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61. 发明授权

US5482649A Aminoacrylates and a process for their preparation 失效
标题翻译：氨基丙烯酸酯及其制备方法
公开(公告)号：US5482649A
公开(公告)日：1996-01-09
申请号：US95886
申请日：1993-07-22
申请人： Jurgen Meixner , Wolfgang Fischer , Christian Zwiener
发明人： Jurgen Meixner , Wolfgang Fischer , Christian Zwiener
IPC分类号： C08F20/36 , C07C69/54 , C07C217/50 , C07C219/08 , C07C227/06 , C07C229/12 , C07C229/14 , C07C229/16 , C08F20/34 , C08F220/36 , C08F299/02 , C08G65/332 , C09D4/00 , C09D4/02 , C09J4/02 , C09K3/00
CPC分类号： C08G65/3322 , C07C227/06 , C07C229/12 , C07C229/14 , C07C69/54 , C08F299/024 , C09D4/00
摘要： The present invention relates to aminoacrylates which have a viscosity of 200 to 3000 mPa.s at 23.degree. C. and 100% solids, a content of olefinic double bonds (calculated as C=C, molecular weight=24) of 8 to 20% by weight and a nitrogen content of 0.4 to 2.0% by weight, and which are prepared by an addition reaction by reacting at a molar ratio of primary amino groups from component a) to olefinic double bonds from component b) of 0.05:1 to 0.25:1a) mono- or diamines having a molecular weight of 31 to 300 and having aliphatically bound amino groups withb) acrylic esters of polyhydric alcohols which have been prepared at a COOH/OH equivalent ratio of 0.8:1 to 1:1 fromb1) acrylic acid andb2) ether-alcohols which have 3 or 4 hydroxyl groups and a molecular weight of 136 to 1000, possess at least one ethylene oxide unit --CH.sub.2 --CH.sub.2 --O-- as part of the ether structure and do not contain propylene oxide units --CH.sub.2 --CH(CH.sub.3)--O--.The present invention also relates to a process for the preparation these aminoacrylates.
摘要翻译：本发明涉及在23℃和100％固体粘度为200-3000mPa.s，烯属双键（C = C，分子量= 24计算）的含量为8至20％的氨基丙烯酸酯，并且氮含量为0.4〜2.0重量％，并且其通过加成反应制备，其通过使组分a）中的伯氨基与组分b）的烯属双键的摩尔比为0.05:1至0.25 ：1a）分子量为31〜300，具有脂族结合氨基的单胺或二胺，b）以0.8:1〜1:1的COOH / OH当量比制备的多元醇丙烯酸酯， b1）丙烯酸和b2）具有3或4个羟基并且分子量为136至1000的醚醇具有至少一个环氧乙烷单元-CH 2 -CH 2 -O-作为醚结构的一部分，并且不含环氧丙烷单元-CH2-CH（CH3）-O-。本发明还涉及制备这些氨基丙烯酸酯的方法。

