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71. 发明授权

US07854945B2 Functionalized nanotubes 失效
标题翻译：功能化纳米管
公开(公告)号：US07854945B2
公开(公告)日：2010-12-21
申请号：US11412350
申请日：2006-04-26
申请人： Alan Fischer , Robert Hoch , David Moy , Chun-Ming Niu , Naoya Ogata , Howard Tennent
发明人： Alan Fischer , Robert Hoch , David Moy , Chun-Ming Niu , Naoya Ogata , Howard Tennent
IPC分类号： D01F9/12 , A61K9/16 , A61K9/50 , B05D7/00 , A01K1/015 , B32B5/16 , D02G3/00
CPC分类号： H01M4/60 , A61K33/44 , A61K48/00 , B82Y30/00 , B82Y40/00 , C01B32/152 , C01B32/174 , C01B2202/34 , C01B2202/36 , C07H21/02 , C07K17/06 , D01F9/12 , D01F11/14 , G01N33/5438 , G01N33/582 , G01N2030/8863 , G11C13/025 , Y10S530/811 , Y10S977/742 , Y10S977/746 , Y10S977/847 , Y10T428/249921 , Y10T428/25 , Y10T428/2927
摘要： Graphitic nanotubes, which includes tubular fullerenes (commonly called “buckytubes”) and fibrils, which are functionalized by chemical substitution or by adsorption of functional moieties. More specifically the invention relates to graphitic nanotubes which are uniformly or non-uniformly substituted with chemical moieties or upon which certain cyclic compounds are adsorbed and to complex structures comprised of such functionalized fibrils linked to one another. The invention also relates to methods of introducing functional groups onto the surface of such fibrils.
摘要翻译：石墨纳米管，其包括管状富勒烯（通常称为“巴氏管”）和原纤维，其通过化学取代或功能部分的吸附官能化。更具体地，本发明涉及由化学部分均匀或不均匀取代或其上吸附某些环状化合物的石墨纳米管和由彼此连接的这种官能化原纤维组成的复合结构。本发明还涉及在这种原纤维的表面上引入官能团的方法。

72. 发明申请

US20100113259A1 Single-walled carbon nanotube catalyst 审中-公开
标题翻译：单壁碳纳米管催化剂
公开(公告)号：US20100113259A1
公开(公告)日：2010-05-06
申请号：US11349651
申请日：2006-02-07
申请人： Jun Ma , David Moy
发明人： Jun Ma , David Moy
IPC分类号： B01J21/18 , B01J23/02 , B01J23/75
CPC分类号： D01F9/127 , B01J21/005 , B01J23/002 , B01J23/005 , B01J23/78 , B01J37/0236 , B01J37/031 , B01J37/08 , B01J37/18 , B01J2523/00 , B82Y30/00 , B82Y40/00 , C01B32/162 , C01B2202/02 , B01J2523/22 , B01J2523/842 , B01J2523/845 , B01J2523/41 , B01J2523/31
摘要： An activated catalyst capable of selectively growing single-walled carbon nanotubes when reacted with carbonaceous gas is provided. The activated catalyst is formed by reducing a catalyst that comprises a complex oxide. The complex oxide may be of formula AxByOz, wherein x/y≦2 and z/y≦4, A being a Group VIII element and B being an element such that an oxide of element B is not reducible in the presence of hydrogen at a temperature less than or equal to about 900° C. Methods of making, uses for and carbon fibril-containing product made with these activated catalysts are also provided.
摘要翻译：提供能够与碳质气体反应时能够选择性地生长单壁碳纳米管的活化催化剂。通过还原包含复合氧化物的催化剂形成活化的催化剂。复合氧化物可以具有式AxByOz，其中x / y和nlE; 2和z / y和nlE; 4，A是VIII族元素，B是使元素B的氧化物在氢存在下不可还原的元素温度低于或等于约900℃。还提供了用这些活化的催化剂制备的用于制备和使用含原纤纤维的产品的方法。

