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1. 发明授权

US08647429B2 Effect pigments 有权
标题翻译：效果颜料
公开(公告)号：US08647429B2
公开(公告)日：2014-02-11
申请号：US13577026
申请日：2011-02-02
申请人： Sabine Melson , Volker Wilhelm , Ulrich Schoenefeld
发明人： Sabine Melson , Volker Wilhelm , Ulrich Schoenefeld
IPC分类号： C09C1/00 , C09C3/06
CPC分类号： C09C1/0015 , A61K8/0258 , A61K8/19 , A61K8/25 , A61K8/26 , A61K8/27 , A61K8/29 , A61K2800/10 , A61K2800/436 , A61Q19/00 , C01P2004/61 , C01P2006/12 , C09C2200/1004 , C09C2200/102 , C09C2200/1037 , C09C2200/1054 , C09C2200/1062 , C09C2200/1087 , C09C2200/20 , C09C2200/30 , C09C2200/307 , C09C2220/10 , C09C2220/106
摘要： The present invention relates to effect pigments based on uncoated or coated flake-form substrates having an outer coating comprising a) TiO2 and b) Al2O3, MgO and/or CaO and c) SiO2 and d) ZnO and/or e) at least one mixed oxide of the elements mentioned under a) to d), and to the use thereof, inter alia in paints, coatings, printing inks, plastics and cosmetic formulations.
摘要翻译：本发明涉及基于未涂覆或涂覆的片状基材的效果颜料，其具有外涂层，其包含a）TiO 2和b）Al 2 O 3，MgO和/或CaO和c）SiO 2和d）ZnO和/或e）至少一种 a）至d）中提到的元素的混合氧化物，以及其在涂料，涂料，印刷油墨，塑料和化妆品制剂中的用途。

2. 发明申请

US20100196296A1 MULTI-LAYER METALLIC EFFECT PIGMENTS, PROCESS FOR THEIR PREPARATION AND USE 有权
标题翻译：多层金属效应颜料，其制备和使用过程
公开(公告)号：US20100196296A1
公开(公告)日：2010-08-05
申请号：US12670007
申请日：2008-07-24
申请人： Bernhard Geissler , Wolfgang Herzing , Jasmin Bleisteiner , Martin Fischer , Ralph Schneider
发明人： Bernhard Geissler , Wolfgang Herzing , Jasmin Bleisteiner , Martin Fischer , Ralph Schneider
IPC分类号： C09C1/62 , B32B15/04 , C23C16/06 , C23C16/40 , C09D11/02 , A61K8/19 , A61Q3/02 , A61Q1/04 , A61Q1/06 , A61Q1/10
CPC分类号： C09C1/0021 , A61K8/0258 , A61K8/11 , A61K2800/412 , A61K2800/436 , A61Q1/02 , A61Q1/06 , A61Q3/02 , C01P2004/20 , C01P2004/54 , C01P2004/60 , C01P2004/61 , C01P2006/60 , C01P2006/62 , C01P2006/63 , C01P2006/64 , C01P2006/65 , C08K3/08 , C08K9/02 , C08K2201/014 , C09C1/62 , C09C1/642 , C09C2200/1037 , C09C2200/20 , C09C2200/30 , C09C2200/308 , C09C2200/502 , C09C2200/505 , C09C2220/20 , C09D5/035 , C09D5/36 , C09D7/62 , C09D7/67 , C09D7/68 , C09D11/037 , C09D11/322 , Y10T428/12056 , Y10T428/12549
摘要： A metallic effect pigment comprising at least three layers:A) a layer A which comprises at least one metal MA and has an average oxygen content OA, based on the total amount of MA and OA in the layer A, B) a layer B comprising at least one metal MB and having an average oxygen content OB of 0 to 77 atom %, more particularly of 0 to 58 atom %, based on the total amount of MB and OB in the layer B, C) a layer C which comprises at least one metal MC and has an average oxygen content OC, based on the total amount of MC and OC in the layer C, the average oxygen content OAC in layers A and C being determined in accordance with the formula (I) O AC = 1 2  ( O A M A + O A + O C M C + O C ) ( I ) and being situated within a range from 2 to 77 atom %, more particularly from 25 to 58 atom %.The disclosure further relates to processes for preparing this effect pigment and also to its use.
摘要翻译：包含至少三层的金属效应颜料：A）包含至少一种金属MA并且具有基于层A中的MA和OA的总量的平均氧含量OA的层A，B）包含至少一种金属MB，其平均氧含量OB为0至77原子％，更特别为0至58原子％，基于B层中的MB和OB的总量，C）包含在至少一种金属MC，并且基于层C中的MC和OC的总量具有平均氧含量OC，层A和C中的平均氧含量OAC根据式（I）确定为：AC = 1 2（OAMA + OA + OCMC + OC）（I），位于2〜77原子％的范围内，更优选为25〜58原子％。本公开还涉及制备该效果颜料的方法以及其用途。

