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31. 发明授权

US5958839A Herbicidal compounds 失效
标题翻译：除草剂
公开(公告)号：US5958839A
公开(公告)日：1999-09-28
申请号：US21992
申请日：1998-02-11
申请人： John E. D. Barton , David Cartwright , John M Cox , Glynn Mitchell , Charles G. Carter , David L Lee , Francis H Walker , Frank X. Woolard
发明人： John E. D. Barton , David Cartwright , John M Cox , Glynn Mitchell , Charles G. Carter , David L Lee , Francis H Walker , Frank X. Woolard
IPC分类号： A01N35/06 , A01N37/08 , A01N43/08 , A01N43/10 , A01N43/12 , A01N43/30 , A01N43/32 , A01N43/36 , A01N43/38 , A01N43/40 , A01N43/42 , A01N43/50 , A01N43/56 , A01N43/58 , A01N43/60 , A01N43/76 , A01N43/78 , A01N43/80 , A01N43/92 , A47J37/12 , C07C45/51 , C07C45/54 , C07C45/60 , C07C45/67 , C07C45/72 , C07C49/403 , C07C49/713 , C07C49/792 , C07C49/813 , C07C49/835 , C07D207/32 , C07D207/333 , C07D207/34 , C07D207/36 , C07D209/12 , C07D215/12 , C07D215/14 , C07D215/36 , C07D231/12 , C07D231/16 , C07D231/20 , C07D231/22 , C07D233/84 , C07D237/12 , C07D237/28 , C07D237/30 , C07D239/26 , C07D239/74 , C07D241/12 , C07D241/16 , C07D241/42 , C07D261/08 , C07D263/54 , C07D263/56 , C07D277/20 , C07D277/24 , C07D277/32 , C07D277/36 , C07D307/70 , C07D307/71 , C07D317/52 , C07D317/62 , C07D319/08 , C07D319/18 , C07D333/22 , C07D333/28 , C07D333/62 , C07D409/04 , C07D417/04 , C07F9/6568 , G05D23/20
CPC分类号： C07D207/333 , A01N35/06 , A01N37/08 , A01N43/08 , A01N43/10 , A01N43/30 , A01N43/32 , A01N43/36 , A01N43/38 , A01N43/40 , A01N43/42 , A01N43/50 , A01N43/56 , A01N43/58 , A01N43/60 , A01N43/78 , A01N43/80 , A47J37/1266 , C07C45/512 , C07C45/54 , C07C45/60 , C07C45/673 , C07C45/72 , C07C49/403 , C07C49/713 , C07C49/792 , C07C49/813 , C07C49/835 , C07D207/36 , C07D209/12 , C07D215/14 , C07D215/36 , C07D231/12 , C07D231/16 , C07D233/84 , C07D237/12 , C07D241/12 , C07D241/16 , C07D241/42 , C07D261/08 , C07D263/56 , C07D277/24 , C07D277/32 , C07D277/36 , C07D307/70 , C07D307/71 , C07D317/52 , C07D317/62 , C07D319/08 , C07D319/18 , C07D333/22 , C07D333/28 , C07D333/62 , C07D409/04 , C07D417/04 , C07F9/6568 , G05D23/1917 , G05D23/20
摘要： A compound of formula (I): ##STR1## or a salt, enamine or the like, acylate, sulphonate, carbamate or ether derivative thereof; wherein X, X.sup.1 and X.sup.2 are independently oxygen or sulphur, R.sup.1 is an optionally substituted heterocyclic or cycloalkyl group, and Y is an optionally substituted C.sub.2 -C.sub.4 alkylene group which is optionally interposed by an oxygen atom, a group ##STR2## a group ##STR3## or an optionally mono-substituted nitrogen atom, wherein p is 0, 1 or 2, s is 0 or 1 and R.sup.b is alkyl or alkoxy; provided that when X, X.sup.1 and X.sup.2 are oxygen, R.sup.1 is not pyridyl or pyrimidinyl. Processes for the preparation of these compounds and herbicidal compositions containing them are also described and claimed.
摘要翻译：式（I）化合物或其盐，烯胺等酰化物，磺酸盐，氨基甲酸酯或醚衍生物; 其中X，X 1和X 2独立地是氧或硫，R 1是任选取代的杂环或环烷基，Y是任选被取代的C 2 -C 4亚烷基，其任选地被氧原子，一个基团或任选的一个取代的氮原子，其中p为0,1或2，s为0或1，Rb为烷基或烷氧基; 条件是当X，X 1和X 2是氧时，R 1不是吡啶基或嘧啶基。还描述和要求保护这些化合物和含有它们的除草组合物的制备方法。