73. 发明申请

US20090093360A1 METHOD FOR PREPARING CATALYST SUPPORTS AND SUPPORTED CATALYSTS FROM SINGLE WALLED CARBON NANOTUBES 审中-公开
标题翻译：从单壁碳纳米管制备催化剂支持物和支持的催化剂的方法
公开(公告)号：US20090093360A1
公开(公告)日：2009-04-09
申请号：US12332908
申请日：2008-12-11
申请人： Jun Ma , David Moy , Howard Tennent , Robert Hoch , Alan Fischer
发明人： Jun Ma , David Moy , Howard Tennent , Robert Hoch , Alan Fischer
IPC分类号： B01J21/18 , B29C47/00
CPC分类号： B82Y30/00 , B01J21/185 , B01J23/40 , B01J35/1023 , B01J35/1061 , B01J35/109 , B01J37/0009 , B01J37/04 , Y02P20/582 , Y10T428/249962 , Y10T428/249967 , Y10T428/25 , Y10T428/2918 , Y10T428/2938 , Y10T428/30
摘要： A new method for preparing a supported catalyst is herein provided. A carbon nanotube structure such as a rigid porous structure is formed from single walled carbon nanotubes. A metal catalyst is then loaded or deposited onto the carbon nanotube structure. The loaded carbon nanotube is preferably ground to powder form.
摘要翻译：本文提供了一种制备负载型催化剂的新方法。诸如刚性多孔结构的碳纳米管结构由单壁碳纳米管形成。然后将金属催化剂装载或沉积到碳纳米管结构上。负载的碳纳米管优选研磨成粉末形式。

74. 发明申请

US20080175787A1 SINGLE-WALLED CARBON NANOTUBE CATALYSTS AND METHODS FOR PREPARING SAME 审中-公开
标题翻译：单壁碳纳米管催化剂及其制备方法
公开(公告)号：US20080175787A1
公开(公告)日：2008-07-24
申请号：US11841853
申请日：2007-08-20
申请人： Jun MA , David Moy
发明人： Jun MA , David Moy
IPC分类号： C01B13/00 , C01B13/14
CPC分类号： D01F9/127 , B01J21/005 , B01J23/002 , B01J23/005 , B01J23/78 , B01J37/0236 , B01J37/031 , B01J37/08 , B01J37/18 , B01J2523/00 , B82Y30/00 , B82Y40/00 , C01B32/162 , C01B2202/02 , B01J2523/22 , B01J2523/842 , B01J2523/845 , B01J2523/41 , B01J2523/31
摘要： An activated catalyst capable of selectively growing single-walled carbon nanotubes when reacted with carbonaceous gas is provided. The activated catalyst is formed by reducing a catalyst that comprises a complex oxide. The complex oxide may be of formula Ax−wFwBy−vGvOz wherein x/y≦2; z/y≦4; 0≦w≦0.3x; 0≦v≦0.3y; A is a Group VIII element; F is an element that is different from A but has, in said composition, the same valence state as A; B is an element different from A and F, and is an element whose simple oxide, in which B is at the same valence state as in the complex oxide, is not reducible in the presence of hydrogen gas at a temperature less than about 900° C.; G is an element different from A, B and F, and is an element whose simple oxide, in which G is at the same valence state as in the complex oxide, is not reducible in the presence of hydrogen gas at a temperature less than about 900° C.; and O is oxygen. The complex oxide is reduced at a temperature less that 950° C. Methods of making, uses for and carbon fibril-containing product made with these activated catalysts are also provided.
摘要翻译：提供能够与碳质气体反应时能够选择性地生长单壁碳纳米管的活化催化剂。通过还原包含复合氧化物的催化剂形成活化的催化剂。复合氧化物可以是式A的化合物，其中R 1，R 2，R 3，R 3，其中x / y <= 2; z / y <= 4; 0 <= w <= 0.3x; 0 <= v <= 0.3y; A是VIII族元素; F是与A不同的元素，在所述组合物中具有与A相同的价态; B是与A和F不同的元素，并且是其中B与复合氧化物处于相同价态的简单氧化物在氢气存在下在小于约900°的温度下不可还原的元素 C。; G是不同于A，B和F的元素，并且是其中G与复合氧化物处于相同价态的简单氧化物的元素在氢气存在下在小于约 900°C。而O是氧。复合氧化物在低于950℃的温度下还原。还提供了用这些活化的催化剂制备，用于含有原纤维的产物的方法。

