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    • 2. 发明授权
    • Varistors based on nanocrystalline powders produced by mechanical grinding
    • 基于通过机械研磨生产的纳米晶体粉末的压敏电阻
    • US06620346B1
    • 2003-09-16
    • US09485401
    • 2000-04-28
    • Robert SchulzSabin BoilyAlain JolyAndré Van NesteHoushang Alamdari
    • Robert SchulzSabin BoilyAlain JolyAndré Van NesteHoushang Alamdari
    • H01B108
    • H01C17/06546H01C7/112
    • The invention concerns novel varistors based on zinc oxide and a method for making same, which consists in using as base products nanocrystalline powders obtained by high-intensity mechanical grinding and in subjecting the mixture resulting from said nanocrystalline powders a consolidating treatment such as sintering, in suitably selected temperature and time conditions so as to retain the smallest possible grain size of ZnO. The resulting varistors have a very fine homogeneous microstructure and an average grain size characteristically not more than 3 mu m, i.e. five times smaller than standard materials. Said novel varistors have a larger number of grain boundaries per length unit and therefore a much higher breakdown voltage. Said voltage is characteristically higher than 10 kV/cm and can reach 17 kV/cm which is almost one order of magnitude above the breakdown voltage of standard varistors. The non-linearity coefficient of the current-voltage curve is also improved, and is greater than 20 and can reach values as high as 60. Moreover, the leakage currents below the breakdown voltage of said varistors, are much weaker.
    • 本发明涉及基于氧化锌的新型变阻器及其制造方法,其特征在于,使用通过高强度机械研磨获得的纳米晶体粉末作为基底产品,并将由所述纳米晶体粉末得到的混合物进行固结处理如烧结, 适当选择的温度和时间条件,以保持ZnO的最小可能的晶粒尺寸。 所得压敏电阻具有非常精细的均匀微结构,平均晶粒尺寸特征不超过3pm,即比标准材料小5倍。 所述新型变阻器具有每单位长度单位更大数量的晶界,因此具有更高的击穿电压。 所述电压特性高于10kV / cm,可达到17kV / cm,比标准压敏电阻的击穿电压高出一个数量级。 电流 - 电压曲线的非线性系数也得到提高,大于20,可达到高达60的值。此外,低于所述压敏电阻的击穿电压的漏电流要低得多。
    • 4. 发明授权
    • Lithium cobalt oxides and methods of making same
    • 锂钴氧化物及其制造方法
    • US06579475B2
    • 2003-06-17
    • US09731949
    • 2000-12-07
    • Yuan GaoMarina YakovlevaJohn L. Burba, IIIJohn F. Engel
    • Yuan GaoMarina YakovlevaJohn L. Burba, IIIJohn F. Engel
    • H01B108
    • C01G51/42C01P2002/20C01P2002/52C01P2002/54C01P2002/72C01P2002/74C01P2006/40H01M4/505H01M4/525H01M10/052H01M10/0525H01M2004/021
    • The present invention includes lithium cobalt oxides having hexagonal layered crystal structures and methods of making same. The lithium cobalt oxides of the invention have the formula LiwCo1−xAxO2+y wherein 0.96≦w≦1.05, 0≦x≦0.05, −0.02≦y≦0.02 and A is one or more dopants. The lithium cobalt oxides of the invention preferably have a position within the principal component space defined by the relationship axi+byi≦c, wherein xi={right arrow over (S)}i&Circlesolid;{right arrow over (P)}c1; yi={right arrow over (S)}i&Circlesolid;{right arrow over (P)}c2; the vector {right arrow over (S)}i is the x-ray spectrum for the LiwCo1−xAxO2+y compound; the vectors {right arrow over (P)}c1 and {right arrow over (P)}c2 defining the principal component space are determined by measuring the x-ray powder diffraction values {right arrow over (S)}i between 15° and 120° using a 0.02° step size and CuK&agr; rays for a large sample set of lithium cobalt oxides and using the regression of {right arrow over (S)}i of the sample set against the capacity fade after 50 cycles of a lithium coin cell that includes a lithium negative electrode and the lithium cobalt oxide as the positive electrode material and that is cycled between 3.0 and 4.3V at a constant current of C/3 during both charge and discharge cycles; and the values a, b and c are determined by using only the xi and yi values for LiwCo1−xAxO2+y compounds in the sample set that have a capacity fade after 50 cycles of less than or equal to 15%.