32. 发明授权

US5929287A Chlorination of substituted alkenes using trichloroisocyanuric acid 失效
标题翻译：使用三氯异氰脲酸氯化取代烯烃
公开(公告)号：US5929287A
公开(公告)日：1999-07-27
申请号：US59062
申请日：1998-04-13
申请人： Renee Caroline Roemmele , Heather Lynnette Rayle
发明人： Renee Caroline Roemmele , Heather Lynnette Rayle
IPC分类号： A01N35/02 , C07B39/00 , C07C45/42 , C07C45/51 , C07C45/54 , C07C45/56 , C07C49/16 , C07C49/457 , C07C67/287 , C07C69/63 , C07C45/00
CPC分类号： C07C45/54 , C07B39/00 , C07C45/42 , C07C45/51 , C07C45/511 , C07C45/562
摘要： This invention relates to a process for the selective monochlorination or dichlorination of certain substituted alkenes using trichloroisocyanuric acid. The chlorinated alkenes can be easily hydrolyzed to provide .alpha.-monochloroketones or .alpha.,.alpha.-dichloroketones with a high degree of selectivity. The resulting .alpha.-monochloroketones or .alpha.,.alpha.-dichloroketones have utility as fungicides or function as useful intermediates for fungicides.
摘要翻译：本发明涉及使用三氯异氰脲酸对某些取代烯烃进行选择性一氯化或二氯化的方法。氯代烯烃可以容易地水解，以提供高选择性的α-单氯代酮或α，α-二氯酮。所得的α-单氯代酮或α，α-二氯酮可用作杀真菌剂或作为杀真菌剂的有用中间体。

33. 发明授权

US5607888A Regioselective methylation of toluene to para-xylene 失效
标题翻译：将甲苯区域选择性甲基化成对二甲苯
公开(公告)号：US5607888A
公开(公告)日：1997-03-04
申请号：US452939
申请日：1995-05-30
申请人： Clarence D. Chang , Paul G. Rodewald
发明人： Clarence D. Chang , Paul G. Rodewald
IPC分类号： B01J29/40 , B01J29/44 , B01J31/02 , B01J31/12 , B01J35/02 , C07C1/20 , C07C2/12 , C07C2/66 , C07C5/27 , C07C5/41 , C07C6/12 , C07C45/54 , C10G45/64 , C10G50/00 , B01J29/06
CPC分类号： C10G50/00 , B01J29/40 , B01J29/44 , B01J31/0274 , B01J31/124 , B01J31/125 , C07C1/20 , C07C2/12 , C07C2/66 , C07C45/54 , C07C5/2708 , C07C5/41 , C07C6/123 , C07C6/126 , C10G45/64 , B01J2229/12 , B01J2229/42 , B01J35/023 , C07C2529/40 , Y02P20/52
摘要： A process and catalyst for Shape Selective Hydrocarbon Conversions such as the regioselective disproportionation of toluene to para-xylene wherein hydrocarbon to be converted is passed over a catalytic molecular sieve which is trim selectivated with a reaction stream comprising toluene and a silicon-containing high efficiency p-xylene selectivating agent under toluene conversion conditions. The toluene disproportionation process attains a single-pass para-xylene product over 95% coupled with a toluene conversion of at least 15%. The present invention also includes the highly para-selective catalyst which results from the treatment of a catalytic molecular sieve with a high efficiency p-xylene selectivating agent under the recited conditions.
摘要翻译：用于形状选择性烃转化的方法和催化剂，例如甲苯对对二甲苯的区域选择性歧化，其中待转化的烃将通过催化分子筛，催化分子筛用包含甲苯和含硅高效p的反应流选择甲苯转化条件下的二甲苯选择剂。甲苯歧化过程达到95％以上的单程对二甲苯产物，甲苯转化率至少为15％。本发明还包括在所述条件下用高效对二甲苯选择性催化剂处理催化分子筛的高度对位选择性催化剂。