75. 发明授权

US07230149B2 Method of using carbide and/or oxycarbide containing compositions 失效
标题翻译：使用碳化物和/或含碳氧化物的组合物的方法
公开(公告)号：US07230149B2
公开(公告)日：2007-06-12
申请号：US10940242
申请日：2004-09-14
申请人： David Moy , Chunming Niu , Jun Ma , Jason M. Willey
发明人： David Moy , Chunming Niu , Jun Ma , Jason M. Willey
IPC分类号： C07C5/03
CPC分类号： B82Y30/00 , B01J21/18 , B01J27/22 , B01J35/023 , B82Y40/00 , C01B32/15 , C01B32/168 , C01B32/18 , C01B32/907 , C01B32/949 , C01B2202/34 , C01B2202/36 , C01P2002/72 , C01P2004/03 , C01P2004/04 , C01P2004/13 , C01P2004/50 , C01P2004/64 , C01P2004/80 , C01P2004/82 , C01P2006/10 , C01P2006/14 , C01P2006/60 , C01P2006/80 , C10G25/003 , C10G45/02 , C10G45/60 , C10G2300/1081 , C10G2300/1088 , C10G2300/202 , C30B23/00 , C30B29/605 , D01F9/12 , D01F11/122
摘要： Compositions including carbide-containing nanorods and/or oxycarbide-containing nanorods and/or carbon nanotubes bearing carbides and oxycarbides and methods of making the same are provided. Rigid porous structures including oxycarbide-containing nanorods and/or carbide containing nanorods and/or carbon nanotubes bearing carbides and oxycarbides and methods of making the same are also provided. The compositions and rigid porous structures of the invention can be used either as catalyst and/or catalyst supports in fluid phase catalytic chemical reactions. Processes for making supported catalyst for selected fluid phase catalytic reactions are also provided.
摘要翻译：提供了包括含碳纳米棒和/或含碳氧化物的纳米棒和/或含有碳化物和碳氧化物的碳纳米管的组合物及其制备方法。还提供了包括含有碳氧化物的纳米棒和/或碳纳米棒和/或含有碳化物和碳氧化物的碳纳米管的刚性多孔结构及其制备方法。本发明的组合物和刚性多孔结构可用作流化相催化化学反应中的催化剂和/或催化剂载体。还提供了用于制备选择的流化相催化反应的负载型催化剂的方法。

76. 发明授权

US07198772B2 Methods and catalysts for the manufacture of carbon fibrils 失效
标题翻译：用于制造碳纤维的方法和催化剂
公开(公告)号：US07198772B2
公开(公告)日：2007-04-03
申请号：US10776140
申请日：2004-02-11
申请人： David Moy , Asif Chishti
发明人： David Moy , Asif Chishti
IPC分类号： D01F9/12
CPC分类号： B82Y30/00 , B01J21/04 , B01J23/85 , B01J23/881 , B01J31/04 , B01J31/1805 , B01J31/28 , B01J31/34 , B01J37/0217 , B01J37/03 , B01J2531/64 , B82Y40/00 , C01B32/15 , D01F9/1273
摘要： An improved catalyst for producing carbon fibrils is made by incorporating an effective yield-enhancing amount of a carboxylate into a fibril-forming catalyst. Alternatively, such a catalyst is made by coprecipitating a compound of a metal having fibril-forming catalytic properties and an aluminum and/or magnesium compound, optionally in the presence of carbon particles or carbon fibril aggregates. The catalyst may also be made by incorporating a compound of a fibril-forming metal onto magnesia particles in carbon particles or carbon fibril aggregates. The catalysts, methods of using them to form carbon fibrils and those carbon fibrils are also disclosed.
摘要翻译：通过将有效的增产量的羧酸盐引入原纤维形成催化剂中来制备用于生产碳原纤维的改进的催化剂。或者，这种催化剂通过共沉淀具有原纤维形成催化性质的金属的化合物和铝和/或镁化合物，任选地在碳颗粒或碳原纤聚集体的存在下制备。催化剂也可以通过将原纤维形成金属的化合物引入到碳颗粒或碳原子聚集体中的氧化镁颗粒上来制备。还公开了催化剂，使用它们形成碳原纤维和那些碳原纤的方法。

