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31. 发明授权

US07704751B2 Polymeric fluorescent chemical sensor 有权
标题翻译：聚合物荧光化学传感器
公开(公告)号：US07704751B2
公开(公告)日：2010-04-27
申请号：US11552825
申请日：2006-10-25
申请人： Michael C. Palazzotto , Neal A. Rakow , Michael S. Wendland
发明人： Michael C. Palazzotto , Neal A. Rakow , Michael S. Wendland
IPC分类号： G01N21/64 , G01N33/00
CPC分类号： G01N33/54373 , G01N21/643 , G01N2021/7786 , Y10T436/17 , Y10T436/170769 , Y10T436/173845 , Y10T436/196666 , Y10T436/20 , Y10T436/200833 , Y10T436/201666 , Y10T436/202499 , Y10T436/203332 , Y10T436/204165 , Y10T436/21 , Y10T436/212 , Y10T436/214 , Y10T436/216 , Y10T436/2525 , Y10T436/25875
摘要： A method of detecting organic vapors is described. More particularly, the method involves the use of an analyte sensor that contains a polymeric material having a relatively large intrinsic porosity and that is capable of fluorescence in the visible region of the electromagnetic spectrum. The method further includes exposing the analyte sensor to an environment that may contain an organic vapor and monitoring the analyte sensor for a change in a fluorescence signal. Although the organic vapor itself typically does not fluoresce in the visible wavelength range, presence of an organic vapor can alter the fluorescence signal of the analyte sensor.
摘要翻译：描述了检测有机蒸汽的方法。更具体地说，该方法涉及使用分析物传感器，该分析物传感器包含具有相对较大的固有孔隙度并且能够在电磁光谱的可见区域中发生荧光的聚合物材料。该方法还包括将分析物传感器暴露于可含有有机蒸气并监测分析物传感器以改变荧光信号的环境。虽然有机蒸汽本身通常在可见光波长范围内不发荧光，但有机蒸汽的存在会改变分析物传感器的荧光信号。

32. 发明授权

US07556774B2 Optochemical sensor and method of making the same 有权
标题翻译：光化学传感器及其制作方法
公开(公告)号：US07556774B2
公开(公告)日：2009-07-07
申请号：US11275268
申请日：2005-12-21
申请人： Neal A. Rakow , Michael S. Wendland , Michael C. Palazzotto , Dora M. Paolucci , Richard J. Poirier , Stefan H. Gryska , John E. Trend , Moses M. David
发明人： Neal A. Rakow , Michael S. Wendland , Michael C. Palazzotto , Dora M. Paolucci , Richard J. Poirier , Stefan H. Gryska , John E. Trend , Moses M. David
IPC分类号： G01N21/00
CPC分类号： G01N21/783 , G01N2021/7779
摘要： A method of making an optochemical sensor, the method comprising: providing a reflective substrate having a major surface; affixing a detection layer comprising at least one intrinsically microporous polymer to at least a portion of the major surface; depositing a substantially continuous semi-reflective metallic layer on at least a portion of the detection layer, the semi-reflective metallic layer comprising palladium and having a network of fine irregular cracks therein; and heating the detection layer and semi-reflective metallic layer in the presence of molecular oxygen at a temperature sufficient to cause the cracks to widen. Sensors prepared according to method are also disclosed.
摘要翻译：一种制造光化学传感器的方法，所述方法包括：提供具有主表面的反射基板; 将包含至少一个本征微孔聚合物的检测层固定在所述主表面的至少一部分上; 在所述检测层的至少一部分上沉积基本上连续的半反射金属层，所述半反射金属层包含钯并且具有细小的不规则裂纹的网络; 并在分子氧存在下，在足以引起裂纹扩大的温度下加热检测层和半反射金属层。还公开了根据方法制备的传感器。

33. 发明授权

US07541389B2 Arylsulfinate salts in photoinitiator systems for polymerization reactions 有权
标题翻译：用于聚合反应的光引发剂体系中的芳基亚磺酸盐
公开(公告)号：US07541389B2
公开(公告)日：2009-06-02
申请号：US11380028
申请日：2006-04-25
申请人： Rajdeep S. Kalgutkar , Michael C. Palazzotto
发明人： Rajdeep S. Kalgutkar , Michael C. Palazzotto
IPC分类号： C08F2/46 , C08F2/50 , G03C1/72
CPC分类号： A61K6/083 , A61K6/0017 , A61K6/0023 , A61K6/0052 , B33Y70/00 , C07C313/02 , C08F2/50 , G03F7/029 , C08L33/04
摘要： Compositions are provided that include an electron donor and a sensitizing compound. More specifically, the electron donor is an arylsulfinate salt. Methods of polymerization are also provided that can be used to prepare polymeric material from a photopolymerizable composition that includes ethylenically unsaturated monomers and a photoinitiator system. The photoinitiator system includes an electron donor and a sensitizing compound.
摘要翻译：提供了包括电子给体和敏化化合物的组合物。更具体地，电子给体是芳基亚磺酸盐。还提供聚合方法，其可用于由包含烯属不饱和单体和光引发剂体系的可光聚合组合物制备聚合物材料。光引发剂体系包括电子给体和增感化合物。