3. 发明授权

US08864899B2 PVD metal effect pigment having gradient on nanoscale metal particles, method for the production thereof and use thereof 有权
标题翻译：具有在纳米级金属颗粒上具有梯度的PVD金属效应颜料，其制备方法及其用途
公开(公告)号：US08864899B2
公开(公告)日：2014-10-21
申请号：US13146254
申请日：2010-01-28
申请人： Bernhard Geissler , Wolfgang Herzing , Frank Henglein , Ralph Schneider , Martin Fischer
发明人： Bernhard Geissler , Wolfgang Herzing , Frank Henglein , Ralph Schneider , Martin Fischer
IPC分类号： C09C1/62 , C09C1/00 , C09C1/64
CPC分类号： C09C1/0015 , C01P2002/70 , C01P2004/04 , C01P2004/54 , C09C1/0018 , C09C1/0078 , C09C1/62 , C09C1/64 , C09C2200/20 , C09C2200/24 , C09C2200/307 , C09C2200/40 , C09C2200/401 , C09C2200/402 , C09C2200/50 , C09C2200/502 , C09C2200/505 , C09C2220/20
摘要： A platelet-shaped PVD metallic effect pigment having first and second outer faces, the platelet-shaped PVD metallic effect pigment having at least one PVD layer, the at least one PVD layer including elemental metal with clusters of elemental metal and metal oxide. The amounts of elemental metal in the first outer face and in the second outer face of the PVD metallic effect pigment are different from one another and they differ by at least 10 atom %. The disclosure further relates to a method for producing these platelet-shaped PVD metallic effect pigments, and to their use.
摘要翻译：一种具有第一和第二外表面的片状PVD金属效应颜料，所述片状PVD金属效应颜料具有至少一个PVD层，所述至少一个PVD层包括具有元素金属和金属氧化物簇的元素金属。 PVD金属效应颜料的第一外表面和第二外表面中的元素金属的量彼此不同，它们相差至少为10原子％。本发明还涉及一种制备这些片状PVD金属效应颜料的方法及其应用。

4. 发明申请

US20080200560A1 Pigments 有权
标题翻译：颜料
公开(公告)号：US20080200560A1
公开(公告)日：2008-08-21
申请号：US11994271
申请日：2006-06-16
申请人： Helge Bettina Kniess , Gerhard Pfaff
发明人： Helge Bettina Kniess , Gerhard Pfaff
IPC分类号： A61K8/19 , C09C1/00 , C08K3/08 , B42D15/10 , A23L1/27 , C09D11/00
CPC分类号： C09C1/0015 , A61K8/19 , A61K2800/436 , A61Q1/02 , A61Q3/02 , C01P2004/86 , C09C1/0021 , C09C1/0078 , C09C2200/1004 , C09C2200/102 , C09C2200/1087 , C09C2200/20 , C09C2210/60 , C09C2220/10 , Y10T428/2982 , Y10T428/2991
摘要： The present invention relates to pigments comprising a substrate and, applied thereto, an iron-containing coating comprising metallic iron, process for the preparation of the pigments according to the invention, and the use thereof.
摘要翻译：本发明涉及包含基材和涂覆在其上的包含金属铁的含铁涂层，用于制备根据本发明的颜料的方法及其用途的颜料。

5. 发明申请

US20020053661A1 Process for preparing electrically conductive pigments 失效
标题翻译：制备导电颜料的方法
公开(公告)号：US20020053661A1
公开(公告)日：2002-05-09
申请号：US09982537
申请日：2001-10-19
申请人： MERCK PATENTGESELLSCHAFT MIT BESCHRANKTER HAFTUNG
发明人： Ralf Glausch
IPC分类号： H01C001/00
CPC分类号： C09C1/0021 , C01P2002/52 , C01P2004/54 , C01P2006/40 , C09C2200/1004 , C09C2200/102 , C09C2200/20 , C09C2200/301 , H01B1/08
摘要： The invention relates to a process for preparing electrically conductive pigments based on Fnull- and/or PO43null-doped tin mixed oxides applied as an electrically conductive layer to a substrate, in which, first of all, SnO2-coated substrates are prepared by precipitation and subsequent calcining and then, in further process steps, this SnO2 layer is converted into a tin mixed oxide layer doped with Fnull and/or PO43null. The invention further relates to electrically conductive pigments prepared by the process of the invention, to the use of these pigments for pigmenting lacquers, printing inks, plastics systems or coatings, and to lacquers, printing inks, plastics systems or coatings pigmented with an electrically conductive pigment prepared by the process of the invention.
摘要翻译：本发明涉及一种制备基于作为导电层施加到衬底上的F - 和/或PO43掺杂锡混合氧化物的导电颜料的方法，其中首先将SnO 2涂覆的衬底由然后在进一步的工艺步骤中将该SnO 2层转化成掺杂有F-和/或PO43-的锡混合氧化物层。本发明还涉及通过本发明的方法制备的导电颜料，用于这些颜料用于着色漆，印刷油墨，塑料体系或涂料以及漆，印刷油墨，塑料体系或用导电颜料着色的涂料通过本发明的方法制备的颜料。