34. 发明授权

US5563297A Intermediates for the preparation of vitamin A and carotenoids and process for their preparation 失效
标题翻译：用于制备维生素A和类胡萝卜素的中间体及其制备方法
公开(公告)号：US5563297A
公开(公告)日：1996-10-08
申请号：US320150
申请日：1994-10-07
申请人： Hugues Bienayme
发明人： Hugues Bienayme
IPC分类号： B01J31/24 , C07B61/00 , C07C45/54 , C07C45/65 , C07C45/67 , C07C47/20 , C07C47/21 , C07C47/228 , C07C47/232 , C07C49/203 , C07C49/213 , C07C49/217 , C07C49/683 , C07C49/796 , C07C69/96 , C07C403/00 , C07C403/14
CPC分类号： C07C403/14 , C07C403/02 , C07C403/12 , C07C45/54 , C07C45/67 , C07C47/20 , C07C47/21 , C07C47/232 , C07C49/217 , C07C49/683 , C07C49/796 , C07C69/96 , C07B2200/09 , C07C2101/16
摘要： The present invention relates to novel intermediates for the preparation of vitamin A and carotenoids, corresponding to the following formula (I): ##STR1## in which X is a carbon atom; n is equal to 1 or 2; R.sub.1, R.sub.2 and R.sub.3, which may be identical or different, each independently represent hydrogen, alkyl containing 1 to 4 carbon atoms, alkenyl containing 2 to 11 carbon atoms or aryl, each alkyl and alkenyl may be linear, branched or cyclic, or R.sub.1 and R.sub.2 can together with the carbon atom to which they are attached form a cycloaliphatic compound which is optionally substituted; and R.sub.4, R.sub.5, R.sub.6, R.sub.7 and R.sub.8, which may be identical or different, each independently represent hydrogen, alkyl containing 1 to 4 carbon atoms or alkenyl containing 2 to 10 carbon atoms, each alkyl or alkenyl being linear, or if containing sufficient numbers of carbon atoms, may also be branched or cyclic, or an aryl containing 6 to 10 carbon atoms, or any two of R.sub.4, R.sub.5, R.sub.6, R.sub.7 and R.sub.8 may together form, along with the carbon atom(s) to which they are attached, a cycloalkylidene group containing 3 to 10 carbon atoms, as well as the process for their preparation and their use.
摘要翻译：本发明涉及用于制备维生素A和类胡萝卜素的新型中间体，其对应于下式（I）：其中X为碳原子的式（I） n等于1或2; R 1，R 2和R 3可以相同或不同，各自独立地表示氢，含有1至4个碳原子的烷基，含有2至11个碳原子的烯基或芳基，每个烷基和烯基可以是直链，支链或环状的，或者R1 并且R 2可以与它们所连接的碳原子一起形成任选被取代的脂环族化合物; 和可以相同或不同的R 4，R 5，R 6，R 7和R 8各自独立地表示氢，含有1至4个碳原子的烷基或含2至10个碳原子的链烯基，每个烷基或烯基是直链的，或者如果含有足够的碳原子数也可以是支链或环状的，或含有6至10个碳原子的芳基，或者R 4，R 5，R 6，R 7和R 8中的任何两个可以一起与它们的碳原子一起形成，，含有3至10个碳原子的亚环烷基，以及其制备方法及其用途。

