物包含具有抗氧化活性的碳纳米材料。在一些实施方案中，碳纳米材料的抗氧化活性对应于约200至约15,000之间的ORAC值。在一些实施方案中，所施用的碳纳米材料包括单壁纳米管，双壁纳米管，三壁纳米管，多壁纳米管，超短纳米管，石墨烯，石墨烯纳米带，石墨，氧化石墨纳米带，碳黑色，氧化炭黑，亲水性碳簇及其组合。在一些实施方案中，碳纳米材料是用多个增溶基团官能化的超短单壁纳米管。在一些实施方案中，碳纳米材料是聚乙二醇官能化的亲水性碳簇（PEG-HCC）。在一些实施方案中，本发明施用的治疗组合物还可以包括与碳纳米材料相关的活性剂或靶向剂。本发明的另外的实施方案涉及上述用于治疗氧化应激的碳纳米材料组合物。

79. 发明申请

US20160379764A1 Ni(OH)2 NANOPOROUS FILMS AS ELECTRODES 审中-公开
标题翻译： Ni（OH）2纳米膜作为电极
公开(公告)号：US20160379764A1
公开(公告)日：2016-12-29
申请号：US15193529
申请日：2016-06-27
申请人： James M. Tour , Yang Yang
发明人： James M. Tour , Yang Yang
IPC分类号： H01G11/30 , H01M4/52 , H01M4/90 , H01G11/86 , H01M4/04 , C25D9/06 , H01G11/68 , H01G11/26 , H01M4/66 , H01M4/88
CPC分类号： H01G11/30 , C25D9/06 , C25D11/34 , H01B1/02 , H01G11/26 , H01G11/68 , H01G11/86 , H01M4/0442 , H01M4/0471 , H01M4/52 , H01M4/661 , H01M4/8817 , H01M4/8853 , H01M4/9016 , H01M8/0206 , H01M8/0232 , H01M2004/021
摘要： The present disclosure pertains to electrodes that include a nickel-based material and at least one porous region with a plurality of nickel hydroxide moieties on a surface of the nickel-based material. The nickel-based material may be a nickel foil in the form of a film. The porous region of the electrode may be directly associated with the surface of the nickel-based material. The nickel hydroxide moieties may be in crystalline form and embedded with the porous region. The electrodes of the present disclosure may be a component of an energy storage device, such as a capacitor. Additional embodiments of the present disclosure pertain to methods of fabricating the electrodes by anodizing a nickel-based material to form at least one porous region on a surface of the nickel-based material; and hydrothermally treating the porous region to form nickel hydroxide moieties associated with the porous region.
摘要翻译：本公开涉及包括镍基材料的电极和在镍基材料的表面上具有多个氢氧化镍部分的至少一个多孔区域。镍基材料可以是膜形式的镍箔。电极的多孔区域可以直接与镍基材料的表面相关联。氢氧化镍部分可以是结晶形式并且嵌入多孔区域。本公开的电极可以是诸如电容器的能量存储装置的部件。本公开的另外的实施例涉及通过阳极氧化镍基材料以在镍基材料的表面上形成至少一个多孔区域来制造电极的方法; 并水热处理多孔区以形成与多孔区相关联的氢氧化镍部分。

80. 发明申请

US20160276411A1 ADDRESSABLE SIOX MEMORY ARRAY WITH INCORPORATED DIODES 审中-公开
标题翻译：可寻址的存储器阵列与入射二极管
公开(公告)号：US20160276411A1
公开(公告)日：2016-09-22
申请号：US15171196
申请日：2016-06-02
申请人： James M. Tour , Jun Yao , Jian Lin , Gunuk Wang , Krishna Palem
发明人： James M. Tour , Jun Yao , Jian Lin , Gunuk Wang , Krishna Palem
IPC分类号： H01L27/24 , H01L29/872 , H01L29/861 , H01L45/00
CPC分类号： H01L27/2463 , H01L27/2409 , H01L29/66136 , H01L29/66143 , H01L29/8611 , H01L29/8613 , H01L29/872 , H01L45/04 , H01L45/1233 , H01L45/1253 , H01L45/145 , H01L45/1608 , H01L45/1616 , H01L45/1625 , H01L45/1675
摘要： Various embodiments of the resistive memory cells and arrays discussed herein comprise: (1) a first electrode; (2) a second electrode; (3) resistive memory material; and (4) a diode. The resistive memory material is selected from the group consisting of SiOx, SiOxNy, SiOxNyH, SiOxCz, SiOxCzH, and combinations thereof, wherein each of x, y and z are equal or greater than 1 or equal or less than 2. The diode may be any suitable diode, such as n-p diodes, p-n diodes, and Schottky diodes.
摘要翻译：本文讨论的电阻式存储器单元和阵列的各种实施例包括：（1）第一电极; （2）第二电极; （3）电阻记忆材料; 和（4）二极管。电阻性存储材料选自SiO x，SiO x N y，SiO x N y H，SiO x C z，SiO x C z H及其组合，其中x，y和z中的每一个等于或大于1或等于或小于2.二极管可以是任何合适的二极管，例如np二极管，pn二极管和肖特基二极管。

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