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1. 发明授权

US5198511A Polymerizable compositions containing olefin metathesis catalysts and cocatalysts, and methods of use therefor 失效
标题翻译：含有烯烃复分解催化剂和助催化剂的可聚合组合物及其使用方法
公开(公告)号：US5198511A
公开(公告)日：1993-03-30
申请号：US811785
申请日：1991-12-20
申请人： Katherine A. Brown-Wensley , Michael C. Palazzotto , William M. Lamanna , Larry D. Boardman , John E. Gozum , Fred B. McCormick
发明人： Katherine A. Brown-Wensley , Michael C. Palazzotto , William M. Lamanna , Larry D. Boardman , John E. Gozum , Fred B. McCormick
IPC分类号： C08F4/06 , C08F4/42 , C08F4/80 , C08G61/06 , C08G61/08 , C08L61/08
CPC分类号： C08G61/08 , Y10S526/943
摘要： Polymerization of ring-strained cyclic olefins takes place in the presence of a one-part or two-part catalyst which is air and moisture stable and which comprises a transition metal-containing compound.The one-part transition metal-containing catalyst is selected from the group consisting of(a) compounds of the formula(L.sup.1) (L.sup.2)Q whereinQ represents Mo or W;L.sup.1 represents one to six CO (carbonyl) ligands;L.sup.2 represents none to 5 ligands, each of which is a non-ionic compound or unit of a polymer which can be the same or different, each contributes two, four, or six electrons to the metal and is different from L.sup.1 ;wherein the sum of the valence electrons of Q and the electrons contributed by the ligands L.sup.1 and L.sup.2 is 18,(b) at least one of cationic ruthenium and osmium-containing organometallic salts having at least one polyene ligand, and(c) [Ir(RO.sub.2 CHC=CHCO.sub.2 R).sub.2 Cl].sub.2 wherein each R independently is hydrogen or lower alkyl (C.sub.1 to C.sub.4), provided that the oxidation state of the metal is in the range of +3 to 0, and that cocatalysts containing C-halogen bonds are not present.The two-part catalyst comprises(a) a transition metal-containing catalyst, provided that the oxidation state of the transition metal is in the range of +3 to 0, and(b) a cocatalyst selected from the group consisting of(i) terminal or silyl alkynes,(ii) organosilanes containing at least ##STR1## (iii) oxidative salts or oxidative compounds containing an oxygen atom to non-oxygen atom double bond, and(iv) heteroatom-containing alkenes.The polymerized composition is useful to provide molded articles, elastomers, dielectric supports, ionophoric or biologically active materials, composite materials, and the like.
摘要翻译：环应变环烯烃的聚合在空气和水分稳定的含有过渡金属的化合物的一部分或两部分催化剂存在下进行。一部分过渡金属的催化剂选自（a）式（L1）（L2）Q化合物，其中Q表示Mo或W; L1代表一至六个CO（羰基）配体; L2代表无5个配体，它们各自是可以相同或不同的非离子化合物或聚合物单元，每个赋予金属二，四或六个电子，并且不同于L1; 其中Q和由配体L1和L2贡献的电子的价数之和为18，（b）至少一种具有至少一个多烯配体的阳离子钌和含锇的有机金属盐，和（c）[Ir （RO2CHC = CHCO2R）2Cl] 2，其中每个R独立地为氢或低级烷基（C1-C4），条件是金属的氧化态在+3至0的范围内，并且含有C-卤键的助催化剂为不存在。两部分催化剂包含（a）含过渡金属的催化剂，条件是过渡金属的氧化态在+3至0的范围内，和（b）选自（i）的助催化剂，（ii）至少含有（iii）氧化盐或含有氧原子的氧化化合物与非氧原子双键的有机硅烷，（iv）含杂原子的烯烃的有机硅烷。聚合的组合物可用于提供模塑制品，弹性体，电介质载体，离子或生物活性材料，复合材料等。