35. 发明授权

US5527948A Naphthalene derivative 失效
标题翻译：萘衍生物
公开(公告)号：US5527948A
公开(公告)日：1996-06-18
申请号：US402569
申请日：1995-03-13
申请人： Makoto Okita , Hiroshi Shirota , Masayuki Tanaka , Toshihiko Kaneko , Katsuya Tagami , Shigeki Hibi , Yasushi Okamoto , Seiichiro Nomoto , Takeshi Suzuki , Kenichi Chiba , Masaki Goto , Ryoichi Hashida , Hideki Ono , Hideto Ohhara , Hideki Sakurai , Shigeru Souda , Yoshimasa Machida , Kouichi Katayama , Isao Yamatsu
发明人： Makoto Okita , Hiroshi Shirota , Masayuki Tanaka , Toshihiko Kaneko , Katsuya Tagami , Shigeki Hibi , Yasushi Okamoto , Seiichiro Nomoto , Takeshi Suzuki , Kenichi Chiba , Masaki Goto , Ryoichi Hashida , Hideki Ono , Hideto Ohhara , Hideki Sakurai , Shigeru Souda , Yoshimasa Machida , Kouichi Katayama , Isao Yamatsu
IPC分类号： C07C39/225 , C07C43/215 , C07C43/23 , C07C43/30 , C07C43/313 , C07C43/315 , C07C45/00 , C07C45/29 , C07C45/30 , C07C45/51 , C07C45/54 , C07C45/59 , C07C45/63 , C07C45/71 , C07C47/57 , C07C47/575 , C07C49/83 , C07C49/84 , C07C59/68 , C07C69/157 , C07F7/18 , C07C69/76 , C07C49/115
CPC分类号： C07F7/1852 , C07C39/225 , C07C43/215 , C07C43/23 , C07C43/30 , C07C43/313 , C07C43/315 , C07C45/00 , C07C45/298 , C07C45/30 , C07C45/305 , C07C45/513 , C07C45/54 , C07C45/59 , C07C45/63 , C07C45/71 , C07C47/57 , C07C47/575 , C07C49/83 , C07C49/84 , C07C59/68
摘要： Naphthalene derivatives of the formula: ##STR1## wherein R.sup.1, represents a hydrogen atom, a lower alkyl group or an acyl group; R.sup.2 independently represents a hydrogen atom, a lower alkyl group, a lower alkoxy group, a halogen atom, a cycloalkyl group, a cycloalkylalkyl group, a hydroxyl group, an aryl group which may be substituted, an arylalkyl group whose aryl group may be substituted, a heteroaryl group, or a heteroaryllakyl group; R.sup.3 represents a hydrogen atom, a lower alkyl group, a lower alkenyl group, an aryl group which may have a substituent, an arylalkyl group whose aryl group may be substituted, an arylalkenyl group whose aryl group may be substituted, a cycloalkyl group, an alkoxyalkyl group, a heteroaryl group, a heteroarylalkyl group, a carboxyl group, a carboxyalkyl group, an aminoalkyl group, or a cyano group; R.sup.6 is C.sub.1-6 alkyl; and m is 0 or an integer of from 1 to 2 useful in treating autoimmune diseases are disclosed.
摘要翻译：下式的萘衍生物：其中R 1，表示氢原子，低级烷基或酰基; R2独立地表示氢原子，低级烷基，低级烷氧基，卤素原子，环烷基，环烷基烷基，羟基，可被取代的芳基，芳基可以被取代的芳基烷基，杂芳基或杂芳基烷基; R 3表示氢原子，低级烷基，低级烯基，可以具有取代基的芳基，可以被取代芳基的芳基烷基，可以被芳基取代的芳基烯基，环烷基，烷氧基烷基，杂芳基，杂芳基烷基，羧基，羧基烷基，氨基烷基或氰基; R6是C1-6烷基; 并且公开了m为0或可用于治疗自身免疫性疾病的1〜2的整数。