6. 发明申请

US20170349756A1 Effect Pigments Having High Transparency, High Chroma and High Brilliancy, Method for the Production and Use Thereof 审中-公开
公开(公告)号：US20170349756A1
公开(公告)日：2017-12-07
申请号：US15536206
申请日：2015-12-21
申请人： Eckart GmbH
发明人： Michael Grüner , Günter Kaupp , Ralph Schneider
IPC分类号： C09C1/00 , A61Q19/00 , A61K8/02 , A61Q1/10 , A61K8/19 , A61K8/25
CPC分类号： C09C1/0024 , A61K8/0262 , A61K8/19 , A61K8/25 , A61K2800/262 , A61K2800/43 , A61Q1/10 , A61Q19/00 , C01P2002/52 , C01P2004/03 , C01P2004/51 , C01P2004/52 , C01P2004/61 , C01P2006/63 , C01P2006/64 , C01P2006/65 , C09C1/0009 , C09C1/0015 , C09C2200/1004 , C09C2200/102 , C09C2200/1033 , C09C2200/1087 , C09C2200/20 , C09C2200/301 , C09C2200/302 , C09C2200/304 , C09C2200/305 , C09C2200/401 , C09C2200/407 , C09C2220/106
摘要： The invention relates to a transparent effect pigment which includes a non-metallic platelet-shaped substrate and a coating applied thereto, wherein the coating has a spacer layer. The invention further relates to a method for the production, as well as the use, of the transparent effect pigment.

7. 发明申请

US20100218703A1 OPTICAL VARIABLE EFFECT PIGMENTS 审中-公开
标题翻译：光学变化效果颜料
公开(公告)号：US20100218703A1
公开(公告)日：2010-09-02
申请号：US12670862
申请日：2008-07-21
申请人： Patrice Bujard , Philippe Bugnon
发明人： Patrice Bujard , Philippe Bugnon
IPC分类号： C09B67/22
CPC分类号： C09C1/0015 , C01P2004/20 , C01P2004/61 , C01P2006/60 , C01P2006/65 , C09C1/0024 , C09C1/0051 , C09C1/62 , C09C1/64 , C09C1/642 , C09C2200/102 , C09C2200/20 , C09C2200/301 , C09D5/36
摘要： The present invention relates to pigments comprising (A) a platelet-shaped substrate (S), (B) a coating comprising two different metal oxides having a difference in refractive index of at least 0.1, wherein the metal oxide having a higher refractive indexis the metal oxide MOH and the metal oxide having a lower refractive index is the metal oxide MOL, wherein the amount of MOH and the amount of MOL changes (continuously), (C) a coating comprising metal oxides MOH and MOL, wherein the amount of MOH and the amount of MOL changes (continuously), and (D) optionally an outer protecting layer; a process for their production and their use in paints, ink-jet printing, for dyeing textiles, for pigmenting coatings (paints), printing inks, plastics, cosmetics, glazes for ceramics and glass. The pigments can show enhanced colour chroma while maintaining the lightness of coventional interference pigments, or vice versa.
摘要翻译：本发明涉及包含（A）片状基材（S）的颜料，（B）包含折射率差异至少为0.1的两种不同金属氧化物的涂层，其中折射率较高的金属氧化物为金属氧化物MOH和具有较低折射率的金属氧化物是金属氧化物MOL，其中MOH的量和MOL的量（连续地）变化，（C）包含金属氧化物MOH和MOL的涂层，其中MOH的量并且MOL的量（连续地）变化，和（D）任选的外部保护层; 用于油漆，喷墨印刷，染色纺织品，着色涂料（油漆），印刷油墨，塑料，化妆品，陶瓷和玻璃的釉料的生产过程。颜料可以显示增强的色度，同时保持常规干涉颜料的亮度，反之亦然。