62. 发明授权

US5440060A Surface-active compounds based on alkoxylated fatty amines 失效
标题翻译：基于烷氧基化脂肪胺的表面活性化合物
公开(公告)号：US5440060A
公开(公告)日：1995-08-08
申请号：US114388
申请日：1993-08-30
申请人： Heinz Uhrig , Albert Munkel
发明人： Heinz Uhrig , Albert Munkel
IPC分类号： B01F17/46 , A01N25/30 , A01N47/18 , B01F17/00 , C07C217/50 , C08G63/685 , C08G63/688 , C08G63/91 , C09B41/00 , C09B67/46 , C09D17/00 , D06P1/52 , D21H17/53 , D21H21/28 , C07C101/80
CPC分类号： A01N25/30 , A01N47/18 , B01F17/0042 , B01F17/005 , C07C217/50 , C08G63/685 , C08G63/688 , C08G63/91 , C09B41/005 , C09B67/0085 , C09D17/001 , C23F11/14 , C23F11/143 , D06P1/5278 , D21H17/53 , D21H21/285
摘要： The demands on the properties of pigments, in particular in the areas of emulsion paints and printing inks, which are continuously becoming more specific made it necessary to develop selective and environmentally safe dispersing and emulsifying agents and coupling auxiliaries.The compounds according to the invention are alkoxylation products prepared from fatty amine dialkylenediamines which, if desired, are linked to give recurring structural units by means of esterification with dicarboxylic acids and in which, preferably, the hydroxyl end groups of these fatty amine alkylenediamine alkoxylates have been esterified with fatty acids, aromatic carboxylic acids and/or resin acids and any hydroxyl groups still present have been converted to the corresponding mono-ester-containing anionic radicals by means of dicarboxylic acids and sulfites.The compounds according to the invention are suitable for a wide range of areas of application in the surfactant sector, for example in the preparation of azo pigments, emulsion paints and printing inks, for the improvement of coloristic and rheological properties. The compounds according to the invention are particularly environmentally safe owing to their biodegradability.
摘要翻译：对于颜料的性质，特别是在乳液漆和印刷油墨领域的性能的要求不断变得更具体，因此需要开发出选择性和环境安全的分散和乳化剂和偶联助剂。根据本发明的化合物是由脂肪胺二烷基二胺制备的烷氧基化产物，如果需要，其通过用二羧酸进行酯化连接以产生重复结构单元，并且其中优选地，这些脂肪胺烷基二胺烷氧基化物的羟基端基具有被脂肪酸酯化，芳族羧酸和/或树脂酸和任何仍然存在的羟基已经通过二羧酸和亚硫酸盐转化为相应的含单酯的阴离子基团。根据本发明的化合物适用于表面活性剂部分中广泛的应用领域，例如制备偶氮颜料，乳液漆和印刷油墨，用于改善着色和流变性质。根据本发明的化合物由于其生物降解性而特别环境安全。

63. 发明授权

US5354907A Amines derived from THPE and processes for preparing the same 失效
标题翻译：衍生自THPE的胺和其制备方法
公开(公告)号：US5354907A
公开(公告)日：1994-10-11
申请号：US179789
申请日：1994-01-11
申请人： Michael T. Sheehan , James R. Sounik , William W. Wilkison, III
发明人： Michael T. Sheehan , James R. Sounik , William W. Wilkison, III
IPC分类号： C07C217/50 , C08G18/50 , C08G65/325 , C08G65/333 , C07C217/44 , C08G18/10 , C08G18/30
CPC分类号： C07C217/50 , C08G18/5024 , C08G18/5033 , C08G65/3255 , C08G65/33306 , C08G2120/00
摘要： Amines endowed with chain extension activity for formulations such as polyureas are disclosed, which have the general formula: ##STR1## wherein n is 0-1000; R.sub.1 .dbd.R.sub.2, and R.sub.1 and R.sub.2 are from the group --CH.sub.2 --CH.sub.2 --; --CH.sub.2 --C(CH.sub.3)H--; and --C(CH.sub.3)H--CH.sub.2 --; and R.sub.3 and R.sub.4 are each independently selected from the group consisting of H, --CH.sub.3, --CH.sub.2 CH.sub.3, --CH.sub.2 OH, and --CH.sub.2 --CH.sub.2 --OH.
摘要翻译：公开了具有如下通式的制剂如聚脲的制剂的链延伸活性的胺：其中n为0-1000; R1 = R2，R1和R2来自基团-CH2-CH2-; -CH2-C（CH3）H-; 和-C（CH 3）H-CH 2 - ; 并且R 3和R 4各自独立地选自H，-CH 3，-CH 2 CH 3，-CH 2 OH和-CH 2 -CH 2 -OH。