    • 本发明包括具有六方晶系结构的锂钴氧化物及其制造方法。 本发明的锂钴氧化物具有式LiwCo1-xAxO2 + y,其中0.96 <= w <= 1.05,0 <= x <= 0.05,0.02 <= y <0.02,A是一种或多种掺杂剂。 本发明的锂钴氧化物优选具有由关系axi + byi <= c定义的主要成分空间内的位置,其中xi = {向右箭头(Si&Circlef; {向右箭头(Pc1; yi = {向右箭头 (Si&Circlef; {向右箭头(Pc2;向量{向右箭头(Si是LiwCo1-xAxO2 + y化合物的x射线光谱);向量(向右箭头(Pc1和{向右箭头(Pc2定义 通过测量x射线粉末衍射值(右箭头(在15°和120°之间的Si,使用0.02°步长的Si和用于大型锂钴氧化物的样品组的CuKalpha射线)并使用{ 向右箭头(相对于包含锂负极和锂钴氧化物作为正极材料的锂电池的循环50次循环后的容量褪色,并且以恒定电流在3.0和4.3V之间循环的样品组的Si 在充电和放电期间的C / 3 循环; 并且通过仅使用少于或等于15%的50个循环之后具有容量衰减的样品组中的LiwCo1-xAxO2 + y化合物的xi和yi值来确定值a,b和c。
    • 8. 发明授权
    • Transparent electrically conductive oxide film for an electronic apparatus and related method
    • 用于电子设备的透明导电氧化物膜及相关方法
    • US06533965B1
    • 2003-03-18
    • US09718982
    • 2000-11-22
    • Makoto SasakiChae Gee SungKazuyuki Arai
    • Makoto SasakiChae Gee SungKazuyuki Arai
    • H01B108
    • C23C14/5806C03C17/2453C03C17/253C03C2217/211C03C2217/215C03C2217/216C03C2217/23C23C14/086C23C14/3414C23C30/00G02F1/13439H01B1/08
    • A transparent electrically conductive oxide film is composed of a compound oxide containing indium oxide, tin oxide, and zinc oxide and includes a connecting section, in which the tin content is higher than the zinc content at least in connecting section, and at least the connection section has crystallinity. Alternatively, in the transparent electrically conductive oxide film, the atomic percentage of zinc to the total of zinc, indium, and tin is in the range of about 1 at % through about 9 at %, the atomic ratio of tin to zinc is about 1 or more, the atomic percentage of tin to the total of zinc, indium, and tin is about 20 at % or less, and at least a portion thereof has crystallinity. An electronic apparatus provided with such a transparent electrically conductive oxide film as at least a portion of the electric circuit thereof, a target for forming a transparent electrically conductive oxide film, and a method for fabricating a substrate provided with a transparent electrically conductive oxide film are also disclosed.
    • 透明导电氧化物膜由包含氧化铟,氧化锡和氧化锌的复合氧化物组成,并且包括至少在连接部分中锡含量高于锌含量的连接部分,并且至少连接 截面具有结晶度。 或者,在透明导电氧化物膜中,锌与锌,铟和锡的总量的原子百分比在约1at%至约9at%的范围内,锡与锌的原子比为约1 以上,锡与锌,铟和锡的合计的原子百分比为约20原子%以下,其至少一部分具有结晶性。 一种具有至少一部分电路的透明导电氧化膜的电子设备,形成透明导电氧化物膜的靶,以及具有透明导电氧化膜的基板的制造方法, 也披露。