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51. 发明授权

US06808806B2 Methods for producing imaged coated articles by using magnetic pigments 有权
标题翻译：通过使用磁性颜料生产成像的涂布制品的方法
公开(公告)号：US06808806B2
公开(公告)日：2004-10-26
申请号：US09850421
申请日：2001-05-07
申请人： Roger W. Phillips , Charlotte R. LeGallee , Charles T. Markantes , Paul G. Coombs , Matthew R. Witzman
发明人： Roger W. Phillips , Charlotte R. LeGallee , Charles T. Markantes , Paul G. Coombs , Matthew R. Witzman
IPC分类号： B32B516
CPC分类号： B32B5/16 , B05D3/067 , B05D3/20 , B05D5/061 , B41M3/00 , B41M3/008 , B41M3/06 , B41M3/14 , B41M3/148 , B42D25/00 , B42D25/29 , B42D25/369 , B42D25/42 , B42D25/455 , B42D25/47 , B42D2033/16 , B42D2033/20 , B44F1/08 , C01P2004/54 , C01P2006/42 , C08J7/04 , C09C1/0015 , C09C1/0024 , C09C1/0033 , C09C1/0039 , C09C1/0045 , C09C1/0051 , C09C1/006 , C09C1/0066 , C09C1/0072 , C09C1/0078 , C09C2200/1004 , C09C2200/1008 , C09C2200/1054 , C09C2200/24 , C09C2200/301 , C09C2200/304 , D06P1/004 , D06P1/0076 , D06P1/44 , D06Q1/00 , Y10T428/24835 , Y10T428/29 , Y10T428/2982 , Y10T428/2989 , Y10T428/2991 , Y10T428/31504
摘要： Methods and devices for producing images on coated articles are provided. The methods generally comprise applying a layer of magnetizable pigment coating in liquid form on a substrate, with the magnetizable pigment coating containing a plurality of magnetic non-spherical particles or flakes. A magnetic field is then applied to selected regions of the pigment coating while the coating is in liquid form, with the magnetic field altering the orientation of selected magnetic particles or flakes. Finally, the pigment coating is solidified, affixing the reoriented particles or flakes in a non-parallel position to the surface of the pigment coating to produce an image such as a three dimensional-like image on the surface of the coating. The pigment coating can contain various interference or non-interference magnetic particles or flakes, such as magnetic color shifting pigments.
摘要翻译：提供了用于在涂层制品上产生图像的方法和装置。所述方法通常包括将液体形式的可磁化颜料涂层施加到基底上，其中可磁化颜料涂层含有多个磁性非球形颗粒或薄片。然后将磁场施加到颜料涂层的选定区域，同时涂层为液体形式，磁场改变所选择的磁性颗粒或薄片的取向。最后，颜料涂层固化，将重新取向的颗粒或薄片固定在与颜料涂层表面不平行的位置，以在涂层的表面上产生诸如三维样图像的图像。颜料涂层可以包含各种干扰或不干扰的磁性颗粒或薄片，例如磁性色移颜料。

52. 发明申请

US20040177788A1 Interference pigments having a mass tone 审中-公开
标题翻译：具有质量色调的干涉颜料
公开(公告)号：US20040177788A1
公开(公告)日：2004-09-16
申请号：US10796187
申请日：2004-03-10
发明人： Norbert Rick , Lilia Heider , Manuela Loch , Nicole Schupp , Ralf Anselmann
IPC分类号： C23C016/00 , B05D007/00
CPC分类号： C09C1/0039 , C01P2006/62 , C01P2006/63 , C01P2006/64 , C01P2006/65 , C09C2200/1004 , C09C2200/102 , C09C2200/302 , C09C2200/303 , C09C2200/306 , C09C2220/106
摘要： Interference pigments having a mass tone based on multicoated flake-form substrates, which have on the substrate: (A) a colorless coating having a refractive index of n>1.8 and a layer thickness of 20-250 nm, (B) a colorless coating having a refractive index of nnull1.8 and a layer thickness of 10-100 nm, (C) a colorless coating having a refractive index of n>1.8 and a layer thickness of 20-250 nm, (D) an absorbent layer having a layer thickness of 1-100 nm, and optionally (E) an outer protective layer, are described. Also described is the use thereof in paints, coatings, printing inks, plastics, ceramic materials, glasses, for laser marking, in cosmetic formulations and for the preparation of pigment compositions and dry preparations.
摘要翻译：在基片上具有基于多层片状基片的质量色调的干涉颜料：（A）折射率为n> 1.8且层厚度为20-250nm的无色涂层，（B）无色涂层具有n <1.8的折射率和10-100nm的层厚度，（C）折射率为n> 1.8且层厚度为20-250nm的无色涂层，（D）具有描述了1-100nm的层厚度和任选的（E）外部保护层。还描述了其在油漆，涂料，印刷油墨，塑料，陶瓷材料，玻璃，激光标记，化妆品配方中的用途以及颜料组合物和干燥制剂的制备。