64. 发明授权

US5348578A Products obtained from the reaction of amine-diol and a polyfunctional substance and application of such products to electroapplicable cationic paint compositions 失效
标题翻译：从胺 - 二醇和多官能物质的反应获得的产物，并将这些产物应用于电解性阳离子涂料组合物
公开(公告)号：US5348578A
公开(公告)日：1994-09-20
申请号：US78229
申请日：1993-06-23
申请人： Yves Le Disert , Jean Roue , Thomas Moriarity , Philippe Faucher
发明人： Yves Le Disert , Jean Roue , Thomas Moriarity , Philippe Faucher
IPC分类号： C07C213/04 , C07C217/08 , C07C217/50 , C07C217/76 , C07C271/20 , C07C271/28 , C08G18/50 , C08G63/685 , C08G65/26 , C09D5/44 , C09D167/02 , C09D175/08
CPC分类号： C08G65/2621 , C07C213/04 , C07C217/50 , C07C217/76 , C08G18/5021 , C08G63/6854 , C09D5/4492
摘要： Product obtained from the reaction of(a) an amine-diol resulting from the reaction of a primary amine having the formula R-NH.sub.2 in which R represents an aliphatic or aromatic radical, with at least one alkylene oxide comprising predominantly propylene oxide, and(b) at least one polyfunctional substance, capable of acting on the hydroxyl groups of said amine-diol.The product disclosed may be used as an additive in an electrodeposition paint composition in order to furnish, after application to a metal substrate, a coating or film having an improved resistance to pinholes and to cratering.
摘要翻译： PCT No.PCT / FR92 / 00988 Sec。 371日期：1993年6月23日 102（e）日期1993年6月23日PCT 1991年10月21日PCT PCT。出版物WO93 / 08157 日本公报1993年4月29日。由（a）由具有式R-NH 2的伯胺（其中R表示脂族或芳族基团）与至少一种烯化氧反应得到的胺 - 二醇反应得到的产物主要包含环氧丙烷，和（b）能够作用于所述胺 - 二醇的羟基的至少一种多官能物质。所公开的产品可以用作电沉积涂料组合物中的添加剂，以便在施加到金属基材之后，提供具有改善的针孔和凹坑抵抗性的涂层或膜。

65. 发明授权

US4960935A Bisphenol derivatives, process for their manufacture, and their use as surfactants 失效
标题翻译：双酚衍生物，其制备方法及其作为表面活性剂的用途
公开(公告)号：US4960935A
公开(公告)日：1990-10-02
申请号：US477837
申请日：1983-03-23
申请人： Erwin Dietz , Erich Hoffmann , Joachim Weide
发明人： Erwin Dietz , Erich Hoffmann , Joachim Weide
IPC分类号： C08G65/00 , B01F17/42 , B01F17/46 , C07C67/00 , C07C213/00 , C07C213/04 , C07C217/08 , C07C217/32 , C07C217/50 , C08G59/14 , C08G59/50 , C08G59/64 , C08G65/08 , C08G65/26 , C09B67/46 , C09D5/00 , C09D5/02 , C09D11/02
CPC分类号： C08G65/08 , C08G59/64 , C08G65/26 , C09B67/0089
摘要： Compounds of the general formulaX--Y--O--(A--O--Y--O).sub.m --A--O--Y--X (1)wherein X is a radical of the general formula[R.sup.1 --G.sub.p --(O--CHR.sup.2 --CHR.sup.3 --).sub.n ].sub.2 N--(1a)in which R.sup.1 is a saturated aliphatic radical of from 6 to 30 carbon atoms or an unsaturated aliphatic radical having one or several ethylenic bonds and being of from 6 to 30 carbon atoms, G is phenylene or naphthylene, p is zero or 1, R.sup.2 and R.sup.3 are hydrogen or methyl, but are not both methyl, and n is a number from 0 to 25, Y is a radical of the formula ##STR1## in which R.sup.2 and R.sup.3 have the indicated meanings and q represents identical or different numbers from 0 to about 200, A is a radical of the general formula ##STR2## in which R.sup.4 and R.sup.5 are hydrogen or alkyl of from 1 to 3 carbon atoms, and m is a number from zero to 5, n and q not being both zero; and their use, in particular as dispersing agents, are disclosed.
摘要翻译：通式XYO-（AOYO）mAOYX（1）的化合物，其中X是通式[R1-Gp-（O-CHR2-CHR3-）n] 2N-（1a）的基团，其中R1是饱和脂族具有6至30个碳原子的基团或具有一个或几个烯键并且具有6至30个碳原子的不饱和脂族基团，G是亚苯基或亚萘基，p是0或1，R2和R3是氢或甲基，但是不是甲基，n是0至25的数，Y是式（1b）的基团，其中R2和R3具有指定的含义，q表示0至约200的相同或不同的数字， A是通式为（Ia）的基团，其中R 4和R 5是氢或1至3个碳原子的烷基，m是从0到5的数，n和q不都是0; 并且其使用，特别是作为分散剂的用途被公开。