36. 发明授权

US5466877A Process for converting perfluorinated esters to perfluorinated acyl fluorides and/or ketones 失效
标题翻译：将全氟化酯转化为全氟化酰基氟化物和/或酮的方法
公开(公告)号：US5466877A
公开(公告)日：1995-11-14
申请号：US213109
申请日：1994-03-15
申请人： George G. I. Moore
发明人： George G. I. Moore
IPC分类号： C07C45/54 , C07C49/167 , C07C49/175 , C07C51/58 , C07C51/60 , C07C53/00
CPC分类号： C07C51/60 , C07C45/54 , C07C49/167 , C07C49/175 , C07C51/58
摘要： A process for converting perfluorinated carboxylic acid esters to perfluorinated acyl fluorides and/or perfluorinated ketones comprises the step of combining at least one perfluorinated carboxylic acid ester with at least one initiating reagent selected from the group consisting of gaseous, non-hydroxylic nucleophiles; liquid, non-hydroxylic nucleophiles; and mixtures of at least one non-hydroxylic nucleophile (gaseous, liquid, or solid) and at least one solvent which is inert to acylating agents. The process enables the dissociation of even high molecular weight, perfluorinated esters.
摘要翻译：将全氟化羧酸酯转化为全氟化酰基氟化物和/或全氟化酮的方法包括将至少一种全氟化羧酸酯与至少一种选自气态，非羟基亲核体的起始试剂混合的步骤; 液体，非羟基亲核体; 和至少一种非羟基亲核试剂（气态，液体或固体）和至少一种对酰化剂是惰性的溶剂的混合物。该方法使得能够解离甚至高分子量的全氟化酯。