2. 发明授权

US5491206A Polymerizable compositions containing olefin metathesis catalysts and cocatalysts, and methods of use therefor 失效
标题翻译：含有烯烃复分解催化剂和助催化剂的可聚合组合物及其使用方法
公开(公告)号：US5491206A
公开(公告)日：1996-02-13
申请号：US172595
申请日：1993-12-21
申请人： Katherine A. Brown-Wensley , Michael C. Palazzotto , William M. Lamanna , Larry D. Boardman , John E. Gozum , Fred B. McCormick
发明人： Katherine A. Brown-Wensley , Michael C. Palazzotto , William M. Lamanna , Larry D. Boardman , John E. Gozum , Fred B. McCormick
IPC分类号： C08F4/06 , C08F4/42 , C08F4/80 , C08G61/06 , C08G61/08 , C08L61/08 , C08F4/22
CPC分类号： C08G61/08 , Y10S526/943
摘要： A polymerizable composition comprises at least one ring-strained non-conjugated cyclic olefin, a two-part transition metal-containing catalyst wherein said transition metal is selected from the group consisting of Periodic Groups 6 to 10, said catalyst being air and moisture stable and comprises a transition metal-containing catalyst, provided that the oxidation state of the transition metal is in the range of +3 to 0, and as cocatalyst an organosilane comprising at least one group selected from the group consisting of ##STR1## groups.
摘要翻译：一种可聚合组合物包含至少一种环应变非共轭环烯烃，两部分过渡金属的催化剂，其中所述过渡金属选自6-10周期，所述催化剂是空气和水分稳定的，包括含过渡金属的催化剂，条件是过渡金属的氧化态在+3至0的范围内，并且作为助催化剂，包含至少一种选自由下列组成的组的有机硅烷组成。

3. 发明授权

US5514728A Catalysts and initiators for polymerization 失效
标题翻译：用于聚合的催化剂和引发剂
公开(公告)号：US5514728A
公开(公告)日：1996-05-07
申请号：US97279
申请日：1993-07-23
申请人： William M. Lamanna , Michael C. Palazzotto , Robert J. DeVoe , Fred B. McCormick , Jeffrey M. Olofson , Allen R. Siedle , Peggy S. Willett
发明人： William M. Lamanna , Michael C. Palazzotto , Robert J. DeVoe , Fred B. McCormick , Jeffrey M. Olofson , Allen R. Siedle , Peggy S. Willett
IPC分类号： C08F4/44 , C07F5/02 , C08F2/46 , C08F4/00 , C08F4/06 , C08F4/42 , C08G18/22 , C08G18/24 , C08G59/68 , C08G73/00
CPC分类号： C07F5/027 , C08F4/00 , C08G59/68
摘要： Salts having a cationic portion of either a mono-, polyvent metal center, onium salts or organometallic salts and a nonnucleophilic anion are useful as catalysts and initiators that may be photochemically or thermally-activated, and polymerizable compositions containing such catalysts and initiator salts and at least one of a cationic or free-radical addition polymerizable monomers, or catalyzed step-growth polymerizable monomers.
摘要翻译：具有阳离子部分为单，多金属中心，鎓盐或有机金属盐和非亲核阴离子的盐可用作可光化学或热活化的催化剂和引发剂，以及含有这些催化剂和引发剂盐的可聚合组合物和阳离子或自由基加成聚合单体中的至少一种或催化的步进生长可聚合单体。

4. 发明授权

US5387492A Energy-curable cyanate compositions 失效
标题翻译：能量固化的氰酸酯组合物
公开(公告)号：US5387492A
公开(公告)日：1995-02-07
申请号：US170522
申请日：1993-12-20
申请人： Fred B. McCormick , Katherine A. Brown-Wensley , Robert J. DeVoe
发明人： Fred B. McCormick , Katherine A. Brown-Wensley , Robert J. DeVoe
IPC分类号： C08G73/00 , C08G73/06 , G03F7/029 , G03F7/038
CPC分类号： C08G73/0661 , G03F7/029 , G03F7/038 , Y10S430/115 , Y10S430/117 , Y10S522/904
摘要： Energy polymerizable compositions comprising at least one cyanate monomer and as curing agent an organometallic compound are disclosed. The compositions are useful in applications requiring high performance, such as high temperature performance; in composites, particularly structural composities; structural adhesives; tooling for structural composities; electronic applications such as printed wiring boards and semiconductor encapsulants; graphic arts; injection molding and prepregs; and high performance binders.
摘要翻译：公开了包含至少一种氰酸酯单体和作为固化剂的有机金属化合物的能量可聚合组合物。该组合物可用于需要高性能的应用，例如高温性能; 在复合材料中，特别是结构复合材料; 结构胶; 结构复合材料模具; 电子应用如印刷线路板和半导体密封剂; 平面艺术; 注塑和预浸料; 和高性能粘合剂。