66. 发明授权

US4952732A Mannich condensates of a substituted phenol and an alkylamine containing internal alkoxy groups 失效
标题翻译：取代苯酚和含有内部烷氧基的烷基胺的曼尼希缩合物
公开(公告)号：US4952732A
公开(公告)日：1990-08-28
申请号：US621332
申请日：1984-06-15
申请人： George P. Speranza , Robert A. Grigsby, Jr. , Ernest L. Yeakey
发明人： George P. Speranza , Robert A. Grigsby, Jr. , Ernest L. Yeakey
IPC分类号： B01F17/00 , C07C217/50 , C09D7/12 , C23F11/14
CPC分类号： C07C217/50 , B01F17/0042 , B01F17/005 , C09D7/1233 , C23F11/142
摘要： Products useful as surfactants, corrosion inhibitors, water repellent agents, paint adhesion promoters, etc. are prepared by reacting formaldehyde and a phenol with an alkyl amine containing internal propoxy or propoxy/ethoxy groups to thereby provide a corresponding Mannich condensate having a desired utility. The Mannich condensates may also be reacted with an alkylene oxide feed stock containing ethylene oxide or propylene oxide or 1,2-butylene oxide or a mixture thereof under conventional alkoxylation conditions to thereby provide a corresponding alkoxylated Mannich condensate having a utility which may be the same as or different from the utility of the initial Mannich condensate.
摘要翻译：通过使甲醛和苯酚与含有内丙氧基或丙氧基/乙氧基的烷基胺反应制备用作表面活性剂，防腐蚀剂，防水剂，涂料粘合促进剂等的产品，从而提供具有所需效用的相应的曼尼希缩合物。曼尼希缩合物也可以在常规烷氧基化条件下与含有环氧乙烷或环氧丙烷或1,2-环氧丁烷或其混合物的烯化氧原料反应，从而提供相应的烷氧基化曼尼希缩合物，其具有可能相同的效用作为或不同于最初的曼尼希凝析油的效用。

67. 发明授权

US4904825A Quaternary ammonium antistatic compounds 失效
标题翻译：季铵抗静电化合物
公开(公告)号：US4904825A
公开(公告)日：1990-02-27
申请号：US268903
申请日：1988-11-08
申请人： Cheruthur Govindan
发明人： Cheruthur Govindan
IPC分类号： C07D295/22 , C03C25/24 , C07C215/40 , C07C217/50 , C07C309/31 , C07D295/088 , C08J5/00 , C08J7/04 , C08K5/19 , C08K5/41 , C08K5/42 , C09K3/16 , D06M13/463
CPC分类号： C07D295/088 , C03C25/246 , C07C215/40 , C07C217/50 , C07C309/31 , C08K5/19 , C08K5/42 , C09K3/16 , D06M13/463
摘要： Described are certain quaternary ammonium alkyl benzene sulfonate salts and certain quaternary ammonium alkane sulfonate salts, e.g., octyl dimethyl hydroxyethyl ammonium dodecyl benzene sulfonate and octyl dimethyl hydroxyethyl ammonium methane sulfonate which are useful as antistatic agents for synthetic polymer articles.
摘要翻译：描述了某些季铵烷基苯磺酸盐和某些季铵烷基磺酸盐，例如辛基二甲基羟乙基铵十二烷基苯磺酸盐和辛基二甲基羟乙基铵甲磺酸盐，它们可用作合成聚合物制品的抗静电剂。