37. 发明授权

US5426091A Herbicidal compounds 失效
标题翻译：除草剂
公开(公告)号：US5426091A
公开(公告)日：1995-06-20
申请号：US102004
申请日：1993-08-04
申请人： John E. D. Barton , David Cartwright , John M. Cox , Glynn Mitchell , Charles G. Carter , David L. Lee , Francis H. Walker , Frank X. Woolard
发明人： John E. D. Barton , David Cartwright , John M. Cox , Glynn Mitchell , Charles G. Carter , David L. Lee , Francis H. Walker , Frank X. Woolard
IPC分类号： A01N35/06 , A01N37/08 , A01N43/08 , A01N43/10 , A01N43/12 , A01N43/30 , A01N43/32 , A01N43/36 , A01N43/38 , A01N43/40 , A01N43/42 , A01N43/50 , A01N43/56 , A01N43/58 , A01N43/60 , A01N43/76 , A01N43/78 , A01N43/80 , A01N43/92 , A47J37/12 , C07C45/51 , C07C45/54 , C07C45/60 , C07C45/67 , C07C45/72 , C07C49/403 , C07C49/713 , C07C49/792 , C07C49/813 , C07C49/835 , C07D207/32 , C07D207/333 , C07D207/34 , C07D207/36 , C07D209/12 , C07D215/12 , C07D215/14 , C07D215/36 , C07D231/12 , C07D231/16 , C07D231/20 , C07D231/22 , C07D233/84 , C07D237/12 , C07D237/28 , C07D237/30 , C07D239/26 , C07D239/74 , C07D241/12 , C07D241/16 , C07D241/42 , C07D261/08 , C07D263/54 , C07D263/56 , C07D277/20 , C07D277/24 , C07D277/32 , C07D277/36 , C07D307/70 , C07D307/71 , C07D317/52 , C07D317/62 , C07D319/08 , C07D319/18 , C07D333/22 , C07D333/28 , C07D333/62 , C07D409/04 , C07D417/04 , C07F9/6568 , G05D23/20 , C07D403/06 , C07D223/06
CPC分类号： C07D207/333 , A01N35/06 , A01N37/08 , A01N43/08 , A01N43/10 , A01N43/30 , A01N43/32 , A01N43/36 , A01N43/38 , A01N43/40 , A01N43/42 , A01N43/50 , A01N43/56 , A01N43/58 , A01N43/60 , A01N43/78 , A01N43/80 , A47J37/1266 , C07C45/512 , C07C45/54 , C07C45/60 , C07C45/673 , C07C45/72 , C07C49/403 , C07C49/713 , C07C49/792 , C07C49/813 , C07C49/835 , C07D207/36 , C07D209/12 , C07D215/14 , C07D215/36 , C07D231/12 , C07D231/16 , C07D233/84 , C07D237/12 , C07D241/12 , C07D241/16 , C07D241/42 , C07D261/08 , C07D263/56 , C07D277/24 , C07D277/32 , C07D277/36 , C07D307/70 , C07D307/71 , C07D317/52 , C07D317/62 , C07D319/08 , C07D319/18 , C07D333/22 , C07D333/28 , C07D333/62 , C07D409/04 , C07D417/04 , C07F9/6568 , G05D23/1917 , G05D23/20
摘要： A compound of formula (I): ##STR1## or a salt, enamine or the like, acylate, sulphonate, carbamate or ether derivative thereof; wherein X, X.sup.1 and X.sup.2 are independently oxygen or sulphur, R.sup.1 is an optionally substituted heterocyclic or cycloalkyl group, and Y is an optionally substituted C.sub.2 -C.sub.4 alkylene group which is optionally interposed by an oxygen atom, a group ##STR2## or an optionally mono-substituted nitrogen atom, wherein p is 0, 1 or 2, s is 0 or 1 and R.sup.b is alkyl or alkoxy; provided that when X, X.sup.1 and X.sup.2 are oxygen, R.sup.1 is not pyridyl or pyrimidinyl. Processes for the preparation of these compounds and herbicidal compositions containing them are also described and claimed.
摘要翻译：式（I）的化合物：其中，酰化物，磺酸盐，氨基甲酸酯或醚衍生物;或其盐，烯胺等; 其中X，X 1和X 2独立地是氧或硫，R 1是任选取代的杂环或环烷基，Y是任选被氧原子插入的任选取代的C 2 -C 4亚烷基，图像>或任选单取代的氮原子，其中p为0,1或2，s为0或1，Rb为烷基或烷氧基; 条件是当X，X 1和X 2是氧时，R 1不是吡啶基或嘧啶基。还描述和要求保护这些化合物和含有它们的除草组合物的制备方法。

38. 发明授权

US5342972A Preparation of 6-bromo-2,2-dialkyl-2,3-dihydrobenzofurans which are optionally fluoro-substituted 失效
标题翻译：任选氟取代的6-溴-2,2-二烷基-2,3-二氢苯并呋喃的制备
公开(公告)号：US5342972A
公开(公告)日：1994-08-30
申请号：US19685
申请日：1993-02-19
申请人： Albrecht Harreus , Bernd Wolf , Jochen Wild
发明人： Albrecht Harreus , Bernd Wolf , Jochen Wild
IPC分类号： C07C39/24 , C07C45/54 , C07C49/825 , C07D307/79 , C07D307/82
CPC分类号： C07D307/79 , C07C39/245 , C07C45/54 , C07C49/825
摘要： A process for the preparation of a 2,3-dihydrobenzofuran I ##STR1## or a derivative thereof, where R.sup.a and R.sup.b are C-organic radicals, involves reacting a 2-hydroxybenzyl alcohol II ##STR2## in the presence of an acidic ion exchanger resin and in the presence of an inert dehydrating substance. Novel 2,3-dihydrobenzofurans Ia, 2-acylphenols IVa and 2-hydroxybenzyl alcohols IIa, a process for their preparation, and their use as intermediates are also described.
摘要翻译：制备2,3-二氢苯并呋喃I或其衍生物的方法，其中Ra和Rb是C-有机基团，包括在酸性存在下使2-羟基苄醇II II 离子交换树脂，并在惰性脱水物质的存在下进行。还描述了新的2,3-二氢苯并呋喃Ia，2-酰基苯酚IVa和2-羟基苄醇IIa，其制备方法及其作为中间体的用途。