34. 发明授权

US6069219A Energy-curable cyanate/ethylenically unsaturated compositions 失效
公开(公告)号：US6069219A
公开(公告)日：2000-05-30
申请号：US67535
申请日：1998-04-27
申请人： Fred B. McCormick , David J. Drath , Ilya Gorodisher , Michael A. Kropp , Michael C. Palazzotto , Melville R. V. Sahyun
发明人： Fred B. McCormick , David J. Drath , Ilya Gorodisher , Michael A. Kropp , Michael C. Palazzotto , Melville R. V. Sahyun
IPC分类号： F16F15/02 , B32B27/00 , B32B27/06 , C08F4/42 , C08G73/00 , C08G73/06 , C08J5/00 , C08L79/04 , C09J4/02 , G03F7/027 , G03F7/029 , C08L67/07 , C08L4/42
CPC分类号： G03F7/027 , B32B27/06 , C08G73/065 , C08G73/0655 , C08G73/0661 , G03F7/029 , Y10T428/31855
摘要： A composition of matter includes a polymerizable mixture comprising 1 to 99 weight percent of a first monomer and an initiator therefor, the first monomer being one of 1) at least one free-radically polymerizable monomer or 2) at least one cyanate ester monomer, and 99 to 1 weight percent of a second monomer and an initiator therefor, the second monomer being the member of 1) or 2) that is not selected as the first monomer, wherein the curative for the cyanate ester is a transition metal-containing organometallic compound curing agent and the curative for the free-radically polymerizable monomer is a free-radical generating curing agent or a transition metal-containing organometallic compound. The polymeric mixtures are useful, for example, in applications requiring high performance, such as high temperature performance; in composites, particularly structural composites; structural adhesives; vibration damping materials; electronic applications such as printed wiring boards, semiconductor encapsulants and electronic adhesives; photoresists; injection molding and prepregs; protective coatings; tough self-supporting films; and high performance binders. In addition, a curable composition including (1) an ethylenically unsaturated monomer or (2) an ethylenically unsaturated monomer and a cyanate ester monomer, and certain organometallic neutral compounds is useful in the graphic arts.

35. 发明授权

US6017660A Inks containing a ternary photoinitiator system and image graphics prepared using same 失效
标题翻译：含有三元光引发剂体系的油墨和使用其制备的图像图形
公开(公告)号：US6017660A
公开(公告)日：2000-01-25
申请号：US94184
申请日：1998-06-09
申请人： Michael C. Palazzotto , F. Andrew Ubel, III , Joel D. Oxman , M. Zaki Ali
发明人： Michael C. Palazzotto , F. Andrew Ubel, III , Joel D. Oxman , M. Zaki Ali
IPC分类号： A61K6/083 , C08F2/46 , C08F2/50 , C09D11/10 , G03F7/028 , G03F7/029 , G03F7/031 , G03C1/73 , B32B27/16
CPC分类号： A61K6/083 , C08F2/50 , C09D11/101 , G03F7/029 , G03F7/031 , Y10S430/116 , Y10S430/117 , Y10S430/12
摘要： Photocurable addition-polymerizable compositions containing a free-radically-polymerizable monomer and a photoinitiator system containing i) an arylidonium salt, ii) a sensitizing compound, and iii) an electron donor having an oxidation potential that is greater than zero and less than or equal to that of p-dimethyoxybenzene (1.32 volts vs. S.C.E.). The compositions cure rapidly and deeply under ultraviolet or visible light.
摘要翻译：含有可自由基聚合的单体和光引发剂体系的光固化的可加成聚合组合物，其含有i）芳基化钠盐，ii）增感化合物，和iii）具有大于零且小于或等于0的氧化电位的电子给体到对二甲基苯（1.32伏对SCE）。组合物在紫外线或可见光下快速且深入地固化。