5. 发明授权

US5215860A Energy-curable cyanate compositions 失效
标题翻译：能量可固化的氰酸酯组合物
公开(公告)号：US5215860A
公开(公告)日：1993-06-01
申请号：US234464
申请日：1988-08-19
申请人： Fred B. McCormick , Katherine A. Brown-Wensley , Robert J. DeVoe
发明人： Fred B. McCormick , Katherine A. Brown-Wensley , Robert J. DeVoe
IPC分类号： C08G73/00 , C08G73/06 , G03F7/029 , G03F7/038
CPC分类号： C08G73/0661 , G03F7/029 , G03F7/038 , Y10S430/115 , Y10S430/117 , Y10S522/904
摘要： Energy polymerizable compositions comprising at least one cyanate monomer and as curing agent an organometallic compound are disclosed. The compositions are useful in applications requiring high performance, such as high temperature performance; in composites, particularly structural composities; structural adhesives; tooling for structural composities; electronic applications such as printed wiring boards and semiconductor encapsulants; graphic arts; injection molding and prepregs; and high performance binders.

6. 发明授权

US5294517A Energy-curable cyanate compositions 失效
标题翻译：能量固化的氰酸酯组合物
公开(公告)号：US5294517A
公开(公告)日：1994-03-15
申请号：US9888
申请日：1993-01-27
申请人： Fred B. McCormick , Katherine A. Brown-Wensley , Robert J. DeVoe
发明人： Fred B. McCormick , Katherine A. Brown-Wensley , Robert J. DeVoe
IPC分类号： C08G73/00 , C08G73/06 , G03F7/029 , G03F7/038 , G03F7/004 , G03F7/30
CPC分类号： C08G73/0661 , G03F7/029 , G03F7/038 , Y10S430/115 , Y10S430/117 , Y10S522/904
摘要： Energy polymerizable compositions comprising at least one cyanate monomer and as curing agent an organometallic compound are disclosed. The compositions are useful in applications requiring high performance, such as high temperature performance; in composites, particularly structural composities; structural adhesives; tooling for structural composities; electronic applications such as printed wiring boards and semiconductor encapsulants; graphic arts; injection molding and prepregs; and high performance binders.
摘要翻译：公开了包含至少一种氰酸酯单体和作为固化剂的有机金属化合物的能量可聚合组合物。该组合物可用于需要高性能的应用，例如高温性能; 复合材料，特别是结构复合材料; 结构胶; 结构复合材料模具; 电子应用如印刷线路板和半导体密封剂; 平面艺术注塑和预浸料; 和高性能粘合剂。

7. 发明授权

US6069219A Energy-curable cyanate/ethylenically unsaturated compositions 失效
公开(公告)号：US6069219A
公开(公告)日：2000-05-30
申请号：US67535
申请日：1998-04-27
申请人： Fred B. McCormick , David J. Drath , Ilya Gorodisher , Michael A. Kropp , Michael C. Palazzotto , Melville R. V. Sahyun
发明人： Fred B. McCormick , David J. Drath , Ilya Gorodisher , Michael A. Kropp , Michael C. Palazzotto , Melville R. V. Sahyun
IPC分类号： F16F15/02 , B32B27/00 , B32B27/06 , C08F4/42 , C08G73/00 , C08G73/06 , C08J5/00 , C08L79/04 , C09J4/02 , G03F7/027 , G03F7/029 , C08L67/07 , C08L4/42
CPC分类号： G03F7/027 , B32B27/06 , C08G73/065 , C08G73/0655 , C08G73/0661 , G03F7/029 , Y10T428/31855
摘要： A composition of matter includes a polymerizable mixture comprising 1 to 99 weight percent of a first monomer and an initiator therefor, the first monomer being one of 1) at least one free-radically polymerizable monomer or 2) at least one cyanate ester monomer, and 99 to 1 weight percent of a second monomer and an initiator therefor, the second monomer being the member of 1) or 2) that is not selected as the first monomer, wherein the curative for the cyanate ester is a transition metal-containing organometallic compound curing agent and the curative for the free-radically polymerizable monomer is a free-radical generating curing agent or a transition metal-containing organometallic compound. The polymeric mixtures are useful, for example, in applications requiring high performance, such as high temperature performance; in composites, particularly structural composites; structural adhesives; vibration damping materials; electronic applications such as printed wiring boards, semiconductor encapsulants and electronic adhesives; photoresists; injection molding and prepregs; protective coatings; tough self-supporting films; and high performance binders. In addition, a curable composition including (1) an ethylenically unsaturated monomer or (2) an ethylenically unsaturated monomer and a cyanate ester monomer, and certain organometallic neutral compounds is useful in the graphic arts.