39. 发明授权

US5321183A Process for the regioselective conversion of aromatics to para-disubstituted benzenes 失效
标题翻译：芳香族区域选择性转化为对二取代苯的方法
公开(公告)号：US5321183A
公开(公告)日：1994-06-14
申请号：US939752
申请日：1992-09-02
申请人： Clarence D. Chang , Paul G. Rodewald
发明人： Clarence D. Chang , Paul G. Rodewald
IPC分类号： B01J29/06 , B01J29/40 , B01J29/44 , B01J31/02 , B01J31/12 , C07B61/00 , C07C1/20 , C07C2/12 , C07C2/66 , C07C2/84 , C07C2/86 , C07C5/22 , C07C5/27 , C07C5/41 , C07C5/52 , C07C6/12 , C07C11/02 , C07C15/02 , C07C15/08 , C07C45/51 , C07C45/54 , C07C49/825 , C10G45/64 , C10G50/00 , C10G50/02 , C10G73/02 , C07C2/00 , C07C4/00 , C07C6/00
CPC分类号： B01J31/124 , B01J29/40 , B01J29/44 , B01J31/0274 , B01J31/125 , C07C1/20 , C07C2/12 , C07C2/66 , C07C45/54 , C07C5/2708 , C07C5/41 , C07C6/123 , C07C6/126 , C10G45/64 , C10G50/00 , B01J2229/12 , B01J2229/42 , C07C2529/40 , Y02P20/52
摘要： Processes for converting a wide variety of aromatic hydrocarbons, such as polyalkylaromatics, into commercially useful para-substituted aromatics such as para-xylene are disclosed. The aromatic hydrocarbon feed stream is first partially converted into toluene which is then subjected to a highly para-selective methylation process. The present invention therefore provides novel processes and catalysts for increasing the para-selectivity in the selective production of para-substituted aromatic compounds. From the description provided herein, those skilled in the art will appreciate that the catalysts and processes of the present invention provide greater para-selectivity at conversion rates unattained by previously known methods.
摘要翻译：公开了将各种芳烃如聚烷基芳烃转化成商业上有用的对位取代的芳族化合物如对二甲苯的方法。首先将芳烃进料流部分转化成甲苯，然后进行高度对位选择性甲基化处理。因此，本发明提供用于增加选择性生产对位取代的芳族化合物中的对选择性的新方法和催化剂。根据本文提供的描述，本领域技术人员将理解，本发明的催化剂和方法在转化率下提供了通过先前已知的方法获得的较高的对选择性。