68. 发明授权

US4888446A Preparation of polyoxyalkylene glycol amines 失效
标题翻译：聚氧亚烷基二醇胺的制备
公开(公告)号：US4888446A
公开(公告)日：1989-12-19
申请号：US179827
申请日：1988-04-11
申请人： Howard P. Klein , Michael Cuscurida
发明人： Howard P. Klein , Michael Cuscurida
IPC分类号： C07C213/02 , C07C213/08 , C07C217/50 , C08G18/32 , C08G18/50 , C08G65/26 , C08G65/325 , C08G65/338
CPC分类号： C07C213/08 , C07C213/02 , C07C217/50 , C08G18/3271 , C08G18/5024 , C08G65/2609 , C08G65/3255 , C08G65/338
摘要： The invention concerns a method for the preparation of polyoxyalkylene compounds wherein each compound has one primary amine group and one primary hydroxyl group. The method comprises alkoxylating a t-butyl ethylene, propylene or butylene glycol then aminating the product. Finally the t-butyl group is cleaved by an acid. The compounds of the method of this invention are useful in urethane/urea plastics including foams, elastomers and coatings.
摘要翻译：本发明涉及一种制备聚氧化烯化合物的方法，其中每种化合物具有一个伯胺基和一个伯羟基。该方法包括将叔丁基乙烯，丙烯或丁二醇烷氧基化，然后胺化产物。最后，叔丁基被酸裂解。本发明方法的化合物可用于聚氨酯/脲塑料，包括泡沫，弹性体和涂料。

69. 发明授权

US4885390A Alkoxylated ethylene glycol diamine bottoms products for rigid urethane foams 失效
标题翻译：用于刚性聚氨酯泡沫的烷氧基化乙二醇二胺底产物
公开(公告)号：US4885390A
公开(公告)日：1989-12-05
申请号：US117559
申请日：1987-10-30
申请人： George P. Speranza , Michael E. Brennan , Jiang-Jen Lin
发明人： George P. Speranza , Michael E. Brennan , Jiang-Jen Lin
IPC分类号： C07C217/50 , C08G18/50 , C07C89/02
CPC分类号： C08G18/5021 , C07C217/50 , C08G2101/0025
摘要： Novel amino polyols made by alkoxylating ethylene glycol diamine bottoms products, such as triethylene glycol diamine bottoms products, and tetraethylene glycol diamine bottoms products are described. For example, these bottoms products, alone or together, maybe propoxylated in a non-catalytic reaction to give amino polyols that are useful in producing rigid polyurethane foams. The resultant foams have better K-factors and a higher percentage of closed cells than comparable foams made with conventional amino polyols.
摘要翻译：描述了通过乙二醇二胺塔底产物烷氧化制备的新型氨基多元醇，例如三甘醇二胺塔底产物和四甘醇二胺塔底产物。例如，单独或一起的这些底部产物可在非催化反应中进行丙氧基化，得到可用于生产刚性聚氨酯泡沫的氨基多元醇。与常规氨基多元醇制成的可比泡沫相比，所得泡沫具有更好的K-因子和更高百分比的闭孔。

70. 发明授权

US4485259A Pigment grinding vehicle 失效
标题翻译：颜料研磨车
公开(公告)号：US4485259A
公开(公告)日：1984-11-27
申请号：US430304
申请日：1982-09-30
申请人： Robert D. Jerabek , Jeffrey G. Koren , Mark W. Johnson
发明人： Robert D. Jerabek , Jeffrey G. Koren , Mark W. Johnson
IPC分类号： C09D5/44 , C07C67/00 , C07C213/00 , C07C213/04 , C07C217/50 , C09C3/00 , C09C3/08 , C09C3/10 , C09D11/00 , C09D11/02 , C09D11/10 , C09D17/00 , C07C91/26
CPC分类号： C09D17/00 , Y10T428/24372
摘要： A novel quaternary ammonium group-containing material which is obtained from reacting a monoepoxide with an amine containing at least one organic group containing an acyclic moiety of from about 8 to 30 carbon atoms is disclosed. The quaternary ammonium group-containing materials are useful as pigment grinding vehicles and in the formulation of pigment paste, particularly pigment paste with high pigment loadings. When formulated in cationic electrodepositable compositions, the pigment grinding vehicles provide for cured electrodeposited coatings of excellent corrosion resistance, particularly over untreated and oily steel.
摘要翻译：公开了一种新的含季铵基的材料，其由单环氧化物与含有至少一个含有约8至30个碳原子的无环部分的有机基团的胺反应获得。含季铵基的材料可用作颜料研磨载体和颜料糊剂的配方，特别是具有高颜料负载的颜料糊剂。当配制在阳离子可电沉积组合物中时，颜料研磨车辆提供具有优异耐腐蚀性的固化电沉积涂料，特别是未处理和油性钢。

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