8. 发明授权

US5863664A Energy-curable cyanate/ethylenically unsaturated compositions 失效
公开(公告)号：US5863664A
公开(公告)日：1999-01-26
申请号：US682224
申请日：1996-07-17
申请人： Fred B. McCormick , David J. Drath , Ilya Gorodisher , Michael A. Kropp , Michael C. Palazzotto , Melville R. V. Sahyun
发明人： Fred B. McCormick , David J. Drath , Ilya Gorodisher , Michael A. Kropp , Michael C. Palazzotto , Melville R. V. Sahyun
IPC分类号： F16F15/02 , B32B27/00 , B32B27/06 , C08F4/42 , C08G73/00 , C08G73/06 , C08J5/00 , C08L79/04 , C09J4/02 , G03F7/027 , G03F7/029
CPC分类号： G03F7/027 , B32B27/06 , C08G73/065 , C08G73/0655 , C08G73/0661 , G03F7/029 , Y10T428/31855
摘要： A composition of matter includes a polymerizable mixture comprising 1 to 99 weight percent of a first monomer and an initiator therefor, the first monomer being one of 1) at least one free-radically polymerizable monomer or 2) at least one cyanate ester monomer, and 99 to 1 weight percent of a second monomer and an initiator therefor, the second monomer being the member of 1) or 2) that is not selected as the first monomer, wherein the curative for the cyanate ester is a transition metal-containing organometallic compound curing agent and the curative for the free-radically polymerizable monomer is a free-radical generating curing agent or a transition metal-containing organometallic compound. The polymeric mixtures are useful, for example, in applications requiring high performance, such as high temperature performance; in composites, particularly structural composites; structural adhesives; vibration damping materials; electronic applications such as printed wiring boards, semiconductor encapsulants and electronic adhesives; photoresists; injection molding and prepregs; protective coatings; tough self-supporting films; and high performance binders. In addition, a curable composition including (1) an ethylenically unsaturated monomer or (2) an ethylenically unsaturated monomer and a cyanate ester monomer, and certain organometallic neutral compounds is useful in the graphic arts.

9. 发明授权

US6069214A Energy-curable cyanate/ethylenically unsaturated compositions 失效
标题翻译：能量可固化的氰酸酯/烯属不饱和组合物
公开(公告)号：US6069214A
公开(公告)日：2000-05-30
申请号：US66966
申请日：1998-04-27
申请人： Fred B. McCormick , David J. Drath , Ilya Gorodisher , Michael A. Kropp , Michael C. Palazzotto , Melville R. V. Sahyun
发明人： Fred B. McCormick , David J. Drath , Ilya Gorodisher , Michael A. Kropp , Michael C. Palazzotto , Melville R. V. Sahyun
IPC分类号： F16F15/02 , B32B27/00 , B32B27/06 , C08F4/42 , C08G73/00 , C08G73/06 , C08J5/00 , C08L79/04 , C09J4/02 , G03F7/027 , G03F7/029 , C08L67/07
CPC分类号： G03F7/027 , B32B27/06 , C08G73/065 , C08G73/0655 , C08G73/0661 , G03F7/029 , Y10T428/31855
摘要： A composition of matter includes a polymerizable mixture comprising 1 to 99 weight percent of a first monomer and an initiator therefor, the first monomer being one of 1) at least one free-radically polymerizable monomer or 2) at least one cyanate ester monomer, and 99 to 1 weight percent of a second monomer and an initiator therefor, the second monomer being the member of 1) or 2) that is not selected as the first monomer, wherein the curative for the cyanate ester is a transition metal-containing organometallic compound curing agent and the curative for the free-radically polymerizable monomer is a free-radical generating curing agent or a transition metal-containing organometallic compound. The polymeric mixtures are useful, for example, in applications requiring high performance, such as high temperature performance; in composites, particularly structural composites; structural adhesives; vibration damping materials; electronic applications such as printed wiring boards, semiconductor encapsulants and electronic adhesives; photoresists; injection molding and prepregs; protective coatings; tough self-supporting films; and high performance binders. In addition, a curable composition including (1) an ethylenically unsaturated monomer or (2) an ethylenically unsaturated monomer and a cyanate ester monomer, and certain organometallic neutral compounds is useful in the graphic arts.
摘要翻译：物质组合物包括可聚合的混合物，其包含1至99重量％的第一单体和其引发剂，第一单体是1）至少一种可自由基聚合的单体之一或2）至少一种氰酸酯单体之一，以及 99至1重量％的第二单体及其引发剂，第二单体为1）或2）未被选择为第一单体的成分，其中氰酸酯的固化剂为含过渡金属的有机金属化合物固化剂和可自由基聚合单体的固化剂是自由基产生固化剂或含过渡金属的有机金属化合物。聚合物混合物可用于例如需要高性能的应用，例如高温性能; 在复合材料中，特别是结构复合材料; 结构胶; 振动阻尼材料; 电子应用如印刷线路板，半导体密封剂和电子粘合剂; 光致抗蚀剂注塑和预浸料; 保护涂层; 强硬的自我支持的电影; 和高性能粘合剂。此外，包含（1）烯键式不饱和单体或（2）烯键式不饱和单体和氰酸酯单体以及某些有机金属中性化合物的可固化组合物在图形领域中是有用的。