40. 发明授权

US5250501A Herbicidal compounds 失效
标题翻译：除草剂
公开(公告)号：US5250501A
公开(公告)日：1993-10-05
申请号：US819080
申请日：1992-01-10
申请人： John E. D. Barton , David Cartwright , John M. Cox , Glynn Mitchell , Charles G. Carter , David L. Lee , Francis H. Walker , Frank X. Woolard
发明人： John E. D. Barton , David Cartwright , John M. Cox , Glynn Mitchell , Charles G. Carter , David L. Lee , Francis H. Walker , Frank X. Woolard
IPC分类号： A01N35/06 , A01N37/08 , A01N43/08 , A01N43/10 , A01N43/12 , A01N43/30 , A01N43/32 , A01N43/36 , A01N43/38 , A01N43/40 , A01N43/42 , A01N43/50 , A01N43/56 , A01N43/58 , A01N43/60 , A01N43/76 , A01N43/78 , A01N43/80 , A01N43/92 , A47J37/12 , C07C45/51 , C07C45/54 , C07C45/60 , C07C45/67 , C07C45/72 , C07C49/403 , C07C49/713 , C07C49/792 , C07C49/813 , C07C49/835 , C07D207/32 , C07D207/333 , C07D207/34 , C07D207/36 , C07D209/12 , C07D215/12 , C07D215/14 , C07D215/36 , C07D231/12 , C07D231/16 , C07D231/20 , C07D231/22 , C07D233/84 , C07D237/12 , C07D237/28 , C07D237/30 , C07D239/26 , C07D239/74 , C07D241/12 , C07D241/16 , C07D241/42 , C07D261/08 , C07D263/54 , C07D263/56 , C07D277/20 , C07D277/24 , C07D277/32 , C07D277/36 , C07D307/70 , C07D307/71 , C07D317/52 , C07D317/62 , C07D319/08 , C07D319/18 , C07D333/22 , C07D333/28 , C07D333/62 , C07D409/04 , C07D417/04 , C07F9/6568 , G05D23/20 , C07D275/02
CPC分类号： C07D207/333 , A01N35/06 , A01N37/08 , A01N43/08 , A01N43/10 , A01N43/30 , A01N43/32 , A01N43/36 , A01N43/38 , A01N43/40 , A01N43/42 , A01N43/50 , A01N43/56 , A01N43/58 , A01N43/60 , A01N43/78 , A01N43/80 , A47J37/1266 , C07C45/512 , C07C45/54 , C07C45/60 , C07C45/673 , C07C45/72 , C07C49/403 , C07C49/713 , C07C49/792 , C07C49/813 , C07C49/835 , C07D207/36 , C07D209/12 , C07D215/14 , C07D215/36 , C07D231/12 , C07D231/16 , C07D233/84 , C07D237/12 , C07D241/12 , C07D241/16 , C07D241/42 , C07D261/08 , C07D263/56 , C07D277/24 , C07D277/32 , C07D277/36 , C07D307/70 , C07D307/71 , C07D317/52 , C07D317/62 , C07D319/08 , C07D319/18 , C07D333/22 , C07D333/28 , C07D333/62 , C07D409/04 , C07D417/04 , C07F9/6568 , G05D23/1917 , G05D23/20
摘要： A compound of formula (I): ##STR1## or a salt, enamine or the like, acylate, sulphonate, carbamate or ether derivative thereof; wherein X, X.sup.1 and X.sup.2 are independently oxygen or sulphur, R.sup.1 is an optionally substituted heterocyclic or cycloalkyl group, and Y is an optionally substituted C.sub.2 -C.sub.4 alkylene group which is optionally interposed by an oxygen atom, a group ##STR2## or an optionally mono-substituted nitrogen atom, wherein p is 0, 1 or 2, s is 0 or 1 and R.sup.b is alkyl or alkoxy; provided that when X, X.sup.1 and X.sup.2 are oxygen R.sup.1 is not pyridyl or pyrimidinyl. Processes for the preparation of these compounds and herbicidal compositions containing them are also described and claimed.
摘要翻译：式（I）的化合物：其中，酰化物，磺酸盐，氨基甲酸酯或醚衍生物;或其盐，烯胺等; 其中X，X 1和X 2独立地是氧或硫，R 1是任选取代的杂环或环烷基，Y是任选被取代的C 2 -C 4亚烷基，其任选被氧原子插入，单取代氮原子，其中p为0,1或2，s为0或1，Rb为烷基或烷氧基; 条件是当X，X 1和X 2为氧时，R 1不是吡啶基或嘧啶基。还描述和要求保护这些化合物和含有它们的除草组合物的制备方法。

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