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41. 发明授权

US5853809A Scratch resistant clearcoats containing suface reactive microparticles and method therefore 失效
标题翻译：因此，含有表面反应性微粒的耐刮擦清漆和方法
公开(公告)号：US5853809A
公开(公告)日：1998-12-29
申请号：US723436
申请日：1996-09-30
申请人： Donald H. Campbell , Janice E. Echols , Walter H. Ohrbom
发明人： Donald H. Campbell , Janice E. Echols , Walter H. Ohrbom
IPC分类号： C09D7/12 , B05D1/36
CPC分类号： C09D7/1266 , C09D7/1216 , C09D7/1275 , C08K3/36 , C08K9/04
摘要： The present invention is a coating composition having good scratch resistance and a method for improving the scratch resistance of a coating composition. The coating composition comprises (A) a film forming binder system containing a crosslinkable resin and optionally a crosslinking agent for the crosslinkable resin; (B) substantially colorless carbide or inorganic microparticles, range in size from about 1 to 1000 nanometers prior to incorporation in the coating composition, and the microparticles are reactive with the crosslinkable portion of the film forming binder system; (C) a solvent system for the crosslinkable resin, optional crosslinking agent, and microparticles, wherein the crosslinkable resin is present in an amount from about 10 to about 80% by weight and the inorganic microparticles are present in an amount from 0.1 to 60.0% by weight based on the sum of the weights of the crosslinkable resin, the optional crosslinking agent, and the inorganic microparticles.
摘要翻译：本发明是具有良好的耐刮擦性的涂料组合物和改善涂料组合物耐擦伤性的方法。涂料组合物包含（A）含有可交联树脂和任选的可交联树脂交联剂的成膜粘合剂体系; （B）基本上无色的碳化物或无机微粒，在引入涂料组合物之前的尺寸范围为约1至1000纳米，并且微粒与成膜粘合剂体系的可交联部分反应; （C）可交联树脂的溶剂体系，任选的交联剂和微粒，其中可交联树脂的存在量为约10至约80重量％，无机微粒以0.1至60.0重量％的量存在，，基于可交联树脂，任选的交联剂和无机微粒的重量之和。

42. 发明授权

US5770650A Curable compositions for coatings 失效
标题翻译：涂料固化组合物
公开(公告)号：US5770650A
公开(公告)日：1998-06-23
申请号：US698523
申请日：1996-08-15
申请人： John D. McGee , Brian D. Bammel , Walter H. Ohrbom , Todd A. Seaver , Gregory G. Menovcik , Paul J. Harris , John W. Rehfuss
发明人： John D. McGee , Brian D. Bammel , Walter H. Ohrbom , Todd A. Seaver , Gregory G. Menovcik , Paul J. Harris , John W. Rehfuss
IPC分类号： C08G18/80 , C08G71/00 , C09D167/04 , C09D201/02 , C08J3/00 , C08G63/91 , C08K3/20 , C08L75/00
CPC分类号： C08G18/8077 , C08G71/00 , C09D167/04 , C09D201/025 , Y10T428/31551
摘要： A curable coating composition is described comprising (A) a compound comprising a plurality of functional crosslinking groups, at least one of which is a carbamate or urea functional group, which compound also includes at least one ester or amide group derived from a reaction of an active hydrogen group with a lactone ring or a hydroxy carboxylic acid, and (B) a curing agent comprising a plurality of groups that are reactive with the functional groups on compound (A).
摘要翻译：描述了可固化涂料组合物，其包含（A）包含多个官能交联基团的化合物，其中至少一个是氨基甲酸酯或脲官能团，该化合物还包括至少一种衍生自具有内酯环或羟基羧酸的活性氢基，和（B）包含与化合物（A）上的官能团反应的多个基团的固化剂。

43. 发明授权

US5756213A Curable coating composition having carbonate-containing component 失效
标题翻译：具有含碳酸盐成分的可固化涂料组合物
公开(公告)号：US5756213A
公开(公告)日：1998-05-26
申请号：US698528
申请日：1996-08-15
申请人： Walter H. Ohrbom , John W. Rehfuss , John D. McGee , Gregory G. Menovcik , Paul J. Harris
发明人： Walter H. Ohrbom , John W. Rehfuss , John D. McGee , Gregory G. Menovcik , Paul J. Harris
IPC分类号： C09D161/20 , C08G71/00 , C08G71/04 , C09D167/04 , C09D169/00 , C09D175/04 , C09D201/00 , C09D201/02 , C09D161/28
CPC分类号： C09D175/04 , C08G71/00 , C08G71/04 , C09D167/04 , C09D169/00 , C09D201/02 , Y10T428/31507 , Y10T428/31942
摘要： A curable coating composition is described comprising (A) a compound comprising a plurality of functional crosslinking groups, at least one of which is a carbamate or urea functional group, which compound also includes at least one carbonate group having the structure: ##STR1## and (B) a curing agent comprising a plurality of groups that are reactive with the functional groups on compound (A).
摘要翻译：描述了可固化涂料组合物，其包含（A）包含多个官能交联基团的化合物，其中至少一个是氨基甲酸酯或脲官能团，该化合物还包括至少一个具有以下结构的碳酸酯基团：和（B）包含与化合物（A）上的官能团反应的多个基团的固化剂。