77. 发明申请

US20060193868A1 Functionalized nanotubes 失效
标题翻译：功能化纳米管
公开(公告)号：US20060193868A1
公开(公告)日：2006-08-31
申请号：US11412350
申请日：2006-04-26
申请人： Alan Fisher , Robert Hoch , David Moy , Chunming Niu , Naoya Ogata , Howard Tennent
发明人： Alan Fisher , Robert Hoch , David Moy , Chunming Niu , Naoya Ogata , Howard Tennent
IPC分类号： A61K39/395 , A61K48/00 , C07H21/02 , A61K38/43 , A61K33/44
CPC分类号： H01M4/60 , A61K33/44 , A61K48/00 , B82Y30/00 , B82Y40/00 , C01B32/152 , C01B32/174 , C01B2202/34 , C01B2202/36 , C07H21/02 , C07K17/06 , D01F9/12 , D01F11/14 , G01N33/5438 , G01N33/582 , G01N2030/8863 , G11C13/025 , Y10S530/811 , Y10S977/742 , Y10S977/746 , Y10S977/847 , Y10T428/249921 , Y10T428/25 , Y10T428/2927
摘要： Graphitic nanotubes, which includes tubular fullerenes (commonly called “buckytubes”) and fibrils, which are functionalized by chemical substitution or by adsorption of functional moieties. More specifically the invention relates to graphitic nanotubes which are uniformly or non-uniformly substituted with chemical moieties or upon which certain cyclic compounds are adsorbed and to complex structures comprised of such functionalized fibrils linked to one another. The invention also relates to methods of introducing functional groups onto the surface of such fibrils.
摘要翻译：石墨纳米管，其包括管状富勒烯（通常称为“巴氏管”）和原纤维，其通过化学取代或功能部分的吸附官能化。更具体地，本发明涉及由化学部分均匀或不均匀取代或其上吸附某些环状化合物的石墨纳米管和由彼此连接的这种官能化原纤维组成的复合结构。本发明还涉及在这种原纤维的表面上引入官能团的方法。

78. 发明申请

US20060142149A1 Method for preparing supported catalysts from metal loaded carbon nanotubes 审中-公开
标题翻译：由负载碳纳米管制备载体催化剂的方法
公开(公告)号：US20060142149A1
公开(公告)日：2006-06-29
申请号：US11281814
申请日：2005-11-16
申请人： Jun Ma , David Moy , Asif Chishti , Jun Yang
发明人： Jun Ma , David Moy , Asif Chishti , Jun Yang
IPC分类号： B01J21/18
CPC分类号： C07C209/36 , B01J21/185 , B01J23/26 , B01J23/28 , B01J23/42 , B01J23/44 , B01J35/006 , B01J35/0066 , B01J35/06 , B01J37/0009 , B01J37/0207 , B01J37/06 , B01J37/20 , B01J37/30 , B82Y30/00 , B82Y40/00 , C01B32/174 , C01B2202/02 , C01B2202/06 , Y10S977/742 , Y10S977/745 , Y10S977/748 , Y10S977/75 , Y10S977/752 , C07C211/46
摘要： A new method for preparing a supported catalyst is herein provided. Carbon nanotubes are functionalized by contacting them with an oxidizing agent to form functionalized carbon nanotubes. A metal catalyst is then loaded or deposited onto the functionalized carbon nanotubes. The mixture is then extruded to form the supported catalyst comprising a carbon nanotube structure containing metal catalyst more evenly dispersed within the internal structure of the carbon nanotube structure.
摘要翻译：本文提供了一种制备负载型催化剂的新方法。通过使碳纳米管与氧化剂接触以形成官能化的碳纳米管来官能化。然后将金属催化剂负载或沉积到官能化的碳纳米管上。然后将混合物挤出以形成负载的催化剂，其包括更均匀地分散在碳纳米管结构的内部结构内的含有金属催化剂的碳纳米管结构。