53. 发明申请

US20040144023A1 Multilayer interference pigments 审中-公开
标题翻译：多层干涉颜料
公开(公告)号：US20040144023A1
公开(公告)日：2004-07-29
申请号：US10757456
申请日：2004-01-15
发明人： Hans-Dieter Bruckner , Andrea Heyland , Christoph Schmidt , Christina Schank , Claudia Seibel
IPC分类号： A01G013/02
CPC分类号： C09C1/0024 , A01G9/1438 , A61K8/0266 , A61K8/19 , A61K8/25 , A61K8/26 , A61K8/29 , A61K2800/412 , A61K2800/436 , A61Q1/02 , B41M5/267 , C01P2006/60 , C04B20/12 , C04B2103/54 , C04B2111/00413 , C08J3/20 , C08K9/02 , C09C1/0039 , C09C2200/1004 , C09C2200/102 , C09C2200/1087 , C09C2200/302 , C09C2200/303 , C09C2200/306 , C09C2210/10 , C09C2220/106 , C09D5/36 , C09D7/62 , C09D11/037 , Y02A40/252 , C04B14/20 , C04B20/1066 , C04B20/126 , C04B14/06 , C04B14/22
摘要： Multilayer interference pigment consisting of a transparent carrier material coated with alternating layers of metal oxides of low and high refractive index, the difference in the refractive indices being at least 0.1, which is obtainable by alternate coating of the transparent carrier material with a metal oxide of high refractive index and with a metal oxide of low refractive index in a wet process by hydrolysis of the corresponding water-soluble metal compounds, separation, drying and, if desired, calcination of the resulting pigment.

54. 发明授权

US06726856B2 Process for preparing electrically conductive pigments 失效
标题翻译：制备导电颜料的方法
公开(公告)号：US06726856B2
公开(公告)日：2004-04-27
申请号：US09982537
申请日：2001-10-19
申请人： Ralf Glausch
发明人： Ralf Glausch
IPC分类号： H01B108
CPC分类号： C09C1/0021 , C01P2002/52 , C01P2004/54 , C01P2006/40 , C09C2200/1004 , C09C2200/102 , C09C2200/20 , C09C2200/301 , H01B1/08
摘要： The invention relates to a process for preparing electrically conductive pigments based on F−- and/or PO43−-doped tin mixed oxides applied as an electrically conductive layer to a substrate, in which, first of all, SnO2-coated substrates are prepared by precipitation and subsequent calcining and then, in further process steps, this SnO2 layer is converted into a tin mixed oxide layer doped with F− and/or PO43−. The invention further relates to electrically conductive pigments prepared by the process of the invention, to the use of these pigments for pigmenting lacquers, printing inks, plastics systems or coatings, and to lacquers, printing inks, plastics systems or coatings pigmented with an electrically conductive pigment prepared by the process of the invention.
摘要翻译：本发明涉及一种制备基于作为导电层施加到衬底上的掺杂有PO 3 - 和/或PO 4 3-的锡混合氧化物的导电颜料的方法，其中首先将SnO 2 - 通过沉淀和随后的煅烧制备涂覆的基材，然后在进一步的工艺步骤中，将该SnO 2层转化为掺杂有F和/或PO 4 3-的锡混合氧化物层。本发明还涉及通过本发明的方法制备的导电颜料，用于这些颜料用于着色漆，印刷油墨，塑料体系或涂料以及漆，印刷油墨，塑料体系或用导电颜料着色的涂料通过本发明的方法制备的颜料。