8. 发明申请

US20070098989A1 Robust Multilayer Magnetic Pigments And Foils 有权
标题翻译：坚固的多层磁性颜料和箔片
公开(公告)号：US20070098989A1
公开(公告)日：2007-05-03
申请号：US11610256
申请日：2006-12-13
申请人： Vladimir Raksha , Paul Coombs , Charles Markantes , Dishuan Chu
发明人： Vladimir Raksha , Paul Coombs , Charles Markantes , Dishuan Chu
IPC分类号： B32B5/16 , B32B15/00
CPC分类号： H01F1/061 , B42D25/29 , B42D2033/16 , B42D2033/18 , B42D2033/20 , B42D2035/24 , C01P2006/42 , C08K7/00 , C08K9/02 , C09C1/0015 , C09C1/0024 , C09C1/0051 , C09C2200/1004 , C09C2200/1054 , C09C2200/20 , C09C2200/24 , C09C2200/301 , C09C2200/304 , C09C2220/20 , C09D5/36 , C09D7/62 , H01F1/0552 , H01F1/0572 , H01F1/113 , H01F1/1475 , H01F1/24 , H01F1/37 , H01F10/126 , H01F10/24 , H01F10/265 , Y10T428/12438 , Y10T428/12465 , Y10T428/12986 , Y10T428/257 , Y10T428/2982 , Y10T428/2991 , Y10T428/32 , Y10T428/325
摘要： Multilayered magnetic pigment flakes and foils are provided. The pigment flakes can have a stacked layer structure on opposing sides of a magnetic core, or can be formed as an encapsulant structure with encapsulating layers around the magnetic core. The magnetic core in the stacked layer structure includes a magnetic layer that is sandwiched between opposing insulator layers, which in turn are sandwiched between opposing reflector layers. Similarly, the magnetic core in the encapsulant structure includes a magnetic layer that is surrounded by an insulator layer, which in turn is surrounded by a reflector layer. The insulator layers in the pigment flakes substantially prevent corrosion of the flakes when exposed to harsh environments. Some embodiments of the pigment flakes and foils exhibit a discrete color shift at differing angles of incident light or viewing. The pigment flakes can be interspersed into liquid media such as paints or inks to produce colorant compositions for subsequent application to objects or papers. The foils can be laminated to various objects or can be formed on a carrier substrate.
摘要翻译：提供多层磁性颜料薄片和薄片。颜料薄片可以在磁芯的相对侧上具有堆叠层结构，或者可以形成为具有围绕磁芯的封装层的密封剂结构。堆叠层结构中的磁芯包括夹在相对的绝缘体层之间的磁性层，它们又夹在相对的反射层之间。类似地，密封剂结构中的磁芯包括被绝缘体层包围的磁性层，绝缘体层又被反射层包围。颜料薄片中的绝缘体层基本上防止了当暴露于恶劣环境时，薄片的腐蚀。颜料片和箔的一些实施方案在入射光或观察的不同角度处表现出离散的颜色偏移。颜料薄片可以散布到液体介质如油漆或油墨中，以产生用于随后应用于物体或纸张的着色剂组合物。箔可以层压到各种物体上，或者可以在载体基底上形成。