44. 发明授权

US5532061A Carbamate-functional polyester polymer or oligomer having pendant carbomate groups 失效
标题翻译：具有侧链羧酸酯基的氨基甲酸酯官能聚酯聚合物或低聚物
公开(公告)号：US5532061A
公开(公告)日：1996-07-02
申请号：US361245
申请日：1994-12-21
申请人： Gregory L. Menovcik , Walter H. Ohrbom
发明人： Gregory L. Menovcik , Walter H. Ohrbom
IPC分类号： C08G63/685 , C09D167/00 , B32B27/36 , C08G63/02
CPC分类号： C08G63/6854 , C09D167/00 , Y10T428/31551 , Y10T428/31786
摘要： Polyester polymers having pendant carbamate groups are disclosed. The polymers are prepared by reacting a polyol having at least one pendant carbamate group with a polyacid to form a polyester having pendant carbamate groups.
摘要翻译：公开了具有氨基甲酸酯基侧基的聚酯聚合物。通过使具有至少一个氨基甲酸酯侧基的多元醇与多元酸反应以形成具有氨基甲酸酯侧基的聚酯来制备聚合物。

45. 发明授权

US5373069A Curable carbamate-functional polymers 失效
标题翻译：可溶性氨基甲酸酯官能聚合物
公开(公告)号：US5373069A
公开(公告)日：1994-12-13
申请号：US98169
申请日：1993-07-28
申请人： John W. Rehfuss , Walter H. Ohrbom
发明人： John W. Rehfuss , Walter H. Ohrbom
IPC分类号： C08G81/00 , C08G18/38 , C08G18/40 , C08G18/64 , C08G18/80 , C08G71/04 , C08L75/04 , C09D161/20 , C09D175/00 , C09D175/04 , C09D201/02 , C08F283/04
CPC分类号： C09D201/025 , C08G18/3831 , C08G18/6415 , C08G71/04 , C09D175/04
摘要： Curable compositions are disclosed comprising:(A) a carbamate-functional polymer that is the reaction product of a mixture comprising:(1) a polymer that is the reaction product of a mixture comprising:(a) a polyisocyanate and(b) an active hydrogen-containing chain extension agent, and(2) a compound comprising a group that is reactive with said polymer (A) (1) and a carbamate group or group that can be converted to carbamate, and(B) a compound having a plurality of functional groups that are reactive with carbamate groups on said carbamate-functional polymer.
摘要翻译：公开了可固化组合物，其包含：（A）作为混合物的反应产物的氨基甲酸酯官能聚合物，其包含：（1）作为混合物的反应产物的聚合物，所述混合物包含：（a）多异氰酸酯和（b）含氢链延伸剂，和（2）包含与所述聚合物（A）（1）反应的基团和可以转化为氨基甲酸酯的氨基甲酸酯基或基团的化合物的化合物，和（B）具有多个在所述氨基甲酸酯官能聚合物上与氨基甲酸酯基反应的官能团。

46. 发明授权

US08653183B2 Method of curing a coating composition comprising a radical curable compound and an organoborane-amine complex 有权
标题翻译：固化包含自由基固化性化合物和有机硼烷 - 胺络合物的涂料组合物的方法
公开(公告)号：US08653183B2
公开(公告)日：2014-02-18
申请号：US13380255
申请日：2010-06-22
申请人： Keith E. Gutowski , Walter H. Ohrbom , David Cranfill , Donald H. Campbell
发明人： Keith E. Gutowski , Walter H. Ohrbom , David Cranfill , Donald H. Campbell
IPC分类号： C09D7/12 , B05D7/24 , B05D3/10 , C09D4/02 , C09D133/08
CPC分类号： C09D133/08 , C08J3/24 , C08K5/55 , C09D4/00
摘要： A method of curing a coating composition and a method of forming a cured coating on an automobile component are provided. The coating composition comprises a radical polymerizable compound and an organoborane-amine complex having an organoborane initiator, an amine blocking agent, and water. The method of curing the coating composition comprises the steps of combining the organoborane-amine complex, the radical polymerizable compound, and water to form the coating composition. Carbon dioxide is introduced into the coating composition or into a composition including at least one of the organoborane-amine complex, the radical polymerizable compound, and water prior to forming the coating composition. Carbonic acid is formed in situ within the coating composition through reaction of the water and carbon dioxide. The organoborane-amine complex is decomplexed with the carbonic acid thereby separating the organoborane initiator and the amine blocking agent. The radical polymerizable compound is polymerized using the organoborane initiator in the presence of oxygen.
摘要翻译：提供固化涂料组合物的方法和在汽车部件上形成固化涂层的方法。涂料组合物包含可自由基聚合的化合物和具有有机硼烷引发剂，胺封闭剂和水的有机硼烷 - 胺络合物。固化涂料组合物的方法包括将有机硼烷 - 胺络合物，可自由基聚合的化合物和水组合以形成涂料组合物的步骤。在形成涂料组合物之前，将二氧化碳引入涂料组合物或包含至少一种有机硼烷 - 胺络合物，可自由基聚合的化合物和水的组合物。碳酸通过水和二氧化碳的反应在涂料组合物中原位形成。有机硼烷 - 胺络合物与碳酸分解，从而分离有机硼烷引发剂和胺封闭剂。使用有机硼烷引发剂在氧的存在下使自由基聚合性化合物聚合。