55. 发明授权

US06719838B2 Colored interference pigments 有权
标题翻译：彩色干涉颜料
公开(公告)号：US06719838B2
公开(公告)日：2004-04-13
申请号：US10279017
申请日：2002-10-24
申请人： Lilia Heider , Manuela Loch , Nicole Schupp , Helge Kniess
发明人： Lilia Heider , Manuela Loch , Nicole Schupp , Helge Kniess
IPC分类号： C04B1420
CPC分类号： A61K8/19 , A61K8/0266 , A61K8/20 , A61K8/25 , A61K8/26 , A61K8/27 , A61K8/29 , A61K2800/412 , A61K2800/436 , A61K2800/621 , A61K2800/63 , A61K2800/651 , A61Q1/06 , A61Q1/08 , A61Q1/10 , A61Q3/02 , A61Q19/10 , B41M5/267 , C01P2006/62 , C01P2006/63 , C01P2006/64 , C01P2006/65 , C01P2006/66 , C03C1/04 , C08K9/02 , C09C1/0015 , C09C1/0039 , C09C1/0042 , C09C2200/1004 , C09C2200/102 , C09C2200/1087 , C09C2220/106 , C09D5/36
摘要： The present invention relates to colored interference pigments based on multicoated, platelet-shaped substrates, which are distinguished in that they comprise (A) a colored coating having a refractive index of n>1.8, (B) a colorless coating having a refractive index of n>1.8, (C) a colorless coating having a refractive index of n≦1.8, (D) a colorless coating having a refractive index of n>1.8, and optionally (E) an outer protective layer, and to their use in paints, surface coatings, printing inks, plastics, ceramic materials, glasses, for laser marking, in cosmetic formulations and for the production of pigment preparations and dry preparations.
摘要翻译：本发明涉及基于多层板状基板的着色干涉颜料，其特征在于它们包括（A）折射率为n> 1.8的着色涂层，（B）无色涂层，折射率为 n≥1.8，（C）折射率为n <1.8的无色涂层，（D）折射率为n> 1.8的无色涂层，和任选地（E）外保护层，以及它们在油漆，表面涂料，印刷油墨，塑料，陶瓷材料，眼镜，激光打标，化妆品配方和颜料制剂和干制剂的生产。

56. 发明授权

US06706785B1 Methods and compositions related to laser sensitive pigments for laser marking of plastics 失效
标题翻译：与激光标记激光激光颜料有关的方法和组成
公开(公告)号：US06706785B1
公开(公告)日：2004-03-16
申请号：US09506701
申请日：2000-02-18
申请人： Guoyi Fu
发明人： Guoyi Fu
IPC分类号： C08K900
CPC分类号： B41M5/267 , C01P2004/20 , C01P2004/84 , C09C1/0021 , C09C2200/1004 , C09C2200/102 , C09C2210/60
摘要： Platelet-shaped substrates that are coated with metal oxides and that are useful in the laser marking of plastics are disclosed. The platelet-shaped substrates may be employed as an additive to plastic for laser marking of a wide variety of plastics and for use with a number of different laser types.
摘要翻译：公开了涂覆有金属氧化物并且可用于塑料的激光标记的片状基材。可以使用血小板形基材作为塑料添加剂，用于各种塑料的激光标记并用于多种不同的激光类型。

57. 发明授权

US06706109B2 Optically variable interference pigments 失效
标题翻译：光学可变干涉颜料
公开(公告)号：US06706109B2
公开(公告)日：2004-03-16
申请号：US10143781
申请日：2002-05-14
申请人： Carmine V. DeLuca, Jr.
发明人： Carmine V. DeLuca, Jr.
IPC分类号： C04B1420
CPC分类号： C09C1/0021 , C01P2004/20 , C01P2004/84 , C09C1/0015 , C09C1/0018 , C09C2200/1004 , C09C2200/102 , C09C2200/301 , C09C2200/308 , C09C2220/10
摘要： Optically variable interference pigments are composed of platelets of at least partly core-free titanium dioxide-coated substrate of about 1-25 mm particle size and an interference thickness of about 5-600 nm which have an oxide coating thereon.
摘要翻译：光学可变干涉颜料由至少部分无芯的二氧化钛涂覆的基材的片状物组成，其中大约1-25mm粒径和约5-600nm的干涉厚度在其上具有氧化物涂层。

58. 发明授权

US06692561B1 Intensely colored interference pigments 有权
标题翻译：强烈的彩色干涉颜料
公开(公告)号：US06692561B1
公开(公告)日：2004-02-17
申请号：US10111772
申请日：2002-09-05
申请人： Sabine Schoen , Klaus Bernhardt , Christoph Schmidt
发明人： Sabine Schoen , Klaus Bernhardt , Christoph Schmidt
IPC分类号： C09C136
CPC分类号： C09C1/0066 , C01P2006/62 , C01P2006/63 , C01P2006/64 , C01P2006/65 , C01P2006/66 , C08K9/02 , C08K2201/014 , C09C1/0009 , C09C2200/1004 , C09C2200/102 , C09C2200/302 , C09C2200/303 , C09C2200/306 , C09C2210/60 , C09C2220/106 , C09D5/36
摘要： The invention relates to intensely colored interference pigments based on multi-layered plate-like substrates with at least two sequences of layers consisting of (A) a colorless layer with a refraction index n≦1,8; (B) a high-index layer consisting of a mixture of TiO2 and Fe2O3 in a ratio of 1:0.1 to 1:5 and optionally, one or more metal oxides in quantities of to layer (B); and optionally (C) an outer protective layer.
摘要翻译：本发明涉及基于多层板状基材的强烈着色的干涉颜料，其具有至少两个由（A）折射率n <1.8的无色层组成的层序列; （B）由比例为1:0.1至1:5的TiO 2和Fe 2 O 3的混合物组成的高折射率层，以及任选的一种或多种量为（B）的金属氧化物; 和（C）外保护层。