36. 发明授权

US5453450A Stabilized curable adhesives 失效
标题翻译：稳定的可固化粘合剂
公开(公告)号：US5453450A
公开(公告)日：1995-09-26
申请号：US78546
申请日：1993-06-16
申请人： Kevin E. Kinzer , Wayne S. Mahoney , Michael C. Palazzotto
发明人： Kevin E. Kinzer , Wayne S. Mahoney , Michael C. Palazzotto
IPC分类号： C09J7/02 , C08F2/50 , C08G59/40 , C08G59/68 , C09J4/00 , C09J4/02 , C09J163/00 , C08K5/16 , C08K5/3432
CPC分类号： C09J4/00 , Y10T428/28 , Y10T428/2804 , Y10T428/2809 , Y10T428/2817 , Y10T428/2826 , Y10T428/2839 , Y10T428/287 , Y10T442/2746
摘要： A stabilized heat curable adhesive prepared from a formulation comprised of (1) at least one free radically polymerizable monomer; (2) at least one epoxy function monomer; (3) at least one free radical polymerization photoinitiator; (4) a thermally-initiated cationic catalyst system comprising (a) at least one salt of an organometallic cation, (b) at least one stabilizing additive; (5) optionally, at least one alcohol-containing material; and (6) optionally, adjuvants.
摘要翻译：一种由由（1）至少一种可自由基聚合的单体组成的配方制备的稳定的可热固化的粘合剂; （2）至少一种环氧官能单体; （3）至少一种自由基聚合光引发剂; （4）热引发的阳离子催化剂体系，其包含（a）至少一种有机金属阳离子盐，（b）至少一种稳定添加剂; （5）任选的至少一种含醇材料; 和（6）任选的佐剂。

37. 发明授权

US5385954A Energy polymerizable compositions containing organometallic initiators 失效
标题翻译：含有机金属引发剂的能量可聚合组合物
公开(公告)号：US5385954A
公开(公告)日：1995-01-31
申请号：US9845
申请日：1993-01-27
申请人： Michael C. Palazzotto , William A. Hendrickson
发明人： Michael C. Palazzotto , William A. Hendrickson
IPC分类号： C08F2/50 , C08F10/00 , C08F16/12 , C08G59/68 , C08G65/12 , C08G77/08 , C08G79/00 , C08F4/44
CPC分类号： C08G79/00 , C08F10/00 , C08F16/12 , C08G59/68 , C08G65/12 , C08G77/08
摘要： An energy polymerizable composition and process therefore, comprising a cationically polymerizable material and a catalytically effective amount of an ionic salt of an organometallic complex cation as polymerization initiator, said ionic salt of an organometallic complex cation being capable of adding an intermediate strength nucleophile or upon photolysis capable of liberating at least one coordination site, said metal in said organometallic complex cation being selected from elements of Periodic Groups IVB, VB, VIB, VIIB, and VIIIB are disclosed. Certain of the organometallic metallic polymerization initiators are novel cationic salts.
摘要翻译：因此，能量可聚合组合物和方法包括阳离子可聚合材料和催化有效量的作为聚合引发剂的有机金属络合物阳离子的离子盐，所述有机金属络合物阳离子的离子盐能够加入中等强度的亲核试剂或在光解能够释放至少一个配位点，所述有机金属络合物阳离子中的所述金属选自周期表IVB，VB，VIB，VIIB和VIIIB的元素。某些有机金属金属聚合引发剂是新型阳离子盐。

38. 发明授权

US5376428A Energy-induced dual curable compositions 失效
公开(公告)号：US5376428A
公开(公告)日：1994-12-27
申请号：US215271
申请日：1994-03-21
申请人： Michael C. Palazzotto , Katherine A. Brown-Wensley , Robert J. DeVoe
发明人： Michael C. Palazzotto , Katherine A. Brown-Wensley , Robert J. DeVoe
IPC分类号： C08G18/58 , C08F2/50 , C08F4/42 , C08F4/44 , C08G18/16 , C08G18/22 , C08G18/63 , C08G59/34 , C08G59/68 , C08G65/12 , C08L63/00 , C08L75/04 , C09D175/00 , C09J175/00 , B41N1/00 , B32B3/00 , B32B7/00 , G03F7/028
CPC分类号： C08F4/44 , C08F2/50 , C08G18/161 , C08G18/22 , C08G18/637 , C08G59/68 , C08G65/12 , Y10S428/90 , Y10S428/901 , Y10S428/928 , Y10S428/932 , Y10S430/115 , Y10S430/122 , Y10S430/124 , Y10T428/24372 , Y10T428/24802 , Y10T428/24835 , Y10T428/24893 , Y10T428/24917
摘要： An energy polymerizable composition comprises at least one ethylenically-unsaturated monomer, one of polyurethane precursors, and at least one epoxy monomer, and a curing agent comprising an organometallic compound, and an onium salt.