47. 发明申请

US20120116013A1 METHOD OF CURING A COATING COMPOSITION COMPRISING A RADICAL CURABLE COMPOUND AND AN ORGANOBORANE-AMINE COMPLEX 有权
标题翻译：固化包含耐光固化性化合物的涂料组合物和有机硼 - 胺复合物的方法
公开(公告)号：US20120116013A1
公开(公告)日：2012-05-10
申请号：US13380255
申请日：2010-06-22
申请人： Keith E. Gutowski , Walter H. Ohrbom , David Cranfill , Donald H. Campbell
发明人： Keith E. Gutowski , Walter H. Ohrbom , David Cranfill , Donald H. Campbell
IPC分类号： C09D7/12 , B05D7/24 , B05D3/10 , C09D4/02 , C09D133/08
CPC分类号： C09D133/08 , C08J3/24 , C08K5/55 , C09D4/00
摘要： A method of curing a coating composition and a method of forming a cured coating on an automobile component are provided. The coating composition comprises a radical polymerizable compound and an organoborane-amine complex having an organoborane initiator, an amine blocking agent, and water. The method of curing the coating composition comprises the steps of combining the organoborane-amine complex, the radical polymerizable compound, and water to form the coating composition. Carbon dioxide is introduced into the coating composition or into a composition including at least one of the organoborane-amine complex, the radical polymerizable compound, and water prior to forming the coating composition. Carbonic acid is formed in situ within the coating composition through reaction of the water and carbon dioxide. The organoborane-amine complex is de-complexed with the carbonic acid thereby separating the organoborane initiator and the amine blocking agent. The radical polymerizable compound is polymerized using the organoborane initiator in the presence of oxygen.
摘要翻译：提供固化涂料组合物的方法和在汽车部件上形成固化涂层的方法。涂料组合物包含可自由基聚合的化合物和具有有机硼烷引发剂，胺封闭剂和水的有机硼烷 - 胺络合物。固化涂料组合物的方法包括将有机硼烷 - 胺络合物，可自由基聚合的化合物和水组合以形成涂料组合物的步骤。在形成涂料组合物之前，将二氧化碳引入涂料组合物或包含至少一种有机硼烷 - 胺络合物，可自由基聚合的化合物和水的组合物。碳酸通过水和二氧化碳的反应在涂料组合物中原位形成。有机硼烷 - 胺络合物与碳酸脱配合，从而分离有机硼烷引发剂和胺封闭剂。使用有机硼烷引发剂在氧气存在下使自由基聚合性化合物聚合。

48. 发明授权

US08076425B2 Carbamate functional silica compounds and methods of making and use thereof 有权
标题翻译：氨基甲酸酯官能二氧化硅化合物及其制备和使用方法
公开(公告)号：US08076425B2
公开(公告)日：2011-12-13
申请号：US11239606
申请日：2005-09-29
申请人： Gregory G. Menovcik , Walter H. Ohrbom
发明人： Gregory G. Menovcik , Walter H. Ohrbom
IPC分类号： C08F283/00 , C08F283/12 , C08G77/00 , C08G77/38 , C08G73/00 , C08L83/00 , C08F6/22 , C01B33/12
CPC分类号： C08G77/02 , C07F7/0838 , C08G77/26 , C08K3/36 , C08K5/205 , C08K5/544 , C08K9/04 , C09D5/033 , C09D7/62 , C09D183/02
摘要： Disclosed is a carbamate functional silica, comprising repeating units: wherein R is H or an alkyl group of from 1 to 50 carbon atoms and n is a number from 1 to 100. Also disclosed is a functional silica comprising repeating units: wherein R is an alkyl group of from 1 to 50 carbon atoms, n is from 1 to 100, R1 and R2 may be the same or different and are at least one of a hydrocarbon group comprising from 1 to 100 carbon atoms with the proviso that at least one of R1 and R2 is not hydrogen. In one embodiment, R1 and R2 are hydrogen or the residual of an aminoplast polymer, an alkylating alcohol, or the like. Methods for making the disclosed functional silicas and coating compositions comprising the same are also provided.
摘要翻译：公开了一种氨基甲酸酯官能二氧化硅，其包含重复单元：其中R是H或1至50个碳原子的烷基，n是1至100的数。还公开了包含重复单元的官能二氧化硅：其中R是 1至50个碳原子的烷基，n为1至100，R 1和R 2可以相同或不同，并且为包含1至100个碳原子的烃基中的至少一个，条件是至少一个 R1和R2不是氢。在一个实施方案中，R 1和R 2是氢或残基的氨基塑料聚合物，烷基化醇等。还提供了制备所公开的功能二氧化硅和包含其的涂料组合物的方法。