79. 发明授权

US06936565B2 Modified carbide and oxycarbide containing catalysts and methods of making and using thereof 失效
公开(公告)号：US06936565B2
公开(公告)日：2005-08-30
申请号：US10005586
申请日：2001-10-29
申请人： Jun Ma , David Moy
发明人： Jun Ma , David Moy
IPC分类号： B01J21/18 , B01J27/22 , B01J27/224 , B01J35/02 , B01J37/24 , B01J37/28 , C01B31/02 , C01B31/30 , C07B61/00 , C07C5/09 , C07C5/22 , C07C5/25 , C07C5/27 , C07C9/06 , C07C9/12 , C07C11/02 , C07C11/08 , C10G35/06 , C30B23/00 , D01F9/12 , D01F11/12 , C04B35/52 , B32B5/24
CPC分类号： B01J21/185 , B01J21/18 , B01J27/22 , B01J35/023 , B01J37/24 , B01J37/28 , B82Y30/00 , B82Y40/00 , C01B32/15 , C01B32/168 , C01B32/18 , C01B32/907 , C01B2202/34 , C01B2202/36 , C01P2002/72 , C01P2004/03 , C01P2004/04 , C01P2004/13 , C01P2004/50 , C01P2004/64 , C01P2004/80 , C01P2004/82 , C01P2006/10 , C01P2006/14 , C01P2006/60 , C01P2006/80 , C30B23/00 , C30B29/605 , D01F9/12 , D01F11/122 , Y10S977/788 , Y10T428/249962 , Y10T428/249967 , Y10T428/25 , Y10T428/2918 , Y10T428/292
摘要： Compositions including modified carbide-containing nanorods and/or modified oxycarbide-containing nanorods and/or modified carbon nanotubes bearing carbides and oxycarbides and methods of making the same are provided. Rigid porous structures including modified oxycarbide-containing nanorods and/or modified carbide containing nanorods and/or modified carbon nanotubes bearing modified carbides and oxycarbides and methods of making the same are also provided. The compositions and rigid porous structures of the invention can be used either as catalyst and/or catalyst supports in fluid phase catalytic chemical reactions. Processes for making supported catalyst for selected fluid phase catalytic reactions are also provided.

80. 发明授权

US06872681B2 Modification of nanotubes oxidation with peroxygen compounds 失效
标题翻译：用过氧化合物改性纳米管氧化
公开(公告)号：US06872681B2
公开(公告)日：2005-03-29
申请号：US09861370
申请日：2001-05-18
申请人： Chunming Niu , David Moy , Jun Ma , Asif Chishti
发明人： Chunming Niu , David Moy , Jun Ma , Asif Chishti
IPC分类号： B82B3/00 , C01B31/02 , D01F11/12 , H01G9/058 , D01F9/12
CPC分类号： D01F11/122 , B82Y30/00 , H01G11/36 , Y02E60/13 , Y10S977/847
摘要： A method of chemically modifying carbon nanotubes having a diameter less than one micron comprising: contacting the nanotubes with a peroxygen compound selected from the group consisting of organic peroxyacids, inorganic peroxoacids and organic hydroperoxides, or a salt thereof, under oxidation conditions and thereby producing modified carbon nanotubes. Oxidation of the nanotubes increases the degree of dispersion of aggregates of nanotubes and aids in the disassembling of such aggregates. The dispersed nanotubes are used to prepare rigid structures and can be used in electrodes and capacitors.
摘要翻译：化学改性直径小于1微米的碳纳米管的方法包括：在氧化条件下使纳米管与选自有机过氧酸，无机过氧酸和有机氢过氧化物或其盐的过氧化合物接触，从而产生改性的碳纳米管。纳米管的氧化增加了纳米管聚集体的分散程度，有助于这种聚集体的分解。分散的纳米管用于制备刚性结构，可用于电极和电容器中。

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