39. 发明授权

US5198511A Polymerizable compositions containing olefin metathesis catalysts and cocatalysts, and methods of use therefor 失效
标题翻译：含有烯烃复分解催化剂和助催化剂的可聚合组合物及其使用方法
公开(公告)号：US5198511A
公开(公告)日：1993-03-30
申请号：US811785
申请日：1991-12-20
申请人： Katherine A. Brown-Wensley , Michael C. Palazzotto , William M. Lamanna , Larry D. Boardman , John E. Gozum , Fred B. McCormick
发明人： Katherine A. Brown-Wensley , Michael C. Palazzotto , William M. Lamanna , Larry D. Boardman , John E. Gozum , Fred B. McCormick
IPC分类号： C08F4/06 , C08F4/42 , C08F4/80 , C08G61/06 , C08G61/08 , C08L61/08
CPC分类号： C08G61/08 , Y10S526/943
摘要： Polymerization of ring-strained cyclic olefins takes place in the presence of a one-part or two-part catalyst which is air and moisture stable and which comprises a transition metal-containing compound.The one-part transition metal-containing catalyst is selected from the group consisting of(a) compounds of the formula(L.sup.1) (L.sup.2)Q whereinQ represents Mo or W;L.sup.1 represents one to six CO (carbonyl) ligands;L.sup.2 represents none to 5 ligands, each of which is a non-ionic compound or unit of a polymer which can be the same or different, each contributes two, four, or six electrons to the metal and is different from L.sup.1 ;wherein the sum of the valence electrons of Q and the electrons contributed by the ligands L.sup.1 and L.sup.2 is 18,(b) at least one of cationic ruthenium and osmium-containing organometallic salts having at least one polyene ligand, and(c) [Ir(RO.sub.2 CHC=CHCO.sub.2 R).sub.2 Cl].sub.2 wherein each R independently is hydrogen or lower alkyl (C.sub.1 to C.sub.4), provided that the oxidation state of the metal is in the range of +3 to 0, and that cocatalysts containing C-halogen bonds are not present.The two-part catalyst comprises(a) a transition metal-containing catalyst, provided that the oxidation state of the transition metal is in the range of +3 to 0, and(b) a cocatalyst selected from the group consisting of(i) terminal or silyl alkynes,(ii) organosilanes containing at least ##STR1## (iii) oxidative salts or oxidative compounds containing an oxygen atom to non-oxygen atom double bond, and(iv) heteroatom-containing alkenes.The polymerized composition is useful to provide molded articles, elastomers, dielectric supports, ionophoric or biologically active materials, composite materials, and the like.
摘要翻译：环应变环烯烃的聚合在空气和水分稳定的含有过渡金属的化合物的一部分或两部分催化剂存在下进行。一部分过渡金属的催化剂选自（a）式（L1）（L2）Q化合物，其中Q表示Mo或W; L1代表一至六个CO（羰基）配体; L2代表无5个配体，它们各自是可以相同或不同的非离子化合物或聚合物单元，每个赋予金属二，四或六个电子，并且不同于L1; 其中Q和由配体L1和L2贡献的电子的价数之和为18，（b）至少一种具有至少一个多烯配体的阳离子钌和含锇的有机金属盐，和（c）[Ir （RO2CHC = CHCO2R）2Cl] 2，其中每个R独立地为氢或低级烷基（C1-C4），条件是金属的氧化态在+3至0的范围内，并且含有C-卤键的助催化剂为不存在。两部分催化剂包含（a）含过渡金属的催化剂，条件是过渡金属的氧化态在+3至0的范围内，和（b）选自（i）的助催化剂，（ii）至少含有（iii）氧化盐或含有氧原子的氧化化合物与非氧原子双键的有机硅烷，（iv）含杂原子的烯烃的有机硅烷。聚合的组合物可用于提供模塑制品，弹性体，电介质载体，离子或生物活性材料，复合材料等。

40. 发明授权

US4733109A Second harmonic generation with Schiff bases 失效
标题翻译：席夫碱二次谐波发生
公开(公告)号：US4733109A
公开(公告)日：1988-03-22
申请号：US825469
申请日：1986-02-03
申请人： Michael C. Palazzotto
发明人： Michael C. Palazzotto
IPC分类号： H01S3/109 , C07C67/00 , C07C241/00 , C07C251/24 , C07C253/00 , C07C255/58 , G02F1/361 , G02F1/37 , H03F7/00 , H04B10/00 , H04B10/22
CPC分类号： C07C255/00 , G02F1/3611 , Y10S359/90
摘要： Devices for and method of generating coherent second harmonic light radiation. The devices comprise a laser source of coherent light radiation at a fixed fundamental frequency, a Schiff base compound, means for directing the output radiation of the laser onto the Schiff base compound, and output means for utilizing the second harmonic frequency. Preferably, one moiety of the Schiff base compound has a hyperpolarizable group and the other moiety of the Schiff base compound has a configuration so that the compound crystallizes in a non-centrosymmetric configuration.
摘要翻译：用于产生相干二次谐波光辐射的装置和方法。这些装置包括固定基频的相干光辐射的激光源，希夫碱化合物，用于将激光的输出辐射引导到希夫碱基化合物上的装置，以及用于利用二次谐波频率的输出装置。优选地，席夫碱化合物的一个部分具有超极性基团，而希夫碱化合物的另一部分具有使得化合物以非中心对称构型结晶的构型。

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