49. 发明申请

US20100297355A1 CURABLE COATING COMPOSITION CONTAINING A COMPOUND HAVING A URETDIONE GROUP AND A DIFFERENT FUNCTIONAL GROUP AND CURED COATINGS 有权
标题翻译：含有脲基团和不同官能团的化合物和固化涂料的可固化涂料组合物
公开(公告)号：US20100297355A1
公开(公告)日：2010-11-25
申请号：US12469158
申请日：2009-05-20
申请人： David C. Cranfill , Walter H. Ohrbom , Patrick J. Mormile
发明人： David C. Cranfill , Walter H. Ohrbom , Patrick J. Mormile
IPC分类号： B05D3/02 , C09D4/00
CPC分类号： C08G18/798 , C08G18/2865 , C08G18/289 , C08G18/3851 , C09D175/04 , Y10T428/31551
摘要： A curable coating composition includes a uretdione compound having one uretdione group and having a plurality of functional groups selected from crosslinkable groups and groups that modify a coating property. The disclosed coating compositions include those having a binder component having a plurality of active hydrogen-containing groups. When the uretdione compound has a functional group that is a crosslinkable group, the coating composition further includes a crosslinker that has a plurality of crosslinking groups reactive under curing conditions with the crosslinkable group. Also disclosed is a method of making the curable coating composition, including preparing the uretdione compound having one uretdione group and having at least one further functional group.
摘要翻译：可固化涂料组合物包括具有一个脲二酮基并具有多个选自可交联基团和改性涂层性质的基团的多个官能团的脲二酮化合物。所公开的涂料组合物包括具有多个含活性氢基团的粘合剂组分的涂料组合物。当脲二酮化合物具有作为可交联基团的官能团时，涂料组合物还包含交联剂，其具有多个在固化条件下与可交联基团反应的交联基团。还公开了制备可固化涂料组合物的方法，包括制备具有一个脲二酮基并具有至少一个其它官能团的脲二酮化合物。

50. 发明授权

US07538130B2 Hindered amine light stabilizer, methods of making, and compositions 失效
标题翻译：受阻胺光稳定剂，制备方法和组合物
公开(公告)号：US07538130B2
公开(公告)日：2009-05-26
申请号：US11234898
申请日：2005-09-26
申请人： Donald H. Campbell , Donald L. St. Aubin , Walter H. Ohrbom , John E. Boisseau
发明人： Donald H. Campbell , Donald L. St. Aubin , Walter H. Ohrbom , John E. Boisseau
IPC分类号： A61K31/421 , A61K31/5375 , C07D263/04 , C07D265/04
CPC分类号： C08K5/35
摘要： A compound in which n is 0, 1, 2, or 3; R1, R2, R7, and R8 are each independently alkyl group, including cycloalkyl, an alkylaryl group, or an aryl group, optionally with one or more heteroatoms, with the proviso that R1 and R2 can together form a cycloalkylene group and, independently, R7 and R8 can together form a cycloalkylene group; Y is an oxygen free radical, a sulfur free radical, OR9 or SR9; R3, R4, R5, R6, and R9 are each independently H or an alkyl group, a cycloalkyl group, an aryl group, or an alkylaryl group, optionally with one or more heteroatoms; and compositions, such as basecoat and clearcoat coating compositions, containing such compounds.
摘要翻译： n为0,1,2或3的化合物; R 1，R 2，R 7和R 8各自独立地为烷基，包括环烷基，烷基芳基或芳基，任选具有一个或多个杂原子，条件是R 1和R 2可以一起形成亚环烷基， R7和R8可以一起形成亚环烷基; Y是氧自由基，无硫自由基，OR9或SR9; R 3，R 4，R 5，R 6和R 9各自独立地为H或烷基，环烷基，芳基或烷基芳基，任选具有一个或多个杂原子; 以及含有这些化合物的组合物，如底漆和透明涂料涂料组合物。

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