10. 发明授权

US5744557A Energy-curable cyanate/ethylenically unsaturated compositions 失效
标题翻译：能量可固化的氰酸酯/烯属不饱和组合物
公开(公告)号：US5744557A
公开(公告)日：1998-04-28
申请号：US078981
申请日：1993-06-16
申请人： Fred B. McCormick , David J. Drath , Ilya Gorodisher , Michael A. Kropp , Michael C. Palazzotto , Melville R. V. Sahyun
发明人： Fred B. McCormick , David J. Drath , Ilya Gorodisher , Michael A. Kropp , Michael C. Palazzotto , Melville R. V. Sahyun
IPC分类号： F16F15/02 , B32B27/00 , B32B27/06 , C08F4/42 , C08G73/00 , C08G73/06 , C08J5/00 , C08L79/04 , C09J4/02 , G03F7/027 , G03F7/029 , C08L67/07
CPC分类号： G03F7/027 , B32B27/06 , C08G73/065 , C08G73/0655 , C08G73/0661 , G03F7/029 , Y10T428/31855
摘要： A composition of matter including a polymerizable mixture comprising 1 to 99 weight percent of a first monomer and an initiator therefor, the first monomer being one of 1) at least one free-radically polymerizable monomer or 2) at least one cyanate ester monomer, and 99 to 1 weight percent of a second monomer and an initiator therefor, the second monomer being the member of 1) or 2) that is not selected as the first monomer, wherein the curative for the cyanate ester is a transition metal-containing organometallic compound curing agent and the curative for the free-radically polymerizable monomer is a free-radical generating curing agent or a transition metal-containing organometallic compound. The polymeric mixtures are useful, for example, in applications requiring high performance, such as high temperature performance; in composites, particularly structural composites; structural adhesives; vibration damping materials; electronic applications such as printed wiring boards, semiconductor encapsulants and electronic adhesives; photoresists; injection molding and prepregs; protective coatings; tough self-supporting films; and high performance binders. In addition, a curable composition including (1) an ethylenically unsaturated monomer or (2) an ethylenically unsaturated monomer and a cyanate ester monomer, and certain organometallic neutral compounds is useful in the graphic arts.
摘要翻译：一种包含可聚合混合物的组合物，其包含1至99重量％的第一单体和其引发剂，所述第一单体是1）至少一种可自由基聚合的单体之一或2）至少一种氰酸酯单体，和 99至1重量％的第二单体及其引发剂，第二单体为1）或2）未被选择为第一单体的成分，其中氰酸酯的固化剂为含过渡金属的有机金属化合物固化剂和可自由基聚合单体的固化剂是自由基产生固化剂或含过渡金属的有机金属化合物。聚合物混合物可用于例如需要高性能的应用，例如高温性能; 在复合材料中，特别是结构复合材料; 结构胶; 振动阻尼材料; 电子应用如印刷线路板，半导体密封剂和电子粘合剂; 光致抗蚀剂注塑和预浸料; 保护涂层; 强硬的自我支持的电影; 和高性能粘合剂。此外，包含（1）烯键式不饱和单体或（2）烯键式不饱和单体和氰酸酯单体以及某些有机金属中性化合物的可固化组合物在图形领域中是有用的。

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