59. 发明授权

US06656259B2 Multilayered interference pigments 失效
标题翻译：多层干涉颜料
公开(公告)号：US06656259B2
公开(公告)日：2003-12-02
申请号：US10210873
申请日：2002-08-02
申请人： Gerhard Pfaff , Helge Kniess , Peter Reynders
发明人： Gerhard Pfaff , Helge Kniess , Peter Reynders
IPC分类号： C04B1400
CPC分类号： A61K8/27 , A61K8/11 , A61K8/19 , A61K8/25 , A61K8/28 , A61K8/29 , A61K2800/412 , A61K2800/436 , A61Q1/02 , C01P2004/20 , C01P2004/84 , C08K9/02 , C09C1/0021 , C09C1/0024 , C09C2200/1004 , C09C2200/301 , C09C2200/302 , C09C2200/303 , C09C2220/106 , C09D5/36 , Y10T428/2993
摘要： The invention relates to multilayered interference pigments which comprise a platelet-shaped substrate of silicon dioxide which is coated alternately with layers of light-transparent materials having refractive indices of n>1.8 and layers of light-transparent materials having refractive indices of n≦1.8, where the optical thickness of the platelet-shaped substrate and the optical thickness of the individual layers of light-transparent materials having refractive indices of n≦1.8 are the same.
摘要翻译：本发明涉及多层干涉颜料，其包括二氧化硅的片状基底，其交替地涂覆折射率为n≥1.8的光透明材料层，并且折射率为n <1.8的透光材料层其中，片状基板的光学厚度和折射率为n <1.8的透明材料的各层的光学厚度相同。

60. 发明申请

US20030178734A1 Process for making angstrom scale and high aspect functional platelets 审中-公开
标题翻译：制作埃及量表和高端功能血小板的方法
公开(公告)号：US20030178734A1
公开(公告)日：2003-09-25
申请号：US10306792
申请日：2002-11-27
发明人： Karl Josephy , James P. Rettker , Howard H. Enlow
IPC分类号： B29C069/00 , C23C016/00
CPC分类号： B22F1/0055 , B22F9/12 , B22F2999/00 , B82Y30/00 , C01P2004/03 , C01P2004/20 , C01P2004/51 , C01P2004/54 , C01P2004/61 , C01P2004/64 , C01P2004/80 , C01P2004/86 , C01P2006/12 , C01P2006/40 , C01P2006/60 , C01P2006/90 , C08K3/013 , C08K3/34 , C08K7/00 , C09C1/0018 , C09C1/62 , C09C1/64 , C09C2200/1004 , C09C2200/1037 , C09C2200/1054 , C09C2200/1062 , C09C2200/301 , C09C2220/20 , C23C14/0005 , C23C14/024 , C23C14/562 , C23C14/568 , C23C14/00
摘要： A multi-layer sandwich of vapor deposited metal and release coats in alternating layers is applied to a drum or carrier in a vapor deposition chamber. The metallized layers are applied by vapor deposition. The release layers are solvent soluble thermoplastic or lightly crosslinked polymeric materials applied by vapor deposition in the chamber. The multi-layer sandwich is removed and treated with solvent to dissolve the release coating from the metal flakes. The release coat material can be a radiation curable, crosslinkable vapor deposited polymeric material of low crosslink density. A high energy radiation source crosslinks the release material to produce tack-free, solvent soluble release coat layers. The multi-layer vapor deposit can be built up on an endless belt passing from the chamber through a separate vacuum lock. Both chambers are at vacuum pressures below atmospheric while depositing the flake material. The vapor deposit is removed by reducing belt speed, idling the vacuum deposition sources, and sealing a collection device to the stripping chamber through vacuum locks below the stripping chamber. The stripping chamber is at vacuum pressure below atmospheric when removing the vapor deposit material from the belt.
摘要翻译：气相沉积金属的多层三明治和交替层的脱模涂层施加到气相沉积室中的鼓或载体上。通过气相沉积施加金属化层。释放层是通过气相沉积在室中施加的溶剂可溶性热塑性或轻质交联的聚合物材料。去除多层三明治并用溶剂处理以从金属薄片溶解脱模涂层。脱模涂层材料可以是低交联密度的可辐射固化的，可交联的气相沉积聚合材料。高能辐射源使释放材料交联以产生无粘性溶剂可溶的脱模涂层。多层蒸气沉积物可以在通过单独的真空锁定从腔室通过的环形带上构建。两个室在真空压力低于大气压的同时沉积薄片材料。通过减小皮带速度，空转真空沉积源来除去气相沉积物，并通过抽吸室下方的真空锁将收集装置密封到汽提室。当从带中去除气相沉积材料时，汽提室的真空压力低于大气压。

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