9. 发明授权

US06565770B1 Color-shifting pigments and foils with luminescent coatings 有权
标题翻译：色移颜料和带发光涂层的箔
公开(公告)号：US06565770B1
公开(公告)日：2003-05-20
申请号：US09715934
申请日：2000-11-17
申请人： Thomas Mayer , Stacey A. Yamanaka , Jaroslaw Zieba
发明人： Thomas Mayer , Stacey A. Yamanaka , Jaroslaw Zieba
IPC分类号： C09K1102
CPC分类号： C09K11/06 , B82Y10/00 , B82Y30/00 , C01P2004/20 , C01P2004/84 , C09C1/0015 , C09C2200/1054 , C09C2200/20 , C09C2200/306 , C09C2200/409 , C09C2210/50 , C09C2220/10 , C09C2220/20 , C09K2211/1011
摘要： Interference pigment flakes and foils are provided which have luminescent and color-shifting properties. A luminescent material coating structure is provided which partially covers or encapsulates a color-shifting pigment flake, or covers the outer surface of a foil. The pigment flakes can have a symmetrical coating structure on opposing sides of a core layer, can have an asymmetrical coating structure with all of the layers on one side of the core layer, or can be formed with encapsulating coatings around the core layer. The coating structure of the flakes and foils includes a core layer, a dielectric layer overlying the core layer, and an absorber layer overlying the dielectric layer. The luminescent pigment flakes and foils exhibit a discrete color shift so as to have a first color at a first angle of incident light or viewing and a second color different from the first color at a second angle of incident light or viewing. The luminescent pigment flakes can be interspersed into liquid media such as paints or inks to produce colorant materials for subsequent application to objects or papers. The luminescent foils can be laminated to various objects or can be formed on a carrier substrate.
摘要翻译：提供了具有发光和色移特性的干涉颜料薄片和薄片。提供了一种发光材料涂层结构，其部分地覆盖或封装色移颜料片，或覆盖箔的外表面。颜料薄片可以在芯层的相对侧上具有对称的涂层结构，可以具有不对称的涂层结构，其具有在芯层的一侧上的所有层，或者可以在芯层周围形成包封涂层。薄片和箔片的涂层结构包括芯层，覆盖芯层的电介质层和覆盖在介电层上的吸收层。发光颜料薄片和薄片呈现出离散的色移，以便在入射光或观察的第一角度具有第一颜色，并且在入射光或观看的第二角度具有不同于第一颜色的第二颜色。发光颜料薄片可以散布到液体介质如油漆或油墨中，以产生用于随后应用于物体或纸张的着色剂材料。发光箔可以层压到各种物体上，或者可以在载体基底上形成。

10. 发明授权

US09175166B2 Multi-layer metallic effect pigments, process for their preparation and use 有权
标题翻译：多层金属效果颜料，其制备及使用过程
公开(公告)号：US09175166B2
公开(公告)日：2015-11-03
申请号：US12670007
申请日：2008-07-24
申请人： Bernhard Geissler , Wolfgang Herzing , Jasmin Bleisteiner , Martin Fischer , Ralph Schneider
发明人： Bernhard Geissler , Wolfgang Herzing , Jasmin Bleisteiner , Martin Fischer , Ralph Schneider
IPC分类号： C09C1/00 , A61K8/11 , A61Q1/02 , C08K9/02 , C09C1/62 , C09C1/64 , C09D5/03 , C09D5/36 , C09D7/12 , C09D11/037 , C09D11/322 , A61Q1/06 , A61Q3/02 , C08K3/08
CPC分类号： C09C1/0021 , A61K8/0258 , A61K8/11 , A61K2800/412 , A61K2800/436 , A61Q1/02 , A61Q1/06 , A61Q3/02 , C01P2004/20 , C01P2004/54 , C01P2004/60 , C01P2004/61 , C01P2006/60 , C01P2006/62 , C01P2006/63 , C01P2006/64 , C01P2006/65 , C08K3/08 , C08K9/02 , C08K2201/014 , C09C1/62 , C09C1/642 , C09C2200/1037 , C09C2200/20 , C09C2200/30 , C09C2200/308 , C09C2200/502 , C09C2200/505 , C09C2220/20 , C09D5/035 , C09D5/36 , C09D7/62 , C09D7/67 , C09D7/68 , C09D11/037 , C09D11/322 , Y10T428/12056 , Y10T428/12549
摘要： A metallic effect pigment comprising at least three layers: A) a layer A which comprises at least one metal MA and has an average oxygen content OA, based on the total amount of MA and OA in the layer A, B) a layer B comprising at least one metal MB and having an average oxygen content OB of 0 to 77 atom %, more particularly of 0 to 58 atom %, based on the total amount of MB and OB in the layer B, C) a layer C which comprises at least one metal MC and has an average oxygen content OC, based on the total amount of MC and OC in the layer C, the average oxygen content OAC in layers A and C being determined in accordance with the formula (I) O AC = 1 2 ⁢ ( O A M A + O A + O C M C + O C ) ( I ) and being situated within a range from 2 to 77 atom %, more particularly from 25 to 58 atom %. The disclosure further relates to processes for preparing this effect pigment and also to its use.
摘要翻译：包含至少三层的金属效应颜料：A）包含至少一种金属MA并且具有基于层A中的MA和OA的总量的平均氧含量OA的层A，B）包含至少一种金属MB，其平均氧含量OB为0至77原子％，更特别为0至58原子％，基于B层中的MB和OB的总量，C）包含在至少一种金属MC，并且基于层C中的MC和OC的总量具有平均氧含量OC，层A和C中的平均氧含量OAC根据式（I）确定为：AC = 1 2（OAMA + OA + OCMC + OC）（I），其位于2〜77原子％的范围内，更优选为25〜58原子％。本公开还涉及制备该效果颜料的方法以及其用途。

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